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Enterobacter hormaechei DVZ29 was isolated from a sediment trap incubated in an 129 I plume at the Hanford Site (Washington State, USA). Whole genome sequencing of the strain resulted in 32 contigs and revealed that the genome is 4.90 Mb, with a G+C content of 55.61%.
Millions of gallons of liquid nuclear wastes generated due to nuclear weapon development during the Cold War are in tank storage at several Department of Energy (DOE) sites across the country. DOE is responsible for disposal of the tank nuclear waste and clean-up of the contaminated sites. These efforts are complex and challenging technically and are costly financially, with the predicted overall cost reaching $377 billion over the next few decades [1]. The current practice of nuclear waste treatment and tank closure is to separate high-level waste (HLW) and low-level waste (LLW) [2]. The HLW is then vitrified into a borosilicate-based glass waste form [3], while the LLW is immobilized into cementitious grout or vitrified into glass [4]. However, these treatment processes have met unsolved technical problems
S20 MRS meeting talk on FAPbI3 decomposition
Abstract not provided.
Abstract not provided.
For enhancing the effectiveness of nonproliferation efforts in neutron detection, most portable instruments rely on 6 Li scintillators, 10 B-based detectors, or gas-filled 3 He proportional counters. Additionally, gamma-ray detectors based on scintillators and semiconductors are often employed for search applications to find radioactive material in the field. These systems typically include dedicated detectors along with separate high voltage supplies and processing electronics for the gamma-ray and neutron detectors. Ideally, a portable radiation detection system should be lightweight, compact, and cost-effective. In the field, scintillators can serve a dual purpose: (1) detecting gamma-rays and (2) detecting neutrons. Gamma-ray detection with scintillators is based on the interaction of gamma-rays within the scintillating material, whereas neutron detection depends indirectly on neutron capture events. These capture events generate conversion electrons and gamma-rays, which can interact with the scintillator. For enhancing neutron capture, the scintillator can be surrounded by neutron absorber materials with a high neutron cross section. The resulting secondary electrons and gamma-rays from neutron interactions, depending on the absorber material used, can then be analyzed to detect the presence of neutron sources. Similarly, semiconductor-based detectors can be employed along with neutron absorbers as liners for neutron detection. 158 Gd has a significantly larger neutron cross section than 3 He, commonly used in gas-filled proportional counters, as shown in Figure 1. For thermal (0.025 eV) neutrons, the absorption cross section of 158 Gd is 10,000 times greater than that of 3 He (refer to Figure 1). This feature makes naturally occurring gadolinium, which consists of 24.8% 158 Gd, a promising neutron absorber material for use in combination with gamma-ray detectors–yielding a hybrid detector–for neutron detection.
Metal halide perovskite materials (MHPs) are a family of next-generation semiconductors that are enabling low-cost, high-performance solar cells and optoelectronic devices. The most-used halogen in MHPs, iodine, can supplement its octet by covalent bonding resulting in atomic charges intermediate to I− and I0. Here, we examine theoretically stabilized defects of iodine using density functional theory (DFT); defect formation enthalpies and iodine Bader charges which illustrate how MHPs adapt to stoichiometry changes. Experimentally, X-ray photoelectron spectroscopy (XPS) is used to identify perovskite defects and their relative binding energies, and validate the predicted chemical environments of iodine defects. Examining MHP samples with excess iodine compared with near stoichiometric samples, we discern additional spectral intensity in the I 3d5/2 XPS data arising from defects, and support the presence of iodine trimers. I 3d5/2 defect peak areas reveal a ratio of 2:1, matching the number of atoms at the ends and middle of the trimer, whereas their binding energies agree with calculated Bader charges. Results suggest the iodine trimer is the preferred structural motif for incorporation of excess iodine into the perovskite lattice. Understanding these easily formed photoactive defects and how to identify their presence is essential for stabilizing MHPs against photodecomposition.
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LiI thermodynamic properties in dimethyl sulfoxide determined by emf method, discussing ionic soluation energies
Electrochemistry of freshly generated titanium surfaces and stress corrosion cracking in aqueous solutions and in molten salts
The possible use of CsI to discriminate between high energy cosmic ray electrons and interacting protons has been investigated. The pulse-shape properties as a function of ionization density, temperature, and spectral response are presented for thallium-activated CsI and as a function of ionization density for sodium-activated CsI. The results are based on previously published data and on corroborative measurements from the present work. Experimental results on the response of CsI to electron-induced electromagnetic cascades and to interacting hadrons are described. Bibliographies of publications dealing with the properties of CsI and with pulse-shape discrimination techniques are presented.
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A major difficulty in medium energy gamma-ray remote sensing spectroscopy and astronomy measurements was the high rate of unwanted background resulting from the following major sources: (1) prompt secondary gamma-rays produced by cosmic-ray interactions in satellite materials; (2) direct charged-particle counts; (3) radioactivity induced in the detector materials by cosmic-ray and trapped protons; (4) radioactivity induced in detector materials by the planetary (e.g., earth or moon) albedo neutron flux; (5) radioactivity induced in the detector materials by the interaction of secondary neutrons produced throughout the spacecraft by cosmic-ray and trapped proton interactions; (6) radioactivity induced in spacecraft materials by the mechanisms outlined in 3, 4, and 5; and (7) natural radioactivity in spacecraft and detector materials. The purpose of this experiment was to obtain information on effects 3, 4, and 5, and from this information start developing calculational methods for predicting the background induced in the crystal detector in order to correct the Apollo gamma-ray spectrometer data for this interference.
In order to obtain information on radioactive background induced in the Apollo 15 and 16 gamma-ray spectrometers (7 cm x 7 cm NaI) by particle irradiation during spaceflight, and identical detector was flown and returned to earth on the Apollo 17 mission. The induced radioactivity was monitored both internally and externally from one and a half hours after splashdown. When used in conjunction with a computation scheme for estimating induced activation from calculated trapped proton and cosmic-ray fluences, these results show an important contribution resulting from both thermal and energetic neutrons produced in the heavy spacecraft by cosmic-ray interactions.
Large area ion chambers for a high energy cosmic ray experiment, scintillating plastic fibers as light pipes for a cosmic ray hodoscope, and an evaluation of clad scintillating light pipes were considered.
The performance of photomultiplier tubes (PMT's) and scintillation detector systems incorporating 50.8 by 1.27 cm NaI (T l) crystals was investigated to determine the characteristics of the photomultiplier tubes and optimize the detector geometry for the Burst and Transient Source Experiment on the Gamma Ray Observatory. Background information on performance characteristics of PMT's and NaI (T l) detectors is provided, procedures for measurement of relevant parameters are specified, and results of these measurements are presented.
A tunable diode laser spectrometer was constructed and used to study: (1) the effects of centrifugal distortion on the transition frequencies and strengths of the nu sub 2 band of H2S, and (2) nuclear quadrupole hyperfine structure in the 1-0 band of HI. A total of 126 line frequencies and 94 line strengths in the nu sub 2 band of H2S were measured. The average accuracy of the line frequency measurements was + or - 0.0016 cm. The line strengths were measured to an average accuracy of about 3 percent. The effect of the finite spectral width of the diode laser on the measurement of line strengths is discussed. The observed H2S line frequencies were fit to Watson's AS and NS reduced Hamiltonian in both the Ir and IIIr coordinate representations in order to determine the best set of rotation distortion constants for the upper state of the nu sub 2 band. Comparisons of the observed line strengths in this band to rigid rotor line strengths are also presented. Nuclear quadrupole hyperfine structure in the low J lines of the 1-0 band of HI was observed. The upper vibrational state nuclear quadrupole coupling constant, determined from the observed splittings, was -1850 MHz + or - 12 MHz or 1.2 percent + or - 0.7 percent larger than the ground state coupling constant.