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An equation of state for oxygen and nitrogen

Preliminary equations of state are presented for oxygen and nitrogen which provide accurate representations of the available P-density-T data for both fluids. The equation for nitrogen is applicable for temperatures from 70 K to 1300 K at pressures to 10,000 atmospheres, and the equation for oxygen for temperatures from 70 K to 323 K at pressures to 350 atmospheres. Deviations of calculated densities from representative experimental data are included. A volume-explicit equation of state for oxygen to be used in estimating density values in the range of applicability of the equation of state is also presented.

Stewart, R. B.↗

Material Density Distribution of Small Debris in Earth Orbit

Over 200 spacecraft and rocket body breakups in Earth orbit have populated that regime with debris fragments in the sub-micron through meter size range. Though the largest debris fragments can cause significant collisional damage to active (operational) spacecraft, these are few and trackable by radar. Fragments on the order of a millimeter to a centimeter in size are as yet untrackable. But this smaller debris can result in damage to critical spacecraft systems and, under the worst conditions, fragmenting collision events. Ongoing research at the NASA Orbital Debris Program Office on the sources of these small fragments has focused on the material components of spacecraft and rocket bodies and on breakup event morphology. This has led to fragment material density estimates, and also the beginnings of shape categorizations. To date the NASA Standard Breakup Model has not considered specific material density distinctions of small debris. The basis of small debris in that model is the fourth hypervelocity impact event of the Satellite Orbital Debris Characterization Impact Test (SOCIT) series. This test targeted a flight-ready, U.S. Transit navigation satellite with a solid aluminum sphere impactor. Results in this event yield characteristic length (size) and area-to-mass distributions of fragments smaller than 10 cm in the NASA model. Recent re-analysis of the SOCIT4 small fragment dataset highlighted the material-specific characteristics of metals and non-metals. Concurrent analysis of Space Shuttle in-situ impact data showed a high percentage of aluminum debris in shuttle orbit regions. Both analyses led to the definition of three main on-orbit debris material density categories -low density (< 2 g/cc), medium density (2 to 6 g/cc), and high density (> 6 g/cc). This report considers the above studies in an explicit extension of the NASA Standard Breakup Model where separate material densities for debris are generated and these debris fragments are propagated in Earth orbit. The near Earth environment is thus parameterized by debris density percentages within subsections of that environment. This model version is used in the upgraded NASA Orbital Debris Engineering Model (ORDEM).

Krisko, P. H.↗

Skimming through Saturn's Atmosphere: The Climax of the Cassini Grand Finale Mission

On September 15, 2017, the long-lived Cassini Mission to Saturn came to a triumphant end as the Cassini orbiter plunged deep into Saturn’s atmosphere, all the while transmitting engineering and science data back to Earth before Saturn’s atmosphere destroyed the orbiter. Even before the final plunge, the Cassini spacecraft became the first spacecraft to successfully skim Saturn’s atmosphere and collect atmospheric data during its final five complete orbits around Saturn (Rev-288 through Rev-292). During those five final orbits, the spacecraft was flying in Reaction Control Subsystem (RCS) control in order to maintain greater control authority. Therefore, by analyzing the thruster on-time flight data telemetered back to Earth after each orbit, atmospheric density estimates can be extracted. This paper proposes a method of using Cassini Attitude Control Flight Data to reconstruct Saturn atmospheric density profiles for each of the five final orbits around Saturn.

Andrade, Luis G.↗

A DECADE-BASELINE STUDY OF THE PLASMA STATES OF EJECTA KNOTS IN CASSIOPEIA A

We present the analysis of 21 bright X-ray knots in the Cassiopeia A supernova remnant from observations spanning 10 yr. We performed a comprehensive set of measurements to reveal the kinematic and thermal state of the plasma in each knot, using a combined analysis of two high energy resolution High Energy Transmission Grating (HETG) and four medium energy resolution Advanced CCD Imaging Spectrometer (ACIS) sets of spectra. The ACIS electron temperature estimates agree with the HETG-derived values for approximately half of the knots studied, yielding one of the first comparisons between high resolution temperature estimates and ACIS-derived temperatures. We did not observe the expected spectral evolution-predicted from the ionization age and density estimates for each knot-in all but three of the knots studied. The incompatibility of these measurements with our assumptions has led us to propose a dissociated ejecta model, with the metals unmixed inside the knots, which could place strong constraints on supernova mixing models.

79 ASTRONOMY AND ASTROPHYSICS↗

SU-G-IeP1-06: Estimating Relative Tissue Density From Quantitative MR Images: A Novel Perspective for MRI-Only Heterogeneity Corrected Dose Calculation

Purpose: To explore the feasibility of extracting the relative density from quantitative MRI measurements as well as estimate a correlation between the extracted measures and CT Hounsfield units. Methods: MRI has the ability to separate water and fat signals, producing two separate images for each component. By performing appropriate corrections on the separated images, quantitative measurement of water and fat mass density can be estimated. This work aims to test this hypothesis on 1.5T.Peanut oil was used as fat-representative, while agar as water-representative. Gadolinium Chloride III and Sodium Chloride were added to the agar solution to adjust the relaxation times and the medium conductivity, respectively. Peanut oil was added to the agar solution with different percentages: 0%, 3%, 5%, 10%, 20%, 30%, 40%, 50%, 60%, 70%, 80%, 90% and 100%. The phantom was scanned on 1.5T GE Optima 450W with the body coil using a multigradient echo sequences. Water/fat separation were performed while correcting for main field (B0) inhomogeneity and T{sub 2}* relaxation time. B1+ inhomogeneities were ignored. The phantom was subsequently scanned on a Philips Brilliance CT Big Bore. MR-corrected fat signal from all vials were normalized to 100% fat signal. CT Hounsfield values were then compared to those obtained from the normalized MR-corrected fat values as well as to the phantom for validation. Results: Good agreement were found between CT HU and the MR-extracted fat values (R{sup 2} = 0.98). CT HU also showed excellent agreement with the prepared fat fractions (R{sup 2}=0.99). Vials with 70%, 80%, and 90% fat percentages showed inhomogeneous distributions, however their results were included for completion. Conclusion: Quantitative MRI water/fat imaging can be potentially used to extract the relative tissue density. Further in-vivo validation are required.

60 APPLIED LIFE SCIENCES↗

Evaluation of ERTS-1 imagery in mapping and managing soil and range resources in the Sand Hills Region of Nebraska

The author has identified the following significant results. Collection of ground truth data provided ground cover percent and the components of ground cover makeup. Percent bare soil appears to have greatest influence on imagery density of sites studied. Forage density estimates can be made on band 5 of MSS, provided site category identification is known. Additional data are provided concerning forage density and vegetation-soil relationship by color composites of MSS imagery. Reflectance differences shown on MSS bands 6 and 7 by Sand Hills lakes are related to water quality and possibly more specifically to total dissolved ions present in the water. Winter imagery with snow cover and low sun angle shows a marked enhancement of topography are associated with differences in forage density. High altitude color infrared photography appears to be a usable tool for recognition, measurement, and evaluation of go-back land.

Seevers, P. M.↗

Properties of Cometary Nuclei

Active long- and short-period comets contribute about 20 to 30 % of the major impactors on the Earth. Cometary nuclei are irregular bodies, typically a few to ten kilometers in diameter, with masses in the range 10(sup 15) to 10(sup 18) g. The nuclei are composed of an intimate mixture of volatile ices, mostly water ice and hydrocarbon and silicate grains. The composition is the closest to solar composition of any known bodies in the solar system. The nuclei appear to be weakly bonded agglomerations of smaller icy planetesimals, and material strengths estimated from observed tidal disruption events are fairly low, typically 10(sup 2) to 10(sup 4) N m(sup -2). Density estimates range between 0.2 and 1.2 g cm(sup -3) but are very poorly determined, if at all. As comets age they develop nonvolitile crusts on their surfaces which eventually render them inactive, similar in appearance to carbonaceous asteroids. However, dormant comets may continue to show sporadic activity and outbursts for some time before they become truly extinct. The source of the long-period comets is the Oort cloud, a vast spherical cloud of perhaps 10(sup 12) to 10(sup 13) comets surrounding the solar system and extending to interstellar distances. The likely source for short-period comets is the Kuiper belt. a ring of perhaps 10(sup 8) to 10(sup 10) remnant icy planetesimals beyond the orbit of Neptune, though some short-period comets may also be long-period comets from the Oort cloud which have been perturbed into short-period orbits.

comets nuclei volitile ices Oort cloud Kuiper belt↗

An adaptive technique for estimating the atmospheric density profile during the AE mission

A technique is presented for processing accelerometer data obtained during the AE missions in order to estimate the atmospheric density profile. A minimum variance, adaptive filter is utilized. The trajectory of the probe and probe parameters are in a consider mode where their estimates are unimproved but their associated uncertainties are permitted an impact on filter behavior. Simulations indicate that the technique is effective in estimating a density profile to within a few percentage points.

Argentiero, P.↗

Constraining magnetic fields in the circumgalactic medium

ABSTRACT We study the properties of magnetic fields in the circumgalactic medium (CGM) of z < 1 galaxies by correlating Faraday rotation measures (RMs) of ∼1000 high-redshift radio sources with the foreground galaxy number density estimated from the DESI Legacy Imaging Surveys. This method enables us to extract signals of RMs contributed by intervening gas around multiple galaxies. Our results show that there is no detectable correlation between the distribution of RMs and the number of foreground galaxies, contrary to several previous results. Utilizing the non-detection signals, we estimate 3σ upper limits to the RMs from the CGM of $\sim \!20 \rm \ rad\, m^{-2}$ within 50 kpc and $\sim \!10 \rm \ rad \, m^{-2}$ at separations of 100 kpc. By adopting a column density distribution of ionized gas obtained from absorption-line measurements, we further estimate the strengths of coherent magnetic fields parallel to the line of sight of $\lt \rm 2 \ \mu G$ in the CGM. We show that the estimated upper limits of RMs and magnetic field strengths are sufficient to constrain outputs of recent galaxy magnetohydrodynamic simulations. Finally, we discuss possible causes for the inconsistency between our results and previous works.

79 ASTRONOMY AND ASTROPHYSICS↗

Development of a Thermophysical Properties Model for Flowsheet Simulation of Biomass Pyrolysis Processes

A properties model was developed for use in commercial process simulators to model pyrolysis of lignocellulosic biomass. The component list was chosen to enable process simulations based on a recently published lumped pyrolysis kinetics model. Since many of the compounds involved in pyrolysis are not found in simulator databanks, estimation based on available literature data was used to establish missing parameters. Standard solid enthalpy of formation, solid heat capacity, and solid density estimates calculated from the limited experimental data available were prepared for six biomass constituents and nine intermediate and end-products of their pyrolysis. Ideal gas enthalpy of formation and heat capacity, critical property, and vapor pressure estimates were prepared for another four pyrolysis end-products and one biomass component. The estimates were all validated against the closest available experimental data in the literature. The addition of these new components and properties allows thermodynamically rigorous simulation of lumped biomass pyrolysis reactions with accurate energy balances. Furthermore enthalpies of reaction calculated from the properties model were compared with reported reaction enthalpies for the same lumped biomass pyrolysis reactions and found to be in general agreement.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Detection of the Ne III 36 micron forbidden line in the planetary nebula NGC 6543

The first observation of the Ne III 36.02 micron forbidden line in a planetary nebula, NGC 6543, is presented. Since the dominant form of neon in medium-excitation to high-excitation planetary nebulae is Ne III, the abundance of this ion is important in determining the total neon abundance. Use of the 36 micron line for an abundance determination has the advantage of insensitivity to temperature uncertainties. However, current atomic parameters lead to a Ne III abundance in NGC 6543 which is 4.5 times the cosmic neon abundance and 2.6 times the abundance from optical line studies. Although such a high abundance cannot be ruled out immediately, inaccuracies in the infrared level collision strengths are suspected because resonances were neglected in their calculation. The 36 micron line is also useful as a temperature probe when combined with the Ne III 3868-A forbidden line. When compared to Ne III 15.56 micron forbidden line fluxes, a temperature-insensitive density estimate may be obtained. The utility of these line ratios depends upon the actual infrared level collision strengths, which will affect the density range over which they are sensitive.

Shure, M. A.↗

Simulation Based Inference with Domain Adaptation for Strong Gravitational Lensing

Simulation based inference leverages machine learning to carry out Bayesian inference for systems with intractable likelihoods. However, transitioning a network trained on simulated data to real data runs the risk of encountering domain shift, leading to performance losses. We attempt to implement domain adaptation into the sbi neural posterior estimation framework using the Maximum Mean Discrepancy as an additional network loss. We test two network architectures and use masked autoregressive flow for density estimation. We test the network on a set of 400,000 simulated strong gravitational lensing images generated using deeplenstronomy. The source domain is defined as low noise whereas the target domain has a noise profile sampled from experimentally derived DES survey conditions. We find that, while DA does lead to performance improvements, they are marginal at ~6% less inference error. We also find a similar marginal improvement in uncertainty calibration at around 8%.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Equation of State of TiN at High Pressures and Temperatures: A Possible Host for Nitrogen in Planetary Mantles

Nitrogen, the most abundant element in Earth's atmosphere, is also a primary component of solid nitride minerals found in meteorites and on Earth's surface. If they remain stable to high pressures and temperatures, these nitrides may also be important reservoirs of nitrogen in planetary interiors. We used synchrotron X-ray diffraction to measure the thermal equation of state and phase stability of titanium nitride (TiN) in a laser-heated diamond anvil cell at pressures up to ~70 GPa and temperatures up to ~2500 K. TiN maintains the cubic B1 (NaCl-type) crystal structure over the entire pressure and temperature range explored. It has K 0 = 274(4) GPa, K 0 ' = 3.9(2), and γ 0 = 1.39(4) for a fixed V 0 = 76.516(30) Å 3 (based on experimental measurements), q = 1, and θ 0 = 579 K. Additionally, we collected Raman spectra of TiN up to ~60 GPa, where we find that the transverse acoustic (TA), longitudinal acoustic (LA), and transverse optical (TO) phonon modes exhibit mode Grüneisen parameters of 1.66(17), 0.54(15), and 0.93(4), respectively. Based on our equation of state, TiN has a density of ~5.6–6.4 g/cm 3 at Earth's lower mantle conditions, significantly more dense than both the mantle of the Earth and the estimated densities of the mantles of other terrestrial planets, but less dense than planetary cores. Furthermore, we find that TiN remains stable against physical decomposition at the pressures and temperatures found within Earth's mantle, making it a plausible reservoir for deep planetary nitrogen if chemical conditions allow its formation.

58 GEOSCIENCES↗

NH{sub 3}(3,3) AND CH{sub 3}OH NEAR SUPERNOVA REMNANTS: GBT AND VLA OBSERVATIONS

We report on Green Bank Telescope 23.87 GHz NH{sub 3}(3,3) emission observations in five supernova remnants (SNRs) interacting with molecular clouds (G1.4−0.1, IC 443, W44, W51C, and G5.7−0.0). The observations show a clumpy gas density distribution, and in most cases the narrow line widths of ∼3–4 km s{sup −1} are suggestive of maser emission. Very Large Array observations reveal 36 and/or 44 GHz CH{sub 3}OH maser emission in a majority (72%) of the NH{sub 3} peak positions toward three of these SNRs. This good positional correlation is in agreement with the high densities required for the excitation of each line. Through these observations we have shown that CH{sub 3}OH and NH{sub 3} maser emission can be used as indicators of high-density clumps of gas shocked by SNRs, and provide density estimates thereof. Modeling of the optical depth of the NH{sub 3}(3,3) emission is compared to that of CH{sub 3}OH, constraining the densities of the clumps to a typical density of the order of 10{sup 5} cm{sup −3} for cospatial masers. Regions of gas with this density are found to exist in the post-shocked gas quite close to the SNR shock front, and may be associated with sites where cosmic rays produce gamma-ray emission via neutral pion decay.

79 ASTRONOMY AND ASTROPHYSICS↗

Comparison of SOHO/UVCS and MLSO MK4 Coronameter Densities

This paper compares the density distributions of the solar corona obtained by UVCS and the Mauna MLSO MK4 coronameter. This is the first attempt to compare the coronal densities estimated by the two instruments. Two UVCS emission lines (O VI 1032 hand 1037.6 A), which have both radiative and collisional components, were used. The coronal number density is determined from the ratio of these two components. The coronal density can be determined by inverting MLSO MK4 polarization maps. It was found that the mean electron number density in a helmet streamer observed by MK4 on 2003 April 28 is fairly consistent with that observed by UVCS. For a coronal hole and an active region observed on 1999 October 19 and 24, the MK4 coronal densities are close to those from the UVCS. The results demonstrate that MK4 polarization data can provide a coronal density distribution in a large field of view with a time cadence of about three minutes.

Lee, K.-S.↗

On the provenance of GEMS, a quarter century post discovery

The provenance of GEMS (glass with embedded metal and sulfides) in cometary type interplanetary dust particles is investigated using analytical scanning transmission electron microscopy and secondary ion mass spectrometry. We review the current state of knowledge and closely examine the densities, elemental compositions and distributions, iron oxidation states, and isotopic compositions of a subset of GEMS in chondritic porous interplanetary dust. We find that GEMS are underdense with estimated densities that are 35–65% of compositionally equivalent crystalline aggregates. GEMS low densities result in a lower contribution to the bulk compositions of IDPs than has been assumed based on their volume fraction. We also find that element/Si ratios, assumed to be primary (indigenous), are instead perturbed by contamination and secondary alteration, including pulse heating during atmospheric entry. Fe in pyrrhotite inclusions was oxidized and Mg, S, Ca, and Fe were depleted relative to lithophile Al and Si, resulting in reduction in element/Si ratios. Because they trap outgassing elements, Fe-rich oxide rims that formed on the surface of GEMS are serendipitous “witness plates” to the changes in composition that accompany atmospheric entry. As a result of alteration, GEMS elemental compositions cannot reliably inform about their provenance. Except for highly anomalous oxygen isotope ratios measured in some large GEMS grains that indicate a contribution from circumstellar dust, oxygen isotope compositions are generally poor indicators of provenance. Prior work indicates that most GEMS fall close to the terrestrial oxygen isotope composition, which, however, does not exclude a presolar interstellar origin. Nitrogen isotopic compositions are more diagnostic. Elevated 15 N/ 14 N ratios indicate that GEMS accreted in conjunction with formation of organic matter by ion–molecule reactions in a cold (<50 K) presolar environment like the extreme outer nebula or interstellar medium. Considering all observations, we conclude that GEMS are most likely processed interstellar silicates.

79 ASTRONOMY AND ASTROPHYSICS↗

A group finder algorithm optimised for the study of local galaxy environments

Context. The majority of galaxy group catalogues available in the literature use the popular friends-of-friends algorithm which links galaxies using a linking length. One potential drawback to this approach is that clusters of points can be linked with thin bridges which may not be desirable. In order to study galaxy groups, it is important to obtain realistic group structures. Aim. Here, in this study, we present a new simple group finder algorithm, TD-ENCLOSER, that finds the group that encloses a target galaxy of interest. Methods. TD-ENCLOSER is based on the kernel density estimation method which treats each galaxy, represented by a zero-dimensional particle, as a two-dimensional circular Gaussian. The algorithm assigns galaxies to peaks in the density field in order of density in descending order (‘top down’) so that galaxy groups ‘grow’ around the density peaks. Outliers in under-dense regions are prevented from joining groups by a specified hard threshold, while outliers at the group edges are clipped below a soft (blurred) interior density level. Results. The group assignments are largely insensitive to all free parameter variations apart from the hard density threshold and the kernel standard deviation, although this is a known feature of density-based group finder algorithms and it operates with a computing speed that increases linearly with the size of the input sample. In preparation for a companion paper, we also present a simple algorithm to select unique representative groups when duplicates occur. Conclusions. TD-ENCLOSER is tested on a mock galaxy catalogue using a smoothing scale of 0.3 Mpc and is found to be able to recover the input group distribution with sufficient accuracy to be applied to observed galaxy distributions.

79 ASTRONOMY AND ASTROPHYSICS↗

Quasar microlensing and dark matter

The amplification of quasar brightness due to gravitational lensing by foreground objects is discussed. It is shown that a recently published sample of X-ray-selected quasars behind foreground galaxies shows a statistically significant brightening compared to a control sample. Correlations with galaxy redshift and impact parameter predicted by microlensing are also demonstrated. A technique is described to measure the mean density of the lenses from a small number of identified cases of microlensing. It is shown that, in this sample, amplification bias is important in determining the mean intensity enhancement and must be included in the density estimate. Assuming that at least two of the four intrinsically brightest quasars behind galaxies are indeed microlensed, the present data yield a formal lower limit on the mean density parameter of lenses Omega(l) greater than 0.25 at 95 percent confidence. These data also imply that a considerable quantity of dark matter exists in macroscopic objects outside the visible parts of galaxies but is still highly correlated with them.

Rix, Hans-Walter↗