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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13

Requirements for long-life operation of inert gas hollow cathodes: Preliminary report

An experimental investigation was initiated to establish conditioning procedures for reliable hollow cathode operation via the characterization of critical parameters in a representative cathode test facility. From vacuum pumpdown rates, it was found that approximately 1.5 hours were required to achieve pressure levels within 5 percent of the lowest attainable pressure for this facility, depending on the purge conditions. The facility atmosphere was determined by a residual gas analyzer to be composed of primarily air and water vapor. The effects of vacuum pumping and inert gas purging were evaluated. A maximum effective leakage rate of 2.0 x 10(exp -3)sccm was observed and its probable causes were examined. An extended test of a 0.64 cm diameter Mo-Re hollow cathode was successfully completed. This test ran for 504 hours at an emission current of 23.0 amperes and a xenon flow rate of 6.1 sccm. Discharge voltage rose continuously from 15 to 21 volts over the course of the test. The temperature of the cathode body during the test was relatively stable at 1160 C. Post-test examination revealed ion-bombardment texturing of the orifice plate to be the only detectable sign of wear on the hollow cathode.

Verhey, Timothy R.↗

Recent advances in efficient long-life, eye-safe solid state and CO2 lasers for laser radar applications

The key problems in the development of eye-safe solid-state lasers are discussed, taking into account the energy transfer mechanisms between the complicated energy level manifolds of the Tm, Ho, Er ion dopants in hosts with decreasing crystal fields such as YAG or YLF. Optimization of energy transfer for efficient lasing through choice of dopant concentration, power density, crystal field and temperature is addressed. The tailoring of energy transfer times to provide efficient energy extraction for short pulses used in DIAL and Doppler lidar is considered. Recent advances in Pt/SnO2 oxide catalysts and other noble metal/metal oxide combinations for CO2 lasers are discussed. Emphasis is given to the dramatic effects of small quantities of H2O vapor for increasing the activity and lifetime of Pt/SnO2 catalysts and to increased lifetime operation with rare isotope (C-12)(O-18)2 lasing mixtures.

Hess, R. V.↗

Materials selection for long life in low earth orbit - A critical evaluation of atomic oxygen testing with thermal atom systems

The use of thermal atom test methods as a materials selection and screening technique for low-earth orbit (LEO) spacecraft is critically evaluated. The chemistry and physics of thermal atom environments are compared with the LEO environment. The relative reactivities of a number of materials determined in thermal atom environments are compared with those observed in LEO and in high-quality LEO simulations. Reaction efficiencies (cu cm/atom) measured in a new type of thermal atom apparatus are one-thousandth to one ten-thousandth those observed in LEO, and many materials showing nearly identical reactivities in LEO show relative reactivities differing by as much as a factor of eight in thermal atom systems. A simple phenomenological kinetic model for the reaction of oxygen atoms with organic materials can be used to explain the differences in reactivity in different environments. Certain speciic thermal atom test environments can be used as reliable materials screening tools.

Koontz, S. L.↗

Requirements for long-life operation of inert gas hollow cathodes - Preliminary results

An experimental investigation was initiated to establish conditioning procedures for reliable hollow cathode operation via the characterization of critical parameters in a representative cathode test facility. From vacuum pumpdown rates, it was found that approximately 1.5 hours were required to achieve pressure levels within 5 percent of the lowest attainable pressure for this facility, depending on the purge conditions. The facility atmosphere was determined by a residual gas analyzer to be composed of primarily air and water vapor. The effects of vacuum pumping and inert gas purging were evaluated. A maximum effective leakage rate of 2.0 x 10 (exp -3) sccm was observed and its probable causes were examined. An extended test of a 0.64 cm diameter Mo-Re hollow cathode was successfully completed. This test ran for 504 hours at an emission current of 23.0 amperes and a xenon flow rate of 6.1 sccm. Discharge voltage rose continuously from 15 to 21 volts over the course of the test. The temperature of the cathode body during the test was relatively stable at 1160 C. Post-test examination revealed ion-bombardment texturing of the orifice plate to be the only detectable sign of wear on the hollow cathode.

Verhey, Timothy R.↗

Development of long-life, low-noise linear bearings for atmospheric interferometry

This paper describes the development of dry-lubricated linear bearings for use on the Michelson interferometer for passive atmospheric sounding (MIPAS). Two candidate bearing systems were developed and tested. In the first, use was made of linear roller (needle) bearings equipped with a pulley-and-cable arrangement to prevent cage drift and to minimize roller slip. The second design was of a roller-guided bearing system in which guidance was provided by all bearings rolling along guide rods. The paper focuses on the development of these linear bearings systems and describes the approach taken in terms of bearing design, lubrication methods, screening programs, and thermal-vacuum testing. Development difficulties are highlighted and the solutions ultimately adopted are described.

Roberts, E. W.↗

Mechanical system reliability for long life space systems

The creation of a compendium of mechanical limit states was undertaken in order to provide a reference base for the application of first-order reliability methods to mechanical systems in the context of the development of a system level design methodology. The compendium was conceived as a reference source specific to the problem of developing the noted design methodology, and not an exhaustive or exclusive compilation of mechanical limit states. The compendium is not intended to be a handbook of mechanical limit states for general use. The compendium provides a diverse set of limit-state relationships for use in demonstrating the application of probabilistic reliability methods to mechanical systems. The compendium is to be used in the reliability analysis of moderately complex mechanical systems.

Kowal, Michael T.↗

Transition-Metal Additives For Long-Life Na/NiCI(2) Cells

Transition-metal additives in cathodes of Na/NiCI(2) high-temperature, rechargeable electrochemical cells found to slow premature fading of charge/discharge capacity. Decline in capacity of cell attributed to agglomeration of Ni particles at cathode: this agglomeration reduces electrochemical area of cathode. Depending on choice of transition-metal additive for particular cell, additive might even participate in desired electrochemical reactions in cell, contributing to specific energy of cell.

Bugga, Ratnakumar V.↗

Long Life Na/NiCl2 Cells

The premature capacity failure of Na/NiCl2 secondary cells due to agglomeration of nickel particles on the surface of the NiCl2 cathode is prevented by addition of a minor amount such as 10 percent by weight of a transition metal such as Co, Fe or Mn to the cathode. The chlorides of the transition metals have lower potentials than nickel chloride and chlorinate during charge. A uniform dispersion of the transition metals in the cathodes prevents agglomeration of nickel, maintains morphology of the electrode, maintains the electrochemical area of the electrode and thus maintains capacity of the electrode. The additives do not effect sintering. The addition of sulfur to the liquid catholyte is expected to further reduce agglomeration of nickel in the cathode.

Bugga, Ratnakumar V.↗

Long Life Nickel Electrodes for Nickel-Hydrogen Cells: Fiber Substrates Nickel Electrodes

Samples of nickel fiber mat electrodes were investigated over a wide range of fiber diameters, electrode thickness, porosity and active material loading levels. Thickness' were 0.040, 0.060 and 0.080 inches for the plaque: fiber diameters were primarily 2, 4, and 8 micron and porosity was 85, 90, and 95%. Capacities of 3.5 in. diameter electrodes were determined in the flooded condition with both 26 and 31% potassium hydroxide solution. These capacity tests indicated that the highest capacities per unit weight were obtained at the 90% porosity level with a 4 micron diameter fiber plaque. It appeared that the thinner electrodes had somewhat better performance, consistent with sintered electrode history. Limited testing with two-positive-electrode boiler plate cells was also carried out. Considerable difficulty with constructing the cells was encountered with short circuits the major problem. Nevertheless, four cells were tested. The cell with 95% porosity electrodes failed during conditioning cycling due to high voltage during charge. Discharge showed that this cell had lost nearly all of its capacity. The other three cells after 20 conditioning cycles showed capacities consistent with the flooded capacities of the electrodes. Positive electrodes made from fiber substrates may well show a weight advantage of standard sintered electrodes, but need considerably more work to prove this statement. A major problem to be investigated is the lower strength of the substrate compared to standard sintered electrodes. Problems with welding of leads were significant and implications that the electrodes would expand more than sintered electrodes need to be investigated. Loading levels were lower than had been expected based on sintered electrode experiences and the lower loading led to lower capacity values. However, lower loading causes less expansion and contraction during cycling so that stress on the substrate is reduced.

Rogers, Howard H.↗

Light Weight Long Life Materials and Structures

High performance materials are enabling or enhancing for numerous engine/vehicle concepts and are critical to meeting safety, cost, and performance goals. A subproject covers polymeric, metallic, and ceramic high temperature materials for rocket propulsion systems. Projects will also include a wide variety of efforts with some fundamental work with late maturity dates.

Glasgow, Tom↗

Design and Manufacturing Processes of Long-Life Hollow Cathode Assemblies

The design and manufacturing processes for Hollow Cathode Assemblies (HCA's) that operate over a broad range of emission currents up to 30 Amperes, at low potentials, with lifetimes in excess of 17,500 hours. The processes include contamination control procedures which cover hollow cathode component cleaning procedures, gas feed system designs and specifications, and hollow cathode activation and operating procedures to thereby produce cathode assemblies that have demonstrated stable and repeatable operating conditions, for both the discharge current and voltage. The HCA of this invention provides lifetimes of greater than 10,000 hours, and expected lifetimes of greater than 17,500 hours, whereas the present state-of-the-art is less than 500 hours at emission currents in excess of 1 Ampere. Stable operation is provided over a large range of operating emission currents, up to a 6:1 ratio, and this HCA can emit electron currents of up to 30 Amperes in magnitude to an external anode that simulates the current drawn to a space plasma at voltages of less than 20 Volts.

Michael J Patterson↗

Long-Life Catalyst

STC Catalysts, Inc. (SCi) manufactures a noble metal reducible oxide catalyst consisting primarily of platinum and tin dioxide deposited on a ceramic substrate. It is an ambient temperature oxidation catalyst that was developed primarily for Carbon Dioxide Lasers.The catalyst was developed by the NASA Langley Research Center for the Laser Atmospheric Wind Sounder Program (LAWS) which was intended to measure wind velocity on a global basis. There are a number of NASA owned patents covering various aspects of the catalyst.

Source record↗

Design and Manufacturing Processes of Long-Life Hollow Cathode Assembles

A process for testing an impregnated insert of a Hollow Cathode Assembly (HCA) subsequent to every exposure of the HCA to air, and prior to ignition, using a heater and an oil-free assembly having a base pressure of less than 5.0 x 10(exp -6) torr. The process comprises the steps of: installing the HCA in a vacuum; energizing the heater to a particular current level; de-energizing the heater after one-half hour; again energizing the heater to a particular current level; and de-energizing the heater for at least one-half hour.

Michael J Patterson↗

Oil-Free Rotor Support Technologies for Long Life, Closed Cycle Brayton Turbines

The goal of this study is to provide technological support to ensure successful life and operation of a 50-300 kW dynamic power conversion system specifically with response to the rotor support system. By utilizing technical expertise in tribology, bearings, rotordynamic, solid lubricant coatings and extensive test facilities, valuable input for mission success is provided. A discussion of the history of closed cycle Brayton turboalternators (TA) will be included. This includes the 2 kW Mini-Brayton Rotating Unit (Mini-BRU), the 10kW Brayton Rotating Unit (BRU) and the 125 kW turboalternator-compressor (TAC) designed in mid 1970's. Also included is the development of air-cycle machines and terrestrial oil-free gas turbine power systems in the form of microturbines, specifically Capstone microturbines. A short discussion of the self-acting compliant surface hydrodynamic fluid film bearings, or foil bearings, will follow, including a short history of the load capacity advances, the NASA coatings advancements as well as design model advances. Successes in terrestrial based machines will be noted and NASA tribology and bearing research test facilities will be described. Finally, implementation of a four step integration process will be included in the discussion.

Lucero, John M.↗