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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Matrix mineralogy of the Lance CO3 carbonaceous chondrite - A transmission electron microscope study

Results are presented on electron microprobe analyses of three CO chondrites, all of which are falls: Lance, Kainsaz, and Warrenton. The TEM mineralogy results of Lance chondrite show that Fe-rich matrix olivines have been altered to Fe-bearing serpentine and Fe(3+) oxide; matrix metal was also altered to produce Fe(3+) oxides, leaving the residual metal enriched in Ni. Olivine grains in Lance's matrix contain channels along their 100-line and 001-line directions; the formation and convergence of such channels resulted in a grain-size reduction of the olivine. A study of Kainsaz and Warrenton showed that these meteorites do not contain phyllosilicates in their matrices, although both contain Fe(3+) oxide between olivine grains. It is suggested that, prior to its alteration, Lance probably resembled Kainsaz, an unaltered CO3 chondrite.

Keller, Lindsay P.↗
NASA NTRS1990

Aqueous alteration in the Kaba CV3 carbonaceous chondrite

Results from TEM and SEM examinations of the Kaba CV3 carbonaceous chondrite are presented, showing that the chondrules and the matrix of Kaba have undergone pervasive low-temperature aqueous alteration, resulting in the formation of Fe-bearing saponite from glass and enstatite in chondrules, and from anhydrous silicates in matrix. The alteration products in Kaba were found to resemble those in other aqueously altered carbonaceous chondrites such as the Mokoia CV3 and in Orgueil CI chondrites and Y-82162 chondrites. However, Kaba lacks the abundant high-Al phyllosilicates, reported for CAIs from Mokoia, and the serpentine and ferrihydrite, found in Orgueil.

Keller, Lindsay P.↗
NASA NTRS1991

GRID3D-v2: An updated version of the GRID2D/3D computer program for generating grid systems in complex-shaped three-dimensional spatial domains

In order to generate good quality systems for complicated three-dimensional spatial domains, the grid-generation method used must be able to exert rather precise controls over grid-point distributions. Several techniques are presented that enhance control of grid-point distribution for a class of algebraic grid-generation methods known as the two-, four-, and six-boundary methods. These techniques include variable stretching functions from bilinear interpolation, interpolating functions based on tension splines, and normalized K-factors. The techniques developed in this study were incorporated into a new version of GRID3D called GRID3D-v2. The usefulness of GRID3D-v2 was demonstrated by using it to generate a three-dimensional grid system in the coolent passage of a radial turbine blade with serpentine channels and pin fins.

Steinthorsson, E.↗
NASA NTRS1991

Characterizing water/rock interaction in simulated comet nuclei via calorimetry: Tool for in-situ science, laboratory analysis, and sample preservation

Although results from the Giotto and Vega spacecraft flybys of comet P/Halley indicate a complex chemistry for both the ices and dust in the nucleus, carbonaceous chondrite meteorites are still regarded as useful analogs for the rocky components. Carbonaceous chondrites mixed with water enable simulation of water/rock interactions which may occur in cometary nuclei. Three general types of interactions can be expected between water and minerals at sub-freezing temperatures: heterogeneous nucleation of ice by insoluble minerals; adsorption of water vapor by hygroscopic phases; and freezing and melting point depression of liquid water sustained by soluble minerals. Two series of experiments were performed in a differential scanning calorimeter (DSC) with homogenized powders of the following whole-rock meteorites and comparison samples: Allende (CV3), Murchison (CM2), Orgueil (CI), Holbrook (L6), and Pasamonte (eucrite) meteorites as well as on peridotite (PCC-1, USGS), saponite (Sap-Ca-1, CMS), montmorillonite (STx-1, CMS), and serpentine (Franciscan Formation, California). Results are briefly discussed.

Allton, Judith H.↗
NASA NTRS1991

Derivation of mid-infrared (5-25 microns) optical constants of some silicates and palagonite

Recent reports concerning the mid-infrared reflectance properties of silicates coupled with recent observations of the Earth and other planets in the mid-infrared and the planned Thermal Emission Spectrometer scheduled as an instrument to be included on the Mars Observer all illustrate the increasing interest in the optical properties of materials in the mid-infrared and their direct application to remote sensing observations of other planetary surfaces. As the laboratory and observational data increase they will ultimately be modeled to aid in the understanding of the composition mineralogy, and distribution of the surface and atmospheric constituents on these bodies. In order to facilitate such quantitative analyses, knowledge regarding the optical constants (real (n) and imaginary (k) indices of refraction) of a wide variety of pertinent materials is required. Examples of the application of such quantitative analyses to the interpretation of Martian surface and atmospheric constituents, based on the optical constants of minerals, are presented. This study was initially conceived in order to aid in the interpretation of Martian surface and atmospheric aerosol mineralogy. As a result, the minerals included are biased toward samples which represent hydrated and hydroxylated silicates. These include the Al and Mg end members of the 1:1 layer lattice silicates, kaolinite and serpentine, respectively; an Al-bearing 2:1 layer lattice silicate, pyrophyllite; the Mg and Al smectite clays saponite and montmorillonite, respectively; and a palagonite, typically a poorly characterized alteration product of basaltic glass. The reflectivities of all samples were determined by placing them at the focus of a near-normal reflective attachment located in a Fourier transform spectrometer. To derive the optical constants of a material as a function of wavelength, researchers used the commonly employed technique of dispersion analysis.

Roush, T. L.↗
NASA NTRS1991

Clay minerals in primitive meteorites and interplanetary dust 2. Smectites and micas

The classification is briefly summarized of stony meteorites and cosmic dust, and the mineralogy and chemistry is described of serpentine group minerals. The occurrence of smectites and micas in extraterrestrial materials is examined. The characterization of fine grained minerals in meteorites and IDPs relies heavily on electron beam instruments, especially the transmission electron microscope (TEM). Typically, phyllosilicates are identified by a combination of high resolution imaging of basal spacings, electron diffraction, and chemical analysis. Smectites can be difficult to differentiate from micas because the smectites lose their interlayer water and the interlayer partly collapse in the high vacuum of the TEM.

Keller, L. P.↗
NASA NTRS1991

Clay minerals in primitive meteorites and interplanetary dust 1

Many meteorites and interplanetary dust particles (IDPs) with primitive compositions contain significant amounts of phyllosilicate minerals, which are generally interpreted as evidence of protoplanetary aqueous alteration at an early period of the solar system. These meteorites are chondrites (near solar composition) of the carbonaceous and ordinary varieties. The former are subdivided (according to bulk composition and petrology) into CI, CM, CV, CO, CR, and ungrouped classes. IDPs are extraterrestrial particulates, collected in stratosphere, which have chemical compositions indicative of a primitive origin; they are typically distinct from the primitive meteorites. Characterization of phyllosilicates in these materials is a high priority because of the important physico-chemical information they hold. The most common phyllosilicates present in chondritic extraterrestrial materials are serpentine-group minerals, smectites, and micas. We discuss these phyllosilicates and describe the interpretation of their occurrence in meteorites and IDPs and what this indicates about history of their parent bodies, which are probably the hydrous asteroids.

Zolensky, M. E.↗
NASA NTRS1992

A magma ocean and the Earth's internal water budget

There are lines of evidence which relate bounds on the primordial water content of the Earth's mantle to a magma ocean and the accompanying Earth accretion process. We assume initially (before a magma ocean could form) that as the Earth accreted, it grew from volatile- (H2O, CO2, NH3, CH4, SO2, plus noble) gas-rich planetesimals, which accreted to form an initial 'primitive accretion core' (PAC). The PAC retained the initial complement of planetesimal gaseous components. Shock wave experiments in which both solid, and more recently, the gaseous components of materials such as serpentine and the Murchison meteorite have demonstrated that planetesimal infall velocities of less than 0.5 km/sec, induce shock pressures of less than 0.5 GPa and result in virtually complete retention of planetary gases.

Ahrens, Thomas J.↗
NASA NTRS1991

Shock wave equation of state of muscovite

Shock wave data were obtained between 20 and 140 GPa for natural muscovite obtained from Methuen Township (Ontario), in order to provide a shock-wave equation of state for this crustal hydrous mineral. The shock equation of state data could be fit by a linear shock velocity (Us) versus particle velocity (Up) relation Us = 4.62 + 1.27 Up (km/s). Third-order Birch-Murnaghan equation of state parameters were found to be K(OS) = 52 +/-4 GPa and K-prime(OS) = 3.2 +/-0.3 GPa. These parameters are comparable to those of other hydrous minerals such as brucite, serpentine, and tremolite.

Sekine, Toshimori↗
NASA NTRS1991

Derivation of midinfrared (5-25 microns) optical constants of some silicates and palagonite

The 5-25 micron real and imaginary refraction indices are presented for palagonite and the silicates pyrophyllite, kaolinite, serpentine, montmorillonite, saponite, and orthopyroxene. Optical constants in the region of the H2O-bending fundamental near 6 microns are obtained for saponite, montmorillonite, and palagonite. It is established that, if a pellet of pure material can be polished to a mirror finish, the optical constants of such noncohesive materials as clays are easily derivable.

Roush, T.↗
NASA NTRS1992

An interplanetary dust particle with links to CI chondrites

W7013F5 is a chondritic, hydrated interplanetary dust particle whose composition and mineralogy is nearly identical to that found in the CI chondrites. Transmission electron microscope observations show that the phyllosilicates in W7013F5 consist largely of a coherent undergrowth of Mg-Fe serpentine and Fe-bearing saponite on the unitcell scale. This distinctive intergrowth of phyllosilicates has only been observed previously in the CI chondrites. Other secondary minerals in W7013F5 include Mg-Fe carbonates, magnetite, and pentlandite. The mineral assemblage in W7013F5 is generally not as oxidized as that in the CI chondrites. The presence of kamacite in W7013F5 indicates that the particle is extraterrestrial, and a thin amorphous rim surrounding the particle provides evidence that it is not a piece of a meteorite that fragmented during transit through the atmosphere. The apparent lack of hydrated IDPs with CI mineralogy and chemistry may indicate that CI-type dust-producing asteroids are uncommon in the asteroid belt.

Keller, Lindsay P.↗
NASA NTRS1991

Kinematic analysis of generalized adaptive trusses

Adaptive trusses offer the greatest stiffness and strength for a given weight of any articulated structure or mechanism. Because of this, there are many potential extraterrestrial applications of these variable-geometry trusses, including serpentine manipulators, payload isolation, tracking, pointing and docking mechanisms, and gimbals. All of these applications will require the ability to precisely control the kinematic parameters of the mechanism, including position, velocity, and acceleration. This paper explores the fundamental nature of adaptive trusses by examining the basic truss elements or unit cells. A general method for analyzing forward and inverse motion of all the basic truss units is presented, followed by a more efficient formulation for the octahedral unit cell. Finally, general closed-form techniques are presented for finding velocity, acceleration, and all higher derivatives of truss motion.

Tidwell, Paul H.↗
NASA NTRS1992

Enhancing control of grid distribution in algebraic grid generation

Three techniques are presented to enhance the control of grid-point distribution for a class of algebraic grid generation methods known as the two-, four- and six-boundary methods. First, multidimensional stretching functions are presented, and a technique is devised to construct them based on the desired distribution of grid points along certain boundaries. Second, a normalization procedure is proposed which allows more effective control over orthogonality of grid lines at boundaries and curvature of grid lines near boundaries. And third, interpolating functions based on tension splines are introduced to control curvature of grid lines in the interior of the spatial domain. In addition to these three techniques, consistency conditions are derived which must be satisfied by all user-specified data employed in the grid generation process to control grid-point distribution. The usefulness of the techniques developed in this study was demonstrated by using them in conjunction with the two- and four-boundary methods to generate several grid systems, including a three-dimensional grid system in the coolant passage of a radial turbine blade with serpentine channels and pin fins.

Steinthorsson, E.↗
NASA NTRS1993

Development of a large space robot - A multi-segment approach. I

A concept of multisegment robot (of a class of large space cranes) is developed for use in space-based construction operations. The robot consists of a collection of segments, which are pinned together to form a snakelike configuration, with a single degree of freedom representing rotation being retained at each pinned connection and with reaction flywheels suspended within each segment for the control necessary to position each body segment. Algorithms are developed for positioning this serpentine robot to a prescribed location and orientation. A multibody dynamics simulation is used to investigate the behavior and interactions of the robot, demonstrating its viability.

Spanos, P. D.↗
NASA NTRS1993

The CR (Renazzo-type) carbonaceous chondrite group and its implications

A petrologic, geochemical, and oxygen isotropic study of the CR chondrites including Renazzo, Al Rais, El Djouf 001 and the paired Acfer meteorites, EET87770 and the paired samples, MAC87320, Y790112, Y793495, and Y791498 is presented. It is concluded that the CR group is characterized by abundant large multilayered, Fe, Ni metal-rich, type I chondrules; abundant matrix and dark inclusions; unique assemblages of serpentine and chlorite-rich phyllosilicates and Ca-carbonates; Ca-carbonate rims on chondrules; abundant Fe, Ni metal with a positive Ni vs. Co trend and a solar Ni:Co ratio; and amoeboid olivine aggregates with Mn-rich and Mn-poor forsterite.

Weisberg, Michael K.↗
NASA NTRS1993

Carbonate compositions in CM and CI chondrites, and implications for aqueous alteration

Carbonate minerals in fourteen CM chondrites and two CI chondrites have been analyzed by electron microprobe to provide a better understanding of the aqueous processes that affected carbonaceous chondrite parent bodies. Calcites in CM chondrites and dolomites and magnesites in CI chondrites display the compositions expected of stable phases formed at low temperatures. Dolomites in CM chondrites, identified here for the first time in five members of the group, have small amounts of excess Ca which may reflect metastable growth. The distribution of Fe between dolomite and coexisting serpentine differs in the two chondrite groups. If the distributions reflect an approach to chemical equilibrium, then the difference implies higher alteration temperatures for the CI group than the CM group in agreement with the results of previously published oxygen isotope thermometry and mineral solubility modeling of the alteration process. Dolomite Fe contents are relatively uniform in the two chondrite groups. Dolomite Mn contents, by contrast, vary widely. The variations may reflect transport-controlled coprecipitation of Mn resulting from a heterogeneous distribution of the element in the anhydrous precursor material. If this interpretation is correct, then the altering fluids were essentially immobile white hydration reactions proceeded on the meteorite parent bodies. The near closed-system character of the alteration process, long known from bulk chemical analyses of the meteorites, is a direct consequence of the limited mobility of dissolved species.

Johnson, Craig A.↗
NASA NTRS1992

Using AVIRIS images to measure temporal trends in abundance of photosynthetic and nonphotosynthetic canopy components

The Jasper Ridge Biological Preserve, Stanford, California is a good example of hardwood rangeland ecosystems in California. Structurally, it is composed of a mosaic of serpentine grasslands, oak savannah, coastal chaparral, and mixed evergreen woodland, representing a broad cross-section of physiognomic classes. The Mediterranean climate produces an extended seasonal drought lasting throughout most of the growing season and has significant impact on the expression of divergent phenological patterns related to contrasting ecological strategies of these taxa. The region is well understood biologically due to the rich history of ecological research at the site. Thus, community characteristics, physiological characteristics, phenology, and temporal dynamics are reasonably well understood for many of the dominant species. Because of its proximity to NASA Ames Research Center, it has been subject to a large number of aircraft data acquisitions over many years. A more complete examination of this database would provide an opportunity to test current remote sensing hypotheses for measurement and detection of ecological attributes, particularly those involving canopy chemistry and physiology. Better definition of ecological rules might permit development of remotely sensed surrogate variables for biological properties that cannot be directly measured or measured with sufficient accuracy.

Ustin, Susan L.↗
NASA NTRS1993

Euhedral metallic-Fe-Ni grains in extraterrestrial samples

Metallic Fe-Ni is rare in terrestrial rocks, being largely restricted to serpentinized peridotites and volcanic rocks that assimilated carbonaceous material. In contrast, metallic Fe-Ni is nearly ubiquitous among extraterrestrial samples (i.e., meteorites, lunar rocks, and interplanetary dust particles). Anhedral grains are common. For example, in eucrites and lunar basalts, most of the metallic Fe-Ni occurs interstitially between silicate grains and thus tends to have irregular morphologies. In many porphyritic chondrules, metallic Fe-Ni and troilite form rounded blebs in the mesostasis because their precursors were immiscible droplets. In metamorphosed ordinary chondrites, metallic Fe-Ni and troilite form coarse anhedral grains. Some of the metallic Fe-Ni and troilite grains has also been mobilized and injected into fractures in adjacent silicate grains where local shock-reheating temperatures reached the Fe-FeS eutectic (988 C). In interplanetary dust particles metallic Fe-Ni most commonly occurs along with sulfide as spheroids and fragments. Euhedral metallic Fe-Ni grains are extremely rare. Several conditions must be met before such grains can form: (1) grain growth must occur at free surfaces, restricting euhedral metallic Fe-Ni grains to systems that are igneous or undergoing vapor-deposition; (2) the metal (+/-) sulfide assemblage must have an appropriate bulk composition so that taenite is the liquidus phase in igneous systems or the stable condensate phase in vapor-deposition systems; and (3) metallic Fe-Ni grains must remain underformed during subsequent compaction, thermal metamorphism, and shock. Because of these restrictions, the occurrence of euhedral metallic Fe-Ni grains in an object can potentially provide important petrogenetic information. Despite its rarity, euhedral metallic Fe-Ni occurs in a wide variety of extraterrestrial materials. Some of these materials formed in the solar nebula; others formed on parent body surfaces by meteoroid impacts.

Rubin, Alan E.↗