Search NASA⌕ Search

SEARCH · Search NASA

Results for “confined diffusion”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Improved analytic modeling of the linear Rayleigh–Taylor instability with plasma transport

The Rayleigh–Taylor (R–T) instability with transport effects has long been studied analytically in the neutral fluid regime. How this picture may differ in plasmas has been given less consideration, however. Leveraging previous numerical simulations with plasma viscosity and diffusion of R–T at a binary plasma interface, we show how plasma transport and kinetic effects alter the linear R–T dispersion relation. Our insight informs a much improved analytical dispersion relation, which better matches the simulation data than previously established models. Additionally, we demonstrate the importance of employing asymptotically correct viscosity coefficients in fluid codes for accurately capturing plasma R–T growth.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Precise Linker Length and Dynamic Bond Exchange Control Penetrant Diffusion in Dense Vitrimers

Polymer networks with dynamic covalent bonds have been investigated for their self-healing ability, recyclability, and potential as more sustainable materials. Recent results have indicated that in some cases, bond exchange can enhance the transport of penetrants in dense networks, pointing to their potential for separations of membranes. Here, imine dynamic bonds in ethylene oxide (EO) networks with precise linker lengths were synthesized to investigate the transport of N,N′-bis(2,5-di-tert-butylphenyl)-3,4,9,10-perylenedicarboximide (BTBP), a large, anisotropic dye molecule. Networks with mesh sizes smaller than, comparable to, and greater than the size of the penetrant axes were investigated to probe the effects of bond exchange and network confinement on transport. Mesh sizes, which ranged from 0.5 to 1.62 nm, were determined from shear rheology, glass transitions by calorimetry, and probe diffusion coefficients by fluorescence recovery after photobleaching. Permanent networks with identical EO chain lengths were prepared as control samples, and up to a 3 orders of magnitude increase in diffusion coefficient is observed in the dynamic systems for short linkers containing 13 backbone atoms. The longest linkers with 71 backbone atoms show no difference between the permanent and dynamic networks. Linkers shorter than 11 backbone atoms, corresponding to a mesh size smaller than the penetrant small axis, diffusion is no longer observable on the experimental time scale, indicating a sharp cutoff attributed to the precise linkers and narrow mesh size distribution. The dynamic imine exchange time scales were compared to the diffusive hopping times of penetrants and indicate that exchange can occur during a diffusive displacement. Furthermore, these findings provide insights into the factors affecting penetrant transport in dense polymers and inspire the development of next-generation selective polymer membranes.

Diffusion↗
NASA NTRS2000

The Sugar Model: Catalytic Flow Reactor Dynamics of Pyruvaldehyde Synthesis from Triose Catalyzed by Poly-L-Lysine Contained in a Dialyzer

The formation of pyruvaldehyde from triose sugars was catalyzed by poly-L-lysine contained in a small dialyzer (100 MWCO) suspended in a much larger triose substrate reservoir. The polylysine confined in the dialyzer functioned as a catalytic flow reactor that constantly brought in triose from the substrate reservoir by diffusion to offset the drop in triose concentration within the reactor caused by its conversion to pyruvaldehyde. A 400 mM solution of poly-L-lysine contained in a 0.35 ml dialyzer placed in a 120 ml solution of triose substrate (pH 5.5, 40 C) generated pyruvaldehyde 11 -times faster than an a control reaction without the catalytic dialyzer. However, since the catalytic dialyzer's volume was 343-times smaller than the control reaction, the synthetic intensity (rate/volume) of pyruvaldehyde synthesis within the catalytic dialyzer was 3400-times greater than that of the control reaction and substrate solution. A similar result was obtained using a dialyzer with a 500 MWCO value. Acting as a catalytic flow reactor the polylysine catalytic dialyzer synthesized about 3.5 molecules of pyruvaldehyde per lysine residue in 7 days -- an amount of triose equal to twice the weight of the catalyst. At 7 days the catalytic activity of polylysine was 16% of its initial value, a result indicating catalyst-poisoning caused by reaction of pyruvaldehyde with the e-amino groups of polylysine. The dialyzer method of catalyst containment was selected it provides a simple, flexible, and easily manipulated experimental system for studying the dynamics and evolutionary development of confined autocatalytic processes related to the origin of life under anaerobic conditions.

Weber, Arthur L.↗
DOE OSTI2025

Cosmic-ray transport in inhomogeneous media

A theory of cosmic-ray transport in multiphase diffusive media is developed, with the specific application to cases in which the cosmic-ray diffusion coefficient has large spatial fluctuations that may be inherently multiscale. We demonstrate that the resulting transport of cosmic rays is diffusive in the long-time limit, with an average diffusion coefficient equal to the harmonic mean of the spatially varying diffusion coefficient. Thus, cosmic-ray transport is dominated by areas of low diffusion even if these areas occupy a relatively small, but not infinitesimal, fraction of the volume. On intermediate time-scales, the cosmic rays experience transient effective subdiffusion, as a result of low-diffusion regions interrupting long flights through high-diffusion regions. In the simplified case of a two-phase medium, we show that the extent and extremity of the subdiffusivity of cosmic-ray transport is controlled by the spectral exponent of the distribution of patch sizes of each of the phases. We finally show that, despite strongly influencing the confinement times, the multiphase medium is only capable of altering the energy dependence of cosmic-ray transport when there is a moderate (but not excessive) level of perpendicular diffusion across magnetic-field lines.

Astronomy and Astrophysics↗
DOE OSTI2023

The physics basis to integrate an MHD stable, high-power hybrid scenario to a cool divertor for steady-state reactor operation

Abstract Coupling a high-performance core to a low heat flux divertor is a crucial step for ITER and a Fusion Pilot Plant or DEMO. Experiments in DIII-D recently expanded the steady-state hybrid scenario to high density and divertor impurity injection to study the feasibility of a radiating mantle solution. This work presents the physics basis for trade-offs between density, current drive and stability to tearing modes (TMs) at high β. EC power is crucial to tailor the plasma profiles into a passively stable state, and to eject impurities from the core. Off-axis EC depositions decrease the heating efficiency, but calculated electron heat transport coefficients show that this effect is partially mitigated by improved confinement inside the EC deposition. Additionally, the reduction in pressure is recovered by increasing the density. This favourable scaling of confinement with density was observed in high power plasmas for years, and this work provides a comprehensive explanation. ELITE predictions indicate that a path in peeling-ballooning stability opens up for certain conditions of density, power, q 95 and shaping, allowing the edge pressure to continue increasing without encountering a limit. In the core, calculated anomalous fast-ion diffusion coefficients are consistent with density fluctuation measurements in the toroidicity-induced Alfvén eigenmode range, showing that smaller fast-ion losses contribute to the enhanced confinement at high density. The edge integration study shows that divertor heat loads can be reduced with Ne and Ar injection, but this eventually triggers a cascade of n = 1, 2, 3 core TMs. We can now show that impurity radiation in the core is small and it is not the cause for the drop in confinement at high Ar and Ne injection rates. The overlap between the core TMs is consistent with the loss of pressure as estimated by the Belt model for the coupled rational surfaces. Optimization of these trade-offs has achieved plasmas with sustained H 98y2 = 1.7, f GW = 0.7 and ∼85% mantle radiation. The scenario and its variations at higher density and on- vs off-axis EC heating has been studied as a candidate for an integrated solution for several reactor designs, such as ITER, ARC, and the ARIES-ACT1 case, showing promising results in terms of fusion power and gain.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Reduction or Enhancement of Stellarator Turbulence by Impurities

A systematic study of the impact of impurities on the turbulent heat fluxes is presented for the stellarator Wendelstein 7-X (W7-X) and, for comparison, the Large Helical Device and ITER. By means of nonlinear multispecies gyrokinetic simulations, it is shown that impurities, depending on the sign of their density gradient, can significantly enhance or reduce turbulent ion heat losses. For the relevant scenario of turbulence reduction, an optimal impurity concentration that minimizes the ion heat diffusivity emerges as a universal feature. This result demonstrates the potential of impurities for controlling turbulence and accessing enhanced confinement regimes in fusion plasmas and, in particular, in W7-X. Published by the American Physical Society 2024

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1993

The X-ray-emitting trail of the nearby pulsar PSR1929 + 10

The paper reports the detection by the Rosat satellite of a nebula associated with the nearby pulsar PSR1929 + 10, which is of a type different from the pulsar-wind nebulae produced by direct interaction of the relativistic wind from older pulsars with the interstellar medium (ISM) (Blandorf et al., 1973). The PSR1929 + 10 nebula appears as a linear diffuse X-ray feature in the direction opposite to the pulsar's proper motion, with the pulsar wind confined by the ram-pressure arising from the high velocity of the pulsar through the ISM. This results in a trail of relativistic electrons with enhanced emissions of synchrotron radiation.

Wang, Q. D.↗
NASA NTRS2005

Cosmic Ray Propagation through the Magnetic Fields of the Galaxy with Extended Halo

In this project we perform theoretical studies of 3-dimensional cosmic ray propagation in magnetic field configurations of the Galaxy with an extended halo. We employ our newly developed Markov stochastic process methods to solve the diffusive cosmic ray transport equation. We seek to understand observations of cosmic ray spectra, composition under the constraints of the observations of diffuse gamma ray and radio emission from the Galaxy. The model parameters are directly are related to properties of our Galaxy, such as the size of the Galactic halo, particle transport in Galactic magnetic fields, distribution of interstellar gas, primary cosmic ray source distribution and their confinement in the Galaxy. The core of this investigation is the development of software for cosmic ray propagation models with the Markov stochastic process approach. Values of important model parameters for the halo diffusion model are examined in comparison with observations of cosmic ray spectra, composition and the diffuse gamma-ray background. This report summarizes our achievement in the grant period at the Florida Institute of Technology. Work at the co-investigator's institution, the University of New Hampshire, under a companion grant, will be covered in detail by a separate report.

Zhang, Ming↗
DOE OSTI2024

The persistence of memory in ionic conduction probed by nonlinear optics

Predicting practical rates of transport in condensed phases enables the rational design of materials, devices and processes. This is especially critical to developing low-carbon energy technologies such as rechargeable batteries. For ionic conduction, the collective mechanisms, variation of conductivity with timescales and confinement, and ambiguity in the phononic origin of translation, call for a direct probe of the fundamental steps of ionic diffusion: ion hops. However, such hops are rare-event large-amplitude translations, and are challenging to excite and detect. Here we use single-cycle terahertz pumps to impulsively trigger ionic hopping in battery solid electrolytes. This is visualized by an induced transient birefringence, enabling direct probing of anisotropy in ionic hopping on the picosecond timescale. The relaxation of the transient signal measures the decay of orientational memory, and the production of entropy in diffusion. We extend experimental results using in silico transient birefringence to identify vibrational attempt frequencies for ion hopping. Using nonlinear optical methods, we probe ion transport at its fastest limit, distinguish correlated conduction mechanisms from a true random walk at the atomic scale, and demonstrate the connection between activated transport and the thermodynamics of information.

25 ENERGY STORAGE↗
DOE OSTI2020

Multilevel Techniques for Compression and Reduction of Scientific Data---The Unstructured Case

Previous work on multilevel techniques for compression and reduction of scientific data is extended to the case of data given on unstructured meshes in two and three dimensions. The centerpiece of the work is a decomposition algorithm which is shown to be optimal, in terms of both storage and operational complexity, applicable to unstructured grids in both two and three dimensions, and which implicitly gives a Riesz basis that can be exploited to reduce the data while maintaining rigorous bounds on the loss incurred. The flexibility of the approach is illustrated by applications to potential flow around an airfoil and the effect of compression on quantities of interest relevant to airfoil design; compression of computational simulation of a nonlinear reaction-diffusion system with special attention given to the problem of time series reduction; and, data from a simulation of magnetically confined plasma in a fusion reactor reduced so as to preserve the electric field computed from the data.

97 MATHEMATICS AND COMPUTING↗
NASA NTRS1975

International Symposium on Combustion, 15th, Tokyo, Japan, August 25-31, 1974, Proceedings

Recent theoretical and experimental studies concerned with detonation and pressure wave combustion interaction, fire and explosion research and safety, heterogeneous combustion, flame-flow interactions, kinetics of elementary reactions, pollution control in and by combustion systems, and ignition are presented. Some of the topics covered include critical power density for direct initiation of unconfined gaseous detonations, extinction of laminar diffusion flames for liquid fuels, combustion of bulk titanium in oxygen, flame propagation in small spheres of unconfined and slightly confined flammable mixtures, kinetics of the reaction of nitric oxide with hydrogen, production of chemi-ions and formation of CH and CH2 radicals in methane-oxygen and ethylene-oxygen flames, NOx emission characteristics in two-stage combustion, and spherical ignition of oxyhydrogen behind a reflected shock wave. Individual items are announced in this issue.

Source record↗
NASA NTRS1990

The diffuse ionized interstellar medium perpendicular to the plane of NGC 891

In an attempt to study the structure and the properties of the diffuse ionized interstellar medium perpendicular to the plane of disk galaxies researchers obtained H alpha images and spectra of NGC 891. Perhaps the most remarkable property of the H alpha emission line in NGC 891 is its extension out of the plane of the galaxy: researchers are able to measure the H alpha line out to more than 30 seconds (1.4 kpc) from the midplane. This means that the ionized hydrogen extends at least four times higher than the neutral hydrogen layer. An anomalously large scale-height for the ionized gas of approx. equals 1 kpc is also found in the Milky Way. The echelle spectra show a changing ratio of NII to H alpha. This excludes the possibility that the large scaleheight of the emission is due to scattering of disk emission by dust high above the plane. The z-extent of the H alpha emission is confirmed by the imaging result. The large z-extent of the ionized gas is confined to the inner half of the visible disk. In this inner region the H alpha distribution also shows a filamentary structure of the diffuse ionized medium. These filaments, sticking out of the plane, originate in HII regions in the plane. The H alpha image also shows a large scale asymmetry if the NE and SW parts of the disk are compared. The NE part is more prominent and extended in H alpha. The same asymmetry is also seen in the radio continuum distribution. This correlation between the diffuse ionized medium and the distribution of relativistic electrons is one example of a relation between star formation processes in the disk and the various components of the halo. Thermal filaments or spurs which are related to HII regions are also known in the Galaxy. These filamentary structures perpendicular to the galactic planes may represent the chimneys which result in the supernova dominated model of the Interstellar Medium by Norman and Ikeuchi (1989).

Dettmar, Ralf-Juergen↗
DOE OSTI2025

Dynamical Ion Correlations in Polymer and Membrane Electrolytes: Recent Advances and Open Questions

Ion transport in polymer and membrane electrolytes is often described using uncorrelated models like the Nernst–Einstein (NE) approximation, which link conductivity, transference number, and salt diffusivity to individual ion mobilities. However, growing evidence shows that dynamical ion correlations─arising from ion pairing, polymer-mediated coupling, confinement, and electrostatic interactions─can substantially alter macroscopic transport properties. The Onsager transport formalism offers a rigorous framework to quantify these effects via cross-correlated ionic displacements. This Perspective highlights how such correlations manifest across dry and hydrated systems, including salt-doped polymers, block copolymers, hydrogels, and ion-exchange membranes. Here, we examine key physical origins, the influence of salt chemistry and polymer structure, and open questions in measuring and controlling correlated motion. Embracing correlation-aware design enables new pathways to optimize conductivity, transference number, and selectivity─shifting the focus from individual ion mobility to engineered collective dynamics for next-generation electrolytes in energy storage and separations.

Charge transport↗
DOE OSTI2020

Magnetic shear effect on plasma transport at T e / T i ~ 1 through electron cyclotron heating in DIII-D plasmas

The effect of magnetic shear on plasma transport for an electron to ion temperature ratio ( T e / T i ) near unity has been explored in DIII-D utilizing electron cyclotron heating (ECH). Previous reports showed that significant confinement degradation occurred at T e / T i ~ 1 in positive shear (PS) plasmas in DIII-D, whereas reduced confinement degradation was observed in negative central shear (NCS) plasmas. In this study, plasma transport in weak magnetic shear (WS) plasmas with ECH is investigated and compared with that in NCS and PS plasmas. Here the magnetic shears ($\hat s$) are $\hat s$ > 0.5, ~0 and <-0.1 in the core region (ρ~ 0.3–0.4) of PS, WS and NCS plasmas, respectively, and flat or negative inside ρ~ 0.4 in the WS and NCS plasmas. Weak magnetic shear is found to be effective in minimizing degradation of ion thermal confinement as T e / T i increases through ECH application, and an improved confinement factor of H 98y2 ~ 1.2 is maintained, similar to NCS plasmas. At T e / T i ~ 1, the ion thermal diffusivity around an internal transport barrier decreases when changing the magnetic shear from positive to weak or negative shear. Also, reduced local particle and momentum transport was indicated by steeper density and toroidal rotation profiles in the weak and negative shear regimes. Linear gyrokinetic simulations predict little change in growth rates of low-k turbulence with ECH application in the WS and NCS plasmas, which is consistent with the transport and profile analyses.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Isotope mass scaling and transport comparison between JET Deuterium and Tritium L-mode plasmas

The dimensionless isotope mass scaling experiment between pure Deuterium and pure Tritium plasmas with matched $\rho^*$, $\nu^*$ , β n , q and $T_e/T_i$ has been achieved in JET L-mode with dominant electron heating (NBI+ohmic) conditions. 28% higher scaled energy confinement time $B_t\tau_{E,\mathrm{th}}/A$ is found in favour of the Tritium plasma. This can be cast in the form of the dimensionless energy confinement scaling law as $\Omega_i \tau_{E,\mathrm{th}} \sim A^{0.48 \pm 0.16}$. This significant isotope mass scaling is consequently seen in the scaled one-fluid heat diffusion coefficient $A \chi_{\mathrm{eff}}/B_t$ which is around 50% lower in the Tritium plasma throughout the whole plasma radius. The isotope mass dependence in the particle transport channel is negligible, supported also by the perturbative particle transport analysis with gas puff modulation. The comparison of the edge particle fuelling or ionisation profiles from the EDGE2D-EIRENE simulations show that the absolute density differences that are necessary for the dimensionless match in the confined plasma dominate over any isotope mass dependencies of particle fuelling and ionization profiles at the plasma edge. Local GENE simulation results indicate a mild anti-gyroBohm effect at $\rho_\mathrm{tor}$ = 0.6 and thereby a small isotope mass dependence in favour of Tritium on heat transport and a negligible effect on particle transport. A significant fraction of the isotope scaling and reduced heat transport observed in the Tritium plasma is not captured in the GENE and ASTRA-TGLF-SAT2 simulations by simply changing the isotope mass for the same input profiles.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1973

Magnetic storm characteristics of the thermosphere.

Energy and diffusive mass transport associated with the thermospheric circulation are considered in a self-consistent, though mathematically relatively simple, form to describe in a three-dimensional two-constituent model magnetic storm characteristics in composition (N2, O, and He), temperature, and mass-density. It is shown that during disturbed conditions the latitudinal variations of composition and gas temperature reflect the local nature of the magnetic storm heat input assumed to be primarily confined to the auroral zones. Thereby gas temperature and N2 increase, He decreases, and O remains constant through the auroral zones at exospheric heights (due to the superposition of temperature and diffusion effects) in agreement with Ogo 6 mass spectrometer measurements. In contrast, the magnetic storm response in the total mass density is characterized by a strong worldwide component and a relatively insignificant increase toward the poles.

Mayr, H. G.↗
DOE OSTI2021

Generalized impurity pinch in partially magnetized multi-ion plasma

In a two-ion-species plasma with disparate ion masses, heavy ions tend to concentrate in the low-temperature region of collisionally magnetized plasma and in the high-temperature region of collisionally unmagnetized plasma, respectively. Moreover, collisional magnetization can be determined as the ratio of the light ion gyrofrequency to the collision frequency of light and heavy ion species, and the behavior of this effect in the intermediate regime of partially magnetized plasma is predominantly dependent on this Hall parameter. Multi-ion cross-field transport has been described before in the collisionally magnetized plasma regime, and generalized pinch relations, which describe densities of ion species in equilibrium in that plasma, are found in the literature. Here, the role of collisional magnetization and Larmor magnetization in multi-ion collisional transport is clarified, and generalized pinch relations are extended to the partially magnetized regime in which the ion Hall parameter may be small, as long as electrons remain collisionally magnetized. Equilibrium ion density profiles have the same dependence on external forces and on each other regardless of collisional magnetization of ions. The expansion of the range of validity of multi-ion collisional transport models makes them applicable to a wider range of laboratory plasma conditions. In particular, ion density profiles evolve sufficiently fast for radial impurity transport to be observable around stagnation on MagLIF, leading to expulsion of heavy ion impurities from the hotspot as long as plasma becomes sufficiently collisionally magnetized during the implosion.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Single-Molecule Fluorescence Investigations of Solute Transport Dynamics in Nanostructured Membrane Separation Materials

Many materials used for membrane separations comprise of nanoscale structures such as pores and domains. Such nanostructures often control the solute permeability and selectivity of separation membranes. Thus, for future development of highly efficient separation membranes, it is important to understand the structural and chemical properties of these nanostructures, and also their influences on solute transport dynamics. For the last two decades, single-molecule fluorescence techniques have been used to measure the detailed dynamics of solute molecules diffusing in various nanostructured materials, giving valuable insights into molecular transport mechanisms influenced by nanoscale material heterogeneity. This Perspective will discuss recent single-molecule fluorescence studies on solute diffusion in materials relevant to membrane separations, including dense polymer films and nanoporous materials. These studies have revealed the formation and properties of nanostructures, and unique transport dynamics of solute molecules manipulated by their confinement and partitioning to the nanostructures, which play key roles in membrane separations. Furthermore, this Perspective will also point out scientific challenges toward thorough understanding of molecular-level mechanisms in membrane separations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗