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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13

Development of a solid polymer electrolyte electrolysis cell module and ancillary components for a breadboard water electrolysis system

Solid polymer electrolyte technology in a water electrolysis system along with ancillary components to generate oxygen and hydrogen for a manned space station application are considered. Standard commercial components are utilized wherever possible. Presented are the results of investigations, surveys, tests, conclusions and recommendations for future development efforts.

Porter, F. J., Jr.↗

Water electrolysis system refurbishment and testing

The electrolytic oxygen generator for the back-up water electrolysis system in a 90-day manned test was refurbished, improved and subjected to a 182-day bench test. The performance of the system during the test demonstrated the soundness of the basic electrolysis concept, the high development status of the automatic controls which allowed completely hands-off operation, and the capability for orbital operation. Some design improvements are indicated.

Greenough, B. M.↗

Study of oxygen gas production phenomenon during stand and discharge in silver-zinc batteries

Standard production procedures for manufacturing silver zinc batteries are evaluated and modified to reduce oxygen generation during open circuit stand and discharge. Production predictions of several variable combinations using analysis models are listed for minimum gassing, with emphasis on the concentration of potassium hydroxide in plate formation. A recommendation for work optimizing the variables involved in plate processing is included.

Source record↗

Development status of solid polymer electrolyte water electrolysis for manned spacecraft life support systems

Details of the design and system verification test results are presented for a six-man-rated oxygen generation system. The system configuration incorporates components and instrumentation for computer-controlled operation with automatic start-up/shutdown sequencing, fault detection and isolation, and with self-contained sensors and controls for automatic safe emergency shutdown. All fluid and electrical components, sensors, and electronic controls are designed to be easily maintainable under zero-gravity conditions. On-board component spares are utilized in the system concept to sustain long-term operation (six months minimum) in a manned spacecraft application. The system is centered on a 27-cell solid polymer electrolyte water electrolysis module which, combined with the associated system components and controls, forms a total system envelope 40 in. high, 40 in. wide, and 30 in. deep.

Nuttall, L. J.↗

Technology advancement of the electrochemical CO2 concentrating process

A five-cell, liquid-cooled advanced electrochemical depolarized carbon dioxide concentrator module was fabricated. The cells utilized the advanced, lightweight, plated anode current collector concept and internal liquid-cooling. The five cell module was designed to meet the carbon dioxide removal requirements of one man and was assembled using plexiglass endplates. This one-man module was tested as part of an integrated oxygen generation and recovery subsystem.

Schubert, F. H.↗

Energy requirements of a biosphere

The question is considered of whether a biosphere similar to that on earth could exist in the region of the outer planets, where relatively little light is available for photosynthetic processes. The type of photosynthesis most abundant on earth is discussed along with light conversion in photosynthesis, the light-harvesting system in plants, photosynthetic efficiency, and carbon production in nature. The dynamic range of metabolic rates is examined, and photosynthesis in anaerobic organisms is described. It is suggested that organisms having very large photosynthetic pigment units would thrive in the light intensities prevailing on Titan and that the surface of Titan might well be able to maintain a biosphere driven by oxygen-generating photosynthesis.

Kok, B.↗

Measurement of total organic concentration in water

Instrument for determining total organic concentration in water uses no corrosive reagents or gases. Instead continuous ultraviolet photolysis process converts organic compounds to carbon dioxide (CO2). CO2 electrode is used to measure CO2 content. Only reagent necessary is oxygen, generated in situ by electrolyzing some water. In addition to application in aerospace industry, system has potential uses in pollution monitoring and in laboratory analyses.

Winkler, E.↗

The fate of the hydroxyl radical in the earth's primitive atmosphere and implications for the production of molecular oxygen

Behavior of the hydroxyl radical produced by the photolysis of water vapor in the earth's early atmosphere is examined. Because of the substantial OH radical reactivity with trace species (CO, HCl, SO2, H2S, NH3, and CH4) the formation of molecular oxygen may be prevented, even at a trace species mixing ratio. The photolysis rate of H2O, with corrections for hydrogen exospheric escape, is capable of describing the oxidation of the atmosphere and crust but may not be used to determine the rate of molecular oxygen generation without consideration of the various OH-trace species reactions.

Vander Wood, T. B.↗

Lightside Atmospheric Revitalization System

The system was studied as a replacement to the present baseline LiOH system for extended duration shuttle missions. The system consists of three subsystems: a solid amine water desorbed regenerable carbon dioxide removal system, a water vapor electrolysis oxygen generating system, and a Sabatier reactor carbon dioxide reduction system. The system is designed for use on a solar powered shuttle vehicle. The majority of the system's power requirements are utilized on the Sun side of each orbit, when solar power is available.

Colling, A. K.↗

Fractional capacity electrolyzer development for CO2 and H2O electrolysis

The electrolyzer module was designed to produce 0.24 kg/d (0.53 lb/d) of breathable oxygen from the electrolysis of metabolic carbon dioxide and water vapor. The fractional capacity electrolyzer module is constructed from three electrochemical tube cells and contains only three critical seals. The module design illustrated an 84 percent reduction in the total number of seals for a one person capacity oxygen generating system based on the solid electrolyte carbon dioxide and water vapor electrolysis concept. The electrolyzer module was successfully endurance tested for 71 days.

Wynveen, R. A.↗

Electrophotolysis oxidation system for measurement of organic concentration in water

Methods and apparatus for determining organic carbon in aqueous solution are described. The method comprises subjecting the aqueous solution to electrolysis, for generating oxygen from water, and simultaneously to ultraviolet radiation, for oxidation of substantially all organic carbon to carbon dioxide. The carbon dioxide is measured and the value is related to the concentration of organic carbon in the aqueous solution.

Winkler, H. E.↗

An integrated regenerative air revitalization system for spacecraft

Progress towards development of an air revitalization system (ARS) for spacecraft breathable atmosphere regeneration is assessed, and a preliminary design for a one-person ARS is described. The ARS is considered a necessary component of any permanently manned orbital station, and studies have demonstrated that penalties for expendable air supplies justify an ARS for missions longer than 40 days. CO2 must be removed and O2 returned along with N2, which can be extracted from hydrazine, with the H2 component returning to the operation of the CO2 reduction subsystem. An experimental ARS (ARX-1) features a cabin humidity control unit, a CO2 concentrator, an air-cooled CO2 reduction reactor, an oxygen generator (electrolysis), the hydrazine N2 generator, and a water handling unit. A 120-day test demonstrated one-button startup and 480 hr operation in a normal mode.

Noyes, G. P.↗

Advanced air revitalization system testing

A previously developed experimental air revitalization system was tested cyclically and parametrically. One-button startup without manual interventions; extension by 1350 hours of tests with the system; capability for varying process air carbon dioxide partial pressure and humidity and coolant source for simulation of realistic space vehicle interfaces; dynamic system performance response on the interaction of the electrochemical depolarized carbon dioxide concentrator, the Sabatier carbon dioxide reduction subsystem, and the static feed water electrolysis oxygen generation subsystem, the carbon dioxide concentrator module with unitized core technology for the liquid cooled cell; and a preliminary design for a regenerative air revitalization system for the space station are discussed.

Heppner, D. B.↗

Extended mission life support systems

The life support systems employed in manned space missions have generally been based on the use of expendables, such as, for instance, liquid oxygen. For the conducted space missions, such systems have advantages related to volume, weight, and economy of power consumption. However, this situation will change in connection with Shuttle Orbiter missions of extended duration, permanent manned facilities in low-earth orbit, and ultimately manned planetary vehicles. A description is given of suitable regenerative life support systems for such extended manned space missions. Attention is given to advanced life support systems technology, air revitalization, CO2 reduction, oxygen generation, nitrogen generation, trace contaminant control, air revitalization system integration, control/monitor instrumentation, water reclamation, solid waste management, manned testing and life support integration, an enhanced duration orbiter, a space operations center, manned interplanetary life support systems, and future development requirements.

Quattrone, P. D.↗

The development status of candidate life support technology for a space station

The establishment of a permanently-manned Space Station has recently been selected as the next major step in the U.S. space program. The requirements of a manned operations base in space appear to be best satisfied by on-board Environmental Control/Life Support Systems (ECLSS) which are free from, or have minimum dependence on, use of expendables and the frequent earth resupply missions which are part of systems using expendables. The present investigation is concerned with the range of regenerative life support system options which NASA is developing to be available for the Space Station designer. An air revitalization system is discussed, taking into account devices concerned with the carbon dioxide concentration, approaches of CO2 reduction, oxygen generation, trace contaminant control, and atmospheric quality monitoring. Attention is also given to an independent air revitalization system, nitrogen generation, a water reclamation system, a waste management system, applications of the technology, and future development requirements.

Samonski, F. H., Jr.↗

Environmental control/life support

It is pointed out that the life support systems technology used on projects Mercury, Gemini, Apollo, and Space Shuttle required an employment of expendables. Skylab was the only manned space project which made use of regenerable life support technology, taking into account the employment of a silica gel/molecular sieve for carbon dioxide removal. A number of investigations indicate that significant launch weight and volume as well as recurring cost savings can be realized by using regenerative life support processes for a Space Station. A number of developed regenerative processes are believed to be applicable to a Space Station. Aspects of air revitalization are discussed, taking into account carbon dioxide reduction, oxygen generation, trace contaminant control, temperature and humidity control, instrumentation, and nitrogen supply. Attention is also given to water reclamation, solid waste treatment, and future development and testing programs.

Quattrone, P. D.↗

Oxygen/hydrogen Space Station propulsion system concept definition for IOC

The potential for the reduction in propulsion system life cycle costs through the use of on-board water electrolysis to generate oxygen and hydrogen propellants, as well as the potential advantages of improved system safety and contamination impact, led to a study to evaluate candidate oxygen-/hydrogen-based propulsion systems. In this study a representative set of propulsion system requirements were compiled and candidate oxygen/hydrogen-based propulsion systems synthesized. These candidate concepts were screened and a systems evaluation was performed on the remaining eight candidate concepts. Detailed system schematics were prepared. Operational design conditions were determined and system weight, volume, energy requirements, and costs were calculated. Evaluation results indicated that the oxygen/hydrogen propulsion systems can provide simple, low cost, and viable systems for the IOC Space Station. Based on these data, a relative concept evaluation was conducted using as selection criteria reliability, safety, cost, technical risk, contamination, operational utility, growth potential, and integration potential. Top ranked candidate systems were recommended to NASA/MSFC for consideration for the IOC Space Station.

Shoji, J. M.↗

Electrochemical generation of useful chemical species from lunar materials

A high temperature electrolytic cell which simultaneously generates oxygen at the anode and liquid alkali metals at the cathode is electrochemically characterized. The electrolytic technology being investigated utilizes the oxygen vacancy conducting solid electrolyte, yttria stabilized zirconia, which effectively separates the oxygen evolving (at La0.89Sr0.10MnO3) and alkali metal (Li, Na) reducing (from a molten salt at either Pt or FeSi2) half cell reactions. In the finally engineered cell liquid alkali metal would be continuously removed from the cathode compartment and used as an effective reductant for the direct thermochemical refining of lunar ores to their metallic state with simultaneous oxidation of the alkali metal to its oxide. The alkali metal oxide would then be reintroduced into the electrolytic cell to complete the overall system cycle.

Sammells, Anthony F.↗