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At least 253 records · Page 14

Determination of Benzene, Toluene, and Xylene by means of an ion mobility spectrometer device using photoionization

The continuous monitoring of changes on the quality of ambient air is a field of advantage of ion mobility spectrometry. Benzene, Toluene, and Xylene are substances of special interest because of their toxicity. We present an optimized drift tube for ion mobility spectrometers, which uses photo-ionization tubes to produce the ions to be analyzed. The actual version of this drift tube has a length of 45 mm, an electric field strength established within the drift tube of about 180 V/cm and a shutter-opening-time of 400 mus. With the hydrogen tube used for ionisation a mean flux of 10(exp 12) photons/sq cm s was established for the experiments described. We discuss the results of investigations on Benzene, Toluene, and Xylene in normal used gasoline SUPER. The detection limits obtained with the ion mobility spectrometer developed in co-operation are in the range of 10 ppbv in this case. Normally, charge transfer from Benzene ions to Toluene takes place. Nevertheless the simultaneous determination in mixtures is possible by a data evaluation procedure developed for this case. The interferences found between Xylene and others are rather weak. The ion mobility spectra of different concentrations of gasoline SUPER are attached as an example for the resolution and the detection limit of the instrument developed. Resolution and sensitivity of the system are well demonstrated. A hand-held portable device produced just now is to be tested for special environmental analytical problems in some industrial and scientific laboratories in Germany.

Leonhardt, J. W.↗

2D Modeling of Plasma Streamer and Glow Phases at Ammonia-Air Flame Conditions

Streamer and glow plasma phases have been modeled at two thermochemical states of an ammonia-air flame: fresh reactants and burnt products. A new AMReX-based solver has been verified against benchmarks in the literature and has been used to perform these simulations. A Helmholtz-equation based photoionization model with parameters accounting for the presence of NH3 in air has been coupled with the solver to accurately model the streamer propagation phase. A detailed plasma kinetics mechanism has been compiled and used to predict the evolution of electrons, excited states, ions, and radicals during streamer propagation and glow formation. The propagation velocity of streamers was found increase by almost two-fold when the mixture was changed from the fresh reactants to the burnt products. Moreover, vibrational excitation was found to be limited to the streamer body, whereas ionization predominantly occurred at the streamer head, as is expected. Finally, the differences in the pathways of O and H radical production during the streamer propagation and glow phases have been briefly discussed.

ammonia-air flame↗

Simulation of decelerating streamers in inhomogeneous atmosphere with implications for runaway electron generation

The dynamics of positive and negative streamers is numerically simulated in atmospheric pressure air in the range of parameters corresponding to the streamer deceleration and termination in the middle of the discharge gap. A detailed comparison with experiments in air at constant and variable density demonstrates good agreement between the 2D simulation results and the observations. It is shown that positive and negative streamers behave in radically different ways when decelerating and stopping. When the head potential drops, the negative streamer transits to the mode in which the propagation is due to the forward electron drift. In this case, the radius of the ionization wave front increases, whereas the electric field at the streamer head decreases further and the streamer stops. Its head diameter continues to increase due to the slow drift of free electrons in the residual under-breakdown field. On the contrary, the only advancement mechanism for a positive streamer with a decreasing head potential is a decrease in the effective radius of the ionization wave, leading to a local increase in the electric field. This mechanism makes it possible to compensate for the reduction in the efficiency of gas photoionization at small head diameters. A qualitative 1D model is suggested to describe streamer deceleration and stopping for different discharge polarities. Estimates show that, during positive streamer stopping, the local electric field at the streamer head can exceed the threshold corresponding to the transition of electrons to the runaway mode when the head potential (relative to the surrounding space) decreases to~1.2 kV in atmospheric pressure air. In this case, pulsed generation of a beam of runaway electrons directed into the channel of a stopping positive streamer can occur. The energy of the formed pulsed electron beam depends on the intensity of photoionization in front of the streamer head. This energy can vary from 700 V (when increasing the photoionization rate by a factor of 10 with respect to the value in atmospheric pressure air) to 2.6 kV (when decreasing the photoionization rate by a factor of 1000). It is possible that this behavior of decelerating positive streamers can explain the observed bursts of x-ray radiation during the streamer propagation in long air gaps.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

True Airspeed Measurement by Ionization-Tracer Technique

Ion bundles produced in a pulse-excited corona discharge are used as tracers with a radar-like pulse transit-time measuring instrument in order to provide a measurement of airspeed that is independent of all variables except time and distance. The resulting instrumentation need not project into the air stream and, therefore, will not cause any interference in supersonic flow. The instrument was tested at Mach numbers ranging from 0.3 to 3.8. Use of the proper instrumentation and technique results in accuracy of the order of 1 percent.

Boyd, B.↗

Detection of Polar Compounds Condensed on Particulate Matter Using Capillary Electrophoresis-Mass Spectrometry

A new analytical method to aid in the understanding of the organic carbon (OC) phase of particulate matter (PM) from advanced compression ignition (ACI) operating modes, is presented. The presence of NO2 and unburned fuel aromatics in ACI emissions, and the low exhaust temperatures that result from this low temperature combustion strategy, provide the right conditions for the formation of carboxylic acids and nitroaromatic compounds. These polar compounds contribute to OC in the PM and are not typically measured using nonpolar solvent extraction methods such as the soluble organic fraction (SOF) method. The new extraction and detection method employs capillary electrophoresis with electrospray ionization mass spectrometry (CE-ESI MS) and was specifically developed to determine polar organic compounds in the ACI PM emissions. The new method identified both nitrophenols and aromatic carboxylic acids in the ACI PM. The ACI air-fuel stratification mode and NOx emissions were found to correlate with the presence and amount of the individual polar species identified.

Lewis Sr, Samuel↗

Prediction of thermal fluxes to very blunt planetary entry vehicles by the integral method.

An integral method which has previously been applied to the hypersonic blunt body thermal problem is improved and extended to obtain downstream flux predictions and to improve stagnation predictions. To account for the effect of downstream conditions propagated upstream through the subsonic shock layer region, the normal momentum equation is solved simultaneously with the other governing conservation equations. The effects of viscosity, conduction, dissociation and ionization, nongray radiation, surface emissivity, and ablation are included. Illustrative results are presented for body models of hemispheres and a continuous curvature body which closely approximates a hemispherically blunted wide angle (60 half angle) cone. The atmospheric models are air and a 50% Co2-50% N mixture at low densities, which should be representative of the Martian or Venusian atmospheres.

Burns, R. K.↗

Smoke detection in low-G fires

Fires in spacecraft are considered a credible risk. To respond to this risk, NASA flew fire detectors on Skylab and the Space Shuttle (STS) and included them in the design for International Space Station Alpha (ISSA). In previous missions (Mercury, Gemini and Apollo), the crew quarters were so cramped that it was not considered credible that the astronauts could fail to observe a fire. The Skylab nodule included approximately 20 UV fire detectors. The space shuttle has 9 ionization detectors in the mid deck and flight deck and Spacelab has six additional ionization detectors. The planned detectors for ISSA are laser-diode, forward-scattering, smoke or particulate detectors. Current plans for the ISSA call for two detectors in the open area of the module and detectors in racks that have both cooling air flow and electrical power. Due to the complete absence of data concerning the nature of particulate and radiant emission from low-g fires, all three of these detector systems were designed based upon 1-g test data. As planned mission durations and complexity increase and the volume of spacecraft increases, the need for and importance of effective, crew independent, fire detection grows significantly. This requires more knowledge concerning low-gravity fires and how they might be detected. To date, no combustion-generated particulate samples have been collected for well-developed microgravity flames. All of the extant data come from drop tower tests and therefore only correspond to the early stages of a fire. The fuel sources were restricted to laminar gas-jet diffusion flames and rapidly overheated wire insulation. These gas-jet drop tower tests indicate, through thermophoretic sampling, that soot primaries and aggregates (groups of primary particles) in micro-g may be significantly larger than those in normal-g (ng). This raises new scientific questions about soot processes as well as practical issues for particulate detection/alarm threshold levels used in on-orbit smoke detectors. Furthermore, it is widely speculated but unverified that the aggregates will grow to very large scales in a microgravity fire of longer duration than available on the ground. Preliminary tests in the 2.2 second drop tower suggest that particulate generated by overheated wire insulation will also be larger in microgravity than in normal gravity. TEM grids downstream of the fire region in the WIF experiment as well as visual observation of long string-like aggregates, further confirm this suggestion. The combined impact of these limited results and theoretical predictions is that direct knowledge of low-g combustion particulate as opposed to extrapolation from 1-g data is needed for a more confident design of smoke detectors for spacecraft.

Urban, David L.↗

Thermal Hydraulic Experimental Test Article (FY2020 Status Report)

The Thermal Hydraulic Experimental Test Article (THETA) is a facility that will be used to develop sodium components and instrumentation as well as acquire experimental data for validation of reactor thermal hydraulic and safety analysis codes. The facility will simulate nominal conditions as well as protected/unprotected loss of flow accidents in a sodium-cooled fast reactor (SFR). High fidelity distributed temperature profiles of the developed flow field will be acquired with Rayleigh backscatter based optical fiber temperature sensors. The facility is being designed in partnership with systems code experts to tailor the experiment to ensure the most relevant and highest quality data for code validation. THETA is comprised of a traditional primary and secondary system. The primary system is submerged in the pool of sodium and consists of a pump, electrically heated core, intermediate heat exchanger, and connected piping and thermal barriers (redan). The secondary system, located outside of the sodium pool, consists of a pump, sodium to air heat exchanger, and connected piping and valves. Figure 1 illustrates the main components of the primary system. THETA will be installed in the Mechanisms Engineering Test Loop (METL) with the primary system in the 28 inch Test Vessel #4, Figure 2. The design work for the facility has been completed. Since the FY19 THETA status report, the THETA primary system components have been assembled and tested using de-ionized water. Some results of this testing at select Richardson and Reynolds numbers are included herein. The custom THETA sodium flowmeter (permanent magnet submersible sodium flowmeter) has been built and calibrated using sodium in an auxiliary facility against a NIST traceable vortex shedder type flowmeter. The permanent magnet flowmeter showed excellent performance, following the theoretical equation for measured voltage quite well, with an error < 3.5% at flow rates ranging from 3-24 GPM at temperatures up to 400 °C. The secondary sodium system for heat rejection from intermediate heat exchanger has been analyzed according to ASME code. All secondary side piping, fittings and a U-stamped air-to-sodium heat exchanger have been procured.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Relativistic heavy cosmic rays

During three balloon flights of a 1 sq m sr ionization chamber/Cerenkov counter detector system, measurements were made of the atmospheric attenuation, flux, and charge composition of cosmic ray nuclei with 16 is less than or = Z is less than or = 30 and rigidity greater than 4.5 GV. The attenuation mean free path in air of VH (20 less than or = Z less than or = 30) nuclei is found to be 19.7 + or - 1.6 g/sq cm, a value somewhat greater than the best previous measurement. The attenuation mean free path of iron is found to be 15.6 + or - 2.2 g/sq cm, consistent with predictions of geometric cross-section formulae. An absolute flux of VH nuclei 10 to 20% higher than earlier experiments at similar geomagnetic cutoff and level of solar activity was measured. The relative abundances of even-charged nuclei are found to be in good agreement with results of other recent high resolution counter experiments. The observed cosmic ray chemical composition implies relative abundances at the cosmic ray source of Ca/Fe = 0.12 + or - 0.04 and S/Fe = 0.14 + or - 0.05.

Mewaldt, R. A.↗

Kinetics of hydrogen release from lunar soil

With increasing interest in a lunar base, there is a need for extensive examination of possible lunar resources. Hydrogen will be needed on a lunar base for many activities including providing fuel, making water, and serving as a reducing agent in the extraction of oxygen from its ores. Previous studies have shown the solar wind has implanted hydrogen in the lunar regolith and that hydrogen is present not only in the outer layer of soil but to considerable depths, depending on the sampling site. If this hydrogen is to be mined and used on the lunar surface, a number of questions need to be answered. How much energy must be expended in order to release the hydrogen from the soil. What temperatures must be attained, and how long must the soil be heated. This study was undertaken to provide answers to practical questions such as these. Hydrogen was determined using a Pyrolysis/GC technique in which hydrogen was released by heating the soil sample contained in a quartz tube in a resistance wire furnace, followed by separation and quantitative determination using a gas chromatograph with a helium ionization detector. Heating times and temperatures were varied, and particle separates were studied in addition to bulk soils. The typical sample size was 10 mg of lunar soil. All of the soils used were mature soils with similar hydrogen abundances. Pre-treatments with air and steam were used in an effort to find a more efficient way of releasing hydrogen.

Bustin, Roberta↗

Comparative Soot Diagnostics: Preliminary Results

The motivation for the Comparative Soot Diagnostics (CSD) experiment lies in the broad practical importance of understanding combustion generated particulate. Depending upon the circumstances, particulate matter can affect the durability and performance of combustion equipment, can be a pollutant, can be used to detect fires and, in the form of soot, can be the dominant source of radiant energy from flames. The nonbuoyant structure of most flames of practical interest makes understanding of soot processes in low gravity flames important to our ability to predict fire behavior on earth. These studies also have direct applications to fire safety in human-crew spacecraft, since smoke is the indicator used for automated detection in current spacecraft. In the earliest missions (Mercury, Gemini and Apollo), the crew quarters were so cramped that it was considered reasonable that the astronauts would rapidly detect any fire. The Skylab module, however, included approximately 20 UV-sensing fire detectors. The Space Shuttle has 9 particle-ionization smoke detectors in the mid-deck and flight deck and Spacelab has six additional particle-ionization smoke detectors. The designated detectors for the ISS are laser-diode, forward-scattering, smoke or particulate detectors. Current plans for the ISS call for two detectors in the open area of the module, and detectors in racks that have both cooling air flow and electrical power. Due to the complete absence of data concerning the nature of particulate and radiant emission from incipient and fully developed low-g fires, all three of these detector systems were designed based upon l-g test data and experience. As planned mission durations and complexity increase and the volume of spacecraft increases, the need for and importance of effective, crew-independent, fire detection grows significantly. To provide this level of protection, more knowledge is needed concerning low-gravity fire phenomena and, in particular, how they might be detected and suppressed. Prior to CSD, no combustion-generated particulate samples had been collected near the flame zone for well-developed microgravity flames. All of the extant data either came from drop tower tests and therefore only corresponded to the early stages of a fire or were collected far from the flame zone. The fuel sources in the drop tower tests were restricted to laminar gas-jet diffusion flames and very rapidly overheated wire insulation. The gas-jet tests indicated, through thermophoretic sampling, (2) that soot primaries and aggregates (groups of primary particles) in low-gravity may be significantly larger than those in normal gravity (1-g). This raises new scientific questions about soot processes as well as practical issues for particulate size sensitivity and detection alarm threshold levels used in on-orbit smoke detectors. Preliminary tests in the 2.2 second drop tower suggest that particulate generated by overheated wire insulation may be larger in low-g than in 1-g. Transmission Electron Microscope (TEM) grids downstream of the fire region in the Wire Insulation Flammability experiment as well as visual observation of long string-like aggregates, further confirm this suggestion. The combined impact of these limited results and theoretical predictions is that, as opposed to extrapolation from l-g data, direct knowledge of low-g combustion particulate is needed for more confident design of smoke detectors for spacecraft. This paper describes the operation and preliminary results of the CSD, a project conceived and developed at NASA Lewis Research Center. The CSD flight experiment was conducted in the Middeck Glovebox Facility (MGBX) on USMP-3. The project is support by NASA Headquarters Microgravity Science and Applications Division and Code Q. The results presented here are from the microgravity portion of the experiment, including the temporal response of the detectors and average sizes of the primary and aggregate particles captured on the thermophoretic probes.

Urban, David L.↗

Decoupled predictions of radiative heating in air using a particle simulation method

A particle simulation technique with decoupled radiation is used to estimate the radiative emission along the stagnation streamline and the radiative heating at the stagnation point of a blunt-nosed vehicle entering the earth's atmosphere at hypersonic speed. The direct simulation Monte Carlo (DSMC) method is used to compute the fluid mechanics of the weakly ionized flow. The radiative emission is computed using the NEQAIR computer code with the radiation decoupled from the flowfield solution. It is concluded that the new models make it possible to decrease the predicted total radiative heating at the stagnation point of the vehicle by a factor of 15. A comparison of the DSMC approach with a continuum flow model shows that the total predicted radiative heating estimates agree within a factor of 2.

Boyd, Iain D.↗

Comparative Soot Diagnostics Experiment Looks at the Smoky World of Microgravity Combustion

From an economic standpoint, soot is one of the most important combustion intermediates and products. It is a major industrial product and is the dominant medium for radiant heat transport in most flames used to generate heat and power. The nonbuoyant structure of most flames of practical interest (turbulent flames) makes the understanding of soot processes in microgravity flames important to our ability to predict fire behavior on Earth. In addition, fires in spacecraft are considered a credible possibility. To respond to this risk, NASA has flown fire (or smoke) detectors on Skylab and the space shuttles and included them in the International Space Station design. The design of these detectors, however, was based entirely on normal gravity (1g) data. The detector used in the shuttle fleet is an ionization detector, whereas the system planned for the space station uses forward scattering of near-infrared light. The ionization detector, which is similar to smoke detectors used in homes, has a comparative advantage for submicron particulates. In fact, the space shuttle model uses a separation system that makes it blind to particles larger than a micron (believed to be dust). In the larger size range, the lightscattering detector is most sensitive. Without microgravity smoke data, the difference in the particle size sensitivities of the two detectors cannot be evaluated. As part of the Comparative Soot Diagnostics (CSD) experiment, these systems were tested to determine their response to particulates generated during long periods of low gravity. This experiment provided the first such measurements toward understanding soot processes on Earth and for designing and implementing improved spacecraft smoke detection systems. The objectives of CSD were to examine how particulates form from a variety of sources and to quantify the performance of several diagnostic techniques. The sources tested included four overheated materials (paper, silicone rubber, Teflon-coated (DuPont) wire, and Kapton-coated (DuPont) wires), each tested at three heating rates, and a candle tested at three air velocities. Paper, silicone rubber, and wire insulation, materials found in spacecraft crew cabins, were selected because of their different smoke properties. The candle yielded hydrocarbon soot typical of many 1g flames. Four diagnostic techniques were employed: thermophoretic sampling collected particulates for size analysis; laser light extinction measurements near the source tallied total particulate production; and laser light scattering and ionization detector measurements far from the particulate source provided data for evaluating the performance of smoke detection systems for these particulate sources.

Urban, David L.↗

Laser Lightcraft Performance

The purpose of this study is to establish the technical ground for modeling the physics of laser powered pulse detonation phenomenon. The principle of the laser power propulsion is that when high-powered laser is focused at a small area near the surface of a thruster, the intense energy causes the electrical breakdown of the working fluid (e.g. air) and forming high speed plasma (known as the inverse Bremsstrahlung, IB, effect). The intense heat and high pressure created in the plasma consequently causes the surrounding to heat up and expand until the thrust producing shock waves are formed. This complex process of gas ionization, increase in radiation absorption and the forming of plasma and shock waves will be investigated in the development of the present numerical model. In the first phase of this study, laser light focusing, radiation absorption and shock wave propagation over the entire pulsed cycle are modeled. The model geometry and test conditions of known benchmark experiments such as those in Myrabo's experiment will be employed in the numerical model validation simulations. The calculated performance data will be compared to the test data.

Chen, Yen-Sen↗

Enhanced Low Dose Rate Effects in Bipolar Circuits: A New Hardness Assurance Problem for NASA

Many bipolar integrated circuits are much more susceptible to ionizing radiation at low dose rates than they are at high dose rates typically used for radiation parts testing. Since the low dose rate is equivalent to that seen in space, the standard lab test no longer can be considered conservative and has caused the Air Force to issue an alert. Although a reliable radiation hardness assurance test has not yet been designed, possible mechanisms for low dose rate enhancement and hardness assurance tests are discussed.

bipolar integrated circuits↗

Interactions between atmospheric pressure plasmas and metallic catalyst particles in packed bed reactors

Atmospheric-pressure plasmas sustained in packed bed reactors (PBRs) are being investigated for chemical conversion of gases and pollution control. Metallic catalysts added to the surfaces of the dielectric beads of PBRs can increase the energy efficiency and selectivity of chemical processes by reducing operating temperature and providing additional reaction pathways. In this paper, results from a computational investigation of plasma surface interactions between micron-scale metallic catalysts and humid-air plasmas in PBRs are discussed. Here we found that high plasma density regions form in the proximity of the metallic catalysts. These higher-density plasma regions were confirmed experimentally using ICCD imaging. The intense plasmas result from geometrical electric field enhancement and redistribution of charges within the conductive particles, leading to further enhancement. The high electric field at the triple points of the catalysts can produce electric field emission of electrons, which provides a pre-ionization source or additional source of electrons. These regions of high electric field and sources of electrons guide discharges towards the catalysts and increases fluxes of excited species, ions, electrons and photons to their surfaces. These fluxes are focused primarily at the triple points between the metal, dielectric and gas. As a result, the catalyst is locally heated, which could lead to further increased rates of thermocatalytic reactions on the surface. Surface roughness of the metal inclusions can lead to additional electric field enhancement, which changes the character of the discharges in the vicinity of the catalysts while reducing breakdown voltage.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Comparison of the energy response of an ionization spectrometer for pions and protons

An ionization spectrometer consisting of a sandwich of iron absorbers and plastic scintillation counters was used to measure the energy of pions and protons in the interval 10 to 1000 GeV. For the limited energy interval of 10 to 40 GeV, pions and protons were identified by an air cerenkov counter. Interactions in carbon were studied in a multiplate cloud chamber placed between the cerenkov counter and the spectrometer. Knowledge of these interactions were used in conjunction with a Monte Carlo simulation of the cascade process to study differences in the response of the spectrometer to pions and protons.

Jones, W. V.↗

Eleven-Species Thermochemical Model Of Air

SPECIES program computes thermodynamic and transport properties and equilibrium constants. Uses least-squares polynomial curve fits of most accurate data available to provide requested values more quickly than table-lookup methods. Subroutines computing transport coefficients and collision cross sections include additional code to correct for any electron pressure when working with ionic species. Species represented: diatomic nitrogen, diatomic oxygen, atomic nitrogen, atomic oxygen, nitric oxide, ionized nitric oxide, free electron, ionized atomic nitrogen, ionized atomic oxygen, ionized diatomic nitrogen, and ionized diatomic oxygen. Written in FORTRAN 77.

Thompson, Richard A.↗