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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13

Optimal Reconfiguaration and Resilient Control Framework for Real-Time Photopholtaic Dispatch to Manage Critical Infrastructure (ReDis-PV)

The consortium is conducting cutting-edge collaborative research that will allow advancing solar energy’s role in strengthening the resilience of the U.S. electricity grid. The U.S Department of Energy Solar Technologies Office (SETO) has awarded 4.6 million to Professor Sukumar Kamalasadan (The University of North Carolina at Charlotte) for the project “Optimal Reconfiguration and Resilient Control Framework for Real-Time Photovoltaic Dispatch to Manage Critical Infrastructure (ReDis-PV)”. The project developed a grid management tool that detects cyber and physical threats and forms dynamic clusters to manage photovoltaic and energy optimally. The project collaborating team includes the University of North Carolina at Charlotte, Clemson University, New Mexico State University, Florida International University, Argonne National Laboratory, Idaho National Laboratory, OPAL-RT Corporation, and Duke Energy.

14 SOLAR ENERGY↗

Self-Aware Local Autonomous and Semi-Cooperative Control for Cross-Layered Resilience (SLAC3R)

The objective of this work is to develop and demonstrate novel, adaptive, lightweight algorithms that enable the decision-making agents in a large cyber-physical network to act both autonomously and in collaborative harmony to enforce assured resilience across spatiotemporal layers, even under unforeseen adversarial scenarios (e.g., high- impact-low-probability events). Towards this end, the proposed solution will serve as minimally invasive add-on layers that bridge the existing (faster, reactive) local myopic controls and (slower, predictive) centralized optimization. Importantly, the proposed algorithms will enable the multi-agent network to autonomously and collaboratively enforce resilient operation under no or limited communication environment typical of severe cyber- physical adversarial events. The expected outcome of this effort is a suite of prototype, open-source, software algorithms for safety-aware local autonomous and semi-cooperative control (SLAC3R), demonstrated on networked microgrids (via RD2C/Thrust-1 OPAL-RT testbed).

97 MATHEMATICS AND COMPUTING↗

High-Efficiency Solar-To-Fuel Photoelectrochemistry in Disordered Photonic Glass Electrodes (Final Technical Report)

This project investigated how photonic glass (PG) photoelectrodes—disordered arrangements of dielectric scatterers—can serve as scalable, tunable platforms for light trapping in photoelectrochemical (PEC) solar-to-fuel systems. By leveraging disorder-driven optical phenomena such as multiple scattering resonances and light localization, PG structures offer an alternative to conventional photonic crystals and inverse opals that require high structural precision. The scientific goals were to twofold: (1) develop approaches to predictive models for high performance PG electrodes based on light absorption simulations, and (2) fabricate, characterize, and optimize PG-based photoelectrodes for solar-to-hydrogen and solar-to-fuel photoelectrochemical applications. To overcome the complexity of ensemble optical simulations for disordered materials, the researchers developed a machine-learning-accelerated emulation of all configurations in the design space. With this approach, PG photoelectrodes based on a TiO2 semiconductor were designed to enhance PEC currents of up to one hundred times higher than the equivalent ultra-thin film photoanodes and several times higher than the equivalent photonic crystal. The research also explored integrated systems for electrochemical hydrogen production based on replacing water oxidation with the specific glycerol oxidation electrocatalysis. Overall, the project outlined an approach to a simple-to-fabricate photoelectrode system to drive photoelectrochemical reactions relevant to solar photochemical energy conversion.

14 SOLAR ENERGY↗

$α_S$ from non-strange hadronic $τ$ decays

We review how the current precision attained in the extraction of $α_s(m_τ)$ from hadronic $τ$ decays requires the inclusion of Duality Violations (DVs) in the analysis, even though these decays are largely dominated by perturbation theory. A weighted average using the OPAL and ALEPH experimental data yields $αs(m_Z) =$ 0.1165$±$0.0012 and $αs(m_Z) =$ 0.1185$±$0.0015 in fixed-orderand contour-improved perturbation theory, respectively.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Comparative and Cost Analysis of a Novel Predictive Power Ramp Rate Control Method: A Case Study in a PV Power Plant in Puerto Rico

One of the most important aspects that need to be addressed to increase solar energy penetration is the power ramp-rate control. In weak grids such as the one found in Puerto Rico, it is important to smooth power fluctuations caused by the intermittence of passing clouds. In this work, a novel power ramp-rate control strategy is proposed. Additionally, a comparison with some of the most common power ramp-rate control methods is performed using a proposed model and real solar radiation data from the Coto Laurel photovoltaic power plant located in Ponce, Puerto Rico. The proposed model was validated using one-year real data from Coto Laurel. The power ramp-rate control methods were compared in real-time simulations using the OP5700 from Opal-RT Technologies considering power ramp rate fluctuations, power ramp-rate violations, fluctuations in the state-of-charge, among other indicators. Moreover, the proposed power ramp-rate control strategy, called predictive dynamic smoothing was explained and compared. Results indicate that the predictive dynamic smoothing produced a considerably reduced Levelized Cost of Storage compared to other power ramp-rate control methods and provided a higher lifetime expectancy for lithium batteries.

36 MATERIALS SCIENCE↗

Methodology to Implement a Microgrid in a University Campus

This paper presents the method we followed to design a microgrid at a university campus based on available resources. Due to introduction of renewable resources to produce energy, a methodology that allows design a microgrid in a university campus is very useful. Hence, we present a series of steps that must be carried out to estimate the resource to be used, the installation, area needed, and the capacity of the systems needed are also described. In addition, the models of the distributed resources that constitutes the microgrid are presented and explained. To validate the proposed methodology, simulations were performed using Opal-RT-LAb. As a test scenario we selected the Mayagüez campus of the University of Puerto Rico where we conducted analysis of the available resource and capacity of the systems is needed to satisfy demand of critical loads, considering a predetermined number of days of austerity. Our study results in determination of dimensions, cost and effectiveness of the microgrid. Simulations results also show that the proposed microgrid satisfy demand with the same reliability, or better, than the traditional electrical network. Additionally, the best options for this purpose are photovoltaic, batteries, and combined heat and power, if the technological advances and availability of resources to the date for Puerto Rico are considered.

36 MATERIALS SCIENCE↗

Opacity Effects on Pulsations of Main-Sequence A-Type Stars

Here, opacity enhancements for stellar interior conditions have been explored to explain observed pulsation frequencies and to extend the pulsation instability region for B-type main-sequence variable stars. For these stars, the pulsations are driven in the region of the opacity bump of Fe-group elements at ~200,000 K in the stellar envelope. Here we explore effects of opacity enhancements for the somewhat cooler main-sequence A-type stars, in which p-mode pulsations are driven instead in the second helium ionization region at ~50,000 K. We compare models using the new LANL OPLIB vs. LLNL OPAL opacities for the AGSS09 solar mixture. For models of two solar masses and effective temperature 7600 K, opacity enhancements have only a mild effect on pulsations, shifting mode frequencies and/or slightly changing kinetic-energy growth rates. Increased opacity near the bump at 200,000 K can induce convection that may alter composition gradients created by diffusive settling and radiative levitation. Opacity increases around the hydrogen and 1st He ionization region (~13,000 K) can cause additional higher-frequency p modes to be excited, raising the possibility that improved treatment of these layers may result in prediction of new modes that could be tested by observations. New or wider convective zones and higher convective velocities produced by opacity increases could also affect angular momentum transport during evolution. More work needs to be done to quantify the effects of opacity on the boundaries of the pulsation instability regions for A-type stars.

79 ASTRONOMY AND ASTROPHYSICS↗

SOLAR OPACITY CALCULATIONS USING THE SUPER-TRANSITION-ARRAY METHOD

A new opacity model has been developed based on the Super-Transition-Array (STA) method for the calculation of monochromatic opacities of plasmas in local thermodynamic equilibrium. The atomic code, named STAR (STA-Revised), is described and used to calculate spectral opacities for a solar model implementing the recent AGSS09 composition. Calculations are carried out throughout the solar radiative zone. The relative contributions of different chemical elements and atomic processes to the total Rosseland mean opacity are analyzed in detail. Monochromatic opacities and charge-state distributions are compared with the widely used Opacity Project (OP) code, for several elements near the radiation–convection interface. STAR Rosseland opacities for the solar mixture show a very good agreement with OP and the OPAL opacity code throughout the radiation zone. Finally, an explicit STA calculation was performed of the full AGSS09 photospheric mixture, including all heavy metals. It was shown that, due to their extremely low abundance, and despite being very good photon absorbers, the heavy elements do not affect the Rosseland opacity.

79 ASTRONOMY AND ASTROPHYSICS↗

An Expanded Set of Los Alamos OPLIB Tables in MESA: Type-1 Rosseland-mean Opacities and Solar Models

Abstract We present a set of 1194 Type-1 Rosseland-mean opacity tables for four different metallicity mixtures. These new Los Alamos OPLIB atomic radiative opacity tables are an order of magnitude larger in number than any previous opacity table release, and span regimes where previous opacity tables have not existed. For example, the new set of opacity tables expands the metallicity range to Z = 10 −6 to Z = 0.2, which allows improved accuracy of opacities at low and high metallicity, increases the table density in the metallicity range Z = 10 −4 to Z = 0.1 to enhance the accuracy of opacities drawn from interpolations across neighboring metallicities, and adds entries for hydrogen mass fractions between X = 0 and X = 0.1 including X = 10 −2 , 10 −3 , 10 −4 , 10 −5 , 10 −6 that can improve stellar models of hydrogen deficient stars. We implement these new OPLIB radiative opacity tables in MESA and find that calibrated solar models agree broadly with previously published helioseismic and solar neutrino results. We find differences between using the new 1194 OPLIB opacity tables and the 126 OPAL opacity tables range from ≈20% to 80% across individual chemical mixtures, up to ≈8% and ≈15% at the bottom and top of the solar convection zone respectively, and ≈7% in the solar core. We also find differences between standard solar models using different opacity table sources that are on par with altering the initial abundance mixture. We conclude that this new, open-access set of OPLIB opacity tables does not solve the solar modeling problem, and suggest the investigation of physical mechanisms other than the atomic radiative opacity.

79 ASTRONOMY AND ASTROPHYSICS↗

Radiance calibration of the High Altitude Observatory white-light coronagraph on Skylab

The processing of over 35,000 photographs of the solar corona obtained by the white-light coronograph on Skylab is described. Calibration of the vast amount of data was complicated by temporal effects of radiation fog and latent image loss. These effects were compensated by imaging a calibration step wedge on each data frame. Absolute calibration of the wedge was accomplished through comparison with a set of previously calibrated glass opal filters. Analysis employed average characteristic curves derived from measurements of step wedges from many frames within a given camera half-load. The net absolute accuracy of a given radiance measurement is estimated to be 20%.

Poland, A. I.↗

Evaluation of LANDSAT MSS vs TM simulated data for distinguishing hydrothermal alteration

The LANDSAT Follow-On (LFO) data was simulated to demonstrate the mineral exploration capability of this system for segregating different types of hydrothermal alteration and to compare this capability with that of the existing LANDSAT system. Multispectral data were acquired for several test sites with the Bendix 24-channel MSDS scanner. Contrast enhancements, band ratioing, and principal component transformations were used to process the simulated LFO data for analysis. For Red Mountain, Arizona, the LFO data allowed identification of silicified areas, not identifiable with LANDSAT 1 and 2 data. The improved LFO resolution allowed detection of small silicic outcrops and of a narrow silicified dike. For Cuprite - Ralston, Nevada, the LFO spectral bands allowed discrimination of argillic and opalized altered areas; these could not be spectrally discriminated using LANDSAT 1 and 2 data. Addition of data from the 1.3- and 2.2- micrometer regions allowed better discriminations of hydrothermal alteration types.

Abrams, M. J.↗

Studies in optical parallel processing

Threshold and A/D devices for converting a gray scale image into a binary one were investigated for all-optical and opto-electronic approaches to parallel processing. Integrated optical logic circuits (IOC) and optical parallel logic devices (OPA) were studied as an approach to processing optical binary signals. In the IOC logic scheme, a single row of an optical image is coupled into the IOC substrate at a time through an array of optical fibers. Parallel processing is carried out out, on each image element of these rows, in the IOC substrate and the resulting output exits via a second array of optical fibers. The OPAL system for parallel processing which uses a Fabry-Perot interferometer for image thresholding and analog-to-digital conversion, achieves a higher degree of parallel processing than is possible with IOC.

Lee, S. H.↗

Measurements of the absorption coefficient of stratospheric aerosols

The absorption coefficients of stratospheric aerosols are measured using a variation on the integrating plate method. The technique is based on the decrease in the transparency of a substrate when an absorbing aerosol is deposited on it. A Lambert scatterer is placed behind the substrate to integrate forward scattered light and minimize the effect of scattering on the measurement. The low pressure in the stratosphere is used for the direct impaction of particles onto a narrow strip of opal glass. The eight samples collected had a median value of 4 x 10 to the -9th m with an uncertainty of + or - 5 x 10 to the -9th m. If this absorption is due to graphitic carbon, then its concentration is estimated at about 0.4 ng/cu m, or about 0.25% of the total aerosol mass concentration. Estimates of the aerosol scattering coefficients based on satellite extinction inversions result in an aerosol single-scattering albedo in the range of 0.96-1.0.

Ogren, J. A.↗

Low-energy gamma rays from Cygnus X-1

The Cyg X-1 was observed by the balloonborne telescope OPALE, in June 1976. The high energy spectrum of the source, which was in its superlow state, was seen to extend well beyond 1 MeV. The observed low energy gamma ray component of Cyg X-1 is compared with the predictions of recent models involving accretion onto a stellar black hole, and including a possible contribution from the pair annihilation 511 keV gamma ray line.

Roques, J. P.↗

Weathering of sulfides on Mars

Pyrrhotite-pentlandite assemblages in mafic and ultramafic igneous rocks may have contributed significantly to the chemical weathering reactions that produce degradation products in the Martian regolith. By analogy and terrestrial processes, a model is proposed whereby supergene alteration of these primary Fe-Ni sulfides on Mars has generated secondary sulfides (e.g., pyrite) below the water table and produced acidic groundwater containing high concentrations of dissolved Fe, Ni, and sulfate ions. The low pH solutions also initiated weathering reactions of igneous feldspars and ferromagnesian silicates to form clay silicate and ferric oxyhydroxide phases. Near-surface oxidation and hydrolysis of ferric sulfato-and hydroxo-complex ions and sols formed gossan above the water table consisting of poorly crystalline hydrated ferric sulfates (e.g., jarosite), oxides (ferrihydrite, goethite), and silica (opal). Underlying groundwater, now permafrost contains hydroxo sulfato complexes of Fe, Al, Mg, Ni, which may be stabilized in frozen acidic solutions beneath the surface of Mars. Sublimation of permafrost may replenish colloidal ferric oxides, sulfates, and phyllosilicates during dust storms on Mars.

Burns, Roger G.↗

Sampling the oxidative weathering products and the potentially acidic permafrost on Mars

Large areas of Mars' surface are covered by oxidative weathering products containing ferric and sulfate ions having analogies to terrestrial gossans derived from sulfide mineralization associated with iron-rich basalts. Chemical weathering of such massive and disseminated pyrrhotite-pentlandite assemblages and host basaltic rocks in the Martian environment could have produced metastable gossaniferous phases (limonite containing poorly crystalline hydrated ferric sulfates and oxyhydroxides, clay silicates and opal). Underlying groundwater, now permafrost on Mars, may still be acidic due to incomplete buffering reactions by wall-rock alteration of unfractured host rock. Such acidic solutions stabilize temperature-sensitive complex ions and sols which flocculate to colloidal precipitates at elevated temperatures. Sampling procedures of Martian regolith will need to be designed bearing in mind that the frozen permafrost may be corrosive and be stabilizing unique complex ions and sols of Fe, Al, Mg, Ni and other minor elements.

Burns, Roger G.↗

Sulfide mineralization: Its role in chemical weathering of Mars

Pyrrhotite-pentlandite assemblages in mafic and ultramafic igneous rocks may have contributed significantly to the chemical weathering reactions that produced degradation products in the Martian regolith. By analogy with terrestrial processes, a model is proposed whereby supergene alteration of these primary Fe-Ni sulfides on Mars has generated secondary sulfides (e.g., pyrite) below the water table and produced acidic groundwater containing high concentrations of dissolved Fe, Ni and sulfate ions. The low pH solutions also initiated weathering reactions of igneous feldspars and ferromagnesian silicates to form clay silicate and ferric oxyhydroxide phases. Near-surface oxidation and hydrolysis of ferric sulfato- and hydroxo-complex ions and sols formed gossans above the water table consisting of poorly crystalline hydrated ferric sulfates (e.g., jarosite), oxides (ferrihydrite, goethite) and silica (opal). Underlying groundwater, now permafrost, contains hydroxo sulfato complexes of Fe, Al, Mg, Ni, etc., which may be stabilized in frozen acidic solutions beneath the surface of Mars. Sublimation of permafrost may replenish colloidal ferric oxides, sulfates and phyllosilicates during dust storms on Mars.

Burns, Roger G.↗

Helium diffusion in the sun

We calculate improved standard solar models using the new Livermore (OPAL) opacity tables, an accurate (exportable) nuclear energy generation routine which takes account of recent measurements and analyses, and the recent Anders-Grevesse determination of heavy element abundances. We also evaluate directly the effect of the diffusion of helium with respect to hydrogen on the calculated neutrino fluxes, on the primordial solar helium abundance, and on the depth of the convective zone. Helium diffusion increases the predicted event rates by about 0.8 SNU, or 11 percent of the total rate, in the chlorine solar neutrino experiment, by about 3.5 SNU, or 3 percent, in the gallium solar neutrino experiments, and by about 12 percent in the Kamiokande and SNO solar neutrino experiments. The best standard solar model including helium diffusion and the most accurate nuclear parameters, element abundances, and radiative opacity predicts a value of 8.0 SNU +/- 3.0 SNU for the C1-37 experiment and 132 +21/-17 SNU for the Ga - 71 experiment, where the uncertainties include 3 sigma errors for all measured input parameters.

Bahcall, J. N.↗