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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Formation of a silicon terminated (100) diamond surface

We report the preparation of an ordered silicon terminated diamond (100) surface with a two domain 3 × 1 reconstruction as determined by low energy electron diffraction. Based on the dimensions of the surface unit cell and on chemical information provided by core level photoemission spectra, a model for the structure is proposed. The termination should provide a homogeneous, nuclear, and electron spin-free surface for the development of future near-surface diamond quantum device architectures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

In Vitro Fabrication and Biocompatibility Assay of a Biomimetic Osteoblastic Niche

A novel HAp-CS/Gel biomimetic osteoblastic niche was fabricated by freeze-drying, and its mechanical strength and biocompatibility were characterized. HAp-CS/Gel scaffolds in various ratios of 100:5, 100:10, and 100:20 (CS/Gel to HAp) were prepared by freeze-drying prior to chemical cross-linking followed by infrared spectrum analysis, EDS, FITR, SEM, fluorescence microscopy, MTT, and ALP experiments. Results from the infrared spectrum analysis showed that HAp doping remained the surface morphology and the architecture of scaffold with interconnected pores in the size range of 135 to 150 μm. The HAp doping ratio of 100:20 was found to be optimal based on its high porosity of 90%, better water uptake folds of 19.1. In addition, EDS and FITR analyses demonstrated that HAps were uniformly distributed on the surface of a scaffold with aggregates and particles, which has sufficient roughness for cell attachment and proliferation of osteoblasts. Under SEM and fluorescent microscopy, osteoblasts seeded onto the scaffold showed evenly distributed viable cells, which is believed to form a biomimetic niche. In the present study, we further demonstrate that osteoblasts can maintain their function and grow well on the scaffold through MTT and ALP tests. Thus, the scaffold has favorable physical properties and biocompatibility to support the proliferation and differentiation of osteoblasts and further to support the constructs of biomimetic osteoblastic niche.

60 APPLIED LIFE SCIENCES↗
NASA NTRS2006

Lunar Relay Satellite Network for Space Exploration: Architecture, Technologies and Challenges

NASA is planning a series of short and long duration human and robotic missions to explore the Moon and then Mars. A key objective of these missions is to grow, through a series of launches, a system of systems infrastructure with the capability for safe and sustainable autonomous operations at minimum cost while maximizing the exploration capabilities and science return. An incremental implementation process will enable a buildup of the communication, navigation, networking, computing, and informatics architectures to support human exploration missions in the vicinities and on the surfaces of the Moon and Mars. These architectures will support all space and surface nodes, including other orbiters, lander vehicles, humans in spacesuits, robots, rovers, human habitats, and pressurized vehicles. This paper describes the integration of an innovative MAC and networking technology with an equally innovative position-dependent, data routing, network technology. The MAC technology provides the relay spacecraft with the capability to autonomously discover neighbor spacecraft and surface nodes, establish variable-rate links and communicate simultaneously with multiple in-space and surface clients at varying and rapidly changing distances while making optimum use of the available power. The networking technology uses attitude sensors, a time synchronization protocol and occasional orbit-corrections to maintain awareness of its instantaneous position and attitude in space as well as the orbital or surface location of its communication clients. A position-dependent data routing capability is used in the communication relay satellites to handle the movement of data among any of multiple clients (including Earth) that may be simultaneously in view; and if not in view, the relay will temporarily store the data from a client source and download it when the destination client comes into view. The integration of the MAC and data routing networking technologies would enable a relay satellite system to provide end-to-end communication services for robotic and human missions in the vicinity, or on the surface of the Moon with a minimum of Earth-based operational support.

Bhasin, Kul B.↗
NASA NTRS2003

Mobile Agents: A Distributed Voice-Commanded Sensory and Robotic System for Surface EVA Assistance

A model-based, distributed architecture integrates diverse components in a system designed for lunar and planetary surface operations: spacesuit biosensors, cameras, GPS, and a robotic assistant. The system transmits data and assists communication between the extra-vehicular activity (EVA) astronauts, the crew in a local habitat, and a remote mission support team. Software processes ("agents"), implemented in a system called Brahms, run on multiple, mobile platforms, including the spacesuit backpacks, all-terrain vehicles, and robot. These "mobile agents" interpret and transform available data to help people and robotic systems coordinate their actions to make operations more safe and efficient. Different types of agents relate platforms to each other ("proxy agents"), devices to software ("comm agents"), and people to the system ("personal agents"). A state-of-the-art spoken dialogue interface enables people to communicate with their personal agents, supporting a speech-driven navigation and scheduling tool, field observation record, and rover command system. An important aspect of the engineering methodology involves first simulating the entire hardware and software system in Brahms, and then configuring the agents into a runtime system. Design of mobile agent functionality has been based on ethnographic observation of scientists working in Mars analog settings in the High Canadian Arctic on Devon Island and the southeast Utah desert. The Mobile Agents system is developed iteratively in the context of use, with people doing authentic work. This paper provides a brief introduction to the architecture and emphasizes the method of empirical requirements analysis, through which observation, modeling, design, and testing are integrated in simulated EVA operations.

Clancey, William J.↗
NASA NTRS2006

Can We Power Future Mars Missions?

The Vision for Space Exploration identified the exploration of Mars as one of the key pathways. In response, NASAs Mars Program Office is developing a detailed mission lineup for the next decade that would lead to future explorations. Mission architectures for the next decade include both orbiters and landers. Existing power technologies, which could include solar panels, batteries, radioisotope power systems, and in the future fission power, could support these missions. Second and third decade explorations could target human precursor and human in-situ missions, building on increasingly complex architectures. Some of these could use potential feed forward from earlier Constellation missions to the Moon, discussed in the ESAS study. From a potential Mars Sample Return mission to human missions the complexity of the architectures increases, and with it the delivered mass and power requirements also amplify. The delivered mass at Mars mostly depends on the launch vehicle, while the landed mass might be further limited by EDL technologies, including the aeroshell, parachutes, landing platform, and pinpoint landing. The resulting in-situ mass could be further divided into payload elements and suitable supporting power systems. These power systems can range from tens of watts to multi-kilowatts, influenced by mission type, mission configuration, landing location, mission duration, and season. Regardless, the power system design should match the power needs of these surface assets within a given architecture. Consequently, in this paper we will identify potential needs and bounds of delivered mass and architecture dependent power requirements to surface assets that would enable future in-situ exploration of Mars.

solar panels↗
NASA NTRSDate not supplied

Mars Entry, Descent, Landing, and Ascent Systems Sensitivities to Landing Site and Atmospheric Dust

Plans for human missions to Mars continue to go through several architectural changes, dating all the way back to the 1950s [1]. The continuous study, reformulation, and refinement of Mars architectures and system concepts is necessary in order to incorporate evolving mission objectives, technology advancements, and growth in the body of knowledge regarding human factors and the various environments of human space travel. This evolution has continued into the 21st century, with architectures concepts such as NASA’s Design Reference Architecture 5.0 in 2009 [2], The Evolvable Mars Campaign in 2016 [3], and as recently as 2020, an architecture focused on a crewed mission as early as the 2030s that aims to minimizing crewed duration and infrastructure investment for the first mission [4]. Within these architectures, numerous studies around the current concept designs for Mars entry, descent, landing, and ascent (EDLA) systems have been performed over the last half a decade [[5], [6], [7], [8], [9], [10]]. Despite the breadth and depth of these studies, landing site, a key design parameter relevant to the design of EDLA systems, has remained nebulous over the years, largely due to the ever evolving mission objectives and architecture concept over the decades. However, the specific landing site has direct impact on the altitude and atmospheric conditions, which subsequently impact the design of EDLA systems. To accommodate the lack of a specific landing site, a baseline reference altitude of 0 km relative to the Mars Orbiter Laser Altimeter (MOLA), which is similar to an Earth sea level reference, has typically been selected and fixed for these past studies. Similarly, a baseline reference atmosphere has typically been utilized in these studies, either the Mars Global Reference Atmospheric Model [11], or a general 1982 standard warm, high pressure atmosphere model derived from Viking lander data [12]. Fig. 1 shows the range of elevations across the surface of Mars. Current architectures are focused on latitudes greater than 30 degrees north in an effort to ensure access to frozen water ice. From the figure, it is quickly evident that elevations over the range of longitudes at or above this latitude are significantly varied between roughly -4 to +4 km MOLA. Based on these observations, initial qualitative assessments of the impacts of landing site elevation on EDLA systems were performed. Fig. 2 depicts the expected trends in EDLA system mass for variations in both land site latitude and elevation. The background coloring is a qualitative evaluation of the current knowledge on ice water availability at the latitudes. Further modeling and simulation was performed to obtain numerical predictions of sensitivities to these parameters. Results indicate up to +2% to -4% mass variation from the current baseline Mars Ascent Vehicle concept, with the potential for greater than 6% mass variation at latitudes greater than 70 degrees north. However, variations in the descent system due to landing site were much more significant with mass variations in the range of -15% to +30% around the current baseline Mars Descent System concept. Additionally, Fig. 3 provides a depiction of potential Mars atmospheric density variations with both dust and Martian season. Though the Martian atmosphere is relatively thin compared to Earth’s atmosphere, it still poses significant impact on the design of EDLA systems. Variations in atmospheric density indicated by this slice of data would have significant impact on the design of EDLA systems. However, due to the highly complex nature of atmospheric flight, a qualitative assessment could not be performed. Rather, sensitivity results relied on modeling and simulation to provide numerical results for sensitivities on the current EDLA design concepts under consideration. Understanding these sensitivities is vital to the overall systems design of a Mars architecture. The resulting mass impacts on EDLA systems, driven by landing site elevation and dust level variations, has rippling impacts throughout the architecture that, ultimately, impact the viability of the architecture. Results showed fairly minor mass impacts to the current Mars Ascent Vehicle baseline configuration, roughly -0.6% to + 0.4% mass variations, while the Mars Descent System say greater variations due to dust, roughly -4% to +6% around the baseline concept.

EDLA↗
NASA NTRS2014

Addressing Challenges to the Design & Test of Operational Lighting Environments for the International Space Station

In our day to day lives, the availability of light, with which to see our environment, is often taken for granted. The designers of land based lighting systems use sunlight and artificial light as their toolset. The availability of power, quantity of light sources, and variety of design options are often unlimited. The accessibility of most land based lighting systems makes it easy for the architect and engineer to verify and validate their design ideas. Failures with an implementation, while sometimes costly, can easily be addressed by renovation. Consider now, an architectural facility orbiting in space, 260 miles above the surface of the earth. This human rated architectural facility, the International Space Station (ISS) must maintain operations every day, including life support and appropriate human comforts without fail. The facility must also handle logistics of regular shipments of cargo, including new passengers. The ISS requires accommodations necessary for human control of machine systems. Additionally, the ISS is a research facility and supports investigations performed inside and outside its livable volume. Finally, the facility must support remote operations and observations by ground controllers. All of these architectural needs require a functional, safe, and even an aesthetic lighting environment. At Johnson Space Center, our Habitability and Human Factors team assists our diverse customers with their lighting environment challenges, via physical test and computer based analysis. Because of the complexity of ISS operational environment, our team has learned and developed processes that help ISS operate safely. Because of the dynamic exterior lighting environment, uses computational modeling to predict the lighting environment. The ISS' orbit exposes it to a sunrise every 90 minutes, causing work surfaces to quickly change from direct sunlight to earthshine to total darkness. Proper planning of vehicle approaches, robotics operations, and crewed Extra Vehicular Activities are mandatory to ensure safety to the crew and all others involved. Innovation in testing techniques is important as well. The advent of Solid State Lighting technology and the lack of stable national and international standards for its implementation pose new challenges on how to design, test and verify individual light fixtures and the environment that uses them. The ISS will soon be replacing its internal fluorescent lighting system to a solid state LED system. The Solid State Lighting Assembly will be used not only for general lighting, but also as a medical countermeasure to control the circadian rhythm of the crew. The new light source has performance criteria very specific to its spectral fingerprint, creating new challenges that were originally not as significant during the original design of the ISS. This presentation will showcase findings and toolsets our team is using to assist in the planning of tasks, and design of operational lighting environments on the International Space Station.

Clark, Toni A.↗
DOE OSTI2023

Chromium Tolerant, Highly Active and Stable Electrocatalytic Internal Surface Coating for Cathode of Commercial SOFCs (Final Report)

This project is aimed to develop a chromium (Cr) tolerant, highly active, and stable coating layer on the internal surfaces of the porous composite cathode from commercially available SOFCs. Such coating layer was developed using the additive manufacturing process of Atomic Layer Deposition (ALD) and has been applied on the cathode consisting of either an electronic conductor of LaxSr 1-x MnyO 3-δ (LSM) or mixed ionic and electronic conducting La x Sr 1-x Co y Fe 1-y O 3-δ (LSCF). PI's work has demonstrated that the internal surface of cathode from the commercial cells, can be further tailored using ALD coating to dramatically enhance the cell performance. For instance, ALD layer consisting heterostructured nano composite of nano-Pt and nano-(Mn 0.8 Co 0.2 ) 3 O 4 oxide on the internal surface of porous LSM/YSZ cathode from SOFCs, has resulted in the large reduction of the cell polarizations resistance by up to 53%, and enormous increase of power density over 370%. For the cells with LSCF/Sm 2 O 3 doped CeO 2 (SDC) cathode, the conformal layer of nano-composite consisting of superjacent CoOx and subjacent minimum amount of Pt nano-grains has resulted in the power density enhancement by 126% for the large scale industry tubular cells at 750°C, and both the performance enhancement and nanostructure of the ALD layer are stable over ~ 2000 h continuous operation performed at industry test station. In the meanwhile, those ALD coating layer developed by PI's work is also inherently Cr-tolerant, and could act as physical barrier for preventing Cr diffusion into the cathode backbone, so as to mitigate the Cr poisoning effect on the cathode. In this project, the impact of Cr on the performance of those ALD coated commercial cells has been evaluated. Based on evolution of the cell performance, the ALD coating layer chemistry and ALD coating layer thickness has been optimized to maximize the overall Cr tolerance, cell power density and cell longevity. Different ALD coating has been applied onto the internal surface of LSM/YSZ and LSCF/SDC backbone respectively. The architecture/scaffold structures on the internal surface of different cathode, designed by this project, was catalogued and analyzed using High Resolution Transmission Electron Microscopy (HRTEM), and cell power/durability performance are assured via comprehensive electrochemical performance testing in the industry operation relevant conditions. The impact of the electrochemical operation current density, the water humidity, the cell operation temperature, and cell operation duration on the Cr tolerance of ALD coated cells has been systematically investigated. There is completely different nanostructure degradation mechanisms between LSM and LSCF cells induced by Cr contamination. For the LSCF/SDC baseline cell, With the Cr source, there is no apparent Sr surface segregation phase even for the baseline cell operated for 3000 h at 750 °C. With the Cr source, there is significant amorphous (SrCr)Ox phase accumulated in the original pore region. For the commercial baseline cells, Cr contaminants on the LSM electrode severely impacted the entire cell's electrochemical performance and nanostructure degradation. Those degradations include (1). Peak power density loss of 64 % after 109 h of operation. The dramatic increase in Rp (2). They are cracking at LSM/SSZ interface, LSM grains. SSZ remains intact but with (CrMn)Ox. By contrast, ALD coating (MnCo)Ox/Pt dramatically improves the Cr resistance, as follows (1). ALD-coated cell with a power density is 280-380 % of the baseline cell, depending on the ALD layer thickness. (2). For a cell with a 20 nm thick ALD layer, there is a large performance enhancement (> 200 % power density) induced by ALD coating of Cr-tolerant Mn 0.8 Co 0.2 Ox. (3). For a cell with a 20 nm thick ALD layer, after 168 h at 750 °C power density of the ALD-coated cell is ~ 600% of that baseline cell upon operation with Cr contamination for 109 h. The ALD coating on the internal surface of cathode developed by this project integrated multi-functions. Those multi-functions include (1). Dramatically improving the cell power density for the commercial cells; (2). Dramatically improving contamination resistance of the cathode, for being an excellent protection coating layer sealing off Cr contamination. (3). Dramatically increasing the cell longevity by potentially preventing the microstructure evolution and grain coarsening of the cathode. Overall, this project will provide a simple solution to simultaneously enhance power density and increase the reliability, robustness, and endurance of commercial SOFCs, over the entire operating temperature range of 650-800 °C. For the inherently functional SOFC, the ALD coating of LSM based cathode mitigate the Cr-contamination. Power density of ALD-coated cell is ~ 600% of that baseline cell upon operation with Cr contamination. In addition to SOFCs, the novel on-demand design approach and creation of multifunctional heterogeneous architecture on the electrode surface presented in this work opens further research for their application in other types of fuel cells, batteries, and sensors for which electrochemical reactions on the surface are similarly critical.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Suppression of surface-originated gate lag by a dual-channel AlN/GaN high electron mobility transistor architecture

A dual-channel AlN/GaN high electron mobility transistor (HEMT) architecture is demonstrated that leverages ultra-thin epitaxial layers to suppress surface-related gate lag. Two high-density two-dimensional electron gas (2DEG) channels are utilized in an AlN/GaN/AlN/GaN heterostructure wherein the top 2DEG serves as a quasi-equipotential that screens potential fluctuations resulting from distributed surface and interface states. The bottom channel serves as the transistor's modulated channel. Dual-channel AlN/GaN heterostructures were grown by molecular beam epitaxy on free-standing hydride vapor phase epitaxy GaN substrates. HEMTs fabricated with 300 nm long recessed gates demonstrated a gate lag ratio (GLR) of 0.88 with no degradation in drain current after bias stressed in subthreshold. These structures additionally achieved small signal metrics f{sub t}/f{sub max} of 27/46 GHz. These performance results are contrasted with the non-recessed gate dual-channel HEMT with a GLR of 0.74 and 82 mA/mm current collapse with f{sub t}/f{sub max} of 48/60 GHz.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRSDate not supplied

Surface Systems Capability Gaps for Enabling NASA’s Sustainable Lunar Operations

This paper discusses the NASA Ground, Test, and Surface Systems Taxonomy (TX-13) related capability gaps, including details of architecture, technology, engineering, and policy gaps for enabling sustainable lunar surface operations and subsequent Mars missions. Architecture gaps include standardized architectures and interfaces, multi-element systems engineering and integration, design for supportability, and nuclear payload processing and launch approach. Technology gaps, primarily focused on uncrewed surface operations, include automated/autonomous cryogenic loading, transfer, servicing, and storage of commodities; health determination and fault management; automated/autonomous planning and scheduling; automated/autonomous inspection, maintenance and repair; logistics management and reliability; launch and landing site preparation; commodity management; and advanced umbilicals and dust tolerant interfaces. Engineering gaps include high-purity propellant production for ground and surface applications and large-scale xenon servicing capabilities. The policy gap includes nuclear propulsion acceptance testing and qualification approach. Strategically identifying human/automation roles and tasks and infusing automation and autonomy practices early in a system’s lifecycle is essential for achieving the mission objectives for a sustainable human lunar presence, improving performance and mission effectiveness, reducing operations costs and reliance on humans to perform tasks, and accommodating ground communication delays.

Surface Systems↗
DOE OSTI2025

Additive Manufacturing of Thermal Energy Storage Composites with Microencapsulated Phase Change Materials Supported in a Multipolymer Matrix

Additive manufacturing (AM) techniques to directly integrate phase change materials (PCMs) are of interest for efficient thermal energy storage (TES) architectures. Complex, high surface-to-volume ratio composites embedded with PCM can improve thermal management with reduced material waste for customizable device fabrication. Reducing feature sizes of TES-integrated heat exchangers using AM can increase heat transfer without thermal conductivity enhancement. Here, composite AM materials containing 60 wt% microencapsulated phase change materials (MEPCM) are fabricated using off-the-shelf printers at common speeds and resolutions. High MEPCM loading in filaments is achieved with powder extrusion using two polymers, thermoplastic-polyurethane (TPU) and polycaprolactone (PCL), that mediate flexibility and rigidity for effective extrusion and printing without filament fracture or buckling. Furthermore, with PCL and TPU at 20 wt% each and 60 wt% MEPCM (P 20 T 20 M 60 ), smooth, form-stable filaments are consistently printed. Powder-based extrusion displays negligible damaging effects on the MEPCM. Printed P 20 T 20 M 60 demonstrates 105 J/g of energy storage with no degradation through 250 thermal cycles, within 5% of the theoretical storage enthalpy. Combining PCL/TPU shows good interfacial adhesion between print layers and produces high surface area objects, like 15% gyroids, and dense, 100% infilled pucks. Prints are also scalable to a 900 cm 3 honeycomb heat exchanger with an estimated 9 Wh energy storage.

25 ENERGY STORAGE↗
DOE OSTI2016

Enabling Quality Interfaces with Mask-Free Approach to Selective Growth of MoS 2 /Graphene Stacked Structures

The mask-free patterning technique is employed to fabricate arrays of MoS2 and WS2 structures on silicon and graphene substrates with quality interfaces. By depositing precursor inks with the AFM cantilevers and subsequent heat treatment in the CVD furnace, it is demonstrated that MoS2 and WS2 structures can be formed on graphene surfaces at predefined device architectures.

2D atomic crystals↗
DOE OSTI2021

Nanoscale Design of Pd-Based Electrocatalysts for Oxygen Reduction Reaction Enhancement in Alkaline Media

Palladium (Pd)-based electrocatalysts have recently emerged as one class of the foremost promising candidates for the oxygen reduction reaction (ORR) in alkaline media due to their excellent ORR activity and durability and lower costs compared with platinum. Insightful design of Pd-based nano-architectures with optimized active surface sites and maximal intrinsic performance is central to promoting the ORR applications. To further accelerate the sluggish ORR kinetics at the cathode of fuel cells and substantially decrease the overall cost of the electrocatalysts, various strategies, including controlled sizes and shapes with selected crystallographic facets, crystal-phase engineering, heteroatom doping, tailored surface strains, and surface engineering by de-alloying, have been extensively developed in the past decade. Here in this review, a brief introduction to the fundamental ORR mechanisms of Pd-based electrocatalysts in alkaline media is presented, followed by a thorough discussion on various strategies for delicately designing high-performance Pd-based catalysts with corresponding examples. Thereafter, the perspectives and new insights into the challenges are outlined, and some emerging research directions related to the rational design and controlled synthesis of Pd-based ORR electrocatalysts are also proposed.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Optimization of Oxygen Electrode Combined with Soluble Catalyst to Enhance the Performance of Lithium-Oxygen Battery

Lithium-air batteries possess a high theoretical energy density among the current battery technologies, and are expected to become the driving power for electric vehicles. However, the practical application of lithium air batteries is handicapped by their poor cycle life, high over-charge potential and low energy efficiency. Numerous studies have performed to improve the kinetics of the electrochemical reaction. Making a good oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalyst system is under intense scrutiny. In this work, we report a rational design of air electrode, which derives from biomass and presents a three-dimensional porous carbon architecture with high specific surface and large volume expansion coefficient. Combining with a soluble catalyst, this oxygen electrode presents an ultrahigh areal specific capacity of 7.95 mAh/cm 2 and a long cycling life up to 1000 cycles with suppressed polarization (about 0.46 V). Finally, the greatly improved overall performance is due to the synergetic effect of the novel designed oxygen electrode capable of mediating the redox mediators to trigger the ORR and OER process.

25 ENERGY STORAGE↗
DOE OSTI2016

A Carbon-Cotton Cathode with Ultrahigh-Loading Capability for Statically and Dynamically Stable Lithium–Sulfur Batteries

Sulfur exhibits a high theoretical capacity of 1675 mA h g -1 via a distinct conversion reaction, which is different from the insertion reactions in commercial lithium-ion batteries. In consideration of its conversion reaction battery chemistry, a custom design for electrode materials could establish the way for attaining high-loading capability while simultaneously maintaining high electrochemical utilization and stability. In this study, this process is undertaken by introducing carbon cotton as an attractive electrode-containment material for enhancing the dynamic and static stabilities of lithium-sulfur (Li-S) batteries. The carbon cotton possessing a hierarchical macro-/microporous architecture exhibits a high surface area of 805 m 2 g -1 and high microporosity with a micropore area of 557 m 2 g -1 . The macroporous channels allow the carbon cotton to load and stabilize a high amount of active material. The abundant microporous reaction sites spread throughout the carbon cotton facilitate the redox chemistry of the high-loading/content Li-S system. As a result, the high-loading carbon-cotton cathode exhibits (i) enhanced cycle stability with a good dynamic capacity retention of 70% after 100 cycles and (ii) improved cellstorage stability with a high static capacity retention of above 93% and a low time-dependent self-discharge rate of 0.12% per day after storing for a long period of 60 days. In conclusion, these carbon-cotton cathodes with the remarkably highest values reported so far of both sulfur loading (61.4 mg cm -2 ) and sulfur content (80 wt %) demonstrate enhanced electrochemical utilization with the highest areal, volumetric, and gravimetric capacities simultaneously.

25 ENERGY STORAGE↗
DOE OSTI2025

Automatic speech recognition predicts contemporaneous earthquake fault displacement

Abstract Significant progress has been made in probing the state of an earthquake fault by applying machine learning to continuous seismic waveforms. The breakthroughs were originally obtained from laboratory shear experiments and numerical simulations of fault shear, then successfully extended to slow-slipping faults. Here we apply the Wav2Vec-2.0 self-supervised framework for automatic speech recognition to continuous seismic signals emanating from a sequence of moderate magnitude earthquakes during the 2018 caldera collapse at the Kīlauea volcano on the island of Hawai’i. We pre-train the Wav2Vec-2.0 model using caldera seismic waveforms and augment the model architecture to predict contemporaneous surface displacement during the caldera collapse sequence, a proxy for fault displacement. We find the model displacement predictions to be excellent. The model is adapted for near-future prediction information and found hints of prediction capability, but the results are not robust. The results demonstrate that earthquake faults emit seismic signatures in a similar manner to laboratory and numerical simulation faults, and artificial intelligence models developed for encoding audio of speech may have important applications in studying active fault zones.

58 GEOSCIENCES↗
DOE OSTI2019

Pathways for practical high-energy long-cycling lithium metal batteries

Lithium (Li)-ion batteries play a critical role in modern day technologies, but their specific energy (Wh kg-1) and energy density (Wh L-1) are approaching the maximum practically achievable values based on existing manufacturing processes with the conventional cathode and anode materials. Developing the next generation rechargeable batteries with a specific energy higher than 300 Wh kg-1, up to 500 Wh kg-1, is a significant challenge. This paper discusses the pathways to build the next generation 500 Wh kg-1 rechargeable Li battery based on Li metal anode and a high nickel-content lithium nickel-manganese-cobalt oxide (high-Ni NMC) cathode. The fundamental requirements and practical technical approaches will be explored to hopefully address this grand challenge. In particular, we discuss the detailed cell level requirements and parameters to achieve high energy density, as well as the significant scientific challenges and potential solutions, including but not limited to enable the direct utilization of Li metal anode with high efficiency and long-term cycling stability, dendrite-free Li metal deposition, high utilization of the cathode materials with high mass loading and reasonable electrode thickness along with minimum parasitic weight in the cathode side. The cell level understanding and validation of the materials properties for high performance and control of interfacial reactions across the whole cell will be explored. New concepts in emerging multifunctional materials and electrolytes/additives and their implications will also be discussed.

lithium metal anode, lithium nickel manganese coba↗