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Siderophile Element Depletion in the Angrite Parent Body (APB) Mantle: Due to Core Formation?

The origin of angrites has evaded scientists due in part to unusual mineralogy, oxidized character, and small numbers of samples. Increased interest in the origin of angrites has stemmed from the recovery of approximately 10 new angrites in the past decade. These new samples have allowed meteoriticists to recognize that angrites are compositionally diverse, old, and record very early differentiation. Also, a magma ocean has been proposed to have been involved in APB early differentiation, but this remains untested for siderophile elements which are commonly cited as one of the main lines of evidence for magma oceans on the early Earth, Moon, Mars and eucrite parent body (e.g., [6]). And recent suggestions that angrites may or may not be from Mercury have also peaked interest in these achondrites. Given all of this background, a detailed understanding of the early differentiation process is desired. Previous efforts at examining siderophile element (SE) concentrations with respect to core formation processes in the APB have not resulted in any definite conclusions regarding segregation of a metallic core. The goal of this study is to summarize what is known about SE concentrations in the suite, estimate depletions of SE compared to chondrites, and apply metal/silicate experimental partition coefficients to assess whether the APB had a core.

Righter, K.↗

Proteomic Retrieval from Nucleic Acid Depleted Space-Flown Human Cells

Compared to experiments utilizing humans in microgravity, cell-based approaches to questions about subsystems of the human system afford multiple advantages, such as crew safety and the ability to achieve statistical significance. To maximize the science return from flight samples, an optimized method was developed to recover protein from samples depleted of nucleic acid. This technique allows multiple analyses on a single cellular sample and when applied to future cellular investigations could accelerate solutions to significant biomedical barriers to human space exploration. Cell cultures grown in American Fluoroseal bags were treated with an RNA stabilizing agent (RNAlater - Ambion), which enabled both RNA and immunoreactive protein analyses. RNA was purified using an RNAqueous(registered TradeMark) kit (Ambion) and the remaining RNA free supernatant was precipitated with 5% trichloroacetic acid. The precipitate was dissolved in SDS running buffer and tested for protein content using a bicinchoninic acid assay (1) (Sigma). Equal loads of protein were placed on SDS-PAGE gels and either stained with CyproOrange (Amersham) or transferred using Western Blotting techniques (2,3,4). Protein recovered from RNAlater-treated cells and stained with protein stain, was measured using Imagequant volume measurements for rectangles of equal size. BSA treated in this way gave quantitative data over the protein range used (Fig 1). Human renal cortical epithelial (HRCE) cells (5,6,7) grown onboard the International Space Station (ISS) during Increment 3 and in ground control cultures exhibited similar immunoreactivity profiles for antibodies to the Vitamin D receptor (VDR) (Fig 2), the beta isoform of protein kinase C (PKC ) (Fig 3), and glyceraldehyde-3-phosphate dehydrogenase (GAPDH) (Fig 4). Parallel immunohistochemical studies on formalin-fixed flight and ground control cultures also showed positive immunostaining for VDR and other biomarkers (Fig 5). These results are consistent with data from additional antigenic recovery experiments performed on human Mullerian tumor cells cultured in microgravity (8).

Hammond, D. K.↗

Linkages Between Ozone-depleting Substances, Tropospheric Oxidation and Aerosols

Coupling between the stratosphere and the troposphere allows changes in stratospheric ozone abundances to affect tropospheric chemistry. Large-scale effects from such changes on chemically produced tropospheric aerosols have not been systematically examined in past studies. We use a composition-climate model to investigate potential past and future impacts of changes in stratospheric ozone depleting substances (ODS) on tropospheric oxidants and sulfate aerosols. In most experiments, we find significant responses in tropospheric photolysis and oxidants, with small but significant effects on methane radiative forcing. The response of sulfate aerosols is sizeable when examining the effect of increasing future nitrous oxide (N2O) emissions. We also find that without the regulation of chlorofluorocarbons (CFCs) through the Montreal Protocol, sulfate aerosols could have increased by 2050 by a comparable amount to the decreases predicted due to relatively stringent sulfur emissions controls. The individual historical radiative forcings of CFCs and N2O through their indirect effects on methane (−22.6mW/sq. m for CFCs and −6.7mW/sq. m for N2O) and sulfate aerosols (−3.0mW/sq. m for CFCs and +6.5mW/sq. m for N2O when considering the direct aerosol effect) discussed here are non-negligible when compared to known historical ODS forcing. Our results stress the importance of accounting for stratosphere-troposphere, gas-aerosol and composition-climate interactions when investigating the effects of changing emissions on atmospheric composition and climate.

troposphere↗

Formation and Preservation of the Depleted and Enriched Shergottite Isotopic Reservoirs in a Convecting Martian Mantle

There is compelling isotopic and crater density evidence for geologically recent volcanism on Mars, in the last 100-200 million years and possibly in the last 50 million years. This volcanism is due to adiabatic decompression melting and thus requires some type of present-day convective upwelling in the martian mantle. On the other hand, martian meteorites preserve evidence for at least 3 distinct radiogenic isotopic reservoirs. Anomalies in short-lived isotopic systems (Sm-146, Nd-142, Hf-182, W-182) require that these reservoirs must have developed in the first 50 to 100 million years of Solar System history. The long-term preservation of chemically distinct reservoirs has sometimes been interpreted as evidence for the absence of mantle convection and convective mixing on Mars for most of martian history, a conclusion which is at odds with the evidence for young volcanism. This apparent paradox can be resolved by recognizing that a variety of processes, including both inefficient mantle mixing and geographic separation of isotopic reservoirs, may preserve isotopic heterogeneity on Mars in an actively convecting mantle. Here, we focus on the formation and preservation of the depleted and enriched isotopic and trace element reservoirs in the shergottites. In particular, we explore the possible roles of processes such as chemical diffusion and metasomatism in dikes and magma chambers for creating the isotopically enriched shergottites. We also consider processes that may preserve the enriched reservoir against convective mixing for most of martian history.

Kiefer, Walter S.↗

Barium Depletion in the NSTAR Discharge Cathode After 30,000 Hours of Operation

Dispenser hollow cathodes rely on a consumable supply of barium released by impregnant materials in the pores of a tungsten matrix to maintain a low work function surface. Examinations of cathode inserts from long duration ion engine tests show deposits of tungsten at the downstream end that appear to block the flow of barium from the interior. In addition, a numerical model of barium transport in the insert plasma indicates that the barium partial pressure in the insert may exceed the equilibrium vapor pressure of the dominant barium-producing reaction, and it was postulated previously that this would suppress barium loss in the upstream part of the insert. New measurements of the depth of barium depletion from a cathode insert operated for 30,352 hours reveal that barium loss is confined to a narrow region near the downstream end, confirming this hypothesis.

plasma transport↗

Barium Depletion in Hollow Cathode Emitters

The effect of tungsten erosion, transport and redeposition on the operation of dispenser hollow cathodes was investigated in detailed examinations of the discharge cathode inserts from an 8200 hour and a 30,352 hour ion engine wear test. Erosion and subsequent re-deposition of tungsten in the electron emission zone at the downstream end of the insert reduces the porosity of the tungsten matrix, preventing the ow of barium from the interior. This inhibits the interfacial reactions of the barium-calcium-aluminate impregnant with the tungsten in the pores. A numerical model of barium transport in the internal xenon discharge plasma shows that the barium required to reduce the work function in the emission zone can be supplied from upstream through the gas phase. Barium that flows out of the pores of the tungsten insert is rapidly ionized in the xenon discharge and pushed back to the emitter surface by the electric field and drag from the xenon ion flow. This barium ion flux is sufficient to maintain a barium surface coverage at the downstream end greater than 0.6, even if local barium production at that point is inhibited by tungsten deposits. The model also shows that the neutral barium pressure exceeds the equilibrium vapor pressure of the impregnant decomposition reaction over much of the insert length, so the reactions are suppressed. Only a small region upstream of the zone blocked by tungsten deposits is active and supplies the required barium. These results indicate that hollow cathode failure models based on barium depletion rates in vacuum dispenser cathodes are very conservative.

plasma discharges↗

Have GRACE Satellites Overestimated Groundwater Depletion in the Northwest India Aquifer?

The Northwest India Aquifer (NWIA) has been shown to have the highest groundwater depletion (GWD) rate globally, threatening crop production and sustainability of groundwater resources. Gravity Recovery and Climate Experiment (GRACE) satellites have been emerging as a powerful tool to evaluate GWD with ancillary data. Accurate GWD estimation is, however, challenging because of uncertainties in GRACE data processing. We evaluated GWD rates over the NWIA using a variety of approaches, including newly developed constrained forward modeling resulting in a GWD rate of 3.1 plus or minus 0.1 centimeters per acre (or 14 plus or minus 0.4 cubic kilometers per acre) for Jan 2005-Dec 2010, consistent with the GWD rate (2.8 centimeters per acre or 12.3 cubic kilometers per acre) from groundwater-level monitoring data. Published studies (e.g., 4 plus or minus 1 centimeter per acre or 18 plus or minus 4.4 cubic kilometers per acre) may overestimate GWD over this region. This study highlights uncertainties in GWD estimates and the importance of incorporating a priori information to refine spatial patterns of GRACE signals that could be more useful in groundwater resource management and need to be paid more attention in future studies.

Long, Di↗

Observations of Deep Ionospheric F-Region Density Depletions with FPMU Instrumentation and their Relationship with the Global Dynamics of the June 22-23, 2015 Geomagnetic Storm

The magnetic storm that commenced on June 22-23, 2015 was one of the largest storms in our current solar cycle, resulting from an active region on the Sun that produced numerous coronal mass ejections (CMEs) and associated interplanetary shock waves. On June 22 at 18:36 UT the magnetosphere was impacted by the shock wave on the magnetosphere. Observations from several spacecraft observed the dynamic response of the magnetosphere and ionosphere. MMS observatories in the near earth tail These low altitude measurements are correlated in the magnetosphere with particle flux dropouts measured by MMS We follow the timing of this storm in the ionosphere with the density depletions throughout the ISS orbits, DMSP drift velocities, and enhanced AMPERE Birkland currents. Together these observations and simulation results will be assembled to provide each region's context to the global dynamics and time evolution of the storm. The models during these event support and flesh out the puzzle of the global dynamics.

Coffey, Victoria↗

Electrically Heated Testing of the Kilowatt Reactor Using Stirling TechnologY (KRUSTY) Experiment Using a Depleted Uranium Core

The Kilopower project aims to develop and demonstrate scalable fission-based power technology for systems capable of delivering 1 to 10 kW of electric power with a specific power ranging from 2.5 to 6.5 W/kg. This technology could enable high-power science missions or could be used to provide surface power for manned missions to the Moon or Mars. NASA has partnered with the U.S. Department of Energy's National Nuclear Security Administration, Los Alamos National Laboratory, Nevada National Security Site (NNSS), and Y−12 National Security Complex to develop and test a prototypic reactor and power system using existing facilities and infrastructure. This technology demonstration, referred to as the "Kilowatt Reactor Using Stirling TechnologY (KRUSTY)," will undergo nuclear ground testing by the end of calendar year (CY) 2017 at the NNSS. The 1-kWe variation of the Kilopower system was chosen for the KRUSTY demonstration. The concept for the 1-kWe flight system consists of a 4 kWt highly enriched uranium-molybdenum reactor operating at 800 degC coupled to sodium heat pipes. The heat pipes deliver heat to the hot ends of eight 125-W Stirling convertors producing a net electrical output of 1 kW. Waste heat is rejected using titanium-water heat pipes coupled to carbon composite radiator panels. The KRUSTY test, based on this design, uses a prototypic highly enriched uranium-molybdenum core coupled to prototypic sodium heat pipes. The heat pipes transfer heat to two Advanced Stirling Convertors (ASC−E2s) and six thermal simulators, which simulate the thermal draw of full-scale power conversion units. Thermal simulators and Stirling engines are gas cooled. The most recent project milestone was the completion of nonnuclear system-level testing using an electrically heated depleted uranium (DU) (nonfissioning) reactor core simulator at the NASA Glenn Research Center. System-level testing has validated performance predictions and has demonstrated system-level operation and control in a test configuration that replicates the one to be used at the Device Assembly Facility (DAF) at the NNSS. Fabrication, assembly, and testing of the DU core has allowed for higher fidelity system-level testing at Glenn, and has validated the fabrication methods to be used on the highly enriched uranium core that will supply heat for the DAF KRUSTY demonstration.

Briggs, Maxwell H.↗

Ozone Sensitivity to Varying Greenhouse Gases and Ozone-Depleting Substances in CCMI-1 Simulations

Ozone fields simulated for the first phase of the Chemistry-Climate Model Initiative (CCMI-1) will be used as forcing data in the 6th Coupled Model Intercomparison Project. Here we assess, using reference and sensitivity simulations produced for CCMI-1, the suitability of CCMI-1 model results for this process, investigating the degree of consistency amongst models regarding their responses to variations in individual forcings. We consider the influences of methane, nitrous oxide, a combination of chlorinated or brominated ozone-depleting substances, and a combination of carbon dioxide and other greenhouse gases. We find varying degrees of consistency in the models' responses in ozone to these individual forcings, including some considerable disagreement. In particular, the response of total-column ozone to these forcings is less consistent across the multi-model ensemble than profile comparisons. We analyse how stratospheric age of air, a commonly used diagnostic of stratospheric transport, responds to the forcings. For this diagnostic we find some salient differences in model behaviour, which may explain some of the findings for ozone. The findings imply that the ozone fields derived from CCMI-1 are subject to considerable uncertainties regarding the impacts of these anthropogenic forcings. We offer some thoughts on how to best approach the problem of generating a consensus ozone database from a multi-model ensemble such as CCMI-1.

CCMI↗

A Deep X-Ray Look at Abell 2142-Viscosity Constraints from Kelvin-Helmholtz Eddies, a Displaced Cool Peak that Makes a Warm Core, and A Possible Plasma Depletion Layer

cold fronts in detail. We find that the southern cold front exhibits well-developed Kelvin–Helmholtz (KH) eddies seen in the sky plane. Comparing their wavelength and amplitude with those in hydrodynamic simulations of cold fronts in viscous gas, and estimating the gas tangential velocity from centripetal acceleration, we constrain the effective viscosity to be at most 1/5 of Spitzer isotropic viscosity, but consistent with full Braginskii anisotropic viscosity for magnetized plasma. While the northwestern front does not show obvious eddies, its shape and the structure of its brightness profile suggest KH eddies seen in projection. The southern cold front continues in a spiral to the center of the cluster, ending with another cold front only 12 kpc from the gas density peak. The cool peak itself is displaced ∼30 kpc from the brightest cluster galaxy (BCG) (the biggest such offset among centrally peaked clusters), while the X-ray emission on a larger scale is still centered on the BCG, indicating that the BCG is at the center of the gravitational potential and the cool gas is sloshing in it. The specific entropy index of the gas in the peak (K≈49 keV sq.cm) makes A2142 a rare “warm core”; apparently the large displacement of the cool peak by sloshing is the reason. Finally, we find a subtle narrow, straight channel with a 10% drop in X-ray brightness, aligned with the southern cold front—possibly a plasma depletion layer in projection.

Wang, Qian H. S.↗

The Toba Supervolcano Eruption Caused Severe Tropical Stratospheric Ozone Depletion

Supervolcano eruptions have occurred throughout Earth’s history and have major environmental impacts. These impacts are mostly associated with the attenuation of visible sunlight by stratospheric sulfate aerosols, which causes cooling and deceleration of the water cycle. Supereruptions have been assumed to cause so-called volcanic winters that act as primary evolutionary factors through ecosystem disruption and famine, however, winter conditions alone may not be sufficient to cause such disruption. Here we use Earth system model simulations to show that stratospheric sulfur emissions from the Toba supereruption 74,000 years ago caused severe stratospheric ozone loss through a radiation attenuation mechanism that only moderately depends on the emission magnitude. The Toba plume strongly inhibited oxygen photolysis, suppressing ozone formation in the tropics, where exceptionally depleted ozone conditions persisted for over a year. This effect, when combined with volcanic winter in the extra-tropics, can account for the impacts of supereruptions on ecosystems and humanity.

Atmospheric chemistry↗

Science CONOPS for Application of Sport Mission Data to Study Large (~1000KM) Ionospheric Plasma Depletions

The Scintillation Prediction Observations Research Task (SPORT) mission is a single 6U CubeSat space weather satellite planned for an October 2022 launch into an ISS-like orbit. The primary purpose of the SPORT mission is to determine the longitudinal effects on equatorial plasma bubble (EPB) growth resulting from the offset dipole magnetic field of the Earth. By combining field and plasma measurements from SPORT with other low-altitude (i.e., alt < 1000 km) spacecraft, it is possible to investigate large-scale (> 1000 km) EPB structures. The types of investigation made possible by measurements from SPORT and other contemporaneous missions include 1) dynamics of depleted magnetic flux tubes; 2) dynamics of field-aligned EPB expansion versus propagation speed; 3) EPB vertical extent; and 4) EPB temporal evolution. To support these investigation types, the respective modes of conjunctions are: 1) simultaneous intersection of a magnetic flux tube; 2) intersection of magnetic flux tube separated in time; 3) Simultaneous Latitude/Longitude position conjunction; and 4) Non-simultaneous latitude/longitude position conjunction. This paper will summarize the SPORT satellite and data used for Science CONOPS to accomplish these objectives.

Ionospheres↗

Science Conops for Application of Sport Mission Data to Study Large (~1000KN) Ionospheric Plasma Depletions

The Scintillation Prediction Observations Research Task (SPORT) mission is a single 6U CubeSat space weather satellite planned for an October 2022 launch into an ISS-like orbit. The primary purpose of the SPORT mission is to determine the longitudinal effects on equatorial plasma bubble (EPB) growth resulting from the offset dipole magnetic field of the Earth. By combining field and plasma measurements from SPORT with other low-altitude (i.e., alt < 1000 km) spacecraft, it is possible to investigate large-scale (> 1000 km) EPB structures. The types of investigation made possible by measurements from SPORT and other contemporaneous missions include 1) dynamics of depleted magnetic flux tubes; 2) dynamics of field-aligned EPB expansion versus propagation speed; 3) EPB vertical extent; and 4) EPB temporal evolution. To support these investigation types, the respective modes of conjunctions are: 1) simultaneous intersection of a magnetic flux tube; 2) intersection of magnetic flux tube separated in time; 3) Simultaneous Latitude/Longitude position conjunction; and 4) Non-simultaneous latitude/longitude position conjunction. This paper will summarize the SPORT satellite and data used for Science CONOPS to accomplish these objectives.

Scintillation↗

Global Total Ozone Recovery Trends Attributed to Ozone-Depleting Substance (ODS) Changes Derived From Five Merged Ozone Datasets

We report on updated trends using different merged zonal mean total ozone datasets from satellite and ground-based observations for the period from 1979 to 2020. This work is an update of the trends reported in Weber et al. (2018) using the same datasets up to 2016. Merged datasets used in this study include NASA MOD v8.7 and NOAA Cohesive Data (COH) v8.6, both based on data from the series of Solar Backscatter Ultraviolet (SBUV), SBUV-2, and Ozone Mapping and Profiler Suite (OMPS) satellite instruments (1978–present), as well as the Global Ozone Monitoring Experiment (GOME)-type Total Ozone – Essential Climate Variable (GTO-ECV) and GOME-SCIAMACHY-GOME-2 (GSG) merged datasets (both 1995–present), mainly comprising satellite data from GOME, SCIAMACHY, OMI, GOME-2A, GOME-2B, and TROPOMI. The fifth dataset consists of the annual mean zonal mean data from ground-based measurements collected at the World Ozone and Ultraviolet Radiation Data Centre (WOUDC). Trends were determined by applying a multiple linear regression (MLR) to annual mean zonal mean data. The addition of 4 more years consolidated the fact that total ozone is indeed slowly recovering in both hemispheres as a result of phasing out ozone-depleting substances (ODSs) as mandated by the Montreal Protocol. The near-global (60° S–60° N) ODS-related ozone trend of the median of all datasets after 1995 was 0.4 ± 0.2 (2σ) %/decade, which is roughly a third of the decreasing rate of 1.5 ± 0.6 %/decade from 1978 until 1995. The ratio of decline and increase is nearly identical to that of the EESC (equivalent effective stratospheric chlorine or stratospheric halogen) change rates before and after 1995, confirming the success of the Montreal Protocol. The observed total ozone time series are also in very good agreement with the median of 17 chemistry climate models from CCMI-1 (Chemistry-Climate Model Initiative Phase 1) with current ODS and GHG (greenhouse gas) scenarios (REF-C2 scenario). The positive ODS-related trends in the Northern Hemisphere (NH) after 1995 are only obtained with a sufficient number of terms in the MLR accounting properly for dynamical ozone changes (Brewer–Dobson circulation, Arctic Oscillation (AO), and Antarctic Oscillation (AAO)). A standard MLR (limited to solar, Quasi-Biennial Oscillation (QBO), volcanic, and El Niño–Southern Oscillation (ENSO)) leads to zero trends, showing that the small positive ODS-related trends have been balanced by negative trend contributions from atmospheric dynamics, resulting in nearly constant total ozone levels since 2000.

Total Column Ozone Trends↗

Groundwater Depletion in California’s Central Valley Accelerates During Megadrought

Groundwater provides nearly half of irrigation water supply, and it enables resilience during drought, but in many regions of the world, it remains poorly, if at all managed. In heavily agricultural regions like California’s Central Valley, where groundwater management is being slowly implemented over a 27-year period that began in 2015, groundwater provides two-thirds or more of irrigation water during drought, which has led to falling water tables, drying wells, subsiding land, and its long-term disappearance. Here we use nearly two decades of observations from NASA’s GRACE satellite missions and show that the rate of groundwater depletion in the Central Valley has been accelerating since 2003 (1.86 km3 /yr, 1961-2021; 2.41 km3 /yr, 2003- 2021; 8.58 km3 /yr, 2019-2021), a period of megadrought in southwestern North America. Results suggest the need for expedited implementation of groundwater management in the Central Valley to ensure its availability during the increasingly intense droughts of the future.

Hydrology↗