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At least 235 records · Page 13

Microscale Distribution of Hydrogen Isotopes in Two Carbonaceous Chondrites

Hydrogen isotopes are highly variable among primitive meteorites and interplanetary dust particles (IDPs) [1, 2]. In particular, many primitive objects exhibit D (and N-15) enrichments, relative to terrestrial values, thought to represent partial preservation of presolar material fractionated in molecular clouds. However, the diversity of D/H ratios among IDPs and chondrites indicates a complex history of processing in the solar nebula and on meteorite parent bodies. Deconvolving this record requires identification and characterization of the carriers of D enrichments in different objects. Isotopic imaging has proven to be a powerful method to quantitatively explore the distribution of D/H ratios on a one to several m scale in IDPs [2-4] and the CR chondrite Renazzo [5, 6]. In this study, we have used ion imaging to explore the microscale D/H distribution of two carbonaceous chondrites, Tagish Lake (unique) and Al Rais (CR2). Previous D/H measurements (on a ~tens of microns scale) of Tagish Lake matrix fragments by Messenger [7] and Engrand et al. [8] have found different results, most likely related to the analytical techniques used. Previous work has also shown a large range of D/H ratios in CR chondrites, including very large variations on a scale of a few microns [5, 6, 9].

Young, A. F.↗

The Evolution and Development of the Lunar Regolith and Implications for Lunar Surface Operations and Construction

The lunar regolith consists of about 90% submillimeter particles traditionally termed lunar soil. The remainder consists of larger particles ranging up to boulder size rocks. At the lower size end, soil particles in the 10s of nanometer sizes are present in all soil samples. Lunar regolith overlies bedrock which consists of either lava flows in mare regions or impact-produced megaregolith in highland regions. Lunar regolith has been produced over billions of years by a combination of breaking and communition of bedrock by meteorite bombardment coupled with a variety of complex space weathering processes including solar wind implantation, solar flare and cosmic ray bombardment with attendant radiation damage, melting, vaporization, and vapor condensation driven by impact, and gardening and turnover of the resultant soil. Lunar regolith is poorly sorted compared to most terrestrial soils, and has interesting engineering properties including strong grain adhesion, over-compacted soil density, an abundance of agglutinates with sharp corners, and a variety of properties related to soil maturity. The NASA program has supported a variety of engineering test research projects, the production of bricks by solar or microwave sintering, the production of concrete, the in situ sintering and glazing of regolith by microwave, and the extraction of useful resources such as oxygen, hydrogen, iron, aluminum, silicon and other products. Future requirements for a lunar surface base or outpost will include construction of protective berms, construction of paved roadways, construction of shelters, movement and emplacement of regolith for radiation shielding and thermal control, and extraction of useful products. One early need is for light weight but powerful digging, trenching, and regolith-moving equipment.

McKay, David↗

Venus Radar Mapper (VRM): Multimode radar system design

The surface of Venus has remained a relative mystery because of the very dense atmosphere that is opaque to visible radiation and, thus, normal photographic techniques used to explore the other terrestrial objects in the solar system are useless. The atmosphere is, however, almost transparent to radar waves and images of the surface have been produced via Earth-based and orbital radars. The technique of obtaining radar images of a surface is variously called side looking radar, imaging radar, or synthetic aperture radar (SAR). The radar requires a moving platform in which the antenna is side looking. High resolution is obtained in the cross-track or range direction by conventional radar pulse encoding. In the along-track or azimuth direction, the resolution would normally be the antenna beam width, but for the SAR case, a much longer antenna (or much sharper beam) is obtained by moving past a surface target as shown, and then combining the echoes from many pulses, by using the Doppler data, to obtain the images. The radar design of the Venus Radar Mapper (VRM) is discussed. It will acquire global radar imagery and altimetry data of the surface of Venus.

Johnson, William T. K.↗

Space astrophysics with large structures - CASES and P/OF

Space instruments for remote sensing, of the types used for astrophysics and solar-terrestrial physics among many disciplines, will grow to larger physical sizes in the future. The zero-g space environment does not inherently restrict such growth, because relatively lightweight structures can be used. Active servo control of the structures can greatly increase their size for a given mass. The Pinhole/Occulter Facility, a candidate Space Station attached payload, offers an example: it will achieve 0.2 arc s resolution by use of a 50-m baseline for coded-aperture telescopes for hard X-ray and gamma-ray imagers.

Hudson, Hugh S.↗

The abundances of Pt, Au, and Hg in the chemically peculiar HgMn-type stars kappa Cancri and chi Lupi

Echelle mode spectra obtained with the Goddard High Resolution Spectrograph (GHRS) onboard the Hubble Space Telescope (HST) have been used to determine the abundances of the heavy elements Pt, Au, and Hg in the chemically peculiar HgMn-type stars kappa Cancri and chi Lupi. The abundances were determined by fitting observed line profiles with synthetically generated spectra and are found to be enhanced relative to solar system values by between three and five orders of magnitude in both stars. The Hg isotope mixture in kappa Cancri is found to resemble the terrestrial mixture while that of chi Lupi is dominated by the heaviest isotope. As determined from multiple ionization states, the abundances place constraints upon theories attempting to explain the large superficial abundances of heavy elements.

Wahlgren, Glenn M.↗

Nitrogen Isotopic Imaging of Tagish Lake Carbon Globules

Chondritic meteorites and interplanetary dust particles commonly exhibit significant enrichments in deuterium (D) and N-15 relative to terrestrial materials. These anomalies are usually ascribed to low temperature chemical processes occurring in a presolar cold molecular cloud and/or physically similar regions of the outer solar nebula. The sizes of these anomalies vary considerably among different classes of meteorites, in some cases on a microscopic scale, reflecting differing degrees of alteration and dilution of the presolar components owing to parent body processing.

Messenger, S.↗

Revisiting the Origin of Macromolecular Carbon (MMC) in Lunar Basalts 15556 & 10044

Volatile elements influence the geo-chemical evolution of planetary bodies and they are in magmas at every stage, from melting within planetary interiors to eruption at the surface. Analyses of lunar mare basalts supported the hypothesis that lunar mag-mas were depleted in volatiles (H-C-F-Cl-S), relative to their terrestrial analogs [1]. Nevertheless, several early studies of samples returned during the Apollo program proposed that the mare basalt eruptions, including the “fire fountain” eruptions, were propelled by the oxidation of magmatic graphite to CO (and/or CO2) gas [2, 3]. Seminal studies during the 1970’s measured the bulk concentration and isotopic compositions of C from Apollo 11 samples, and identified several carbonaceous compounds, including: (a) gaseous (CO, CO2, and traces of CH4), (b) metallic carbide, and (c) potentially elemental carbon [4-6]. These studies reported a relatively broad range of C contents (~100-400 μg/g) and isotopic values (δC13 = -30 to +20), and suggested that these heterogeneities can be explained by contribution from multiple factors, including: (a) indigenous carbon, (b) solar wind implantation, (c) bombardment and/or meteorite impact, and (d) terrestrial contamination [5,6]. However, unequivocal observations of magmatic graphite in lunar basalts have never been made. Macromolecular carbon (MMC)—graphitic carbon varying from nearly amorphous to highly crystalline varieties—was identified as inclusions hosted by igneous pyroxenes from Martian meteorites and were attributed to being indigenous to Mars [8]. The authors carefully considered the textural and mineralogical relationship of the MMC phases, and concluded that the subset of MMC located within and/or adjacent to cracks, or at a disrupted surface (e.g., cut) were most consistent with terrestrial contamination. The near absence of con-firmed instances of lunar magmatic MMC within the literature [9], combined with the wide range of isotopic values and bulk carbon contents measured in lunar bas-alts begs the question as to whether previously measured carbon is of an indigenous origin, or the result of terrestrial contamination. Using Raman spectroscopy, we have observed MMC in lunar basalts subjected to different forms of anthropogenic modification related to sample preparation including polished sections, sawn surfaces, and fractured surfaces adjacent to sawn sur-faces. We have observed MMC of unknown origin in all of these settings. Here we report the preliminary textural and spectroscopic characteristics of MMC hosted within the groundmass of Apollo 15 (15556) and Apollo 11 basalts (10044) as part of our ongoing investigation of the origin of these carbonaceous materials.

lunar↗

Characterization of terrestrial service environments - The simultaneous occurrence of combined conditions of solar insolation and climatic variables

Computational methods for occurrences of combined environmental and pollution variables are compared. General statistical data and diurnal statistics on 24 environmental variables are treated. Combinations of variables dealt with include: air temperature, relative humidity, wind speed, total insolation; air temperature and weather event (rain, fog); air pollutant and weather event; wind speed, wind direction, and weather event; air temperature, total insolation, and weather event; air temperature, relative humidity, wind speed, computed direct insolation levels; air temperature, relative humidity, air pollution.

Thomas, R. E.↗

Magnesium Isotopes in the Earth, Moon, Mars, and Pallasite Parent Body: High-Precision Analysis of Olivine by Laser-Ablation Multi-Collector ICPMS

Magnesium isotopes potentially offer new insights into a diverse range of processes including evaporation and condensation in the solar nebula, melting and metasomatism in planetary interiors, and hydrothermal alteration [1,2,3,4]. Volatility-related Mg isotopic variations of up to 10 per mil/amu relative to a terrestrial standard have been found in early nebular phases interpreted as evaporation residues [1], and relatively large variations (up to 3 per mil/amu) in the terrestrial mantle have been reported recently [4]. In order to investigate possible differences in the nebular history of material contributing to the terrestrial planets, and to search for evidence of a high-temperature origin of the Moon, we have measured the magnesium isotopic composition of primitive olivines from the Earth, Moon, Mars, and pallasite parent body using laser-ablation multicollector ICPMS.

Norman, M.↗

Manufacturing Large Membrane Mirrors at Low Cost

Relatively inexpensive processes have been developed for manufacturing lightweight, wide-aperture mirrors that consist mainly of reflectively coated, edge-supported polyimide membranes. The polyimide and other materials in these mirrors can withstand the environment of outer space, and the mirrors have other characteristics that make them attractive for use on Earth as well as in outer space: With respect to the smoothness of their surfaces and the accuracy with which they retain their shapes, these mirrors approach the optical quality of heavier, more expensive conventional mirrors. Unlike conventional mirrors, these mirrors can be stowed compactly and later deployed to their full sizes. In typical cases, deployment would be effected by inflation. Potential terrestrial and outer-space applications for these mirrors include large astronomical telescopes, solar concentrators for generating electric power and thermal power, and microwave reflectors for communication, radar, and short-distance transmission of electric power. The relatively low cost of manufacturing these mirrors stems, in part, from the use of inexpensive tooling. Unlike in the manufacture of conventional mirrors, there is no need for mandrels or molds that have highly precise surface figures and highly polished surfaces. The surface smoothness is an inherent property of a polyimide film. The shaped area of the film is never placed in contact with a mold or mandrel surface: Instead the shape of a mirror is determined by a combination of (1) the shape of a fixture that holds the film around its edge and (2) control of manufacturing- process parameters. In a demonstration of this manufacturing concept, spherical mirrors having aperture diameters of 0.5 and 1.0 m were fabricated from polyimide films having thicknesses ranging from <20 m to 150 m. These mirrors have been found to maintain their preformed shapes following deployment.

FROM↗

A Chlorine Isotope Transect Across the Sudbury Impact Deposits Reveals Enigmatic Isotopic Fractionation

Volatile elements play an important role in a variety of cosmochemical and geochemical processes. As such, there has been significant interest in their abundance and isotopic composition. Chlorine is an important element for tracing these processes because it is incompatible in nearly all minerals, extremely volatile, and strongly hydrophilic [1]. The Cl isotope composition ( 37 Cl/ 35 Cl) of meteoritic components, therefore, can provide useful information regarding the isotopic reservoirs that were present in the early Solar System and any secondary processes that may have occurred on different parent bodies (e.g., [2-4]). There is a relatively narrow range in the Cl isotope compositions of terrestrial, Martian, and chondritic meteorites (δ 37 Cl ~ −6 to +4‰) (e.g., [2,3,5,6]), with exceptions to this being the Moon and Vesta (up to ~ +81‰ and ~ +40‰, respectively) [4, 5, 7-10]. One hypothesis for the extreme Cl isotope fractionation observed on the Moon is degassing following large-scale (possibly even crust-breaching) impact events [7-9]. The role of hypervelocity impacts and impact-generated magmatism in the isotopic evolution of planetary materials, however, has been until recently an area of limited published research with the majority of works focusing on the effects of impact shock (e.g., [10-13]). The ~ 1.85 Ga Sudbury impact crater [14] located in Ontario, Canada, is one of the three largest impact craters on Earth with good exposures of its impact melt sheet and overlying breccias [15,16]. The impact melt sheet, called the Sudbury Igneous Complex (SIC), is up to 5 km thick [17], with an estimated original volume of >10 4 km 3 [18], and differentiated. Recent work demonstrated evaporative loss and isotope fractionation of the moderately volatile element zinc and suggest melt sheets produced by impacts could have a significant effect on the Earth’s volatile inventory [19]. In this study we investigate the abundance and isotopic composition of Cl as well the water abundance of apatite from the SIC and the overlying crater-fill to test the hypothesis that large-scale impacts may have generated the extensive Cl isotopic fractionation observed on the Moon.

Sudbury↗

Xenon fractionation in porous planetesimals

The distinctively fractionated Xe on Mars and earth may have its root in a common source from which both planets accreted. Beginning with Ozima and Nakazawa's (1980) hypothesis that terrestrial Xe fractionation was caused by gravitational separation of adsorbed solar nebular gases inside large porous planetesimals, it is pointed out that Xe would have been trapped as the planetesimal grew and pores were squeezed shut by lithostatic pressure. It is shown that enough fractionated Xe to supply the earth could have been trapped this way. The degree of fractionation is controlled by the lithostatic pressure at the pore-closing front and so would have been roughly the same for all large planetesimals. The predicted degree of fractionation agrees well with that preserved in terrestrial and Martian Xe. Relative to Xe, this source is strongly depleted in other noble gases. In contrast to the original Ozima and Nakazawa hypothesis, the present hypothesis predicts the observed fractionation, and it allows planetary accretion to occur after the dissipation of the solar nebula.

Zahnle, Kevin↗

Historical perspective of barriers to achieving high-efficiency silicon solar cells

Early silicon solar cells were made of metallurgical-grade silicon with very low efficiency. The single-crystal silicon introduced in the mid-50's increased the efficiency to the 5% to 10% region. Throughout the 1960s the technology of the 2 x 2 cm or 2 x 4 cm space solar cell with 10% efficiency was established. In the early 1970s work related to the violet cell upset the status quo and space solar cells and cells in general became more efficient. The rest of the decade became characterized by establishing a terrestrial photovoltaic technology to support the development of a new industry. Costs per watt became the dominant consideration and frequently the efficiency was compromised. The introduction of materials and other forms of silicon dropped the efficiency and it is now a state of mine that accomplishing 10% efficiency with some alternative combination is regarded as success. Silicon solar cells are capable of delivering efficiences much greater than 10%.

Lindmayer, J.↗

Trapped noble gases in meteorites

The trapped noble gases in meteorites come in two main varieties, usually referred to as solar and planetary. The solar noble gases are implanted solar-wind or solar-flare materials, and thus their relative elemental abundances provide a good estimate of those of the sun. The planetary noble gases have relative elemental abundances similar to those in the terrestrial atmosphere, but there are also important distinctions. At least one other elemental pattern (subsolar) and several isotopic patterns have also been identified.

Swindle, Timothy D.↗

Determination of launch conditions for Spacelab satisfying the constraints of an absorption spectroscopy project

The conditions for absorption spectroscopy of the homosphere between 20 and 100 km from a space platform such as Spacelab are considered. Using nominal orbital elements, and taking launch data and time as parameters of the problem, formula were established that give the data necessary for determining the flight plan. The geographical coordinates of the tangential points of the solar illumination boundaries were also calculated. It is shown that the latitude coverage of the observation is closely related to launch conditions. Expressions for the pointing angles referred to an instantaneous terrestrial trihedron are given. These angular elements are needed to determine the real pointing angles in a reference system linked to Spacelab.

Vercheval, J.↗

Scientific study in solar and plasma physics relative to rocket and balloon projects

The goals of this research are to provide scientific and technical capabilities in the areas of solar and plasma physics contained in research programs and instrumentation development relative to current rocket and balloon projects; to develop flight instrumentation design, flight hardware, and flight program objectives and participate in peer reviews as appropriate; and to participate in solar-terrestrial physics modeling studies and analysis of flight data and provide theoretical investigations as required by these studies.

Wu, S. T.↗

Environmental tests of metallization systems for terrestrial photovoltaic cells

Seven different solar cell metallization systems were subjected to temperature cycling tests and humidity tests. Temperature cycling excursions were -50 deg C to 150 deg C per cycle. Humidity conditions were 70 deg C at 98% relative humidity. The seven metallization systems were: Ti/Ag, Ti/Pd/Ag, Ti/Pd/Cu, Ni/Cu, Pd/Ni/Solder, Cr/Pd/Ag, and thick film Ag. All metallization systems showed a slight to moderate decrease in cell efficiencies after subjection to 1000 temperature cycles. Six of the seven metallization systems also evidenced slight increases in cell efficiencies after moderate numbers of cycles, generally less than 100 cycles. The copper based systems showed the largest decrease in cell efficiencies after temperature cycling. All metallization systems showed moderate to large decreases in cell efficiencies after 123 days of humidity exposure. The copper based systems again showed the largest decrease in cell efficiencies after humidity exposure. Graphs of the environmental exposures versus cell efficiencies are presented for each metallization system, as well as environmental exposures versus fill factors or series resistance.

Alexander, P., Jr.↗

Direct solar energy conversion for large scale terrestrial use

Various techniques to increase the open circuit voltage are being explored. It had been previously observed that cells made on CdS deposited from a single source gave a consistently higher V sub oc. Further tests have now shown that this effect may in fact relate to differences in source and substrate temperatures. The resulting differences in CdS structure and crystallinity are being documented. Deposits of mixed CdS and ZnS are being produced and will be initially made into cells using the conventional barriering technique. Analysis of I-V characteristics at temperatures between 25 and 110 C is being perfected to provide nondestructive analysis of the Cu2S. Changes due to vacuum heat treatments and exposure to oxygen are also being monitored by the same technique. Detailed spectral response measurements are being made.

Boeer, K. W.↗