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Comet Shoemaker-Levy 9, Jupiter, and Impact Shock Chemistry

Four years ago this month, a hitherto unknown comet in loose orbit around Jupiter passed so near the giant planet that it was torn apart into 20 fragments by tides. One orbit later, two years ago this month, the fragments of doomed comet P/Shoemaker Levy (SL9) fell into Jupiter. The enormous energies of these impacts (the largest fragments were nearly 1 km across and, hitting at 60 km/s, released some 2-4 x 10(exp 27) ergs) produced enormous explosions. Several of the ejecta plumes were imaged towering 3000 km above Jupiter's limb. The heat released when the plumes fell was considerable and easily observed on Earth. The impacts produced strong shocks, both promptly at the impact site and again, later, and over thousands of kilometers, when the ejecta plume reentered the atmosphere. The focus of this talk will be to discuss what the SL9 impacts taught us about impact shock chemistry - the processes, the ingredients, the results - and what inferences we may draw for impacts on early Earth. Shock chemistry generates a suite of molecules not usually seen on Jupiter. The most surprising report was of a huge amount of diatomic sulfur S2 at the site of the G impact. Other unusual products include CS, CS2, OCS, H2S, SO2, HCN, CO, and H2O; although H2S and H2O are doubtless abundant below the visible clouds. Hot or enhanced CH4 and NH3 were also detected. A general rule of shock chemistry is that CO forms until either C or O is exhausted. If O greater than C, the other products are oxidized, and excess O goes to H2O. If C greater than O, the other products are reduced, and excess C goes to HCN, C2H2, and a wide variety of more complicated organics. Ultimately, given time, the carbon would react all the way to graphite, but in practice the reactions are incomplete. The dark ejecta debris were probably composed in part of carbonaceous particles generated by the shocks. In a sense, the SL9 impacts performed the famous Miller-Urey experiment on a grand scale, with one result being the production of a lot of complex brown organic solids (called "tholins"). We use, a straightforward chemical kinetics model for the H, N, C, O, S system to follow the nonequilibrium chemistry behind the shocks. The model traces the evolving chemical composition of a parcel of gas by directly integrating the web of chemical reactions. Pressure and temperature histories of the parcels are patterned after those calculated by numerical hydrodynamic simulations of the ejecta plume. A given plume parcel is generally shocked twice; t.e a parcel shocked near the impact site is ejected at high velocity and is shocked again when it reenters the atmosphere. The final state of the gas depends mostly on the second shock, provided that the latter is hot enough. The chemical evidence is ambiguous, but most indications are that C greater than O in the shocked, reacting gas. Telltale signatures of abundant oxygen - SO2, SO, CO2, O2 - were not seen, while signatures of abundant carbon - CS, CS2, and HCN - were. On the other hand, abundant H2O would appear to require O greater than C, and two other observed sulfur species, S2 and OCS, appear to form more easily in a somewhat oxidized gas, presumable vaporized from the comet itself. Since on general principles one expects the -comet to have had a more-or-less cosmic composition, i.e. O greater than C, the production of CS, CS2, and HCN probably requires C greater than O in the shocked jovian air. This in turn implies that even the largest fragments released the bulk of their energy above the jovian water table, in all likelihood above 5 bars . There is no evidence in favor of the proposition that a significant amount of wet jovian air was shocked strongly enough to coax water to react; i.e. wet jovian air saw only temperatures significantly below 2000 K.

Zahnle, Kevin↗

The Dynamics of a High Mach Number Quasi-Perpendicular Shock: MMS Observations

Shock parameters at Earth’s bow shock, in rare instances, can approach the Mach numbers predicted at astrophysical shocks and supernova remnants. We present our analysis of a high Alfv ́en Mach number (MA= 27) shock, by utilizing multipoint measurements from the Magnetospheric Multiscale (MMS) spacecraft during a crossing of Earth’s quasi-perpendicular bow shock. We find that the shock dynamics are mostly driven by reflected ions, perturbations that they generate, and nonlinear amplification of the perturbations. Our analyses indicate that reflected ions create modest magnetic enhancements upstream of the shock front which evolve in a nonlinear manner as they traverse the shock foot. They can transform into proto-shocks that propagate at small angles to the magnetic field and towards the bow shock. The nonstationary bow shock shows signatures of both reformation and surface ripples. Our observations indicate that although shock reformation occurs, the main shock layer never disappears. These observations are at high plasmaβ, a parameter regime which has not been well explored by numerical models.

H Madanian↗

Oblique High Mach Number Heliospheric Shocks: The Role of α Particles

Spacecraft observations of heliospheric shocks often find oscillations in the magnetic field and density both, upstream and downstream. The downstream magnetic oscillations of oblique collisionless shocks were detected by Wind with 10.9 samples/s and DSCOVR spacecraft with high temporal resolution of 50 samples/s. The density oscillations associated with the shocks are also evident in proton and α particle density by Wind (with much lower temporal resolution). Recently, we have investigated low Mach number low-β oblique shock oscillations using satellite data and 2.5D hybrid modeling with electrons modeled as fluid and ions modeled as particles and found that α particles—an important component of heliospheric plasma—may affect considerably the downstream oscillations and the shock structure. The objective of the present study is to investigate the effects of α particles on high Mach number heliospheric shocks dynamics, oscillations, nonstationarity, and shock-front rippling. We extend the study to high Mach number shocks (M > 3), investigate several α particle typical densities, and compare the results for the various shock parameters. We model the effects of α particles on the shock ramp, wake, and downstream oscillation structure and the kinetic properties of proton and α particle velocity distributions at various locations downstream of the shocks. Using the 2.5D hybrid model we found that the modeled high Mach number quasi-perpendicular shock magnetic and density structures are significantly affected by α particles with typical solar wind relative abundances, suggesting that the observed high Mach number shocks are similarly affected by α particles.

Leon Ofman↗

The evolution of interplanetary shocks

Unambiguous identification of the solar events associated with 48 interplanetary (IP) shocks has been facilitated by the observation of radio emission generated by the shocks. This identification makes possible an investigation of the way in which these shocks evolve and of the relationship between solar event 'strength' and shock velocity. All but two of the 48 solar events associated with IP type II radio emission included long-duration soft X-ray events (LDE's). In addition, it is shown that all intense LDE's are associated with IP shocks. A weak correlation between the integral flux of soft X-rays and the average velocity of the associated shock is suggested. However, for two events all of the usual flare signatures were absent, and the events are associated with the disappearance of solar filaments. It is shown that the shocks propagate isotropically over about 50 deg from the source site. Beyond 50 deg the shocks weaken particularly on their eastern flanks. As a consequence, shocks originating on the west limb cannot reach the earth. IP type II radio emission is dependent on shock velocity with faster shocks producing more intense emission. The study shows that radio intensities provide information about the evolution of IP shocks.

Cane, H. V.↗

Shock evolution in the outer heliosphere - Voyager and Pioneer observations

Observations are reported of 35 interplanetary shocks detected at heliocentric distances between 6.5 and 9.4 AU in mid-1980 by the Voyager 1, Voyager 2, and Pioneer 11 spacecraft. These shocks were all evidently generated by the interaction of corotating streams. Measurements of the pre- and postshock plasma parameters are used to determine the shock normals and speeds for each shock. Twelve of these 35 events are observed at all three spacecraft. The shock parameters at each spacecraft are compared to determine the time history for the 12 shocks. The single-spacecraft determinations of shock normal and speed are compared wih the results of several techniques for determining shock velocities using all three spacecraft. It is found that shocks undergo significant evolution as they travel past the three spacecraft. Every shock seen by both end spacecraft was also seen by the middle spacecraft. Shock formation possibly may be occurring at a heliocentric distance as great as 7 AU. It appears that the shock surfaces have a complex three-dimensional structure with 'ripples' on a scale of 0.001-1.0 AU.

Gazis, P. R.↗

Fast-shock formation in line-tied magnetic reconnection models of solar flares

In a previous study by the author, an approximately stationary fast shock was tentatively identified in a numerical experiment designed to study line-tied magnetic reconnection. Here the evidence for the occurrence of a stationary fast shock is reexamined, and the previous identification is confirmed. In the numerical experiment, line-tied reconnection is modeled by a configuration which produces two supermagnetosonic outflow jets - one directed upward, away from the photosphere, and one directed downward, toward an arcade of closed magnetic loops tied to the photosphere. The fast shock occurs when the downward-directed jet encounters the obstacle formed by the closed loops. Although the existence of a stationary, or nearly stationary, fast shock is confirmed, the transition from the supermagnetosonic flow region upstream of the shock to the nearly static region downstream of the shock is more complicated than was previously thought. Immediately downstream of the shock, there exists a deflection sheath in which the submagnetosonic flow coming out of the shock is diverted around the region of static closed loops. The MHD jump conditions are used to investigate the characteristics of the fast shock and to show that a stationary shock cannot exist unless accompanied by a deflection sheath. Analysis of the shock's location and dimensions suggests that such fast shocks may contribute to particle acceleration and to thermal condensation in flares.

Forbes, T. G.↗

Survival of carbon grains in shocks

Supernova shocks play a significant part in the life of an interstellar grain. In a typical 10 to the 9th power year lifetime, a grain will be hit by an average of 10 shocks of 100 km s(sup -1) or greater velocity, and even more shocks of lower velocity. Evaluation of the results of this frequent shock processing is complicated by a number of uncertainties, but seems to give about 10 percent destruction of silicate grains and about half that for graphite grains. Because of the frequency of shocking, the mineralogy and sizes of the grain population is predominately determined by shock processing effects, and not by the initial grain nucleation and growth environment. One consequence of the significant role played by interstellar shocks is that a certain fraction (up to 5 percent) of the carbon should be transformed into the diamond phase. Diamond transformation is observed in the laboratory at threshold shock pressures easily obtainable in grain-grain collisions in supernova shocks. Yields for transforming graphite, amorphous carbon, glassy carbon, and other nearly pure carbon solids into diamond are quite high. Impurities up to at least the 10 percent level (for oxygen) are tolerated in the process. The typical size diamond expected from shock transformation agrees well with the observed sizes in the Lewis et al. findings in meteoritic material. Isotropic anomalies already contained in the grain are likely to be retained through the conversion process, while others may be implanted by the shock if the grain is close to the supernova. The meteoritic diamonds are likely to be the results of transformation of carbon grains in grain-grain collisions in supernova shock waves.

Seab, C. Gregory↗

Experimental studies of hypersonic shock-wave boundary-layer interactions

Two classes of shock-wave boundary-layer interactions were studied experimentally in a shock tunnel in which a low Reynolds number, turbulent flow at Mach 8 was developed on a cold, flat test surface. The two classes of interactions were: (1) a swept interaction generated by a wedge ('fin') mounted perpendicularly on the flat plate; and (2) a two-dimensional, unseparated interaction induced by a shock impinging near an expansion corner. The swept interaction, with wedge angles of 5-20 degrees, was separated and there was also indication that the strongest interactions prossessed secondary separation zones. The interaction spread out extensively from the inviscid shock location although no indication of quasi-conical symmetry was evident. The surface pressure from the upstream influence to the inviscid shock was relatively low compared to the inviscid downstream value but it rose rapidly past the inviscid shock location. However, the surface pressure did not reach the downstream inviscid value and reasons were proposed for this anomalous behavior compared to strongly separated, supersonic interactions. The second class of interactions involved weak shocks impinging near small expansion corners. As a prelude to studying this interaction, a hypersonic similarity parameter was identified for the pure, expansion corner flow. The expansion corner severely damped out surface pressure fluctuations. When a shock impinged upstream of the corner, no significant changes to the surface pressure were found as compared to the case when the shock impinged on a flat plate. But, when the shock impinged downstream of the corner, a close coupling existed between the two wave systems, unlike the supersonic case. This close coupling modified the upstream influence. Regardless of whether the shock impinged ahead or behind the corner, the downstream region was affected by the close coupling between the shock and the expansion. Not only was the mean pressure distribution modified but the unsteadiness in the surface pressure was reduced compared to the flat-plate case.

Lu, Frank K.↗

Interaction between perpendicular magnetohydrodynamic shocks

A general analysis is made of the collision and merging of perpendicular shocks as well as the interaction between a shock and a tangential discontinuity. It is found that two head-on shocks diminish both in strength after collisions and a tangential discontinuity forms between them. The property of the discontinuity depends on the relative strength of the two shocks. No discontinuity occurs if the shocks are equal in strength. The emerging of two shocks propagating in the same direction results in a strong shock followed by a tangential discontinuity and a reverse wave. The reverse wave is a rarefaction wave if one or both of the shocks are strong. If the shocks are both weak, a critical adiabatic index (CAI) exists. The reverse wave is a rarefaction wave if the wavelength is less than the CAI and a shock exists if the wavelength is greater than the CAI. As a wake shock enters from a medium of higher wave impedance into that of lower wave impedance, the reflected wave is a rarefaction wave and the total pressure ratio decreases and the velocity jump increases after the shock passes through the border.

Hu, Y. Q.↗

Standing shocks in a two-fluid solar wind

We present a numerical study of the formation of standing shocks in the solar wind using a two-fluid time-dependent model in the presence of Alfven waves. Included in this model is the adiabatic cooling and thermal conduction of both electrons and protons. In this study, standing shocks develop in the flow when additional critical points form as a result of either localized momentum addition or rapid expansion of the flow tube below the existing sonic point. While the flow speed and density exhibit the same characteristics as found in earlier studies of the formation of standing shocks, the inclusion of electron and proton heat conduction produces different signatures in the electron and proton temperature profiles across the shock layer. Owing to the strong heat conduction, the electron temperature is nearly continuous across the shock, but its gradient has a negative jump across it, thus producing a net heat flux out of the shock layer. The proton temperature exhibits the same characteristics for shocks produced by momentum addition but behaves differently when the shock is formed by the rapid divergence of the flow tube. The adiabatic cooling in a rapidly diverging flow tube reduces the proton temperature so substantially that the proton heat conduction becomes negligible in the vicinity of the shock. As a result, protons experience a positive jump in temperature across the shock. While Alfven waves do not affect the formation of standing shocks, they contribute to the change of the mmomentum and energy balance across them. We also find that for this solar wind model the inclusion of thermal conduction and adiabatic cooling for the elctrons and protons increases significantly the range of parameters characterizing the formation of standing shocks over those previously found for isothermal and polytropic models.

Habbal, Shadia R.↗

Shock propagation and the generation of magnetohydrodynamic wave fields in inhomogeneous molecular clouds

We develop a simple one-dimensional model for the interaction of a steady, thin, planar shock wave with a nonrigid cloud which may be in motion relative to the surrounding medium, and we apply the model to shocks impinging on, and propagating through, molecular clouds. Both 'adiabatic' (gamma = 5/3) and radiative (gamma = 1) shocks are considered and we allow for the presence of a uniform magnetic field directed either parallel or perpendicular to the shock normal. The former field orientation is equivalent to the hydrodynamic case, and the latter involves only fast MHD shocks. We focus on the manner in which such shocks can generate internal kinetic motions in the cloud on a range of size and density scales through the direct acceleration of cores and clumps by shocks transmitted into them and through the generation of an MHD wavefield via the reflection of the incident shock at clump boundaries. We find that stronger incident Mach numbers and smaller density contrasts lead to more efficient cloud acceleration, as do isothermal intercloud shocks and small intercloud magnetic field strengths. The acceleration efficiency is insensitive to the adiabatic index and the magnetic field strength in the cloud itself. For typical parameter choices, the direct acceleration of clouds and clumps by strong shocks is found to be substantial and could at least in part account for their observed velocity dispersions. If the shocks are moderately weak, the final velocity of the cloud is linearly related to its initial velocity, with higher acceleration giving shallower slopes (i.e., final velocity distributions which are less sensitive to the initial distribution). Compared to the kinetic energy of the postshock cloud, the energy given to the wavefield at each encounter is small, and the heating of the interclump medium by the dissipation of this wavefield is found to be insufficient to balance the cooling rate in the cloud as a whole (although it may be important in particular regions), even if this medium is warm, unless it is also extremely tenuous (n approximately less than 0.1/cu cm). Nevertheless, the correction for the velocity imparted to the cloud leads to a substantial increase in the critical incident Mach numner for wave emission over that reported by Spitzer for the rigid case. The implications of our model for shock-induced star formation are discussed briefly.

Miesch, Mark S.↗

Motion of the Heliospheric Termination Shock at High Heliographic Latitude

We expect the mean distance of the heliospheric termination shock to be greater (smaller) at polar latitudes than at equatorial latitudes, depending on whether the mean dynamic pressure of the solar wind is greater or smaller at high latitudes. The heliospheric termination shock is expected to move in response to variation in upstream solar wind conditions, so that at any particular instant the termination shock will resemble a distorted asymmetric balloon with some parts moving inward and others moving outward. If the shock is a gasdynamic or magnetohydrodynamic shock the results of the analysis depend only very weakly on the nature of the upstream disturbance; typical speeds of the disturbed shock are approximately 100 to 200 km/s. In the absence of a significant latitude gradient of the typical magnitude of solar wind disturbances typical motions of the disturbed shock at polar latitudes would be about twice as fast, due to the higher speed of the high-latitude wind. If the dynamics of the termination shock are dominated by acceleration of the anomalous component of the cosmic rays, the motion of the shock in response to a given disturbance is substantially slower than in the gasdynamic case. Conceivably, particle acceleration might be a less important effect at higher latitudes, and we envision the possibility of a termination shock that is dominated by particle acceleration at lower latitudes and is an MHD shock at high latitudes. In this event high latitude solar wind disturbances would produce substantially larger inward and outward motions of the shock in the polar regions.

Barnes, Aaron↗

A Study of Fundamental Shock Noise Mechanisms

This paper investigates two mechanisms fundamental to sound generation in shocked flows: shock motion and shock deformation. Shock motion is modeled numerically by examining the interaction of a sound wave with a shock. This numerical approach is validated by comparison with results obtained by linear theory for a small-disturbance case. Analysis of the perturbation energy with Myers' energy corollary demonstrates that acoustic energy is generated by the interaction of acoustic disturbances with shocks. This analysis suggests that shock motion generates acoustic and entropy disturbance energy. Shock deformation is modeled numerically by examining the interaction of a vortex ring with a shock. These numerical simulations demonstrate the generation of both an acoustic wave and contact surfaces. The acoustic wave spreads cylindrically. The sound intensity is highly directional and the sound pressure increases with increasing shock strength. The numerically determined relationship between the sound pressure and the Mach number is found to be consistent with experimental observations of shock noise. This consistency implies that a dominant physical process in the generation of shock noise is modeled in this study.

Meadows, Kristine R.↗

Hybrid Simulations of Interstellar Pickup Ion Acceleration at the Solar Wind Termination Shock

Hybrid (kinetic ion/fluid electron) simulations have been used to study self-consistently the injection and initial stages of acceleration of interstellar pickup ions at the solar wind termination shock. Results are presented from one-dimensional simulations of high Mach number oblique (40 deg-50 deg) shocks with a 10% population of interstellar pickup hydrogen. In these simulations, the pickup ions, the solar wind ions, the shock fields and the waves are all treated self-consistently. Pickup ions reflected by the shock excite large amplitude (DELTA.B / B approximately 0.3) upstream magnetosonic waves. These waves, in turn, scatter the pickup hydrogen, as expected in the diffusive shock acceleration process. The spectrum of excited waves broadens in time. We find that, for the parameters studied, the termination shock efficiently injects and accelerates the interstellar pickup hydrogen, and thus this work represents a microscopic verification of this anomalous cosmic ray injection mechanism. Comparison of injected fluxes from the simulations with Voyager fluxes extrapolated to the termination shock suggests that injection at the termination shock is probably greater than injection by interplanetary shocks. A study of accelerated pickup ion orbits shows that the energy gain comes predominantly from shock drift acceleration in the shock front, with the upstream waves aiding the acceleration by allowing multiple encounters with the shock.

Liewer, P. C.↗

Magnetohydrodynamic Jump Conditions for Oblique Relativistic Shocks with Gyrotropic Pressure

Shock jump conditions, i.e., the specification of the downstream parameters of the gas in terms of the upstream parameters, are obtained for steady-state, plane shocks with oblique magnetic fields and arbitrary flow speeds. This is done by combining the continuity of particle number flux and the electromagnetic boundary conditions at the shock with the magnetohydrodynamic conservation laws derived from the stress-energy tensor. For ultrarelativistic and nonrelativistic shocks, the jump conditions may be solved analytically. For mildly relativistic shocks, analytic solutions are obtained for isotropic pressure using an approximation for the adiabatic index that is valid in high sonic Mach number cases. Examples assuming isotropic pressure illustrate how the shock compression ratio depends on the shock speed and obliquity. In the more general case of gyrotropic pressure, the jump conditions cannot be solved analytically with- out additional assumptions, and the effects of gyrotropic pressure are investigated by parameterizing the distribution of pressure parallel and perpendicular to the magnetic field. Our numerical solutions reveal that relatively small departures from isotropy (e.g., approximately 20%) produce significant changes in the shock compression ratio, r , at all shock Lorentz factors, including ultrarelativistic ones, where an analytic solution with gyrotropic pressure is obtained. In particular, either dynamically important fields or significant pressure anisotropies can incur marked departures from the canonical gas dynamic value of r = 3 for a shocked ultrarelativistic flow and this may impact models of particle acceleration in gamma-ray bursts and other environments where relativistic shocks are inferred. The jump conditions presented apply directly to test-particle acceleration, and will facilitate future self-consistent numerical modeling of particle acceleration at oblique, relativistic shocks; such models include the modification of the fluid velocity profile due to the contribution of energetic particles to the momentum and energy fluxes.

Double, Glen P.↗

Coronal Mass Ejection-driven Shocks and the Associated Sudden Commencements-sudden Impulses

Interplanetary (IP) shocks are mainly responsible for the sudden compression of the magnetosphere, causing storm sudden commencement (SC) and sudden impulses (SIs) which are detected by ground-based magnetometers. On the basis of the list of 222 IP shocks compiled by Gopalswamy et al., we have investigated the dependence of SC/SIs amplitudes on the speed of the coronal mass ejections (CMEs) that drive the shocks near the Sun as well as in the interplanetary medium. We find that about 91% of the IP shocks were associated with SC/SIs. The average speed of the SC/SI-associated CMEs is 1015 km/s, which is almost a factor of 2 higher than the general CME speed. When the shocks were grouped according to their ability to produce type II radio burst in the interplanetary medium, we find that the radio-loud (RL) shocks produce a much larger SC/SI amplitude (average approx. 32 nT) compared to the radio-quiet (RQ) shocks (average approx. 19 nT). Clearly, RL shocks are more effective in producing SC/SIs than the RQ shocks. We also divided the IP shocks according to the type of IP counterpart of interplanetary CMEs (ICMEs): magnetic clouds (MCs) and nonmagnetic clouds. We find that the MC-associated shock speeds are better correlated with SC/SI amplitudes than those associated with non-MC ejecta. The SC/SI amplitudes are also higher for MCs than ejecta. Our results show that RL and RQ type of shocks are important parameters in producing the SC/SI amplitude.

Coronal mass ejections↗

Kinetic Properties of an Interplanetary Shock Propagating Inside a Coronal Mass Ejection

We investigate the kinetic properties of a typical fast-mode shock inside an interplanetary coronal mass ejection (ICME) observed on 1998 August 6 at 1 au, including particle distributions and wave analysis with the in situ measurements from Wind. Key results are obtained concerning the shock and the shock-ICME interaction at kinetic scales: (1) gyrating ions, which may provide energy dissipation at the shock in addition to wave-particle interactions, are observed around the shock ramp; (2) despite the enhanced proton temperature anisotropy of the shocked plasma, the low plasma beta inside the ICME constrains the shocked plasma under the thresholds of the ion cyclotron and mirror-mode instabilities; (3) whistler heat flux instabilities, which can pitch-angle scatter halo electrons through a cyclotron resonance, are observed around the shock, and can explain the disappearance of bi-directional electrons (BDEs) inside the ICME together with normal betatron acceleration; (4) whistler waves near the shock are likely associated with the whistler heat flux instabilities excited at the shock ramp, which is consistent with the result that the waves may originate from the shock ramp; (5) the whistlers share a similar characteristic with the shocklet whistlers observed by Wilson et al., providing possible evidence that the shock is decaying because of the strong magnetic field inside the ICME.

Liu, Mingzhe↗

Novel Shock Microstructures in Accessory Minerals from the Haughton Dome, Devon Island, Nunavut, Canada

The 23 km-diameter, ca. 24 Ma Haughton Dome impact structure in the Canadian Arctic on Devon Island, Nunavut (89deg41′W, 75deg22′N) occurred within a two layered target composed of a shallowly-dipping ~1700 m thick succession of Paleozoic limestones and evaporates overlying ca.1.9 Ga high grade gneisses [1, 2]. Within the structure a well preserved impact melt bearing breccia unit contains a variety of shocked clasts from the pre-impact sediments and basement gneisses [3]. Due to their high level of preservation a variety of studies have been undertaken on the clast population of the melt bearing breccia, including characterization of shock within the accessory minerals of the basement lithologies [4, 5]. This study presents high resolution electron backscatter diffraction (EBSD) microstructural data for zircon and monazite from historic samples of the basement gneiss, in which bulk shock pressures have been previously constrained based on major phases [4, 6]. Shocked zircon and monazite grains have been investigated from shock stage 1b (sample 72110), 2 (7273) and 3 (7192, Dig-9) [4, 6]. At lower shock levels zircon displays planar microstructures consistent with mechanical shock {112} twin formation [7] and deviatoric transformation to the high pressure polymorph reidite [8]. Zircon grains from shock stage three show a more chaotic microstructure with multiple orientations of tightly spaced sets of reidite that are variably recrystallized to zircon neoblasts. Monazite from lower shock stages contains a number of mechanical twin orientations that are indicative of shock deformation [9]. At higher shock pressures a lath like structure of interlocking twin orientations has been identified. This microstructure is suggestive of a reversion transformation from a high pressure polymorph [10] and is the first evidence for the transformation of monazite during shock.

Erickson, Timmons M.↗