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At least 235 records · Page 13

NMR (Nuclear Magnetic Resonance) and macromolecular migration in a melt or in concentrated solutions

The purpose of this paper is to analyze the migration process of long polymer molecules in a melt or in concentrated solutions as it may be observed from the dynamics of the transverse magnetization of nuclear spins linked to these chains. The low frequency viscoelastic relaxation of polymer systems is known to be mainly controlled by the mechanism of dissociation of topological constraints excited on chains and which are called entanglements. This mechanism exhibits a strong dependence upon the chain molecular weight. These topological constraints also govern the diffusion process of polymer chains. So, the accurate description of the diffusion motion of a chain may be a convenient way to characterize disentanglement processes necessarily involved in any model proposed to explain viscoelastic effects.

Addad, J. P. C.↗

Provenance Representation in the Global Change Information System (GCIS)

Global climate change is a topic that has become very controversial despite strong support within the scientific community. It is common for agencies releasing information about climate change to be served with Freedom of Information Act (FOIA) requests for everything that led to that conclusion. Capturing and presenting the provenance, linking to the research papers, data sets, models, analyses, observation instruments and satellites, etc. supporting key findings has the potential to mitigate skepticism in this domain. The U.S. Global Change Research Program (USGCRP) is now coordinating the production of a National Climate Assessment (NCA) that presents our best understanding of global change. We are now developing a Global Change Information System (GCIS) that will present the content of that report and its provenance, including the scientific support for the findings of the assessment. We are using an approach that will present this information both through a human accessible web site as well as a machine readable interface for automated mining of the provenance graph. We plan to use the developing W3C PROV Data Model and Ontology for this system.

Tilmes, Curt↗

Pilot workload prediction

A predicting model of pilot workload is developed using a time-based algorithm, work-load values from previous research, and experimental data obtained by a group of experienced pilots on a Singer-Link Gat-1 instrument trainer with three degrees of motion (roll, pitch, and yaw). Each pilot performed three experimental flights presented in a counterbalanced order; each flight consisted of short, medium, or long cruise and initial approach segments. Results strongly suggest that pilots were more sensitive to the rate at which work was done than to the total amount of work accomplished. The result of predictions obtained with the model showed that the time-weighted average of the component work-load ratings were able to predict the obtained work-load ratings accurately.

Pepitone, David D.↗

Aerosol-Induced Changes of Convective Cloud Anvils Produce Strong Climate Warming

The effect of aerosol on clouds poses one of the largest uncertainties in estimating the anthropogenic contribution to climate change. Small human-induced perturbations to cloud characteristics via aerosol pathways can create a change in the top-of-atmosphere radiative forcing of hundreds of Wm(exp-2) . Here we focus on links between aerosol and deep convective clouds of the Atlantic and Pacific Intertropical Convergence Zones, noting that the aerosol environment in each region is entirely different. The tops of these vertically developed clouds consisting of mostly ice can reach high levels of the atmosphere, overshooting the lower stratosphere and reaching altitudes greater than 16 km. We show a link between aerosol, clouds and the free atmosphere wind profile that can change the magnitude and sign of the overall climate radiative forcing. We find that increased aerosol loading is associated with taller cloud towers and anvils. The taller clouds reach levels of enhanced wind speeds that act to spread and thin the anvi1 clouds, increasing areal coverage and decreasing cloud optical depth. The radiative effect of this transition is to create a positive radiative forcing (warming) at top-of-atmosphere. Furthermore we introduce the cloud optical depth (r), cloud height (Z) forcing space and show that underestimation of radiative forcing is likely to occur in cases of non homogenous clouds. Specifically, the mean radiative forcing of towers and anvils in the same scene can be several times greater than simply calculating the forcing from the mean cloud optical depth in the scene. Limitations of the method are discussed, alternative sources of aerosol loading are tested and meteorological variance is restricted, but the trend of taller clouds; increased and thinner anvils associated with increased aerosol loading remains robust through all the different tests and perturbations.

Koren, I.↗

Effects of diabatic heating on the ageostrophic circulation of an upper tropospheric jet streak

Interaction between the mass circulation within a mesoscale convective complex (MCC) and a direct mass circulation in the entrance region of an upper tropospheric polar jet streak was examined within the isentropic structure to investigate mechanisms responsible for linking these two scales of motion. The results establish that latent heating in the MCC modifies the direct mass circulation in the jet streak entrance region through the diabatically induced components of ageostrophic motion analyzed within isentropic coordinates. Within the strong mesoscale mass circulation of each MCC, strong horizontal mass flux convergence into the MCC at low levels is balanced by strong horizontal mass flux divergence away from the convergence at upper levels. Locations of large diabatic heating rates correspond well to the MCC position for each case; diabatic heating forces the upward vertical branch for the mesoscale mass circulation.

Keyser, D. A.↗

Effect of X-ray flux on polytetrafluoroethylene in X-ray photoelectron spectroscopy

The effect of the X-ray flux in X-ray photoelectron spectroscopy (STAT) on the constitution of the polytetrafluoroethylene (PTFE) surface has been examined. The radiation dose rate for our specimen was about 10 to the 7th rad/s. The structure, magnitude and binding energy of the C(1s) and F(1s) features of the XPS spectrum and the mass spectrum of gaseous species evolved during irradiation are observed. The strong time dependence of these signals over a period of several hours indicated that the surface constitution of PTFE is greatly affected by this level of radiation dose. The results are consistent with the development of a heavily cross-linked or branched structure in the PTFE surface region and the evolution of short chain fragments into the gas phase.

Wheeler, D. R.↗

Flickering Gamma Flashes, the Missing Link Between Gamma Glows and TGFs

Two different hard radiation phenomena are known to originate from thunderclouds: Terrestrial Gamma-ray Flashes (TGFs) and gamma-ray glows. Both involve avalanche of electrons accelerated to relativistic energies but are different phenomena. Glows are known to last for one-to-hundreds of seconds, have moderate intensities and originate from quasi-stationary thundercloud fields. TGFs exhibit high intensities and have characteristic durations of tens-to-hundreds of microseconds. TGFs often show close association with emission of strong radio signals and optical pulses indicating involvement of lightning leaders in their generation. Here we report unique observations of a different phenomenon, which we call Flickering Gamma-ray Flashes (FGFs). FGFs resemble usual multi-pulse TGFs, but with larger number of pulses and each pulse has a longer duration than ordinary TGFs. FGF durations span from 20 to 250 milliseconds, which reaches the lower boundary of the gamma-ray glow duration. FGFs are radio and optically silent, which makes them distinct from normal TGFs. An FGF starts as an ordinary gamma-ray glow, then suddenly increases exponentially in intensity, and turns into an unstable, “flickering” mode with a sequence of pulses. FGFs could be the missing link between the gamma-ray glows and conventional TGFs, whose absence has been puzzling atmospheric electricity community for two decades.

N Østgaard↗

High-Resolution Mid-Infrared Molecular Line Survey of the Orion Hot Core

The basic building blocks of life are synthesized in space as part of the natural stellar evolutionary cycle, whereby elements ejected into the interstellar medium by dying stars are incorporated back into the dense clouds, which form the next generation of stars and planets. The formation of stars and planets are fundamental to the evolution of matter in the Universe as complex molecules are created and destroyed during this step. Understanding these processes will allow us to answer “What is the relation between the molecules we see in the ISM and the molecular inventory of Earth and the terrestrial planets in the Solar System?” Measuring and cataloging the inventory of organic molecules and understanding their evolution requires observations over a broad wavelength range (IR, MIR, FIR, (sub)mm, and radio) to cover all stages of this evolutionary cycle needed to link interstellar material to that delivered to planets. High-resolution molecular line surveys provide chemical inventories for star forming regions and are essential for studying their chemistry, kinematics and physical conditions. Previous high spectral resolution surveys have been limited to radio, sub-mm and FIR wavelengths; however, Mid-infrared observations are the only way to study symmetric molecules that have no dipole moment and thus cannot be detected in the (sub)mm line surveys from ALMA. Past midinfrared missions such as ISO and Spitzer had low to moderate resolving power that were only able to link broad features with particular molecular bands and could not resolve the individual rovibrational transitions. JWST will provide exceptional sensitivity in the MIR, but will also not have sufficient spectral resolution, which can lead to confusion in identifying the contribution from strong to moderate strength molecular species. We present new results from an on-going high resolution (R ~ 60,000) line survey of the Orion hot core between 12.5 - 28.3 μm and 7 - 8 μm, using the EXES instrument on the SOFIA airborne observatory. SOFIA's higher-resolution and smaller beam compared to ISO allows us to spatially and spectrally isolate the emission towards the hot core. This survey will provide the best infrared measurements (to date) of molecular column densities and physical conditions, providing strong constraints on the current chemical network models for star forming regions. This survey will greatly enhance the inventory of resolved line features in the MIR, making it an invaluable reference to be used by the JWST and ALMA scientific communities.

Rangwala, Naseem↗

From dwarfs to giants - Signposts of galaxy formation

A two-dimensional parametrization of galactic evolution from the primordial state involving mean surface density and velocity dispersion is presented. A dissipation diagram for large-scale structure is presented and its evolutionary significance explored while considering both the pancake and the hierarchical clustering models of galaxy formation. Gaseous dissipation is studied by assuming that individual clouds or turbulent elements of gas interact supersonically, producing strong shocks. It is found that many diverse properties of galaxies can be understood in terms of an evolutionary sequence operative during an early gas-rich protogalactic phase in which dissipation played a key role. Dwarf galaxies may be the fossilized link between primordial fluctuations and the giant galaxies observed today, relics of a past era of prolific galaxy formation.

Silk, J.↗

All high Tc edge-geometry weak links utilizing Y-Ba-Cu-O barrier layers

High quality YBa2Cu3O(7-x) normal-metal/YBa2Cu3O(7-x) edge-geometry weak links have been fabricated using nonsuperconducting Y-Ba-Cu-O barrier layers deposited by laser ablation at reduced growth temperatures. Devices incorporating 25-100 A thick barrier layers exhibit current-voltage characteristics consistent with the resistively shunted junction model, with strong microwave and magnetic field response at temperatures up to 85 K. The critical currents vary exponentially with barrier thickness, and the resistances scale linearly with Y-Ba-Cu-O interlayer thickness and device area, indicating good barrier uniformity, with an effective mormal metal coherence length of 20 A.

Hunt, B. D.↗

Magnetohydrodynamic Origin of Jets from Accretion Disks

A review is made of magnetohydrodynamic (MHD) theory and simulation of outflows from disks for different distributions of magnetic field threading the disk. In one limit of a relatively weak, initially diverging magnetic field, both thermal and magnetic pressure gradients act to drive matter to an outflow, while a toroidal magnetic field develops which strongly collimates the outflow. The collimation greatly reduces the field divergence and the mass outflow rate decreases after an initial peak. In a second limit of a strong magnetic field, the initial field configuration was taken with the field strength on the disk decreasing outwards to small values so that collimation was reduced. As a result, a family of stationary solutions was discovered where matter is driven mainly by the strong magnetic pressure gradient force. The collimation in this case depends on the pressure of an external medium. These flows are qualitatively similar to the analytic solutions for magnetically driven outflows. The problem of the opening of a closed field line configuration linking a magnetized star and an accretion disk is also discussed.

Lovelace, R. V. E.↗

Solar System Connections to the Organic Material In the ISM

The organic component of the interstellar medium (ISM) has relevance to the formation of the early solar nebula, since our solar system formed out of ISM material. Comparisons of near infrared spectra of the diffuse ISM dust with those of primitive solar system bodies (such as comets and meteorites) show a remarkable similarity, suggesting that perhaps some of the interstellar organic material made its way, unaltered, into our solar system. Tracing the interstellar organic material is necessary to understand how these materials may be important links in the development of prebiotic phenomena. Studies of the ISM reveal that the organic refractory component of the diffuse ISM is largely hydrocarbon in nature, possessing little N or O, with carbon distributed between the aromatic and aliphatic forms. There is a strong similarity in the near IR spectra of the diffuse ISM (the 3.4 micron hydrocarbon bands) and those seen in the Murchison and Orgueil meteorites, however, detailed comparisons at longer wavelengths reveal critical dissimilarities. Here we will present comparisons and discussion of relevant spectra. As we continue to explore, we will gain insight into the connection between planetesimals in the solar system and chemistry in the dusty space between the stars.

Pendleton, Yvonne J.↗

Heliocentric zoning of the asteroid belt by aluminum-26 heating

Variations in petrology among meteorites attest to a strong heating event early in solar system history, but the heat source has remained unresolved. Aluminum-26 has been considered the most likely high-energy, short-lived radionuclide (half-life 0.72 million years) since the discovery of its decay product - excess Mg-26 - in Allende CAI's. Furthermore, observation of relict Mg-26 in an achondritic clast and in feldspars within ordinary chondrites (3,4) provided strong evidence for live Al-26 in meteorite parent bodies and not just in refractory nebular condensates. The inferred amount of Al-26 is consistent with constraints on the thermal evolution of both ordinary and carbonaceous chondrite parent objects up to a few hundred kilometers in diameter. Meteorites can constrain the early thermal evolution of their parent body locations, provided that a link can be established between asteroid spectrophotometric signature and meteorite class. Asteroid compositions are heliocentrically distributed: objects thought to have experienced high metamorphic or even melting temperatures are located closer to the sun, whereas apparently unaltered or mildly heated asteroids are located farther away. Heliocentric zoning could be the result of Al-26 heating if the initial amount of the radionuclide incorporated into planetesimals was controlled by accretion time, which in turn varies with semimajor axis. Analytic expressions for planetary accretion may be integrated to given the time, tau, required for a planetesimal to grow to a specified radius: tau varies as a(sup n), where n = 1.5 to 3 depending on the assumptions about variations in the surface density of the planetesimal swarm. Numerical simulations of planetesimal accretion at fixed semimajor axis demonstrate that variations in accretion time among small planetesimals can be strongly nonlinear depending on the initial conditions and model assumptions. The general relationship with semimajor axis remains valid because it depends only on the initial orbit properties and distribution of the planesimal swarm. In order to demonstrate the basic dependence of thermal evolution on semimajor axis, we parameterized accretion time across the asteroid belt according to tau varies as a(sup n) and calculated the subsequent thermal history. Objects at a specified semimajor axis were assumed to have the same accretion time, regardless of size. We set the initial Al-26/Al-27 ratio = 6 x 10(exp -5) and treated n and tau(sub 0) at a(sub 0) = 3 AU as adjustable parameters. The thermal model included temperature-dependent properties of ice and rock (CM chondrite analog) and the thermodynamic effects of phase transitions.

Grimm, R. E.↗

Investigation of Seasonal Landscape Freeze/Thaw Cycles in Relation to Cloud Structure in the High Northern Latitudes

The seasonal freezing and thawing of Earth's cryosphere (the portion of Earth's surface permanently or seasonally frozen) has an immense impact on Earth's climate as well as on its water, carbon and energy cycles. During the spring, snowmelt and the transition between frozen and non-frozen states lowers Earth's surface albedo. This change in albedo causes more solar radiation to be absorbed by the land surface, raising surface soil and air temperatures as much as 5 C within a few days. The transition of ice into liquid water not only raises the surface humidity, but also greatly affects the energy exchange between the land surface and the atmosphere as the phase change creates a latent energy dominated system. There is strong evidence to suggest that the thawing of the cryosphere during spring and refreezing during autumn is correlated to local atmospheric conditions such as cloud structure and frequency. Understanding the influence of land surface freeze/thaw cycles on atmospheric structure can help improve our understanding of links between seasonal land surface state and weather and climate, providing insight into associated changes in Earth's water, carbon, and energy cycles that are driven by climate change.Information on both the freeze/thaw states of Earth's land surface and cloud characteristics is derived from data sets collected by NOAA's Special Sensor Microwave/Imager (SSM/I), the Advanced Microwave Scanning Radiometer on NASA's Earth Observing System(AMSR-E), NASA's CloudSat, and NASA's SeaWinds-on-QuickSCAT Earth remote sensing satellite instruments. These instruments take advantage of the microwave spectrum to collect an ensemble of atmospheric and land surface data. Our analysis uses data from radars (active instruments which transmit a microwave signal toward Earth and measure the resultant backscatter) and radiometers (passive devices which measure Earth's natural microwave emission) to accurately characterize salient details on Earth's surface and atmospheric states. By comparing the cloud measurements and the surface freeze-thaw data sets, a correlation between the two phenomena can be developed.

clouds↗

A Rapid change in x-ray variability and a jet ejection in the black hole transient MAXI J1820+070

We present Neutron Star Interior Composition Explorer X-ray and Arcminute Microkelvin Imager Large Array radio observations of a rapid hard-to-soft state transition in the black hole X-ray transient MAXI J1820+070. During the transition from the hard state to the soft state a switch between two particular types of quasiperiodic oscillations (QPOs) was seen in the X-ray power density spectra, from type-C to type-B, along with a drop in the strength of the broadband X-ray variability and a brief flare in the 7–12 keV band. Soon after this switch (∼2–2.5 hr) a strong radio flare was observed that corresponded to the launch of superluminal ejecta. Although hints of a connection between QPO transitions and radio flares have been seen in other black hole X-ray transients, our observations constitute the strongest observational evidence to date for a link between the appearance of type-B QPOs and the launch of discrete jet ejections.

Jeroen Homan↗

Are Hyperion and Phoebe Linked to Iapetus?

Narrowband reflectance spectra of the Saturnian satellites S VII Hyperion and S IX Phoebe were obtained across the 0.4 - 0.8 micron spectral region. The spectrum of Phoebe is similar to the spectrum of a C-class asteroid, with an absorption feature centered near 0.43 micron superimposed on the UV/blue intervalence charge transfer transition present in the spectrum. The spectrum of Hyperion shows the strong spectral slope apparent in spectra of many outer Solar System materials and attributed to organics. We use a linear mixing model to separate the reflectance spectrum of the dark material on Hyperion from the icy material. A distinct absorption feature centered at 0.67 micron is present. A slight inflection near 0.4 - 0.6 micron and change in slope near 0.73 micron suggesting the lower wavelength edge of an absorption are also present. These absorptions are very similar to those identified in the spectrum of the dark material on the surface of Iapetus, suggesting that the dark material on these two satellites is compositionally similar and has a similar origin. These absorption features are attributed to the (6)A(sub 1) yields (4)T(sub 2)(G) and (6)A(sub 1) yields (4)T(sub 1)(G) ferric charge transfer transitions in iron alteration minerals such as goethite and hematite that are products of the aqueous alteration of anhydrous silicates.

Jarvis, Kandy S.↗

The Dust Properties of Hot R Coronae Borealis Stars and a Wolf-Rayet Central Star of a Planetary Nebula: In Search of the Missing Link

We present new Spitzer IIRS spectra of two hot R Coronae Borealis (RCB) stars, one in the Galaxy,V348 Sgr, and one lying in the Large Magellanic Cloud, HV 2671. These two objects constitute a link between the RCB stars and the [WCL] class of central stars of planetary nebula (CSPNe) that has little or no hydrogen in their atmospheres such as CPD -560 8032. HV 2671 and V348 Sgr are members of a rare subclass that has significantly higher effective temperatures than most RCB stars, but sharing the traits of hydrogen deficiency and dust formation that define the cooler RCB stars. The [WC] CSPNe star, CPD -560 8032, displays evidence for dual-dust chemistry showing both PAHs and crystalline silicates in its mid-IR spectrum. HV 2671 shows strong PAH emission but shows no sign of having crystalline silicates. The spectrum of V348 Sgr is very different from those of CPD -56deg 8032 and HV 2671. The PAH emission seen strongly in the other two stars is only weakly present. Instead, the spectrum is dominated by a broad emission centered at about 8.5 microns. This feature is not identified with either PAHs or silicates. Several other novae and post-asymptotic giant branch stars show similar features in their IR spectra. The mid-IR spectrum of CPD -56deg 8032 shows emission features associated with C60 . The other two stars do not show evidence for C60. The nature of the dust around these stars does not help us in establishing further links that may indicate a common origin.

Clayton, Geoffrey C.↗

Validation of the communications link analysis and simulation system (CLASS)

CLASS (Communication Link Analysis and Simulation System) is a software package developed for NASA to predict the communication and tracking performance of the Tracking and Data Relay Satellite System (TDRSS) services. The methods used to verify CLASS are described. The usefulness of a software tool such as CLASS depends strongly on the reliability and accuracy of the results it produces. For this reason, considerable attention was paid to validation throughout the CLASS development.

Braun, W. R.↗