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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13

Performance Improvement of the CHeX Flight Cryostat

The JPL flight cryostat last flew on the Space Shuttle in October 1992 in support of the Lambda Point Experiment. A new experiment, the Confined Helium Experiment (CHeX), now in development will reuse this cryostat. An improvement to the cryostat performance was necessitated by the CHeX experiment having a longer mission requirement and stricter requirements imposed by NASA with respect to a launch-scrub turnaround scenario. The parasitic heat load reduction necessary to relieve both constraints was about 15percent or 1 liter/day. The techniques implemented to achieve this goal, and subsequent results are presented along with a thermal model used during the analysis of the cryostat.

cryostats↗

Heat Transfer Modeling and Validation for Optically Thick Alumina Fibrous Insulation

Combined radiation/conduction heat transfer through unbonded alumina fibrous insulation was modeled using the diffusion approximation for modeling the radiation component of heat transfer in the optically thick insulation. The validity of the heat transfer model was investigated by comparison to previously reported experimental effective thermal conductivity data over the insulation density range of 24 to 96 kg/cu m, with a pressure range of 0.001 to 750 torr (0.1 to 101.3 x 10(exp 3) Pa), and test sample hot side temperature range of 530 to 1360 K. The model was further validated by comparison to thermal conductivity measurements using the transient step heating technique on an insulation sample at a density of 144 kg/cu m over a pressure range of 0.001 to 760 torr, and temperature range of 290 to 1090 K.

Daryabeigi, Kamran↗

Characterization of initial cure reactions in propargyl and nadic end capped model compounds

Imide model compounds containing propargyl and nadic groups were studied to obtain a fundamental understanding of the reaction of these groups attached to imide oligomers. The initial cure reactions were examined by a variety of characterization techniques including high pressure liquid chromatography, infrared spectroscopy, thermal analyses, and mass spectroscopy. The initial step in the cure of propargyl end capped model compounds probably involved the formation of a new terminal acetylenic group. Configurational changes involving endo/exo isomerism was found in the nadimide model compounds. Nadimide compounds heated in air and in nitrogen appeared to cure by different mechanisms.

Young, P. R.↗

Computational Fluid Dynamics Based Extraction of Heat Transfer Coefficient in Cryogenic Propellant Tanks

Current reduced-order thermal model for cryogenic propellant tanks is based on correlations built for flat plates collected in the 1950's. The use of these correlations suffers from: inaccurate geometry representation; inaccurate gravity orientation; ambiguous length scale; and lack of detailed validation. The work presented under this task uses the first-principles based Computational Fluid Dynamics (CFD) technique to compute heat transfer from tank wall to the cryogenic fluids, and extracts and correlates the equivalent heat transfer coefficient to support reduced-order thermal model. The CFD tool was first validated against available experimental data and commonly used correlations for natural convection along a vertically heated wall. Good agreements between the present prediction and experimental data have been found for flows in laminar as well turbulent regimes. The convective heat transfer between tank wall and cryogenic propellant, and that between tank wall and ullage gas were then simulated. The results showed that commonly used heat transfer correlations for either vertical or horizontal plate over predict heat transfer rate for the cryogenic tank, in some cases by as much as one order of magnitude. A characteristic length scale has been defined that can correlate all heat transfer coefficients for different fill levels into a single curve. This curve can be used for the reduced-order heat transfer model analysis.

Yang, H. Q.↗

The impact of non-ideal phase change properties on phase change thermal energy storage device performance

Phase change materials have been known to improve the performance of energy storage devices by shifting or reducing thermal/electrical loads. While an ideal phase change material is one that undergoes a sharp, reversible phase transition, real phase change materials do not exhibit this behavior and often have one or more non-idealities – glide, hysteresis, supercooling – associated with them. Experimental and modeling techniques to characterize these non-ideal properties are reasonably well understood, however, their impact on the performance of a thermal energy storage system is not fully understood. Herein, we analyze the performance of a heat exchanger with a phase change material as a function of the different non-idealities, for a heating and a cooling application. We focus on the impact of these non-ideal behaviors on different modes of operation of the thermal energy storage device, which will serve as a useful guide to researchers on the relative importance of the non-ideal properties, along with the necessary accuracy required during an experimental characterization.

25 ENERGY STORAGE↗

Developing tools and process controls to manufacture energy-efficient powders for additive manufacturing feedstocks: Computational analysis of metal powder manufacturing via machining

Traditionally, metal powders have been produced through methods such as grinding, atomization, and electrolysis. In contrast to these techniques, Metal Powder Works, Inc. has pioneered a methodology based on metal cutting. This innovative approach utilizes a vibrating cutting tool to machine metal particles, in the form of chips, from a workpiece. This technique allows for control of powder particle size, morphology, and avoids any thermally induced material changes. This collaboration aims to elucidate metal cutting characteristics and assess performance on tough materials like Inconel alloys. Computational models, using FEA and SPH techniques, will be developed initially, focusing on aluminum alloy (Al 7075-T6) for studying mesh sensitivity, cutting forces, and chip morphology.

99 GENERAL AND MISCELLANEOUS↗

Developing tools and process controls to manufacture energy-efficient powders for additive manufacturing feedstocks

Traditionally, metal powders have been produced through methods such as grinding, atomization, and electrolysis. In contrast to these techniques, Metal Powder Works, Inc. has pioneered a methodology based on metal cutting. This innovative approach utilizes a vibrating cutting tool to machine metal particles, in the form of chips, from a workpiece. This technique allows for control of powder particle size, morphology, and avoids any thermally induced material changes. This collaboration aims to elucidate metal cutting characteristics and assess performance on tough materials like Inconel alloys. Computational models, using FEA and SPH techniques, will be developed initially, focusing on aluminum alloy (Al 7075- T6) for studying mesh sensitivity, cutting forces, and chip morphology.

36 MATERIALS SCIENCE↗

Enabling Mission Flexibility to Battery Driven Deep Space Endeavors With Generalized Battery-Health-Monitoring Using Physics-Based and Data-Driven Reduced-Order Models

The needs and requirements for an electrochemical energy storage for deep space exploration is well explored. It is often understood that different mission sites and environmental conditions require different battery chemistries or technologies. Additionally, various engineering solutions are deployed to overcome specific chemical challenges. One often overlooked need is the “health” monitoring of an electrochemical storage system. The term generalized health monitoring, as envisioned in this work, refers to the monitoring of various aspects such as electrode health, electrolyte health, reaction pathway health, cooling system health, sensor health, and BMS health [1]. Generalized health monitoring allows mission leads, engineers, and scientists to incorporate flexibility in mission designs, make on-the-fly mission changes, and extend the duration of science missions. Moreover, it enables automation and data-driven decision-making without compromising safety and performance. Recently, our group developed a hierarchy of thermal reduced-order models (TROM) by combining a physics-based modeling approach and data-driven model reduction techniques applied to flight data [2]. The resulting TROMs were found to be not only accurate but also identifiable from the flight data. Consequently, the coefficient of variance of the model parameters is small over the course of hundreds of flights, allowing for monitoring the parameter evolution trajectories as the battery ages and degrades. These parameters constitute the metrics of the generalized health of a battery. Monitoring their evolution allows such models to be used for anomaly detection and prognostics, improving early detection of abnormal behavior and thus enabling timely maintenance, longer battery life, and enhanced battery safety. For this presentation, the practicality of the thermal model will be validated on a pack of 14cells under various topology configurations such as 1S14P, 2P7S, 7S2P, and 1P14S. It is well known that manufacturing and non-uniform aging lead to variability in the performance of a cell, which is exacerbated by cell balancing during active load. Additionally, in extreme scenarios, the paramount objective is to complete the mission, regardless of the stresses on the battery. Topology-induced balancing issues further stress the battery. The goal of this study is to determine if the noise (identifiability) in the reduced-order thermal model parameters is sensitive to topology, cell spacing, cooling strategy, and manufacturing or age variability. The variability in cells is considered by assuming a multimodal distribution for microscopic parameters of a cell (such as porosity, tortuosity, reaction kinetics, volumetric thermal conductivity, and volumetric heat capacity). The compounded effect of manufacturing variability, topological selection, cooling strategies, and cell balancing ages each cell in a battery differently. The study aims to clarify whether the challenge in extracting maximum information depends on the minimum number of sensors or models used for data extraction.

Automation↗

STOP Modeling for the JWST: Techniques, Results, and Sensitivities

The James Web Space Telescope (JWST) is a large, infrared-optimized, space telescope scheduled for launch to L2 in 2011. It must meet rigorous thermal stability requirements, almost all of which will be verified through analysis. Terrestrial testing will be performed but even that will require significant analytical interpretation of results. Preliminary analysis indicates that traditional second-order effects could cause the telescope to exceed established performance requirements. This leads to very large detailed models, primarily since composite tubes are being modeled using solid elements. To minimize differences between the current baseline and the model the project is using a number of rapid analysis cycles. The large size of the telescope models and the short cycle time creates a demanding multidisciplinary analysis environment.

John D. Johnston↗

High-resolution heat-transfer-coefficient maps applicable to compound-curve surfaces using liquid crystals in a transient wind tunnel

Tests were performed in a transient heat transfer tunnel in which the model under test was preheated prior to allowing room temperature air to be suddenly drawn over the model. The resulting movement of isothermal contours on the model is revealed using a surface coating of thermochromic liquid crystals that display distinctive colors at particular temperatures. A video record is obtained of a temperature and time data pair for all points on the model during a single test. Experiments on a duct model are reported in which the model was preheated using a hot air stream. A manner in which initial model temperature nonuniformities could be taken into account was investigated. The duct model was also tested with a steady-state measurement technique and results were compared with the transient measurements, but recognizing that differences existed between the upstream thermal boundary conditions. The steady-state and transient measurements were shown to be consistent with predicted values. The main advantage of this transient heat transfer technique using liquid crystals is that since the test model need not be actively heated, high-resolution measurements on surfaces with complex shapes may be obtained.

Jones, T. V.↗

High-resolution heat-transfer-coefficient maps applicable to compound-curve surfaces using liquid crystals in a transient wind tunnel

Tests were performed in a transient heat transfer tunnel in which the model under test was preheated prior to allowing room temperature air to be suddenly drawn over the model. The resulting movement of isothermal contours on the model is revealed using a surface coating of thermochromic liquid crystals that display distinctive colors at particular temperatures. A video record is obtained of a temperature and time data pair for all points on the model during a single test. Experiments on a duct model are reported in which the model was preheated using a hot air stream. A manner in which initial model temperature nonuniformities could be taken into account was investigated. The duct model was also tested with a steady-state measurement technique and results were compared with the transient measurements, but recognizing that differences existed between the upstream thermal boundary conditions. The steady-state and transient measurements were shown to be consistent with predicted values. The main advantage of this transient heat transfer technique using liquid crystals is that since the test model need not be actively heated, high-resolution measurements on surfaces with complex shapes may be obtained.

Jones, Terry V.↗

Thermal decomposition of neptunyl ammonium nitrate: mechanistic insights and structural characterization of the Np 2 O 5 intermediate phase

Neptunium (Np) possesses a rich and unique chemistry that often diverges from other actinide elements yet remains relatively underexplored compared with the other light actinides. A resurgence of interest in Np has been spurred by the application of 237 Np for plutonium-238 ( 238 Pu) production for use in radioisotope thermoelectric generators (RTGs), necessitating evaluation of Np chemical reactions and materials. The work presented here studied the thermal decomposition of neptunyl ammonium nitrate (NH 4 Np VI O 2 (NO 3 ) 3 ) for synthesis of neptunium dioxide (NpO 2 ), which is the target material used for production of 238 Pu. Additionally, structural characterization of the intermediate solid Np pentoxide (Np 2 O 5 ) was performed. Advanced solid-state characterization techniques, including simultaneous thermal analysis (STA), powder X-ray diffraction (pXRD), Raman spectroscopy, and density functional theory (DFT) modeling have been combined to study the reaction pathways. Analysis revealed that NH 4 Np VI O 2 (NO 3 ) 3 thermally decomposes to a proposed neptunyl nitrate intermediate, followed by Np 2 O 5 and finally NpO 2 , all within the temperature range of 150 °C–600 °C. Further characterization of the pentoxide intermediate provided the first Raman spectra of pure-phase Np 2 O 5 and associated DFT modeling confirmed Raman peak assignments for this phase. These findings provide mechanistic information to advance production of the critical radioisotope 238 Pu and advance the state of knowledge on Np materials chemistry using modern characterization techniques.

Lawson, Kathryn M. [Oak Ridge National Laboratory ↗

Thermomechanical evolution of oceanic fracture zones

To explain the topographic and gravitational signals of fracture zones (FZs), a realistic model is developed and compared with Seasat altimeter data across three major FZs. The model is based on the thermal, subsidence, and mechanical models of the oceanic lithosphere. The model is used to calculate the FZ topography and the evolution of the geoid signature across a FZ. When lithospheric flexure is included, the model explains the persistence of sharp FZ geoid steps on old seafloor as well as the asymmetry of the geoid steps across major FZs. The model does not explain the disappearance of the thermal part of the FZ geoid signature. The model profiles are used to access the various techniques for estimating the overall geoid offsets across FZs. It is shown that steps may be underestimated by as much as 50 percent. These predictions, if correct, will force reinterpretation of published geoid height versus age data derived from altimeter profiles across FZs.

Sandwell, D. T.↗

Linear dynamic analysis of the Space Station Freedom thermal/environmental control system

A methodology for dynamic analysis of the Space Station Freedom thermal/environmental control system is described which uses linear system analysis techniques to determine the ability of the system to accommodate thermal load transients. A nonlinear integrated model of the system as it exists at Stage 6, Man Tended Capability (MTC), is described which encompasses the cabin air cooling system, avionics air cooling system, internal and external thermal control systems. The nonlinear model is linearized at an assumed design operating point, and the linear model is evaluated by comparison with the nonlinear model. Transfer functions are derived to determine the response of the heat rejection system to time-varying thermal loads applied at various points in the heat acquisition system. The frequency response calculated from the transfer functions is used to determine allowable operating envelopes of thermal load magnitude and frequency for each point of application of thermal load. The dynamic operating envelopes provide a quantitative indication of the degree and duration of peak loads which the thermal/environmental system is able to transport and reject.

Tandler, John↗

Low altitude plume impingement handbook

Plume Impingement modeling is required whenever an object immersed in a rocket exhaust plume must survive or remain undamaged within specified limits, due to thermal and pressure environments induced by the plume. At high altitudes inviscid plume models, Monte Carlo techniques along with the Plume Impingement Program can be used to predict reasonably accurate environments since there are usually no strong flowfield/body interactions or atmospheric effects. However, at low altitudes there is plume-atmospheric mixing and potential large flowfield perturbations due to plume-structure interaction. If the impinged surface is large relative to the flowfield and the flowfield is supersonic, the shock near the surface can stand off the surface several exit radii. This results in an effective total pressure that is higher than that which exists in the free plume at the surface. Additionally, in two phase plumes, there can be strong particle-gas interaction in the flowfield immediately ahead of the surface. To date there have been three levels of sophistication that have been used for low altitude plume induced environment predictions. Level 1 calculations rely on empirical characterizations of the flowfield and relatively simple impingement modeling. An example of this technique is described by Piesik. A Level 2 approach consists of characterizing the viscous plume using the SPF/2 code or RAMP2/LAMP and using the Plume Impingement Program to predict the environments. A Level 3 analysis would consist of using a Navier-Stokes code such as the FDNS code to model the flowfield and structure during a single calculation. To date, Level 1 and Level 2 type analyses have been primarily used to perform environment calculations. The recent advances in CFD modeling and computer resources allow Level 2 type analysis to be used for final design studies. Following some background on low altitude impingement, Level 1, 2, and 3 type analysis will be described.

Smith, Sheldon D.↗

Cure Chemistry of Phenylethynyl Terminated Oligomers

The ability to process high performance polymers into quality, void-free composites has been significantly advanced using oligomers terminated with reactive groups which cure or crosslink at elevated temperature without the evolution of volatile byproducts. Several matrix resin systems of considerable interest to the aerospace community utilize phenylethynyl-terminated imide (PETI) technology to achieve this advantage. The present paper addresses the cure chemistry of PETI oligomers. The thermal cure of a low molecular weight model compound was studied using a variety of analytical techniques including differential scanning calorimetry, Fourier transform infrared spectroscopy, and liquid chromatography-mass spectroscopy. The studies indicate an extremely complex cure process. Many stable products were isolated and this paper reports current work on identification of those products. The intent of this research is to provide fundamental insight into the molecular structure of the cured PETI engineering materials so that performance and durability can be more fully assessed.

Wood, Karen H.↗

Comparison Analysis Between Nevada and TSS Using a Jet Engine Exhaust Nozzle Test Rig

Thermal analysis in both simple and complex models can require calculating the propagation of radiant energy to and from multiple surfaces. This can be accomplished through simple estimation techniques or complex computationally intense computer modeling simulations. Currently there are a variety of computer analysis techniques used to simulate the propagation of radiant energy, each having advantages and disadvantages. The major objective of this effort was to compare two ray tracing radiation propagation analysis programs (NEVADA and TSS) Net Energy Verification and Determination Analyzer and Thermal Synthesizer System with experimental data. Results from a non-flowing, electrically heated test rig was used to verify the calculated radiant energy propagation from a nozzle geometry that represents an aircraft propulsion nozzle system. In general the programs produced comparable overall results, and results slightly higher then the experimental data. Upon inspection of individual radiation interchange factors, differences were evident and would have been magnified if a more radical model temperature profile was analyzed. Bidirectional reflectivity data (BRDF) was not used do to modeling limitations in TSS. For code comparison purposes, this nozzle geometry represents only one case for one set of analysis conditions. Since each computer code has advantages and disadvantages bases on scope, requirements, and desired accuracy, the usefulness of this single case study may be limiting.

Baumeister, Joseph F.↗

An optical study of grain formation: Casting and solidification technology (2-IML-1)

By studying the unidirectional growth of a metal-model material in microgravity, an attempt is made to characterize alloy solidification. Using holograms and supporting temperature measurements obtained during processing in the Fluids Experiment System (FES), the solute and thermal fields associated with the dendrite growth front and extraneous nucleation will be measured and compared to a theoretical (computational) model. Ground based supporting experiments include particle tracking to measure the velocity fields, and optical phase shift techniques (confocal optical signal processing, interferometry, and Schlieren) to study thermal and solutal fields.

Mccay, Mary H.↗