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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 235 records · Page 13
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

A Distributed Control Architecture for Cascaded H-Bridge Converter with Integrated Battery Energy Storage

Cascaded H-bridge topology has been used in grid-tied converters for battery energy storage system due to its modular structure. To fully utilize the converter’s modularity, this paper proposes a hierarchical distributed control architecture that consists of primary control, secondary control and battery state of charge (SOC) balancing control. Primary control ensures accurate current tracking while a distributed secondary control based on consensus algorithm is presented to regulate power sharing among modules and is proved to be stable theoretically. Here, a distributed SOC balancing control is further introduced to improve energy efficiency of battery energy storage system. Finally, the hierarchical distributed control strategy is implemented using hardware controllers and a software platform. Besides, a carrier phase shift control is also implemented to achieve multilevel output voltage and harmonic reduction. The experimental results demonstrate the performance of the proposed control scheme effectively.

25 ENERGY STORAGE↗
DOE OSTI2023

Critical Contribution of Imbalanced Charge Loss to Performance Deterioration of Si-Based Lithium-Ion Cells during Calendar Aging

Increasing the energy density of lithium-ion batteries, and thereby reducing costs, is a major target for industry and academic research. One of the best opportunities is to replace the traditional graphite anode with a high-capacity anode material, such as silicon. However, Si-based lithium-ion batteries have been widely reported to suffer from a limited calendar life for automobile applications. Heretofore, there lacks a fundamental understanding of calendar aging for rationally developing mitigation strategies. Both open-circuit voltage and voltage-hold aging protocols were utilized to characterize the aging behavior of Si-based cells. Particularly, a high-precision leakage current measurement was applied to quantitatively measure the rate of parasitic reactions at the electrode/electrolyte interface. The rate of parasitic reactions at the Si anode was found 5 times and 15 times faster than those of LiNi 0.8 Mn 0.1 Co 0.1 O 2 and LiFePO 4 cathodes, respectively. Here, the imbalanced charge loss from parasitic reactions plays a critical role in exacerbating performance deterioration. In addition, a linear relationship between capacity loss and charge consumption from parasitic reactions provides fundamental support to assess calendar life through voltage-hold tests. These new findings imply that longer calendar life can be achieved by suppressing parasitic reactions at the Si anode to balance charge consumption during calendar aging.

25 ENERGY STORAGE↗
DOE OSTI2023

Circuit-level design principles for transmission-mode microwave impedance microscopy

A recently developed technique of transmission-mode microwave impedance microscopy (T-MIM) has greatly extended the capabilities of standard reflection-mode MIM to novel applications, such as the in operando study of nanoscale electro-acoustic devices. As is common for new techniques, systematic design principles for boosting sensitivity and balancing bandwidth are lacking. Here, we show numerically and analytically that the T-MIM signal is proportional to the reflection-mode voltage enhancement factor η of the circuit, as long as the output impedance of the local voltage source is properly treated. We show that this proportionality holds in the currently achievable “weak sampling” regime and beyond, for which we demonstrate a realistic path with commercially available superconducting components and critically coupled impedance matching networks. Furthermore, we demonstrate that for these next-generation designs, the sensitivity is generally maximized at a slightly different frequency from the unloaded S 11 resonance, which can be explained by the maximum power transfer theorem.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2024

Triboplasma assisted chemical conversion in granular systems: a semi-analytic model

We present a semi-analytic model for a novel plasma-assisted chemical conversion pathway using triboplasmas generated in granular flows. Triboelectric charge relaxation is a well known phenomena where the potential generated from contact charging of particles exceeds the breakdown voltage of the background gas. In this work, we extend the triboelectric charge relaxation theory to include non equilibrium plasma energy and particle balance equations to predict the formation of dissociated and excited species that act as precursors to chemical conversion, for example in plasma-assisted ammonia synthesis. Our example case study with nitrogen background gas and teflon/aluminum tribomaterial system yielded high excited nitrogen species densities per collision that are comparable to current plasma-assisted conversion pathways. We also present a regime diagram for various gases where Paschen breakdown parameters are used to determine whether triboplasmas can be formed for a given effective work-function difference between two materials. Our sensitivity studies indicate particle velocity, particle radius, solids fraction and space charge effects play a critical role in overall plasma densities and excited species production.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1983

Laboratory experience with voltage breakdown

Voltage breakdown failures in photovoltaic module electrical insulations lead to loss of entire source circuits and require costly maintenance and replacement. Avoiding such catastrophes requires that modules be designed so that voltage breakdown either never occurs or occurs so rarely that it affects the least life cycle energy costs insignificantly. To achieve this desired balance of cost and reliability, the module design engineer must understand the failure mechanisms and use data on materials and failue rates to suppress or retard them. Recently obtained failure mechanism information, rate data and materials property data and a qualitative model of module failure prediction are presented.

Mon, G. R.↗
NASA NTRS2014

Martian Atmospheric Pressure Static Charge Elimination Tool

A Martian pressure static charge elimination tool is currently in development in the Electrostatics and Surface Physics Laboratory (ESPL) at NASA's Kennedy Space Center. In standard Earth atmosphere conditions, static charge can be neutralized from an insulating surface using air ionizers. These air ionizers generate ions through corona breakdown. The Martian atmosphere is 7 Torr of mostly carbon dioxide, which makes it inherently difficult to use similar methods as those used for standard atmosphere static elimination tools. An initial prototype has been developed to show feasibility of static charge elimination at low pressure, using corona discharge. A needle point and thin wire loop are used as the corona generating electrodes. A photo of the test apparatus is shown below. Positive and negative high voltage pulses are sent to the needle point. This creates positive and negative ions that can be used for static charge neutralization. In a preliminary test, a floating metal plate was charged to approximately 600 volts under Martian atmospheric conditions. The static elimination tool was enabled and the voltage on the metal plate dropped rapidly to -100 volts. This test data is displayed below. Optimization is necessary to improve the electrostatic balance of the static elimination tool.

Johansen, Michael R.↗
DOE OSTI2026

Coupling Redox Compensation and Interfacial Stabilization in Low-Ni O3-Type Sodium Layered Oxide Cathodes

Low-Ni O3-type sodium layered oxides are attractive cathodes for cost-robust sodium-ion batteries, yet high-voltage cycling is often limited by Fe-driven degradation, including cation migration/dissolution, irreversible slab gliding with large strain, particle cracking, and accelerated interfacial parasitic reactions. Here, in this study, we introduce a redox-interface codesign strategy using stoichiometric, charge-balanced Cu 2+ /Ti 4+ cosubstitution while preserving full Na stoichiometry, transitioning from NaNi 1/4 Fe 1/2 Mn 1/4 O 2 to NaNi 1/4 Fe 1/5 Mn 1/4 Cu 3/20 Ti 3/20 O 2 . With the cosubstitution, Cu and Ti suppress Fe migration and dissolution and facilitate sustained Fe oxidation at high voltage. Meanwhile, Cu is also shown to be redox-active, providing reversible cationic charge compensation that mitigates the capacity penalty typically associated with reducing Fe participation. Operando diffraction and spectroscopy collectively indicate a more reversible high-voltage structural evolution with suppressed Fe-related irreversibility. Particularly, spontaneous Ti enrichment at surface/grain-boundary regions stabilizes the cathode−electrolyte interface and promotes a more NaF-rich interphase signature. This work establishes a generalizable route to reconcile stability and capacity in low-Ni, Fe-containing O3 sodium layered oxide cathodes via compositionally encoded bulk-interfacial coupling.

25 ENERGY STORAGE↗
DOE OSTI2022

Performance Evaluation of an Advanced Distributed Energy Resource Management Algorithm

This paper presents performance evaluation of a new distributed energy resource management system (DERMS) algorithm via an advanced hardware-in-the-loop (HIL) platform. The HIL platform provides realistic testing in a laboratory environment, including the accurate modeling of sub-transmission and distribution networks, the DERMS software controller, and 84 power hardware solar photovoltaic (PV) inverters, standard communication protocols, and a capacitor bank controller. The DERMS algorithm is also called, Grid-Optimization of Solar (GO-Solar) platform which includes predictive state estimation (PSE) and online multiple objective optimization (OMOO) to dispatch the legacy devices and distributed energy resources (e.g., PV). The voltage regulation performance is evaluated under three scenarios, volt-var smart inverter (baseline), and DERMS control for 100% and 30% of PV. The results show that controlling 30% of PV systems with the GO-Solar platform may provide the best balance of control performance and implementation cost.

distributed energy resource management system (DER↗
DOE OSTI2023

Balanced current-source inverter

A switching circuit for a current source inverter includes a first inverter leg, a second inverter leg, and a controller. The first inverter leg includes a first reverse-voltage-blocking (RB) switch, a second RB switch, and a third RB switch that are connected in series between a first bus line and a second bus line. The second inverter leg includes a fourth RB switch, a fifth RB switch, and a sixth RB switch are connected in series between the first bus line and the second bus line. The controller is configured to control a switch between an on-state and an off-state for each RB switch. When in the on-state, a reverse voltage is blocked by a respective RB switch, and a current with a positive polarity is conducted through the respective RB switch. When in the off-state, a voltage and the current are blocked by the respective RB switch.

Jahns, Thomas Merlin↗
DOE OSTI2022

Optically thick GaInAs/GaAsP strain-balanced quantum-well tandem solar cells with 29.2% efficiency under the AM0 space spectrum

GaAs is often used as a multijunction subcell due to its high material quality on GaAs substrates, despite having a non-optimal bandgap. The bandgap can be beneficially reduced using many layers of thin, strain-balanced GaInAs in a superlattice or quantum well device, but achieving excellent carrier collection without increased recombination has proven challenging. Here, we develop and demonstrate high performance, optically thick GaInAs/GaAsP strain-balanced solar cells. Excellent material quality is achieved in thick superlattices by using growth conditions that limit progressive thickness and composition fluctuations. Bandgap-voltage offsets as low as 0.31V are shown in superlattice cells using thin, highly strained GaP barriers. Optically thick superlattice cells with over 2500 nm of total GaInAs in the depletion region are developed, enabling 3.8 mA/cm 2 of extra photocurrent beyond the GaAs band edge under the AM0 space spectrum. Optimized superlattice solar cells are incorporated into two-junction devices that achieve 29.2% efficiency under the AM0 space spectrum due to their improved bandgap combination and high subcell voltages.

14 SOLAR ENERGY↗
DOE OSTI2026

Optimal Hairpin Winding Configuration for EV Traction Motors to Enhance Active CMV Cancellation Capability of NPL.X Inverter

Active common-mode voltage (CMV) cancellation in neutral-point-less (NPL.X) inverter is an effective approach for reducing common-mode electromagnetic interference and alleviating voltage stress associated with high-speed switching in EV traction drives. However, the existing hairpin winding configuration often exhibits impedance imbalance due to slot leakage inductance and manufacturing constraints, limiting the effectiveness of active CMV cancellation. This paper investigates symmetric hairpin winding configurations for a dual-three-phase EV traction machine to improve impedance symmetry. Considering the manufacturing constraints of six-layer hairpin windings, four feasible symmetric winding configurations are analyzed. Two-dimensional finite-element analysis is performed to extract the impedance parameters of each configuration. The extracted impedance parameters are used to quantify the impedance mismatch between complementary phase pairs and evaluate its influence on active CMV cancellation. The results show that the fully interleaved winding configuration achieves perfectly balanced phase impedances with 0 % mismatch, whereas the mismatch in the other configurations ranges from approximately 2.4 % to 0.8 %. Consequently, the resulting total CMV overshoot is significantly suppressed to near zero voltage under high-voltage and high switching frequency operating conditions, demonstrating the importance of winding symmetry for maximizing the active CMV cancellation capability of the NPL.X inverter.

Lee, Kangbeen [Purdue Univ., West Lafayette, IN (U↗
NASA NTRS1992

Application of engineering codes to the assessment of spacecraft charging induced hazards

One of the major hurdles to developing a better understanding of the environmentally induced interactions in spacecraft systems (spacecraft charging) is the lack of simple tools to analyze the behavior of the spacecraft in a sub-storm environment. The available tool, NASA Charging Analyzer Program (NASCAP), is expensive to use and treats only half of the problem - surface effects only. In response to this need, we have developed, under our IRAD Program, a set of engineering tools that operate on personal computers and addresses both the surface and bulk charging aspects of the interactions. These engineering codes utilize circuit analysis techniques and model simplifications to allow rapid computations. The codes were compared to both NASCAP predictions and to bulk charging data with excellent agreement for both phenomena. The models used in our engineering codes are shown, and in the engineering codes, the models are defined in terms of plates or triangles in an unconfined space. The predictions are based upon current balances to each plate. The code has routines to allow interactions between the plates to simulate 'barrier' effects. The agreement for the predicted differential surface voltages for the model is given. In conducting the comparison of engineering codes to NASCAP predictions, it was found that some inconsistencies existed in the NASCAP code that are not obvious to the user. The use of the grid imposes constraints that voltage gradients exist between the grid points. This allows the existence of voltage gradients in conductors and influences surface resistivity predictions. These points are discussed along with the predictions for treating these inconsistencies properly. The model predictions for a variable intensity substorm is also presented.

Stevens, N. J.↗
NASA NTRSDate not supplied

Orion Power Transfer: Impacts of a Battery-on-Bus Power System Architecture

The Orion Multi-Purpose Crew Vehicle (MPCV) has the capability to transfer power to a co-manifested payload (CPL) during transit from low-Earth orbit to the lunar vicinity. This paper discusses a time-phased parametric power analysis to determine the Orion power transfer capability limit. Charge and discharge curves were generated for various power transfer conditions and measured against various minimum system voltage limits. The Orion electrical power system (EPS) utilizes an unregulated bus architecture, which has important implications when the system is operating under very high load demand conditions, such as during power transfer. This analysis highlights three important effects of this architecture. First, increasing load demand decreases the maximum state of charge (SOC) the batteries can reach when charging. Second, increasing load demand also decreases the allowable battery depth of discharge. These two together can significantly reduce the effective useable capacity of the batteries. Finally, low battery voltage decreases the power generation of the solar arrays. This can lead to significantly longer recharge times or even push the system out of energy balance. These effects have important implications for mission design and vehicle operations and must be accounted for when conducting sizing and design of an unregulated spacecraft EPS.

Electrical Power System↗
DOE OSTI2022

Forming Interphase Microgrids in Distribution Systems Using Cooperative Inverters

Interphase-microgrids formed by three islanded single-phase feeders in distribution systems are proposed in this paper. Loss of utility caused by natural and human-made disasters may isolate each residential subdivision from the utility. In this case, the household loads are supplied by distributed generation (DG) units which may not be enough to meet the load demand. This can lead to deviations in voltage and frequency, and the deviations may vary for each phase. The proposed solution is to form an interphase-microgrid by seamlessly interconnecting the islanded single-phase feeders. This interphase-microgrid can effectively balance the load demands and DG generation in distribution systems after losing the utility supply. This paper presents different case studies to demonstrate the viability of forming interphase-microgrids for residential distribution systems.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2023

Modeling Intercalation Chemistry with Multiredox Reactions by Sparse Lattice Models in Disordered Rocksalt Cathodes

Modern battery materials can contain many elements with substantial site disorder, and their configurational state has been shown to be critical for their performance. The intercalation voltage profile is a critical parameter to evaluate the performance of energy storage. The application of commonly used cluster expansion techniques to model the intercalation thermodynamics of such systems ab initio is challenged by the combinatorial increase in configurational degrees of freedom as the number of species grows. Such challenges necessitate the efficient generation of lattice models without overfitting and proper sampling of the configurational space under the requirement of charge balance in ionic systems. In this work, we introduce a combined approach that addresses these challenges by (1) constructing a robust cluster expansion Hamiltonian using the sparse regression technique, including -norm regularization and structural hierarchy; and (2) implementing semigrand-canonical Monte Carlo to sample charge-balanced ionic configurations using the table-exchange method and an ensemble average approach. These techniques are applied to a disordered rocksalt oxyfluoride (LMNOF) that is part of a family of promising earth-abundant cathode materials. The simulated voltage profile is found to be in good agreement with experimental data and particularly provides a clear demonstration of the and oxygen contributions to the redox potential as a function of content.

25 ENERGY STORAGE↗
NASA NTRS1979

Power loss for high-voltage solar-cell arrays

Electric field particle collection and power loss are calculated in program written in FORTRAN IV for use on UNIVAC 1100/40 computer. Program incorporates positive and negative and negative charge flows and balance between positive and negative flows is performed by iteration.

Parker, L. W.↗
DOE OSTI2021

Introducing Low-Cost Pyrazine Unit into Terpolymer Enables High-Performance Polymer Solar Cells with Efficiency of 18.23%

Recently, a random ternary copolymerization strategy has become a promising and efficient approach to develop high-performance polymer donors for polymer solar cells (PSCs). Here, in this study, a low-cost electron-withdrawing unit, 2,5-bis(4-(2-ethylhexyl)thiophen-2-yl)pyrazine (PZ-T), is incorporated into the polymer backbone of PM6 as the third component, and three D-A 1 -D-A 2 type terpolymers PMZ-10, PMZ-20, and PMZ-30 are synthesized by the random copolymerization strategy, with the PZ-T proportion of 10%, 20%, and 30%, respectively. The terpolymers exhibit downshifted highest occupied molecular orbital energy levels than PM6, which is beneficial for obtaining higher open-circuit voltage (V oc ) of the PSCs with the polymer as a donor. Importantly, the PSCs based on PMZ-10:Y6 demonstrate efficient exciton dissociation, higher and balanced electron/hole mobilities, desirable aggregation, and high power conversion efficiency of 18.23%, which is the highest efficiency among the terpolymer-based PSCs so far. The results indicate that the ternary copolymerization strategy with PZ-T as the second A-unit is an efficient approach to further improve the photovoltaic performance and reduce the synthetic cost of the D-A copolymer donors.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Evaluating Methods for Measuring Grid Frequency in Low-Inertia Power Systems: Preprint

Accurate measurement of grid frequency is a critical component of reliable grid control. Traditionally, methods such as phase locked loops (PLLs) and discrete Fourier transforms (DFTs) have been used in inverters and phasor measurement units (PMUs) to measure frequency. However, as the percentage of inverter-based resources (IBRs) such as solar and wind has increased, these conventional frequency measurement methods are proving unable to guarantee reliable control in some cases. One challenge is measuring frequency during transient events, where there is a disruption in the steady state sinusoidal voltage. During these events, the underlying frequency of the grid may barely change, but measurement methods report a large spike in frequency due to the disrupted waveform. New methods must balance between suppressing spikes in frequency during faults, and providing fast, accurate, measurements in all other grid operation conditions, especially during events with high rate-of-change-of frequency (ROCOF), which are more prevalent in high-IBR power systems. This paper first surveys frequency measurement methods that have been proposed to reduce measurement errors during transient events. Then, both conventional and more novel frequency measurement methods are tested against an IEEE standard and industry recommendations, and their performance is evaluated for events simulated in PSCAD. Results quantify the trade-offs in performance during different grid conditions and lead to suggestions for the most appropriate frequency and ROCOF measurement methods for low inertia grids.

frequency↗