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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS2013

Assessment of Error in Aerosol Optical Depth Measured by AERONET Due to Aerosol Forward Scattering

We present an analysis of the effect of aerosol forward scattering on the accuracy of aerosol optical depth (AOD) measured by CIMEL Sun photometers. The effect is quantified in terms of AOD and solar zenith angle using radiative transfer modeling. The analysis is based on aerosol size distributions derived from multi-year climatologies of AERONET aerosol retrievals. The study shows that the modeled error is lower than AOD calibration uncertainty (0.01) for the vast majority of AERONET level 2 observations, ~99.53%. Only ~0.47% of the AERONET database corresponding mostly to dust aerosol with high AOD and low solar elevations has larger biases. We also show that observations with extreme reductions in direct solar irradiance do not contribute to level 2 AOD due to low Sun photometer digital counts below a quality control cutoff threshold.

AERONET↗
NASA NTRS1995

Flight test evaluation of the E-systems Differential GPS category 3 automatic landing system

Test flights were conducted to evaluate the capability of Differential Global Positioning System (DGPS) to provide the accuracy and integrity required for International Civil Aviation Organization (ICAO) Category (CAT) III precision approach and landings. These test flights were part of a Federal Aviation Administration (FAA) program to evaluate the technical feasibility of using DGPS based technology for CAT III precision approach and landing applications. An IAI Westwind 1124 aircraft (N24RH) was equipped with DGPS receiving equipment and additional computing capability provided by E-Systems. The test flights were conducted at NASA Ames Research Center's Crows Landing Flight Facility, Crows Landing, California. The flight test evaluation was based on completing 100 approaches and landings. The navigation sensor error accuracy requirements were based on ICAO requirements for the Microwave Landing System (MLS). All of the approaches and landings were evaluated against ground truth reference data provided by a laser tracker. Analysis of these approaches and landings shows that the E-Systems DGPS system met the navigation sensor error requirements for a successful approach and landing 98 out of 100 approaches and landings, based on the requirements specified in the FAA CAT III Level 2 Flight Test Plan. In addition, the E-Systems DGPS system met the integrity requirements for a successful approach and landing or stationary trial for all 100 approaches and landings and all ten stationary trials, based on the requirements specified in the FAA CAT III Level 2 Flight Test Plan.

Kaufmann, David N.↗
DOE OSTI2023

Light-independent regulation of algal photoprotection by CO 2 availability

Photosynthetic algae have evolved mechanisms to cope with suboptimal light and CO 2 conditions. When light energy exceeds CO 2 fixation capacity, Chlamydomonas reinhardtii activates photoprotection, mediated by LHCSR1/3 and PSBS, and the CO 2 Concentrating Mechanism (CCM). How light and CO 2 signals converge to regulate these processes remains unclear. Here, we show that excess light activates photoprotection- and CCM-related genes by altering intracellular CO 2 concentrations and that depletion of CO 2 drives these responses, even in total darkness. High CO 2 levels, derived from respiration or impaired photosynthetic fixation, repress LHCSR3/CCM genes while stabilizing the LHCSR1 protein. Finally, we show that the CCM regulator CIA5 also regulates photoprotection, controlling LHCSR3 and PSBS transcript accumulation while inhibiting LHCSR1 protein accumulation. This work has allowed us to dissect the effect of CO 2 and light on CCM and photoprotection, demonstrating that light often indirectly affects these processes by impacting intracellular CO 2 levels.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

Foreword: Special Section on Multiphysics Aspects of Power Electronics Packaging—Power Die, Power Module, and Converter Level: Part 2

Power electronics are increasingly being used to condition electricity for a wide array of applications, such as transportation (on land, air, and water), data centers, radio frequency, directed energy, wind, solar, and grid-tied applications. Here, to increase power density, performance, efficiency, and reliability-as well as to reduce cost-innovations and developments are needed in the multiphysics packaging of power electronics at a die, module, and converter level. This includes fundamental R&D related to emerging high-voltage, high-temperature, and high-switching-frequency power electronics, packaging materials, thermal materials and interfaces, fluid-based thermal management technologies, reliability, condition monitoring, and prognostics. Latest developments in this area are published as a Special Section on Multiphysics Aspects of Power Electronics Packaging. The first part was published in the May 2024 issue of the IEEE Transactions on Components, Packaging and Manufacturing Technology (Volume 14, Issue 5). The second part of that Special Section is being published in this issue. A brief summary of the papers included in the second part are given below.

24 POWER TRANSMISSION AND DISTRIBUTION↗
NASA NTRS2002

Global Aerosol Remote Sensing from MODIS

The physical characteristics, composition, abundance, spatial distribution and dynamics of global aerosols are still very poorly known, and new data from satellite sensors have long been awaited to improve current understanding and to give a boost to the effort in future climate predictions. The derivation of aerosol parameters from the MODerate resolution Imaging Spectro-radiometer (MODIS) sensors aboard the Earth Observing System (EOS) Terra and Aqua polar-orbiting satellites ushers in a new era in aerosol remote sensing from space. Terra and Aqua were launched on December 18, 1999 and May 4, 2002 respectively, with daytime equator crossing times of approximately 10:30 am and 1:30 pm respectively. Several aerosol parameters are retrieved at 10-km spatial resolution (level 2) from MODIS daytime data. The MODIS aerosol algorithm employs different approaches to retrieve parameters over land and ocean surfaces, because of the inherent differences in the solar spectral radiance interaction with these surfaces. The parameters retrieved include: aerosol optical thickness (AOT) at 0.47, 0.55 and 0.66 micron wavelengths over land, and at 0.47, 0.55, 0.66, 0.87, 1.2, 1.6, and 2.1 micron over ocean; Angstrom exponent over land and ocean; and effective radii, and the proportion of AOT contributed by the small mode aerosols over ocean. To ensure the quality of these parameters, a substantial part of the Terra-MODIS aerosol products were validated globally and regionally, based on cross correlation with corresponding parameters derived from ground-based measurements from AERONET (AErosol RObotic NETwork) sun photometers. Similar validation efforts are planned for the Aqua-MODIS aerosol products. The MODIS level 2 aerosol products are operationally aggregated to generate global daily, eight-day (weekly), and monthly products at one-degree spatial resolution (level 3). MODIS aerosol data are used for the detailed study of local, regional, and global aerosol concentration, distribution, and temporal dynamics, as well as for radiative forcing calculations. We show several examples of these results and comparisons with model output.

Ichoku, Charles↗
NASA NTRSDate not supplied

MISR Level 1B2 Terrain Data (MI1B2T_V1)

The MISR instrument consists of nine pushbroom cameras which measure radiance in four spectral bands. Global coverage is achieved in nine days. The cameras are arranged with one camera pointing toward the nadir, four cameras pointing forward and four cameras pointing aftward. It takes 7 minutes for all nine cameras to view the same surface location. The view angles relative to the surface reference ellipsoid, are 0, 26.1, 45.6, 60.0, and 70.5 degrees. The spectral band shapes are nominally gaussian, centered at 443, 555, 670, and 865 nm. The Terrain data are re-projected to the terrain altitude. In this product, surface data from all cameras will appear in the same geographic location. Thus, this product is the primary input to Level 2 aerosol/surface processing, which requires co-registration of the L1B2 imagery at the surface. Clouds will still be displaced due to their elevation above the surface, but this time with respect to the terrain rather than the ellipsoid. (The mountain location T is now assigned the geographic location at T, and the Cloud at F appears at the geographic location T.) In Level 2 aerosol/surface processing, algorithms are applied to screen out the clouds. Terrain data only exist for MISR blocks containing some land. [Temporal_Coverage: Start_Date=2000-02-24; Stop_Date=] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=180] [Data_Resolution: Latitude_Resolution=563.2 km (cross-track); Longitude_Resolution=140.8 km (along-track).; Temporal_Resolution=about 15 orbits/day; Temporal_Resolution_Range=about 15 orbits/day].

NEAR IR WAVELENGTHS↗
NASA NTRSDate not supplied

MISR Level 1B2 Terrain Data (MI1B2T_V2)

The MISR instrument consists of nine pushbroom cameras which measure radiance in four spectral bands. Global coverage is achieved in nine days. The cameras are arranged with one camera pointing toward the nadir, four cameras pointing forward and four cameras pointing aftward. It takes 7 minutes for all nine cameras to view the same surface location. The view angles relative to the surface reference ellipsoid, are 0, 26.1, 45.6, 60.0, and 70.5 degrees. The spectral band shapes are nominally gaussian, centered at 443, 555, 670, and 865 nm. The Terrain data are re-projected to the terrain altitude. In this product, surface data from all cameras will appear in the same geographic location. Thus, this product is the primary input to Level 2 aerosol/surface processing, which requires co-registration of the L1B2 imagery at the surface. Clouds will still be displaced due to their elevation above the surface, but this time with respect to the terrain rather than the ellipsoid. (The mountain location T is now assigned the geographic location at T, and the Cloud at F appears at the geographic location T.) In Level 2 aerosol/surface processing, algorithms are applied to screen out the clouds. Terrain data only exist for MISR blocks containing some land. [Location=GLOBAL LAND] [Temporal_Coverage: Start_Date=2000-02-24; Stop_Date=] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=180] [Data_Resolution: Latitude_Resolution=563.2 km (cross-track); Longitude_Resolution=140.8 km (along-track).; Temporal_Resolution=about 15 orbits/day; Temporal_Resolution_Range=about 15 orbits/day].

SPECTRAL BANDS↗
NASA NTRSDate not supplied

MISR Level 1B2 Terrain Data (MI1B2T_V3)

The MISR instrument consists of nine pushbroom cameras which measure radiance in four spectral bands. Global coverage is achieved in nine days. The cameras are arranged with one camera pointing toward the nadir, four cameras pointing forward and four cameras pointing aftward. It takes 7 minutes for all nine cameras to view the same surface location. The view angles relative to the surface reference ellipsoid, are 0, 26.1, 45.6, 60.0, and 70.5 degrees. The spectral band shapes are nominally gaussian, centered at 443, 555, 670, and 865 nm. The Terrain data are re-projected to the terrain altitude. In this product, surface data from all cameras will appear in the same geographic location. Thus, this product is the primary input to Level 2 aerosol/surface processing, which requires co-registration of the L1B2 imagery at the surface. Clouds will still be displaced due to their elevation above the surface, but this time with respect to the terrain rather than the ellipsoid. (The mountain location T is now assigned the geographic location at T, and the Cloud at F appears at the geographic location T.) In Level 2 aerosol/surface processing, algorithms are applied to screen out the clouds. Terrain data only exist for MISR blocks containing some land. [Location=GLOBAL LAND] [Temporal_Coverage: Start_Date=2000-02-24; Stop_Date=] [Spatial_Coverage: Southernmost_Latitude=-90; Northernmost_Latitude=90; Westernmost_Longitude=-180; Easternmost_Longitude=180] [Data_Resolution: Latitude_Resolution=563.2 km (cross-track); Longitude_Resolution=140.8 km (along-track).; Temporal_Resolution=about 15 orbits/day; Temporal_Resolution_Range=about 15 orbits/day].

IMAGERY↗
NASA NTRS2019

EARLINET Evaluation of the CATS L2 Aerosol Backscatter Coefficient Product

We present the evaluation activity of the European Aerosol Research Lidar Network (EARLINET) for the quantitative assessment of the Level 2 aerosol backscatter coefficient product derived by the Cloud-Aerosol Transport System (CATS) onboard the International Space Station (ISS). The study employs correlative CATS and EARLINET backscatter measurements within 50km distance between the ground station and the ISS overpass and as close in time as possible, typically within 90min, from February 2015 to September 2016. The results demonstrate the good agreement of CATS Level 2 backscatter coefficient and EARLINET. Three ISS overpasses close to the EARLINET stations of Leipzig-Germany, Évora-Portugal and Dushanbe-Tajikistan are analysed here to demonstrate the performance of CATS lidar system under different conditions. The results show that under cloud-free, relative homogeneous aerosol conditions CATS is in good agreement with EARLINET, independently of daytime/nighttime conditions. CATS low negative biases, partially attributed to the deficiency of lidar systems to detect tenuous aerosol layers of backscatter signal below the minimum detection thresholds, may lead to systematic deviations and slight underestimations of the total Aerosol Optical Depth (AOD) in climate studies. In addition, CATS misclassification of aerosol layers as clouds, and vice versa, in cases of coexistent and/or adjacent aerosol and cloud features, may lead to non-representative, unrealistic and cloud contaminated aerosol profiles. The distributions of backscatter coefficient biases show the relatively good agreement between the CATS and EARLINET measurements, although on average underestimations are observed, 22.3% during daytime and 6.1% during nighttime.

EARLINET/CATS evaluation↗
DOE OSTI2024

Solar Energy Extension Project

The town of Stratford plans to develop and own a 6 kilowatt (kW) solar array on the roof of a municipal-owned public pavilion on the town green. A SolarEdge level 2 EV charging station will be installed at the pavilion to be used by the public. The charging station will have one charging port. The town will install 3 air source heat pumps in the library located adjacent to the pavilion to reduce the use of propane to heat the library. The town will install 4 air source heat pumps in the Town Hall to reduce the use of #2 heating oil to heat the facility. The 6 kW solar array will provide electricity to the library to offset electricity usage, and when an EV plugs into the charging station the solar will provide electricity to the charging station. There is no ground disturbance or ground trenching associated with this project. The 6 kW solar array on the roof of the pavilion will include 20 (390) watt all black panels. A SolarEdge level 2 EV charger will be installed at the pavilion with the 240 V inverter. The solar array will provide electricity to the library and when a vehicle plugs into the EV charger the solar array will switch to power the charger. Any excess electricity that is generated by the array and not used by the library or the EV charger will be fed onto the grid and the town will receive a net metering credit applied towards future consumption. There is no ground disturbance associated with the EV charger or solar array, and the town will install signage to direct the public to the charger. The library will install 2 (18,000) BTU ductless air source heat pumps and 1 (24,000) BTU unit. This will significantly reduce the amount of propane required to heat the library. The Town Hall will install 2 (36,000) BTU ductless air source heat pumps and 2 (9,000) BTU units to reduce the amount of #2 heating oil required to heat the building.

14 SOLAR ENERGY↗
NASA NTRS2010

Strategies for Improved CALIPSO Aerosol Optical Depth Estimates

In the spring of 2010, the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) project will be releasing version 3 of its level 2 data products. In this paper we describe several changes to the algorithms and code that yield substantial improvements in CALIPSO's retrieval of aerosol optical depths (AOD). Among these are a retooled cloud-clearing procedure and a new approach to determining the base altitudes of aerosol layers in the planetary boundary layer (PBL). The results derived from these modifications are illustrated using case studies prepared using a late beta version of the level 2 version 3 processing code.

Vaughan, Mark A.↗
NASA NTRS2016

Assessment of the SMAP Passive Soil Moisture Product

The National Aeronautics and Space Administration (NASA) Soil Moisture Active Passive (SMAP) satellite mission was launched on January 31, 2015. The observatory was developed to provide global mapping of high-resolution soil moisture and freeze-thaw state every two to three days using an L-band (active) radar and an L-band (passive) radiometer. After an irrecoverable hardware failure of the radar on July 7, 2015, the radiometer-only soil moisture product became the only operational Level 2 soil moisture product for SMAP. The product provides soil moisture estimates posted on a 36 kilometer Earth-fixed grid produced using brightness temperature observations from descending passes. Within months after the commissioning of the SMAP radiometer, the product was assessed to have attained preliminary (beta) science quality, and data were released to the public for evaluation in September 2015. The product is available from the NASA Distributed Active Archive Center at the National Snow and Ice Data Center. This paper provides a summary of the Level 2 Passive Soil Moisture Product (L2_SM_P) and its validation against in situ ground measurements collected from different data sources. Initial in situ comparisons conducted between March 31, 2015 and October 26, 2015, at a limited number of core validation sites (CVSs) and several hundred sparse network points, indicate that the V-pol Single Channel Algorithm (SCA-V) currently delivers the best performance among algorithms considered for L2_SM_P, based on several metrics. The accuracy of the soil moisture retrievals averaged over the CVSs was 0.038 cubic meter per cubic meter unbiased root-mean-square difference (ubRMSD), which approaches the SMAP mission requirement of 0.040 cubic meter per cubic meter.

passive↗
NASA NTRSDate not supplied

Improvements in CALIOP Smoke Optical Depth over Clouds

Smoke over marine stratocumulus is ubiquitous off the south west coast of Africa during biomass burning season. The vertical profile measurements provided by the CALIOP lidar are successfully able to distinguish between smoke and underlying clouds. With over 14 years of observations, the CALIOP data set is a valuable asset for quantifying the radiative impact of smoke over clouds in this region. However past studies have shown that CALIOP overestimates the base altitudes of strongly attenuating smoke layers. This is because CALIOP layer detection operates on the 532 nm attenuated backscatter signal. Smoke strongly attenuates light at this wavelength, so CALIOP feature detection at times assigns a base altitude that is higher than the true layer base for optically thick layers. This can be confirmed by the 1064 nm attenuated backscatter signal, also measured by CALIOP. In order to improve the AOD for smoke over clouds, a new algorithm has been implemented in for an upcoming CALIOP level 2 data release that will extend the base altitudes of smoke layers over clouds. Tunable restrictions are put in place to ensure that smoke bases are only extended within a reasonable smoke-to-cloud gap distance and only when there is strong reason to believe that smoke exists within the gap. This presentation will summarize the new smoke base extension algorithm and summarize its performance. We will demonstrate that base extension is primarily invoked off the south west coast of Africa as expected. We will also quantify the increase in smoke AOD that will be reported in the upcoming level 2 data release.

Jason L Tackett↗
NASA NTRS1992

Validating a large geophysical data set: Experiences with satellite-derived cloud parameters

We are validating the global cloud parameters derived from the satellite-borne HIRS2 and MSU atmospheric sounding instrument measurements, and are using the analysis of these data as one prototype for studying large geophysical data sets in general. The HIRS2/MSU data set contains a total of 40 physical parameters, filling 25 MB/day; raw HIRS2/MSU data are available for a period exceeding 10 years. Validation involves developing a quantitative sense for the physical meaning of the derived parameters over the range of environmental conditions sampled. This is accomplished by comparing the spatial and temporal distributions of the derived quantities with similar measurements made using other techniques, and with model results. The data handling needed for this work is possible only with the help of a suite of interactive graphical and numerical analysis tools. Level 3 (gridded) data is the common form in which large data sets of this type are distributed for scientific analysis. We find that Level 3 data is inadequate for the data comparisons required for validation. Level 2 data (individual measurements in geophysical units) is needed. A sampling problem arises when individual measurements, which are not uniformly distributed in space or time, are used for the comparisons. Standard 'interpolation' methods involve fitting the measurements for each data set to surfaces, which are then compared. We are experimenting with formal criteria for selecting geographical regions, based upon the spatial frequency and variability of measurements, that allow us to quantify the uncertainty due to sampling. As part of this project, we are also dealing with ways to keep track of constraints placed on the output by assumptions made in the computer code. The need to work with Level 2 data introduces a number of other data handling issues, such as accessing data files across machine types, meeting large data storage requirements, accessing other validated data sets, processing speed and throughput for interactive graphical work, and problems relating to graphical interfaces.

Kahn, Ralph↗
NASA NTRSDate not supplied

Open Source Application of Fusing Aerosol Products from GEO and LEO Satellites

Retrieving aerosol optical depths (AODs) from sun-synchronous polar orbiting (aka low earth orbit, LEO) satellites, such as MODISs, and VIIRSs, OMI, TROPOMI, etc, has become well-established as a tool for extracting information on particulate matter (PM) and related processes in the atmosphere. However, with recently launched geostationary satellites (GEO), such as GOES-16/17/18, and Himawari-8/9, and Meteosat Third Generation (MTG) they provide a much higher temporal resolution (order of 10 minutes), typically an image once or more per hour during daylight compared to LEO once per day. By combining these observations, we may be able to characterize the diurnal cycle of global AOD at the local, regional and global scale. While the science community is still exploring the new data from GEO observations, we have been thinking about how to properly combine/merge/fuse those data considering differences in their spatial and temporal resolutions. However, this poses a “Big Data” challenge. The big data challenge is not just about data storage, but also about data discoverability, and accessibility, and even more, about data migration/mirroring in the cloud-computing environment. This paper is merely showing some of the efforts and approaches we have attempted in fusing six satellites’ Level 2 aerosol data (three are from GEO (GOES-16/17 and Himawari-8), and the other three are from LEO (TERRA/MODIS, AQUA/MODIS, SNPP-VIIRS) from Dark Target (DT) aerosol retrieval algorithm. Having the on-demand capability of fusing remote sensing products onto the desired temporal and spatial domain enables researchers and application practitioners to better manipulate and work with satellite and sensor data. It is our hopeWe hope that by making such an open-source package, and the accompanying functionality, the scientific community will be granted easier access to aerosol data processing resources. The MEaSUREs Program (Making Earth System Data Records for Use in Research Environments) expands our understanding of the Earth's current system through atmospheric and surface measurements. In an effort to aid the scientific research component and improve open source methods, this project developed Python code for fusing six satellite Level 2 aerosol data (three are from geostationary satellites (GEO), and the other three are from low earth orbital satellites (LEO)) from Dark Target Aerosol Retrieval Algorithm.

Jennifer Wei↗
NASA NTRS2020

The AERONET Version 3 Aerosol Retrieval Algorithm, Associated Uncertainties and Comparisons to Version 2

The Aerosol Robotic Network (AERONET) Version 3 (V3) aerosol retrieval algorithm is described, which is based on the Version 2 (V2) algorithm with numerous updates. Comparisons of V3 aerosol retrievals to those of V2 are presented, along with a new approach to estimate uncertainties in many of the retrieved aerosol parameters. Changes in the V3 aerosol retrieval algorithm include (1) a new polarized radiative transfer code (RTC), which replaced the scalar RTC of V2, (2) detailed characterization of gas absorption by adding NO2 and H2O to specify total gas absorption in the atmospheric column, specification of vertical profiles of all the atmospheric species, (3) new bidirectional reflectance distribution function (BRDF) parameters for land sites adopted from the MODIS BRDF/Albedo product, (4) a new version of the extraterrestrial solar flux spectrum, and (5) a new temperature correction procedure of both direct Sun and sky radiance measurements. The potential effect of each change in V3 on single scattering albedo (SSA) retrievals was analyzed. The operational almucantar retrievals of V2 versus V3 were compared for four AERONET sites: GSFC, Mezaira, Mongu, and Kanpur. Analysis showed very good agreement in retrieved parameters of the size distributions. Comparisons of SSA retrievals for dust aerosols (Mezaira) showed a good agreement in 440 nm SSA, while for longer wavelengths V3 SSAs are systematically higher than those of V2, with the largest mean difference at 675 nm due to cumulative effects of both extraterrestrial solar flux and BRDF changes. For non-dust aerosols, the largest SSA deviation is at 675 nm due to differences in extraterrestrial solar flux spectrums used in each version. Further, the SSA 675 nm mean differences are very different for weakly (GSFC) and strongly (Mongu) absorbing aerosols, which is explained by the lower sensitivity to a bias in aerosol scattering optical depth by less absorbing aerosols. A new hybrid (HYB) sky radiance measurement scan is introduced and discussed. The HYB combines features of scans in two different planes to maximize the range of scattering angles and achieve scan symmetry, thereby allowing for cloud screening and spatial averaging, which is an advantage over the principal plane scan that lacks robust symmetry. We show that due to an extended range of scattering angles, HYB SSA retrievals for dust aerosols exhibit smaller variability with solar zenith angles (SZAs) than those of almucantar (ALM), which allows extension of HYB SSA retrievals to SZAs less than 50∘ to as small as 25∘. The comparison of SSA retrievals from closely time-matched HYB and ALM scans in the 50 to 75∘ SZA range showed good agreement with the differences below ∼0.005. We also present an approach to estimate retrieval uncertainties which utilizes the variability in retrieved parameters generated by perturbing both measurements and auxiliary input parameters as a proxy for retrieval uncertainty. The perturbations in measurements and auxiliary inputs are assumed as estimated biases in aerosol optical depth (AOD), radiometric calibration of sky radiances combined with solar spectral irradiance, and surface reflectance. For each set of Level 2 Sun/sky radiometer observations, 27 inputs corresponding to 27 combinations of biases were produced and separately inverted to generate the following statistics of the inversion results: average, standard deviation, minimum and maximum values. From these statistics, standard deviation (labeled U27) is used as a proxy for estimated uncertainty, and a lookup table (LUT) approach was implemented to reduce the computational time. The U27 climatological LUT was generated from the entire AERONET almucantar (1993–2018) and hybrid (2014–2018) scan databases by binning U27s in AOD (440 nm), Angström exponent (AE, 440–870 nm), and SSA (440, 675, 870, 1020 nm). Using this LUT approach, the uncertainty estimates U27 for each individual V3 Level 2 retrieval can be obtained by interpolation using the corresponding measured and inverted combination of AOD, AE, and SSA.

Aliaksandr Siniuk↗
DOE OSTI2025

Electro-activated indigos intensify ampere-level CO 2 reduction to CO on silver catalysts

The electrochemical reduction of carbon dioxide (CO 2 ) to carbon monoxide (CO) is challenged by a selectivity decline at high current densities. Here we report a class of indigo-based molecular promoters with redox-active CO 2 binding sites to enhance the high-rate conversion of CO 2 to CO on silver (Ag) catalysts. Theoretical calculations and in situ spectroscopy analyses demonstrate that the synergistic effect at the interface of indigo-derived compounds and Ag nanoparticles could activate CO 2 molecules and accelerate the formation of key intermediates (*CO 2 – and *COOH) in the CO pathway. Indigo derivatives with electron-withdrawing groups further reduce the overpotential for CO production upon optimizing the interfacial CO 2 binding affinity. By integrating the molecular design of redox-active centres with the defect engineering of Ag structures, we achieve a Faradaic efficiency for CO exceeding 90% across a current density range of 0.10 − 1.20 A cm –2 . The Ag mass activity toward CO increases to 174 A mg –1 Ag . This work showcases that employing redox-active CO 2 sorbents as surface modification agents is a highly effective strategy to intensify the reactivity of electrochemical CO 2 reduction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Discerning molecular-level CO 2 adsorption behavior in amine-modified sorbents within a controlled CO 2 /H 2 O environment towards direct air capture

Sorbents designed for direct air capture (DAC) play a crucial role in the pursuit of achieving net-zero carbon dioxide emissions. This study elucidates CO 2 adsorption from dilute, humidified CO 2 streams onto an amine-modified benchmark DAC adsorbent via solid-state NMR spectroscopy. Various NMR techniques, including 1D 1 H MAS, 13 C MAS, 2D 1 H– 13 C HETCOR NMR, and 1 H R 2 and R 1ρ relaxometry reveal the impact of CO 2 partial pressure and H 2 O on CO 2 adsorption behavior. Here we find that CO 2 concentration governs the stepwise formation of ammonium carbamate, carbamic acid, and physisorbed CO 2 , where relative humidity (RH) at a desired low (<400 ppm) CO 2 loading affects total CO 2 uptake. The relaxation studies reveal the cooperative or competitive nature of H 2 O–CO 2 sorption in CO 2 -dilute humid gas, and in particular polymer swelling upon humidification. From those results, we demonstrate that the observed absorption capacity enhancement by humidity is caused by pore opening due to sorbent swelling, and not by bicarbonate formation. This NMR-discerned speciation provides insights into sorption behavior at different RHs in dilute CO 2 gas streams, simulating real-world atmospheric conditions, and governs the design of efficient and adaptable material-process combinations for solid sorbent DAC.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗