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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

An Artificial Z-Scheme Constructed from Dye-Sensitized Metal Oxide Nanosheets for Visible Light-Driven Overall Water Splitting

Sensitization of a wide-gap oxide semiconductor with a visible-light-absorbing dye has been studied for decades as a means of producing H 2 from water. However, efficient overall water splitting using a dye-sensitized oxide photocatalyst has remained an unmet challenge. Here in this paper we demonstrate visible-light-driven overall water splitting into H 2 and O 2 using HCa 2 Nb 3 O 10 nanosheets sensitized by a Ru(II) tris-diimine type photosensitizer, in combination with a WO 3 -based water oxidation photocatalyst and a triiodide/iodide redox couple. With the use of Pt-intercalated HCa 2 Nb 3 O 10 nanosheets further modified with amorphous Al 2 O 3 clusters as the H 2 evolution component, the dye-based turnover number and frequency for H 2 evolution reached 4580 and 1960 h –1 , respectively. The apparent quantum yield for overall water splitting using 420 nm light was 2.4%, by far the highest among dye- sensitized overall water splitting systems reported to date. The present work clearly shows that a carefully designed dye/oxide hybrid has great potential for photocatalytic H 2 production, and represents a significant leap forward in the development of solar-driven water splitting systems.

14 SOLAR ENERGY↗
NASA NTRS1980

VLA observations of impulsive solar flares at 4.9 GHz

A series of snapshot synthesis maps constructed as a function of time provided a complete mapping of source structure in one dimension and absolute location in two dimensions of five impulsive solar microwave bursts observed during July 15-18, 1978. It was found that all five flares were dominated by a single 12-18 arcsec source located between the H-alpha kernels, near the magnetic neutral line. Spectral data from Sagamore Hill (1.4-35 GHz) show that the spectral turnover at low frequencies results from the absorption by the ambient active region; these results, together with the observed magnetic configuration, suggest a model which could explain the evolution in source structure at 4.9 GHz in terms of magnetic reconnection which starts below the optical depth of the ambient active region equal to 1.

Marsh, K. A.↗
NASA NTRS1989

G25.5 + 0.2 - A very young galactic supernova remnant

Radio emission has been detected from a compact source which satisfies the criteria for a very young galactic supernova remnant. The source, G25.5 + 0.2 has a partially-filled shell structure, a total integrated flux density at 20 cm of 315 mJy, and a flat spectrum between 2 and 20 cm. Observations at 843 and 327 MHz indicate thermal absorption at low frequencies with a turnover in the spectrum near 1 GHz. It is suggested that the lower limit for the age of the supernova remnant is 25 yr, while the upper limit is about 100 yr. It is concluded that G25.5 + 0.2 could be the youngest known supernova remnant in the Galaxy.

Cowan, John J.↗
NASA NTRS1986

Multifrequency observations of blazars. II - The variability of the 1 micron to 2 mm continuum

The results of monitoring, over a period of two years, a sample of 12 blazars, in 11 wave bands between 1 micron and 2 mm are presented. All sources exhibit some variability, both in flux density and spectral shape. The infrared variability is consistent with repeated injections of reaccelerations of electrons, which subsequently suffer radiative losses. For OJ 287, 3C 279, and 3C 345, a decay and steepening of the infrared spectrum occurred as the submillimeter turnover evolved to lower frequencies, consistent with expansion of the emitting region. The peak flux, however, increased during this evolution. This behavior is inconsistent with most models for compact extragalactic sources, but it is naturally explained by shock waves traveling in an adiabatically expanding relativistic jet (Marscher and Gear, 1985).

Gear, W. K.↗
NASA NTRS2009

Precise Stabilization of the Optical Frequency of WGMRs

Crystalline whispering gallery mode resonators (CWGMRs) made of crystals with axial symmetry have ordinary and extraordinary families of optical modes. These modes have substantially different thermo-refractive constants. This results in a very sharp dependence of differential detuning of optical frequency on effective temperature. This frequency difference compared with clock gives an error signal for precise compensation of the random fluctuations of optical frequency. Certain crystals, like MgF2, have turnover points where the thermo-refractive effect is completely nullified. An advantage for applications using WGMRs for frequency stabilization is in the possibility of manufacturing resonators out of practically any optically transparent crystal. It is known that there are crystals with negative and zero thermal expansion at some specific temperatures. Doping changes properties of the crystals and it is possible to create an optically transparent crystal with zero thermal expansion at room temperature. With this innovation s stabilization technique, the resultant WGMR will have absolute frequency stability The expansion of the resonator s body can be completely compensated for by nonlinear elements. This results in compensation of linear thermal expansion (see figure). In three-mode, the MgF2 resonator, if tuned at the turnover thermal point, can compensate for all types of random thermal-related frequency drift. Simplified dual-mode method is also available. This creates miniature optical resonators with good short- and long-term stability for passive secondary frequency ethalon and an active resonator for active secondary frequency standard (a narrowband laser with long-term stability).

Savchenkov, Anatoliy↗
NASA NTRS1991

The ultraviolet spectrum and continuum energy distribution of the bright quasar H1821 + 643

The first UV observations of the bright QSO H1821 + 643 are reported. With V = 14.2 mag and z = 0.297, H1821 + 643 is the second brightest object in the sky at z above 0.1. The IUE data are combined with new optical spectroscopy, and existing IR and X-ray data, to reveal a strong optical/UV 'big bump', which continues past the Lyman limit in the rest frame of the QSO. A possible turnover at the high-frequency side of the UV continuum constrains fits of a thin accretion disk model to a large black hole mass and high accretion rate, but a small disk size. The shape of the UV continuum was found to be variable, with a hardening of the spectrum when the source was brighter. Because of its location, only 3 deg from the ecliptic pole, H1821 + 643 will be an important object for simultaneous UV and soft X-ray monitoring to test for a common origin of the UV bump and soft X-ray excess.

Kolman, Michiel↗
NASA NTRS1989

Production of self-absorbed synchrotron spectra steeper than nu to the 5/2

Self-absorbed synchrotron radiation produced by electrons with a power-law distribution of energies has a unique spectral shape: intensity is proportional to nu to the 5/2, where nu is the frequency, irrespective of the power law index of the electrons. It has been asserted that the measurement of a spectral index greater than 5/2 at frequencies below the 'far-IR turnovers' observed in the spectra of many radio-quiet AGN is incompatible with the physics of self-absorbed synchrotron sources. It is shown here that plausible electron energy distributions can lead to self-absorbed synchrotron spectra which are steeper than nu to the 5/2 over 1-1.5 orders of magnitude in frequency. This indicates that none of the existing observations are in fact incompatible with self-absorbed synchrotron radiation as the source.

De Kool, Martijn↗
DOE OSTI2023

Uncovering the dominant role of root metabolism in shaping rhizosphere metabolome under drought in tropical rainforest plants

Plant-soil-microbe interactions are crucial for driving rhizosphere processes that contribute to metabolite turnover and nutrient cycling. With the increasing frequency and severity of water scarcity due to climate warming, understanding how plant-mediated processes, such as root exudation, influence soil organic matter turnover in the rhizosphere is essential. In this study, we used 16S rRNA gene amplicon sequencing, rhizosphere metabolomics, and position-specific 13 C-pyruvate labeling to examine the effects of three different plant species (Piper auritum, Hibiscus rosa sinensis, and Clitoria fairchildiana) and their associated microbial communities on soil organic carbon turnover in the rhizosphere. Here, our findings indicate that in these tropical plants, the rhizosphere metabolome is primarily shaped by the response of roots to drought rather than direct shifts in the rhizosphere bacterial community composition. Specifically, the reduced exudation of plant roots had a notable effect on the metabolome of the rhizosphere of P. auritum, with less reliance on neighboring microbes. Contrary to P. auritum, H. rosa sinensis and C. fairchildiana experienced changes in their exudate composition during drought, causing alterations to the bacterial communities in the rhizosphere. This, in turn, had a collective impact on the rhizosphere's metabolome. Furthermore, the exclusion of phylogenetically distant microbes from the rhizosphere led to shifts in its metabolome. Additionally, C. fairchildiana appeared to be associated with only a subset of symbiotic bacteria under drought conditions. These results indicate that plant species-specific microbial interactions systematically change with the root metabolome. As roots respond to drought, their associated microbial communities adapt, potentially reinforcing the drought tolerance strategies of plant roots. These findings have significant implications for maintaining plant health and preference during drought stress and improving plant performance under climate change.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1977

Transfer of polarized radiation in self-absorbed synchrotron sources. II - Treatment of inhomogeneous media and calculation of emergent polarization

As an extension of previous treatments of polarized radiation transfer in homogeneous synchrotron sources, a transfer procedure is derived, based on the coupled-wave formulation, which allows consideration of inhomogeneous sources. It is shown that plasma characteristic wave eccentricities in a source must be fairly large unless Faraday rotation per absorption depth is very large, and that coupling between characteristic waves can be strong in inhomogeneous self-absorbed sources. Calculations are made of the polarized radiation emergent from a source with a boundary of finite thickness. It is found that neglect of propagation effects in the source boundary introduces no significant errors at optically thin frequencies, but that below the self-absorption turnover the emergent polarization may depend significantly upon such effects. In particular, the sign of the circular polarization and the linear polarization position angle depend upon the absorption depth in the boundary region.

Jones, T. W.↗
NASA NTRS1979

Simultaneous multifrequency observations of Jovian S bursts

The millisecond component of the Jovian decameter emission was studied at high resolution in order to examine the short-term behavior of the S-burst drift rates and to define the drift rate spectrum at high frequencies. By using dynamic spectra of 300 microsec and 3.3 kHz resolution and covering discrete frequency bands in the 26-33 MHz range, large systematic changes in the magnitude of the S-burst drift rates are observed on a time scale of seconds to minutes. The drift rate variability, its dependence on frequency, and absence of the predicted drift rate turnover in the spectrum are interpreted in terms of an ionospheric electron source. Low-resolution intensity-time tracings, abrupt changes in mean drift rates from group to group, and systematic variations in the group-to-group mean drift rates due to predictable temporal changes in the magnetic field gradient on the Io flux tube are discussed. These temporal changes are due to motion of the Io-associated magnetic flux tube in the Jovian magnetosphere.

Flagg, R. S.↗
NASA NTRS1992

The integrated radio continuum spectrum of M33 - Evidence for free-free absorption by cool ionized gas

We present measurements of the integrated radio continuum flux density of M33 at frequencies between 22 and 610 MHz and discuss the radio continuum spectrum of M33 between 22 MHz and 10 GHz. This spectrum has a turnover between 500 and 900 MHz, depending on the steepness of the high frequency radio spectrum of M33. Below 500 MHz the spectrum is relatively flat. We discuss possible mechanisms to explain this spectral shape and consider efficient free-free absorption of nonthermal emission by a cool (not greater than 1000 K) ionized gas to be a very likely possibility. The surface filling factor of both the nonthermal and the thermal material appears to be small (of order 0.001), which could be explained by magnetic field/density fluctuations in the M 33 interstellar medium. We briefly speculate on the possible presence of a nuclear radio source with a steep spectrum.

Israel, F. P.↗
NASA NTRS2006

Progress Report for a New Cryogenic Sapphire Oscillator

We present design progress and subsystem test results for a new short-term frequency standard, the Voltage Controlled Sapphire Oscillator (VCSO). Included are sapphire resonator and coupling design, cryocooler environmental sensitivity tests, Q measurement results, and turnover temperature results. A previous report presented history of the design related to resonator frequency and frequency compensation [1]. Performance goals are a frequency stability of 1x10(exp -14) (1 second less than or equal to (tau) less than or equal to 100 seconds) and two years or more continuous operation. Long-term operation and small size are facilitated by use of a small Stirling cryo-cooler (160W wall power) with an expected 5 year life.

oscillator↗
NASA NTRS2018

A NICER Look at the Aql X-1 Hard State

We report on a spectral-timing analysis of the neutron star low-mass X-ray binary(LMXB)AqlX-1 with the Neutron Star Interior Composition Explorer (NICER) on the International Space Station (ISS). AqlX-1 wasobserved with NICER during a dim outburst in 2017 July, collecting approximately 50 ks of good exposure. The spectral and timing properties of the source correspond to that of a (hard) extreme island state in the atoll classification. We find that the fractional amplitude of the low-frequency (<0.3Hz) band-limited noise shows adramatic turnover as a function of energy: it peaks at 0.5keV with nearly 25% rms, drops to 12% rms at 2keV,and rises to 15% rms at 10keV. Through the analysis of covariance spectra, we demonstrate that band-limited noise exists in both the soft thermal emission and the power-law emission. Additionally, we measure hard timelags, indicating the thermal emission at 0.5keV leads the power-law emission at 10 keV on a timescale of 100ms at 0.3Hz to10ms at 3Hz. Our results demonstrate that the thermal emission in the hard state is intrinsically variable, and is driving the modulation of the higher energy power-law. Interpreting the thermal spectrum as disk emission, we find that our results are consistent with the disk propagation model proposed for accretion onto black holes.

Bult, Peter↗
NASA NTRS1985

Multifrequency observations of blazars. I - The shape of the 1 micron to 2 millimeter continuum

Near-simultaneous measurements in 11 wavebands between 1 micron and 2 mm of a sample of 13 'blazars' are presented. These measurements represent the first comprehensive attempt to determine the infrared-to-millimeter-wave properties of this class of object, which emit the bulk of their luminosity in the far-infrared region. Most of the sources have very flat millimeter/submillimeter spectra up to the highest observed frequency. However, 3C 279 and 3C 446 show evidence of turnovers in their submillimeter spectra. The 1-4 micron spectra can be characterized by simple power laws, all steeper than -0.9; several sources, however, show evidence of spectral beaks in the 10-20 micron region, suggestive of energy losses. It is shown that the spectral properties are consistent with synchrotron emission from relativistic jets aligned close to the line of sight and the observations are discussed in relation to such models.

Gear, W. K.↗
DOE OSTI2025

Catalytic Resonance Theory: Experimental and Kinetic Interpretation of Programmable Catalysis

The complexity of programmable catalysts that change in the physical or electronic state on the time scale of a catalytic turnover results in uncertainty in the kinetic outcome of common measurements with dynamic catalyst experiments. To provide an interpretation of utility to experimentalists, a general programmable catalytic reaction exhibiting high turnover efficiency was simulated to understand the kinetic behavior of catalysts with varying frequency, binding energy, oscillation amplitude, and minimum oscillation binding energy at different temperatures and reactant gas pressures. The time-averaged catalytic rate for varying temperature in the form of an Arrhenius plot exhibited three distinct kinetic regimes, with the intermediate temperatures or applied frequencies exhibiting zero slope, indicative of barrier-free kinetic control. Transitions in experimentally measurable kinetic regimes with both temperature and applied catalyst oscillation frequency were associated with transitions in the sensitivity of reaction rate constants and degrees of rate control. Furthermore, these distinct kinetic macroscopic features specific to programmable catalysts were identified for observation in experimental dynamic kinetic measurements.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2011

Nutrition Research: Basis for Station Requirements

Prior to the Shuttle program, all understanding of nutritional needs in space came from Skylab metabolic research. Because Shuttle flights were short, most less than 14 days, research focused on major nutritional issues: energy (calories), protein and amino acids, water and electrotypes, with some more general physiology studies that related to iron and calcium. Using stable isotope tracer studies and diet intake records, we found that astronauts typically did not consume adequate calories to meet energy expenditure. To monitor energy and nutrient intake status and provide feedback to the flight surgeon and the astronauts, the International Space Station (ISS) program implemented a weekly food frequency questionnaire and routine body mass measurements. Other Shuttle investigations found that protein turnover was higher during flight, suggesting there was increased protein degradation and probably concurrent increase in protein synthesis, and this occurred even in cases of adequate protein and caloric intake. These results may partially explain some of the loss of leg muscle mass. Fluid and electrolyte flight studies demonstrated that water intake, like energy intake, was lower than required. However, sodium intakes were elevated during flight and likely related to other concerns such as calcium turnover and other health-related issues. NASA is making efforts to have tasty foods with much lower salt levels to reduce sodium intake and to promote fluid intake on orbit. Red blood cell studies conducted on the Shuttle found decreased erythrogenesis and increased serum ferritin levels. Given that the diet is high in iron there may be iron storage health concerns, especially related to the role of iron in oxidative damage, complicated by the stress and radiation. The Shuttle nutrition research lead to new monitoring and research on ISS. These data will be valuable for future NASA and commercial crewed missions.

Lane, Helen W.↗
NASA NTRS1991

Mechanically induced alterations in cultured skeletal muscle growth

Model systems are available for mechanically stimulating cultured skeletal muscle cells by passive tensile forces which simulate those found in vivo. When applied to embryonic muscle cells in vitro these forces induce tissue organogenesis, metabolic adaptations, and muscle cell growth. The mechanical stimulation of muscle cell growth correlates with stretch-induced increases in the efflux of prostaglandins PGE2 and PGF2(alpha) in a time and frequency dependent manner. These prostaglandins act as mechanical 'second messengers' regulating skeletal muscle protein turnover rates. Since they also effect bone remodelling in response to tissue loading and unloading, secreted prostaglandins may serve as paracrine growth factors, coordinating the growth rates of muscle and bone in response to external mechanical forces. Cell culture model systems will supplement other models in understanding mechanical transduction processes at the molecular level.

Vandenburgh, H. H.↗