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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Activity-based protein profiling of chitin catabolism

Microbial catabolism of chitin, a highly abundant component of polymeric organic matter worldwide, is a fundamental cog in the carbon and nitrogen cycles that govern CO2 emissions, nutrient dynamics in aquatic systems, and soil vitality. Despite this critical biogeochemical function, we have a poor understanding of the synergy between various microbial chitinases and key accessory enzymes involved in chitin catabolism. We designed and synthesized activity-based probes (ABPs) for profiling active chitinolytic enzymes by modifying the chitin derivatives N-acetyl glucosamine and chitotriose. The ABPs were used to determine the active complement of chitinolytic enzymes produced over time by the soil bacterium Cellvibrio japonicus treated with various C substrates. This approach allowed us to demonstrate the utility of these ABPs in determining the intricate synergy between chitinases and other glycoside hydrolases that microbes employ to catabolize chitin. The strategy can be used to gain molecular level insights that can be used to better understand microbial roles in soil C and N cycling in the face of a changing climate.

Zegeye, Elias↗
DOE OSTI2020

Wet Cooling Tower Cooling System Spreadsheet Model for sCO2

The attached cost and performance spreadsheet model is for a wet cooling tower system, one of four cooling system models developed for use in optimizing indirectly-heated supercritical CO2 (sCO2) power cycles. Running the model requires that the user has REFPROP version 9 or below installed, as well as the Microsoft Excel REFPROP Add-In. Upon opening, use Excel’s Edit Links feature to link to the user’s installed REFPROP.xla or REFPROP.xlam file. For the spreadsheet model compatible with REFPROP version 10 and above, contact Nathan Weiland at nathan.weiland@netl.doe.gov. Technical documentation for the model can be found here: https://www.netl.doe.gov/energy-analysis/details?id=3199.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2020

Indirect Dry Cooling System Spreadsheet Model for sCO2

The attached cost and performance spreadsheet model is for an indirect dry cooling system, one of four cooling system models developed for use in optimizing indirectly-heated supercritical CO2 (sCO2) power cycles. Running the model requires that the user has REFPROP version 9 or below installed, as well as the Microsoft Excel REFPROP Add-In. Upon opening, use Excel’s Edit Links feature to link to the user’s installed REFPROP.xla or REFPROP.xlam file. For the spreadsheet model compatible with REFPROP version 10 and above, contact Nathan Weiland at nathan.weiland@netl.doe.gov. Technical documentation for the model can be found here: https://www.netl.doe.gov/energy-analysis/details?id=3199.

30 DIRECT ENERGY CONVERSION↗
NASA NTRS2000

Spring and Summer Changes at the South Pole as Seen by the Mars Orbiter Camera

The Mars Orbiter Camera (MOC) on the Mars Global Surveyor (MGS) spacecraft has been able to follow individual features as the CO2 frost disappears and exposes the material underneath. Because the orbit of MGS is inclined at an angle of 93 degrees relative to the equator, the spacecraft gets especially good coverage of the ring at 87 degrees latitude. The following is a list of phenomena that have been seen during the spring and summer at the South Pole: (1) Circular depressions that are approximately ten meters deep and hundreds of meters in diameter. They are found only within the residual polar cap, the part that survives the summer. The high areas between the depressions are flat-topped mesas whose sides are concave circular arcs. In some places the depressions form patterns that exhibit north-south symmetry, suggesting some control by sunlight; (2) Dark layers that are exposed on the walls of the mesas. Each layer is at most a few meters thick. The dark layers might accumulate during climatic episodes of high atmospheric dust content, or they might accumulate during the annual cycling of dusty CO2; (3) Albedo differences that develop during the summer within the residual cap. These include subtle darkening of the floors of the depressions relative to the mesas and occasional major darkening of the floors, especially near the edge of the cap. The floors and mesas form a distinct stratum, suggesting they represent a distinct compositional boundary. For instance the floors may be water and the mesas may be CO2; (4) Small dark features that appear in spring on the seasonal frost outside the residual cap. Some of the features have parallel tails that are clearly shaped by the wind. Others are more symmetric, like dark snowflakes, with multiple branching arms. After the CO2 frost has disappeared the arms are seen as troughs and the centers as topographic lows; (5) Polygons whose sides are dark troughs. Those that are outside the residual cap seem to disappear when the frost disappears. The polygons and the dark snowflakelike structures may be related, and suggest that CO2 frost may form cohesive slabs; (6) Irregular depressions outside the residual cap. They look like degraded versions of the circular depressions inside the residual cap, and may be a remnant of the cap's changing location; and (7) Areas of burial and exhumation of circular depressions. Thomas et al. give an example with a sharp boundary: On one side the depressions are buried and on the other side they are exposed. In other cases there are rounded troughs up to one kilometer wide, which are dark in summer and appear to have eroded down below the floor of the circular depressions.

Ingersoll, A. P.↗
DOE OSTI2023

Performance and Cost Potential for Direct-Fired Supercritical CO2 Natural Gas Power Plants

Direct-fired supercritical CO2 (sCO2) power cycles are being explored as an attractive alternative to natural gas combined cycle (NGCC) plants with carbon capture and storage (CCS). Therefore, understanding their performance and cost potential is important for the commercialization of the technology. This study presents the techno-economic optimization results of natural gas-fired, utility-scale power plants based on the direct sCO2 power cycle, which are lacking in public literature. To identify the optimum plant configuration, the study considered multiple cases with varying levels of thermal integration with the plant air separation unit (ASU). Several design variables for each power cycle configuration were identified and optimized to minimize the levelized cost of electricity (LCOE) for each case. The optimization design variables include the sCO2 cooler outlet temperatures, recuperator approach temperatures, and pressure drops. High fidelity models for recuperators, coolers, and turbines were developed and used to capture the impact of design variables on plant efficiency and capital costs. The optimization was conducted using a combination of manual sensitivity analyses and automated derivative-free optimization algorithms available under NETL’s Framework for Optimization and Quantification of Uncertainty and Sensitivity platform. The optimized direct sCO2 power plants offered similar or slightly higher plant efficiencies than the reference NGCC plants based on the F-class gas turbine with CCS. The LCOE of the optimized direct sCO2 plants is 13 to 17% higher than the reference NGCC plants with CCS due to high capital costs associated with the ASU and sCO2 power block, though there is significant room for improvement due to the high uncertainty in component capital costs for these new plants. Recuperators make up over 50% of the sCO2 power block costs. Consequently, any research and development efforts to reduce the recuperator capital costs will benefit the technology’s commercialization. The study also presents preliminary results showing the impact of co-firing landfill gas and natural gas on plant efficiency, LCOE, and CO2 emissions.

Pidaparti, Sandeep↗
DOE OSTI2023

Performance and Cost Potential for Direct-Fired Supercritical CO2 Natural Gas Power Plants

Direct-fired supercritical CO2 (sCO2) power cycles are being explored as an attractive alternative to natural gas combined cycle (NGCC) plants with carbon capture and storage (CCS). Therefore, understanding their performance and cost potential is important for the commercialization of the technology. This study presents the techno-economic optimization results of natural gas-fired, utility-scale power plants based on the direct sCO2 power cycle, which are lacking in public literature. To identify the optimum plant configuration, the study considered multiple cases with varying levels of thermal integration with the plant air separation unit (ASU). Several design variables for each power cycle configuration were identified and optimized to minimize the levelized cost of electricity (LCOE) for each case. The optimization design variables include the sCO2 cooler outlet temperatures, recuperator approach temperatures, and pressure drops. High fidelity models for recuperators, coolers, and turbines were developed and used to capture the impact of design variables on plant efficiency and capital costs. The optimization was conducted using a combination of manual sensitivity analyses and automated derivative-free optimization algorithms available under NETL’s Framework for Optimization and Quantification of Uncertainty and Sensitivity platform. The optimized direct sCO2 power plants offered similar or slightly higher plant efficiencies than the reference NGCC plants based on the F-class gas turbine with CCS. The LCOE of the optimized direct sCO2 plants is 13 to 17% higher than the reference NGCC plants with CCS due to high capital costs associated with the ASU and sCO2 power block, though there is significant room for improvement due to the high uncertainty in component capital costs for these new plants. Recuperators make up over 50% of the sCO2 power block costs. Consequently, any research and development efforts to reduce the recuperator capital costs will benefit the technology’s commercialization. The study also presents preliminary results showing the impact of co-firing landfill gas and natural gas on plant efficiency, LCOE, and CO2 emissions.

Pidaparti, Sandeep↗
DOE OSTI2024

Numerical Investigation of High Delta T Sensible Storage Integrated CO2 Heat Pump: Preprint

To assist building heating electrification, this paper numerically investigates a load flexible heat pump system for commercial buildings. The system consists of a CO2 vapor compression cycle, a sensible thermal storage tank, and an air handling unit. The thermal storage medium is inexpensive, non-toxic and stable anti-freeze solution (30% potassium acetate). The air handing unit has an indoor coil and a ventilation coil. The system can be used to manage building electric load. During peak hours, the heat pump is off and the hot solution water is discharged from the tank to heat up the indoor air and ventilation air. During the hour of charge, the heat pump delivers hot solution water to the tank and to the air. The tank can also stand by while the heat pump provides space heating directly. We selected a medium sized office building located in Minnesota as the representative building and used EnergyPlus to obtain its 24 hour load data. We designed three storage tank volumes assuming 50 degrees C, 65 degrees C and 80 degrees C tank temperatures to independently provide the building load for 4 hours in the morning. The higher the tank temperature, the smaller the required volume, and thus higher energy density. The effective energy density is 78 with an 80 degrees C tank, and 40 kWhth/m3 with 50 degrees C. We simulated the tank integrated heat pump performance subjected to the 24-hour building load profile and ambient data. The baseline is the same system without storage tank. There was a trade-off between the storage energy density and the charging COP. The charge hour COP was 2.77 to charge the tank to 80 degrees C, and 3.01 to 50 degrees C. The proposed system could shift building load from the peak hours (8:00 - 12:00) to off-business hour (23:00 - 7:00+1). It eliminated 100% compressor electricity use during the peak hours, and avoided a peak electric power of 34 kW. The 65 degrees C tank saved 9.5 kWhe (4%) considering all day operation, which was the best balance between energy density and the system operation efficiency among the three options.

CO2 heat pump↗
DOE OSTI2023

Compatibility of Wrought Superalloys with Supercritical CO2

Supercritical CO2 (sCO2) power cycles, particularly direct-fired cycles, have the possibility of revolutionizing clean fossil energy with peak temperatures above 700 °C and wrought precipitation strengthened alloys like Haynes 282™ for structural components. At temperatures <650 °C, it would be desirable to use less expensive alloys, however, steels are known to be susceptible to carburization. Laboratory 300 bar sCO2 autoclave results were collected on a range of alloys including less expensive Ni-based alloys like 825 compared to advanced austenitic steels like alloy 709 at 600 °C. Both alloys 825 and 709 formed thin, protective Cr-rich oxides after 1,000 h. Alloy 825 also was exposed for 1,000 h in sCO2 at 800 °C and compared to a range of Ni-based alloys. Comparing alloys 625, 825, and 282, the mass gain increased with increasing alloy Ti content under these conditions. High Al superalloys did not perform significantly better under these conditions at 800 °C.

Pint, Bruce↗
DOE OSTI2023

Manufacturing and Hydro Testing of a 10 MWe sCO2 Axial Turbine

Abstract Supercritical CO2 (sCO2) power cycles designed for thermodynamic efficiencies above 50% push component designs into pressure and temperature combinations that approach the limits of American Society of Mechanical Engineers (ASME) Boiler and Pressure Vessel Code and ASME Piping Design Codes with Turbine inlet conditions near 250 bar and 715 °C. These design conditions which limit available materials to high nickel alloys are compounded by the high fluid densities of sCO2 at these conditions which result in very compact machinery at the 10 MWe class which are currently being developed for the DOE supercritical transformational electric power (STEP) program. Design of the STEP Turbine is complete with integrated lessons learned from a previous 1 MWth subscale demonstration of a high temperature 10 MWe Turbine designed under the DOE SunShot Program. Fabrication of the STEP Turbine is nearing completion with all housings and pressure containing components in hand. This paper provides a detailed look at design intentions and limitations for the pressurized sections of the main pressure casing and the fabrication of key turbine components. Additional discussion is provided regarding postfabrication inspection and acceptance of the casing for use after issues with casing welds were identified late in the fabrication process.

Engineering↗
DOE OSTI2022

Creep and Fatigue Characterization of High Strength Alloy Thin Sections in Advanced CO2 Heat Exchangers

The objective of this work was to characterize and model elevated temperature creep and fatigue behavior for thin sheet and foil forms of gamma-prime strengthened alloys in wrought form and as-processed folded and brazed constructions. This work was motivated by the demanding temperature and pressure service conditions of the GEN3 Concentrated Solar Power (CSP) and supercritical CO2 (sCO2) power cycle working fluid. More specifically, the possibility of leveraging the superior creep strength of gamma-prime alloys in folded-fin and brazed-plate heat exchanger constructions. Gamma-prime alloys represent a step-change in raw-material strength over solid-solution strengthened alloys. And the folded-fin and brazed-plate heat exchanger architecture is lightweight and leverages cost-effective material stock forms. The investigation contained two parallel paths. (1) The first is referred to as a fundamental investigation where Oak Ridge National Laboratory conducts uniaxial creep testing on thin sheet and foil in wrought form. This effort aimed to serve as a benchmark against a relatively sparse existing database and a baseline comparison for path number 2. (2) The second path is referred to as the practical investigation where Brayton Energy manufactures plate-fin heat exchangers and performs pressurized creep and fatigue testing. This effort aimed to de-risk heat exchanger manufacturing process for service under sCO2 CSP conditions. A total of 14 uniaxial creep tests were completed using Haynes 282 thin sheet and foil. A variety of heat treatments were specified to coincide with path number 2. Baseline metallography of test samples and creep strength performance are contained. Benchmarks relatively to existing thick-form Haynes 282 are made, as well as to other thin-form Nickel-based superalloys. Description of a wrought-form modeling approach for thin gamma-prime alloys is also discussed. A total of 11 pressurized creep and fatigue tests were completed successfully with Haynes 282 heat exchanger prototypes. Manufacturing processing details, testing details, testing results, and failure analysis are discussed. Additionally, creep modeling techniques to predict failure are discussed, and modeling to support technological-to-market. In conclusion, Haynes 282 foils were demonstrated to yield rupture two-to-three orders of magnitude higher than Haynes 230 foils under similar conditions. And the manufactured heat exchanger prototypes demonstrated strength similar to the wrought constituents. Both of which contribute to elevated performance potential or cost savings in practice. Discussion is included.

14 SOLAR ENERGY↗
DOE OSTI2023

Assessing carbon storage capacity and saturation across six central US grasslands using data–model integration

Abstract. Future global changes will impact carbon (C) fluxes and pools in most terrestrial ecosystems and the feedback of terrestrial carbon cycling to atmospheric CO2. Determining the vulnerability of C in ecosystems to future environmental change is thus vital for targeted land management and policy. The C capacity of an ecosystem is a function of its C inputs (e.g., net primary productivity – NPP) and how long C remains in the system before being respired back to the atmosphere. The proportion of C capacity currently stored by an ecosystem (i.e., its C saturation) provides information about the potential for long-term C pools to be altered by environmental and land management regimes. We estimated C capacity, C saturation, NPP, and ecosystem C residence time in six US grasslands spanning temperature and precipitation gradients by integrating high temporal resolution C pool and flux data with a process-based C model. As expected, NPP across grasslands was strongly correlated with mean annual precipitation (MAP), yet C residence time was not related to MAP or mean annual temperature (MAT). We link soil temperature, soil moisture, and inherent C turnover rates (potentially due to microbial function and tissue quality) as determinants of carbon residence time. Overall, we found that intermediates between extremes in moisture and temperature had low C saturation, indicating that C in these grasslands may trend upwards and be buffered against global change impacts. Hot and dry grasslands had greatest C saturation due to both small C inputs through NPP and high C turnover rates during soil moisture conditions favorable for microbial activity. Additionally, leaching of soil C during monsoon events may lead to C loss. C saturation was also high in tallgrass prairie due to frequent fire that reduced inputs of aboveground plant material. Accordingly, we suggest that both hot, dry ecosystems and those frequently disturbed should be subject to careful land management and policy decisions to prevent losses of C stored in these systems.

58 GEOSCIENCES↗
NASA NTRS1987

Climatic consequences of anthropogenic vegetation changes from 1880-1980

The changes in the surface albedo associated with land-use alterations from 1880-1980 and the climatic implications of these changes are discussed. Changes in atmospheric CO2, the hydrologic cycle, atmospheric particulates and aerosols are reviewed. A global survey of the growth of agriculture and forestry data is presented. The anthopogenic vegetation changes in western Africa are examined in detail. Maps and tables of anthopogenic vegetation and albedo changes are presented for western Africa, South America, and worldwide. It is found that the mean regional albedo increased from 17.4 in 1880 to 17.8 in 1980. No apparent secular decrease in precipitation linked to vegetation clearing is observed. It is suggested that disruption of the hydrologic cycle as a result of devegetation may have led to reductions in soil moisture.

Gornitz, Vivien↗
NASA NTRS1990

Potential technology transfers of research on low-temperature carbon monoxide-oxygen recombination catalysts

Results from research on catalytic recombination of CO-O2 for stable closed-cycle operation of CO2 lasers hold much promise for a variety of technology transfer. Expansion of CO2 laser remote sensing applications toward chemical detection and pollution monitoring would certainly be expected. However, the catalysts themselves may be especially effective in low-temperature oxidation of a number of chemicals in addition to CO. It is therefore of interest to compare the CO-O2 catalysts with chemical systems designed for chemical sensing, air purification and process catalysis. Success in understanding the catalytic mechanisms of the recombination of CO-O2 could help to shed light on how catalyst systems operate. New directions in low-temperature oxidation catalysts, coatings for chemical sensors and sorbents for air purification could well emerge.

Poziomek, Edward J.↗
NASA NTRS2000

The State and Future of Mars Polar Science and Exploration

As the planet's principal cold traps, the martian polar regions have accumulated extensive mantles of ice and dust that cover individual areas of approx. 10(exp 6)sq km and total as much as 3-4 km thick. From the scarcity of superposed craters on their surface, these layered deposits are thought to he comparatively young-preserving a record of the seasonal and climatic cycling of atmospheric CO2, H2O, and dust over the past approx. 10(exp 5)-10(exp 8) years. For this reason, the martian polar deposits may serve as a Rosetta Stone for understanding the geologic and climatic history of the planet-documenting variations in insolation (due to quasiperiodic oscillations in the planet's obliquity and orbital elements), volatile mass balance, atmospheric composition, dust storm activity, volcanic eruptions, large impacts, catastrophic floods, solar luminosity, supernovae, and perhaps even a record of microbial life. Beyond their scientific value, the polar regions may soon prove important for another reason-providing a valuable and accessible reservoir of water to support the long-term human exploration of Mars. In this paper we assess the current state of Mars polar research, identify the key questions that motivate the exploration of the polar regions, discuss the extent to which current missions will address these questions, and speculate about what additional capabilities and investigations may be required to address the issues that remain outstanding.

Clifford, Stephen M.↗
NASA NTRS2015

V-SUIT Model Validation Using PLSS 1.0 Test Results

The dynamic portable life support system (PLSS) simulation software Virtual Space Suit (V-SUIT) has been under development at the Technische Universitat Munchen since 2011 as a spin-off from the Virtual Habitat (V-HAB) project. The MATLAB(trademark)-based V-SUIT simulates space suit portable life support systems and their interaction with a detailed and also dynamic human model, as well as the dynamic external environment of a space suit moving on a planetary surface. To demonstrate the feasibility of a large, system level simulation like V-SUIT, a model of NASA's PLSS 1.0 prototype was created. This prototype was run through an extensive series of tests in 2011. Since the test setup was heavily instrumented, it produced a wealth of data making it ideal for model validation. The implemented model includes all components of the PLSS in both the ventilation and thermal loops. The major components are modeled in greater detail, while smaller and ancillary components are low fidelity black box models. The major components include the Rapid Cycle Amine (RCA) CO2 removal system, the Primary and Secondary Oxygen Assembly (POS/SOA), the Pressure Garment System Volume Simulator (PGSVS), the Human Metabolic Simulator (HMS), the heat exchanger between the ventilation and thermal loops, the Space Suit Water Membrane Evaporator (SWME) and finally the Liquid Cooling Garment Simulator (LCGS). Using the created model, dynamic simulations were performed using same test points also used during PLSS 1.0 testing. The results of the simulation were then compared to the test data with special focus on absolute values during the steady state phases and dynamic behavior during the transition between test points. Quantified simulation results are presented that demonstrate which areas of the V-SUIT model are in need of further refinement and those that are sufficiently close to the test results. Finally, lessons learned from the modelling and validation process are given in combination with implications for the future development of other PLSS models in V-SUIT.

Olthoff, Claas↗
NASA NTRS2017

The Modern Near-Surface Martian Climate: A Review of In-Situ Meteorological Data from Viking to Curiosity

We analyze the complete set of in-situ meteorological data obtained from the Viking landers in the 1970s to todays Curiosity rover to review our understanding of the modern near-surface climate of Mars, with focus on the dust, CO2 and H2O cycles and their impact on the radiative and thermodynamic conditions near the surface. In particular, we provide values of the highest confidence possible for atmospheric opacity, atmospheric pressure, near-surface air temperature, ground temperature, near-surface wind speed and direction, and near-surface air relative humidity and water vapor content. Then, we study the diurnal, seasonal and interannual variability of these quantities over a span of more than twenty Martian years. Finally, we propose measurements to improve our understanding of the Martian dust and H2O cycles, and discuss the potential for liquid water formation under Mars present day conditions and its implications for future Mars missions.

Martinez, G. M.↗