Search NASA⌕ Search

SEARCH · Search NASA

Results for “optical spectroscopy”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Fiber-optic thermometer using Fourier transform spectroscopy

An integrated-optic Mach-Zender interferometer is used as a Fourier transform spectrometer to analyze the input and output spectra of a temperature-sensing thin-film etalon. This configuration provides a high degree of immunity to the effects of changes in the source spectrum, and it readily permits the interrogation of a number of different sensors using a single spectrometer. In addition, this system has a potentially low cost because it uses optical communications hardware that may in the future be manufactured in large quantities.

Beheim, Glenn↗
NASA NTRS1994

UV laser long-path absorption spectroscopy

Long path Differential Optical Absorption Spectroscopy (DOAS) using a picosecond UV laser as a light source was developed in our institute. Tropospheric OH radicals are measured by their rotational absorption lines around 308 nm. The spectra are obtained using a high resolution spectrograph. The detection system has been improved over the formerly used optomechanical scanning device by application of a photodiode array which increased the observed spectral range by a factor of 6 and which utilizes the light much more effectively leading to a considerable reduction of the measurement time. This technique provides direct measurements of OH because the signal is given by the product of the absorption coefficient and the OH concentration along the light path according to Lambert-Beers law. No calibration is needed. Since the integrated absorption coefficient is well known the accuracy of the measurement essentially depends on the extent to which the OH absorption pattern can be detected in the spectra. No interference by self generated OH radicals in the detection lightpath has been observed. The large bandwidth (greater than 0.15 nm) and the high spectral resolution (1.5 pm) allows absolute determination of interferences by other trace gas absorptions. The measurement error is directly accessible from the absorption-signal to baseline-noise ratio in the spectra. The applicability of the method strongly depends on visibility. Elevated concentrations of aerosols lead to considerable attenuation of the laser light which reduces the S/N-ratio. In the moderately polluted air of Julich, where we performed a number of OH measurement spectra. In addition absorption features of unidentified species were frequently detected. A quantitative deconvolution even of the known species is not easy to achieve and can leave residual structures in the spectra. Thus interferences usually increase the noise and deteriorate the OH detection sensitivity. Using diode arrays for sensitive absorption measurements some specific problems of those detectors have to be solved experimentally (i.e. fixed pattern noise, dark signal noise, nonuniform efficiency of individual elements, spatial sensitivity variations). In order to improve the low spatial resolution we performed laboratory studies using a multiple reflection cell to convert the long path technique to a real in situ point measurement. Under the conditions of field experiments in Julich residual absorbance signals at present are about 1.5x10(exp -4) corresponding to an OH detection sensitivity of 2x10(exp 6) OH/cm(exp 3) using a light path of 5.8 km. Total integration times for one measurement point vary between a few minutes and an hour.

Dorn, Hans-Peter↗
NASA NTRS1986

On the application of optical-fiber image scramblers to astronomical spectroscopy

Single, step-index optical fibers, when properly employed, can function as optically efficient image scramblers. Their use as optical feeds for astronomical slit spectrographs can reduce zonal error levels in those instruments by orders of magnitude. As a consequence, the application of optical-fiber couplers to new and existing spectrographs may greatly increase the wavelength metric quality of conventional astronomical spectroscopy. The optical efficiencies of fiber couplers of a few tens of meters in length can be comparable to those of typical coude mirror trains in the visible portions of the spectrum. Elements of the design of fiber couplers are illustrated by discussion of a currently operational instrument.

Heacox, W. D.↗
NASA NTRS1984

Wide-angle radio tail QSOs as members of clusters of galaxies. II - Direct optical observations and spectroscopy of QSO fields

Deep, direct observations are obtained for the fields of 19 QSOs (redshift values 0.3-1.5) whose 'excess' galaxy counts in 1.17-sq arcmin fields centered on the QSOs confirm QSO redshift cosmological interpretations at the 99-percent confidence level. It is in addition indicated with 97-percent confidence that wide angle radio tail QSOs lie in richer concentrations of galaxies than undistorted QSOs. The results obtained also confirm that the 'excess' galaxies detected in the QSO fields have the same redshifts as the QSOs. These observations indicate that deep CCD observations of the fields of radio tail QSOs would provide a sample of distant clusters of galaxies at known redshifts (those of the QSOs).

Hintzen, P.↗
NASA NTRS1985

High-resolution spectroscopy of the optical candidate for the X-ray transient X0331 + 53

High-resolution spectral observations of the optical candidate for the X-ray transient X0331 + 53 are presented. The data show broad hydrogen and helium emission and strong interstellar absorption corresponding to a visual extinction of about 7 mag. No photospheric absorption in the emission lines, and no radial-velocity variations greater than 0.5 km/s were found over a three-day period. It is concluded that the optical continuum does not arise at or near the primary star. As an example of the spectrographic data, a resolution profile of H-alpha emission in X0331 + 53 is provided.

Stocke, J.↗
NASA NTRS1985

Optical and UV spectroscopy of the peculiar RS CVn system, RT Lacertae

Spectra in the H-alpha and H-beta regions of the peculiar double-lined RS CVn binary, RT Lacertae, were obtained in the fall of 1984. Limited International Ultraviolet Explorer (IUE) long wavelength low and high resolution spectra were obtained concurrently. The ground based spectra have shown an asymmetry with orbital phase in the H-alpha profile. The H-beta profiles were consistent with the same effect. One hemisphere showed excess emission and the other excess absorption, with a broad Gaussian emission component superposed upon the excess H-alpha line. An improved radial velocity curve, giving a better determined mass ratio and geometry was derived. This combined with the radii implied by the rotational broadening of the spectra, showed one component to be 80 to 90% filling the equilibrium Roche surface. The two-faced nature is, therfore, very likely due to mass transfer from the contact component impacting upon its companion. Low resolution ultraviolet data showed that the supposed cooler component is bluer than its companion. High resolution ultraviolet data taken during secondary eclipse showed Mg II emission strength which decreased more slowly than the area visible. The phase behavior of the low resolution data support the former situation, indicating traditional chromospheric activity.

Huenemoerder, D. P.↗
NASA NTRS1986

Optical and UV spectroscopy of the peculiar RS CVn system RT Lacertae

H-alpha and H-beta spectra of the peculiar double-lined RS CVn binary RT Lacertae have been obtained using the IUE, together with a ground-based coude-feed telescope at KPNO. The ground-based spectra show an asymmetry related to the orbital phase in the H-alpha profile. H-beta profiles showed excess emission in one hemisphere and excess absorption in the other, with a broad Gaussian emission component superposed on the excess H-alpha line. A radial velocity curve was derived to estimate the mass ratio and geometry of the system. It is shown that the component of RT Lac fills 80-90 percent of the equilibrium Roche surface. Low-resolution ultraviolet data show that the supposed cooler component is bluer than its companion, suggesting evidence of a scattering shell or a cloud produced by the splash of a gas stream. The phase behavior of the low resolution ultraviolet data support the conclusion that RT Lac is a mass transfer system and that mass transfer is the primary cause of its activity.

Huenemoerder, D. P.↗
NASA NTRS1989

Electron cyclotron resonance deposition and plasma diagnostics of a-Si:H and a-C:H films

Amorphous silicon (a-Si:H) and amorphous carbon (a-C:H) films deposited by electron cyclotron resonance (ECR) microwave plasma-enhanced chemical vapor deposition are discussed. It is shown that the ECR microwave plasma deposition technique can produce a-Si:H films with material qualities similar to and with a deposition rate one order of magnitude higher than for films deposited by radio-frequency glow discharge. The ECR-deposited a-C:H films are characterized by fluorescence, IR, and Raman spectroscopy. In situ optical emission spectroscopy plasma diagnostics indicates that ECR plasmas have a strong emission at 434 nm, which indicates a higher chemical reactivity than radio-frequency glow discharge plasmas. The radio frequency bias to the substrate is found to play a critical role in determining the film structure and the carbon bonding configuration of ECR-deposited a-C:H films.

Shing, Y. H.↗
NASA NTRS1993

Mid- and far-infrared spectroscopy of ices - Optical constants and integrated absorbances

Laboratory spectra through the mid-infrared (4000 to 500/cm (2.5-20 microns) have been used to calculate the optical constants (n and k) and integrated absorption coefficients (A) for a variety of pure and mixed molecular ices of relevance to astrophysics. The ices studied were H2O, CH3OH, CO2, OCS, CH4, CO2 + CH4, CO2 + OCS, CO + CH4, CO + OCS, O2 + CH4, O2 + OCS, N2 + CH4, N2 + OCS, H2O + CH4, H2O + OCS, and H2O + CH3OH + CO + NH3. In addition, the measurements have been extended through the far-infrared (500 to 50/cm (20-200 microns) for the H2O, CH3OH, and H2O + CH3OH + CO + NH3 ices.

Hudgins, D. M.↗
NASA NTRS1992

Cosmic X-ray spectroscopy with multilayer optics

Multilayer optics operated at normal incidence offer a powerful new technology for the study of the solar spectrum in the XUV. The spectra of most cosmic X-ray sources are strongly extinguished at wavelengths above 40 A due to absorption and scattering by interstellar grains. We describe a number of configurations which allow multilayer optics to be used at nonnormal angles of incidence in conjunction with grazing incidence optics to analyze the spectra of cosmic X-ray sources in the wavelength interval between 1.5 and 40 A. These optical configurations utilize both multilayer mirrors and gratings, and permit the efficient observation of extended sources using stigmatic spectrographs. The response of the instruments described to typical cosmic X-ray sources is also discussed.

Walker, Arthur B. C., Jr.↗
NASA NTRS2018

Development of Transition Edge Sensor Detectors Optimized for Single-Photon Spectroscopy in the Optical and Near-Infrared

The search for biosignatures in the atmospheres of exoplanets will be a key focus of future space telescopes that operate in the ultraviolet, visible, and near-infrared bands. Detection of biosignatures requires an instrument with moderate spectral resolving power ($R \sim 100$) and a large bandwidth ($\sim 400$ nm -- $\sim 1.8$ $\mu$m). Additionally, biosignature detection is a photon-starved science; instruments designed for these measurements would ideally combine high optical efficiency with quantum-limited photon detectors (i.e., detectors that exhibit zero dark current). In this work, we report on our efforts to develop energy resolving transition edge sensor (TES)-based detectors designed for biosignature detection. TESs operated as microcalorimeters are compelling detectors for this application. Unlike semiconductor detectors, TESs eliminate the need for dispersive optics and are truly single photon detectors -- fundamental TES noise yields uncertainty in the energies of detected photons, not in the number of detected photons. We introduce TESs designed for this application and discuss the path toward realizing a TES-based dispersionless spectrometer optimized for biosignature detection.

Instrumentation and Photography↗
NASA NTRS2018

Development of Transition Edge Sensor Detectors Optimized for Single-Photon Spectroscopy in the Optical and Near-Infrared

The search for biosignatures in the atmospheres of exoplanets will be a key focus of future space telescopes that operate in the ultraviolet, visible, and near-infrared bands. Detection of biosignatures requires an instrument with moderate spectral resolving power (R ~ 100) and a large bandwidth (~ 400 nm – ~ 1.8 µm). Additionally, biosignature detection is a photon-starved science; instruments designed for these measurements would ideally combine high optical efficiency with quantum-limited photon detectors (i.e., detectors that exhibit zero dark current). In this work, we report on our efforts to develop energy resolving transition edge sensor (TES)-based detectors designed for biosignature detection. TESs operated as microcalorimeters are compelling detectors for this application. Unlike semiconductor detectors, TESs eliminate the need for dispersive optics and are truly single photon detectors – fundamental TES noise yields uncertainty in the energies of detected photons, not in the number of detected photons. We introduce TESs designed for this application and discuss the path toward realizing a TES-based dispersionless spectrometer optimized for biosignature detection.

Instrumentation and Photography↗
NASA NTRS1987

Single-tone and two-tone AM-FM spectral calculations for tunable diode laser absorption spectroscopy

A generalized theory for optical heterodyne spectroscopy with phase modulated laser radiation is used which allows the calculation of signal line shapes for frequency modulation spectroscopy of Lorentzian gas absorption lines. In particular, synthetic spectral line shapes for both single-tone and two-tone modulation of lead-salt diode lasers are presented in which the contributions from both amplitude and frequency modulations are included.

Chou, Nee-Yin↗
NASA NTRS2004

X-Ray Weak Broad-Line Quasars: Absorption or Intrinsic X-Ray Weakness

XMM observations of X-ray weak quasars have been performed during 2003. The data for all but the last observation are now available (there has been a delay of several months on the initial schedule, due to high background flares which contaminated the observations: as a consequence, most of them had to be rescheduled). We have reduced and analyzed these data, and obtained interesting preliminary scientific results. Out of the eight sources, 4 are confirmed to be extrimely X-ray weak, in agreement with the results of previous Chandra observations. 3 sources are confirmed to be highly variable both in flux (by factors 20-50) and in spectral properties (dramatic changes in spectral index). For both these groups of objects, an article is in preparation. Preliminary results have been presented at an international workshop on AGN surveys in December 2003, in Cozumel (Mexico). In order to further understand the nature of these X-ray weak quasars, we submitted proposals for spectroscopy at optical and infrared telescopes. We obtained time at the TNG 4 meter telescope for near-IR observations, and at the Hobby-Eberly Telescope for optical high-resolution spectroscopy. These observations will be performed in early 2004, and will complement the XMM data, in order to understand whether the X-ray weakness of these sources is an intrinsic property or is due to absorption by circumnuclear material.

Risaliti, Guido↗
NASA NTRS1991

Space Shuttle Main Engine nozzle mounted optic for throat plane spectroscopy

A program intended to develop a flight-capable nozzle mounted optic for monitoring emissions from metals entrained in the Space Shuttle Main Engine (SSME) flowfield is described. The optic will collect light emitted from metal atoms within the high-temperature, high-pressure SSME chamber and transfer the optical signal to a high-resolution spectrometer via a fiber-optic cable. The nozzle mounted optic makes it possible to conduct earth-to-orbit monitoring of flowfield emissions without requiring modifications to the SSME.

Bickford, R. L.↗
NASA NTRS1992

Optical remote measurement of toxic gases

Enactment of the Clean Air Act Amendments (CAAA) of 1990 has resulted in increased ambient air monitoring needs for industry, some of which may be met efficiently using open-path optical remote sensing techniques. These techniques include Fourier transform spectroscopy, differential optical absorption spectroscopy, laser long-path absorption, differential absorption lidar, and gas cell correlation spectroscopy. With this regulatory impetus, it is an opportune time to consider applying these technologies to the remote and/or path-averaged measurement and monitoring of toxic gases covered by the CAAA. This article reviews the optical remote sensing technology and literature for that application.

Review↗
NASA NTRS1993

Spatially resolved optical and near-infrared spectroscopy of I Zw 18

Long-slit optical and near-IR spectroscopy are presented for the bright NW and faint SE components of the oxygen-poor H II galaxy I Zw 18, yielding physical conditions and O, N, S, and He abundances for these components. All of the elemental abundances for the two components of I Zw 18 are equal (within errors), thereby placing constraints on evolutionary theories for this system.

Skillman, Evan D.↗