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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS2018

Carbon on Mercury's Surface - Origin, Distribution, and Concentration

Distinctive low-reflectance material (LRM) was first observed on Mercury in Mariner 10 flyby images. Visible to near-infrared reflectance spectra of LRM are flatter than the average reflectance spectrum of Mercury, which is strongly red sloped (increasing in reflectance with wavelength). From Mariner 10 and early MErcury, Surface, Space, ENvironment, GEochemistry, and Ranging (MESSENGER) flyby observations, it was suggested that a higher content of ilmenite, ulvospinel, carbon, or iron metal could cause both the characteristic dark, flat spectrum of LRM and the globally low reflectance of Mercury. Once MESSENGER entered orbit, low Fe and Ti abundances measured by the X-Ray and Gamma-Ray Spectrometers ruled out ilmenite, and ulvospinel as important surface constituents and implied that LRM was darkened by a different phase, such as carbon or small amounts of micro- or nanophase iron or iron sulfide dispersed in a silicate matrix. Low-altitude thermal neutron measurements of three LRM-rich regions confirmed an enhancement of 1-3 weight-percent carbon over the global abundance, supporting the hypothesis that LRM is darkened by carbon.

Klima, Rachel L.↗
NASA NTRS1991

Derivation of mid-infrared (5-25 microns) optical constants of some silicates and palagonite

Recent reports concerning the mid-infrared reflectance properties of silicates coupled with recent observations of the Earth and other planets in the mid-infrared and the planned Thermal Emission Spectrometer scheduled as an instrument to be included on the Mars Observer all illustrate the increasing interest in the optical properties of materials in the mid-infrared and their direct application to remote sensing observations of other planetary surfaces. As the laboratory and observational data increase they will ultimately be modeled to aid in the understanding of the composition mineralogy, and distribution of the surface and atmospheric constituents on these bodies. In order to facilitate such quantitative analyses, knowledge regarding the optical constants (real (n) and imaginary (k) indices of refraction) of a wide variety of pertinent materials is required. Examples of the application of such quantitative analyses to the interpretation of Martian surface and atmospheric constituents, based on the optical constants of minerals, are presented. This study was initially conceived in order to aid in the interpretation of Martian surface and atmospheric aerosol mineralogy. As a result, the minerals included are biased toward samples which represent hydrated and hydroxylated silicates. These include the Al and Mg end members of the 1:1 layer lattice silicates, kaolinite and serpentine, respectively; an Al-bearing 2:1 layer lattice silicate, pyrophyllite; the Mg and Al smectite clays saponite and montmorillonite, respectively; and a palagonite, typically a poorly characterized alteration product of basaltic glass. The reflectivities of all samples were determined by placing them at the focus of a near-normal reflective attachment located in a Fourier transform spectrometer. To derive the optical constants of a material as a function of wavelength, researchers used the commonly employed technique of dispersion analysis.

Roush, T. L.↗
NASA NTRS2000

Radiative Properties of Smoke and Aerosol Over Land Surfaces

This talk discusses smoke and aerosol's radiative properties with particular attention to distinguishing the measurement over clear sky from clouds over land, sea, snow, etc. surfaces, using MODIS Airborne Simulator data from (Brazil, arctic sea ice and tundra and southern Africa, west Africa, and other ecosystems. This talk also discusses the surface bidirectional reflectance using Cloud Absorption Radiometer, BRDF measurements of Saudi Arabian desert, Persian Gulf, cerrado and rain forests in Brazil, sea ice, tundra, Atlantic Ocean, Great Dismal Swamp, Kuwait oil fire smoke. Recent upgrades to instrument (new TOMS UVA channels at 340 and 380 planned use in Africa (SAFARI 2000) and possibly for MEIDEX will also be discussed. This talk also plans to discuss the spectral variation of surface reflectance over land and the sensitivity of off-nadir view angles to correlation between visible near-infrared reflectance for use in remote sensing of aerosol over land.

King, Michael D.↗
NASA NTRS2007

High-Speed Noninvasive Eye-Tracking System

The figure schematically depicts a system of electronic hardware and software that noninvasively tracks the direction of a person s gaze in real time. Like prior commercial noninvasive eye-tracking systems, this system is based on (1) illumination of an eye by a low-power infrared light-emitting diode (LED); (2) acquisition of video images of the pupil, iris, and cornea in the reflected infrared light; (3) digitization of the images; and (4) processing the digital image data to determine the direction of gaze from the centroids of the pupil and cornea in the images. Relative to the prior commercial systems, the present system operates at much higher speed and thereby offers enhanced capability for applications that involve human-computer interactions, including typing and computer command and control by handicapped individuals,and eye-based diagnosis of physiological disorders that affect gaze responses.

Talukder, Ashit↗
NASA NTRS2010

Algorithms for High-Speed Noninvasive Eye-Tracking System

Two image-data-processing algorithms are essential to the successful operation of a system of electronic hardware and software that noninvasively tracks the direction of a person s gaze in real time. The system was described in High-Speed Noninvasive Eye-Tracking System (NPO-30700) NASA Tech Briefs, Vol. 31, No. 8 (August 2007), page 51. To recapitulate from the cited article: Like prior commercial noninvasive eyetracking systems, this system is based on (1) illumination of an eye by a low-power infrared light-emitting diode (LED); (2) acquisition of video images of the pupil, iris, and cornea in the reflected infrared light; (3) digitization of the images; and (4) processing the digital image data to determine the direction of gaze from the centroids of the pupil and cornea in the images. Most of the prior commercial noninvasive eyetracking systems rely on standard video cameras, which operate at frame rates of about 30 Hz. Such systems are limited to slow, full-frame operation. The video camera in the present system includes a charge-coupled-device (CCD) image detector plus electronic circuitry capable of implementing an advanced control scheme that effects readout from a small region of interest (ROI), or subwindow, of the full image. Inasmuch as the image features of interest (the cornea and pupil) typically occupy a small part of the camera frame, this ROI capability can be exploited to determine the direction of gaze at a high frame rate by reading out from the ROI that contains the cornea and pupil (but not from the rest of the image) repeatedly. One of the present algorithms exploits the ROI capability. The algorithm takes horizontal row slices and takes advantage of the symmetry of the pupil and cornea circles and of the gray-scale contrasts of the pupil and cornea with respect to other parts of the eye. The algorithm determines which horizontal image slices contain the pupil and cornea, and, on each valid slice, the end coordinates of the pupil and cornea. Information from multiple slices is then combined to robustly locate the centroids of the pupil and cornea images. The other of the two present algorithms is a modified version of an older algorithm for estimating the direction of gaze from the centroids of the pupil and cornea. The modification lies in the use of the coordinates of the centroids, rather than differences between the coordinates of the centroids, in a gaze-mapping equation. The equation locates a gaze point, defined as the intersection of the gaze axis with a surface of interest, which is typically a computer display screen (see figure). The expected advantage of the modification is to make the gaze computation less dependent on some simplifying assumptions that are sometimes not accurate

Talukder, Ashit↗
NASA NTRS1995

Space qualification of IR-reflecting coverslides for GaAs solar cells

Improvements to GaAs solar array performance, from the use on solar cell coverslides of several reflecting coatings that reject unusable portions of the solar spectrum, are quantified. Blue-red-rejection (BRR) coverslides provide both infrared reflection (IRR) and ultraviolet rejection (UVR). BRR coverslides were compared to conventional antireflection (AR) and ultraviolet (UV) coated coverslides. A 2% improvement in peak-power output, relative to that from Ar-coated coverslides, is seen for cells utilizing BRR coverslides with the widest bandpass. Coverslide BRR-filter bandpass width and covered-solar-cell short-circuit current is a function of incident light angle and the observed narrower-bandpass filters are more sensitive to change in angle from the normal than are wide-bandpass filters. The first long-term (3000 hours) UV testing of unirradiated and 1 MeV electron-irradiated GaAs solar cells, with multilayer-coated coverslides to reduce solar array operating temperature, has indicated that all multilayer coatings on coverslides and solar cells will experience degradation from the space environment (UV and/or electrons). Five types of coverslide coatings, designed for GaAs solar cells, were tested as part of a NASA-sponsored space-flight qualification for BRR, multi-layer-coated, coverslides. The reponse to the different radiations varied with the coatings. The extent of degradation and its consequences on the solar cell electrical characteristics depend upon the coatings and the radiation. In some cases, an improved optical coupling was observed during long-term UV exposure to the optical stack. The benefits of multi-layered solar cell optics may depend upon both the duration and the radiation environment of a mission.

Meulenberg, Andrew↗
NASA NTRS2014

Estimating Major Ion and Nutrient Concentrations in Mangrove Estuaries in Everglades National Park Using Leaf and Satellite Reflectance

Coastal mangrove ecosystems are under duress worldwide because of urban development, sea-level rise, and climate change, processes that are capable of changing the salinity and nutrient concentration of the water utilized by the mangroves. This study correlates long-term water chemistry in mangrove environments, located in Everglades National Park,with mangrove spectral reflectance measurements made at both the leaf and canopy scales. Spectral reflectance measurements were collected using a handheld spectrometer for leaf-level measurements and Landsat 5TMdata for regional coverage. Leaf-level reflectance data were collected from three mangrove species (i.e., red, black and white mangroves) across two regions; a tall mangrove (approximately 18m) and dwarf mangrove (1- 2 m) region. The reflectance data were then used to calculate a wide variety of biophysical reflectance indices (e.g., NDVI, EVI, SAVI) to determine signs of stress. Discrete, quarterly water samples from the surface water, groundwater, and pore water (20 and 85 cm depths) and daily autonomous surface water samples were collected at each site and analyzed for major anions (Cl(−) and SO(2(-)/4)), cations (Na(+), K(+), Mg(sup 2(+)), and Ca(sup 2(+)), total nitrogen (TN) and total phosphorus (TP).Mangrove sites that exhibited the highest salinity and ionic concentrations in the surface and subsurface water also had the lowest near-infrared reflectance at both the leaf and satellite levels. Seasonal reflectance responses were measured in the near-infrared (NIR) wavelengths at both the leaf and canopy scales and were strongly correlated with nutrient and ionic concentrations in the surface and subsurface water, even though there was no significant separability between the three mangrove species. Study sites that experienced the greatest variability in surface and subsurface water ionic concentrations also exhibited the greatest fluctuations in NIR spectral reflectance. Landsat 5TM images were able to detect tall and dwarf mangroves by the differences in spectral indices (e.g., NDVI, NDWI, and EVI) because of the variability in the background conditions amongst the environments. In addition, Landsat 5TM images spanning 16 years (1993- 2009) were successfully used to estimate the seasonal variability in ionic concentrations in the surface water across the Florida Coastal mangrove ecotone. This study has shown that water chemistry can be estimated indirectly by measuring the change in spectral response at the leaf- or satellite-scale. Furthermore, the results of this research may be extrapolated to similar coastal mangrove systems throughout the Caribbean and world-wide wherever red, black, and white mangroves occur.

Mangroves↗
NASA NTRS1974

Use of remote sensing in agriculture

Remote sensing studies in Virginia and Chesapeake Bay areas to investigate soil and plant conditions via remote sensing technology are reported ant the results given. Remote sensing techniques and interactions are also discussed. Specific studies on the effects of soil moisture and organic matter on energy reflection of extensively occurring Sassafras soils are discussed. Greenhouse and field studies investigating the effects of chlorophyll content of Irish potatoes on infrared reflection are presented. Selected ground truth and environmental monitoring data are shown in summary form. Practical demonstrations of remote sensing technology in agriculture are depicted and future use areas are delineated.

Pettry, D. E.↗
NASA NTRS1978

An infrared study of the Ophiuchus dark cloud

A near-infrared survey has been conducted of nearly 18 square degrees of the Ophiuchus dark cloud complex. Additional observations have been made of selected objects found in this survey and of the brighter objects found by Grasdalen et al. and by Vrba et al. in this region in order to identify and study the young stars associated with the cloud. These observations show that very recent star formation has been largely restricted to a small region at the center of the dark cloud complex, no more than a few parsecs in extent. Most of the young stars do not appear to be main-sequence stars. At least three of these objects appear to be surrounded by infrared reflection nebulae. Many of the objects studied are background K and M giants which can be used to determine the near-infrared extinction due to the cloud.

Elias, J. H.↗
NASA NTRS2018

The Optoretinogram at 38

As early as 1980, Donald MacLeod coined the term "optoretinogram" to describe a change in the near-infrared reflectance of the retina following visual stimulation. The hope that such signals might exist was stimulated by an observation of a change in the infrared transmission of isolated toad retinae. This signal showed a time course of several seconds, much slower than the electroretinogram, and was thought to be related to some chemical step in the phototransduction cascade. During the early 1980's, we made several attempts to observe such signals in vivo in humans, without success. In the intervening decades, however, researchers have succeeded in observing what are now known as "intrinsic optical signals" or IOSs. Responses from single photoreceptors (obtained using adaptive optics) are surprisingly heterogenous, with some cells increasing their reflectance in response to visual stimulation, while others decrease. This talk will review our early work, survey recent findings, and consider various theories for the origin of the effect.

noninvasive monitoring↗
NASA NTRS1997

Reflective Coating on Fibrous Insulation for Reduced Heat Transfer

Radiative heat transfer through fibrous insulation used in thermal protection systems (TPS) is significant at high temperatures (1200 C). Decreasing the radiative heat transfer through the fibrous insulation can thus have a major impact on the insulating ability of the TPS. Reflective coatings applied directly to the individual fibers in fibrous insulation should decrease the radiative heat transfer leading to an insulation with decreased effective thermal conductivity. Coatings with high infrared reflectance have been developed using sol-gel techniques. Using this technique, uniform coatings can be applied to fibrous insulation without an appreciable increase in insulation weight or density. Scanning electron microscopy, Fourier Transform infrared spectroscopy, and ellipsometry have been performed to evaluate coating performance.

Hass, Derek D.↗
NASA NTRS1977

An infrared foreoptics adaptor for the Learjet Telescope

A foreoptics adapter has been built for the Learjet telescope which permits simultaneous viewing of the visible star field in the image plane and acquisition of astronomical data at infrared wavelengths (less than 1 micrometer). The device uses an adjustable dichroic beamsplitter to transmit visible wavelengths to an eyepiece (or television camera), and to reflect infrared wavelengths to a port where an infrared detector system can be mounted. The instrument is intended as a multiple user facility for the Learjet telescope. This report describes the adapter and its use.

Erickson, E. F.↗
NASA NTRS1979

Two-stream theory of reflectance of snow

Spectral reflectance of snow under diffuse illumination is studied using the two-stream approximation of the radiative transfer equation. The scattering and absorption parameters of the radiative transfer equation - the single scattering albedo, the optical depth, and the integrated phase function are obtained from the grain size and density of snow. Analytical expressions for the intensity within the snowpack, the reflectance, and the asymptotic flux extinction coefficient, are given. Good agreement is shown between the theory and available experimental data on visible and near-infrared reflectance, and the asymptotic flux extinction coefficient. The theory may also be used to explain the observed effect of aging on the snow reflectance.

Choudhury, B. J.↗
NASA NTRS1978

Infrared observations of asteroids from earth and space

Infrared reflectances at wavelength between 1 and 4 micrometers are used for determining asteroid surface mineralogy, surface composition, diameters, and albedos. Thermal models were developed for analyzing infrared observations at longer wavelengths. The discovery of a spectral feature due to water of hydration on Ceres seems to contradict the mineralogy inferred from spectrophotometry.

Matson, D. L.↗
NASA NTRS1977

Polarimeter measures sea state characteristics using emitted infrared radiation

An infrared polarimeter, capable of operating between 1 and 12 micrometers wavelength has been used to measure the polarization of emitted radiation from the sea. The observed polarization at 10.6 micrometers from a smooth sea was found to be positive, indicating the dominance of reflected infrared sky radiation over the emitted. With the appearance of waves, the percent polarization increased, as expected, for a zenith angle well above the Brewster angle for water. This is qualitatively in accordance with a model presented to explain the behavior. Initial analyses indicate that the polarized components of the sea's emitted and reflected radiation are affected by type and direction of waves, angle of viewing, and foam. The effects of variations in these parameters require further delineation. The infrared polarimetric technique appears to be a novel new passive method for remote monitoring of waves.

Egan, W. G.↗
DOE OSTI2020

Improved Infrared Optical Constants from Pressed Pellets: II. Ellipsometric n and k Values for Ammonium Sulfate with Variability Analysis

Infrared spectral imaging is facilitated via the comparison of spectra recorded in situ to a databank of actual or synthetic infrared reflectance spectra. It has recently been shown that reference spectra corresponding to the many different morphological forms of the same chemical can be generated synthetically using the imaginary, k, and real, n, components of the complex refractive index, n~ = n + ik. One method to obtain the n and k vectors is infrared ellipsometry, which measures the changes in amplitude, tan ?, and phase, ?, of polarized light reflected from the sample both as a function of wavenumber and angle of incidence. The method requires specularly reflected light so best results are usually obtained with polished planar samples of large surface area. Due to the difficulties of obtaining such samples, however, we investigate the possibility of pressing powders of neat materials and obtaining the corresponding optical constants from the pellets. In this paper, variability in the sample pellet and preparation method is investigated, as is variability in the fitting procedure for the derived optical constants. The n/k vectors are derived from the measured ellipsometric parameters, tan ? and ?, as they are fit by an oscillator model which yield n(?) and k(?) vectors as a function of wavenumber, ?. Construction of the oscillator model is not automatic and depends on significant input from the analyst as well as the sample’s physical characteristics. For the pellet pressing, the experimental variability was found to be minimized for size-selected powdered samples as gauged by the minimal variance in ? and ? for three different pellets; similarly, the analytical precision for multiple measurements of the same pellet was also quite good, suggesting that a pressed pellet is a viable sample preparation method. The greatest variability came in the analytic fitting procedure with differences up to 20% arising from four different fits to the same data set. The final ellipsometric n/k data are compared to literature values obtained from crystalline (NH4)2SO4 samples as well as single-angle reflectance measurements that also used pressed pellets. Comparison with the previous literature values shows generally good agreement although higher k-values are observed for the independent sets of data derived from pressed pellets. These data are suggested as an improved set of optical constants for (NH4)2SO4.

optical constants, ellipsometry, ammonium sulfate,↗