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DOE OSTI2020

Experimental Investigation of Polymer Induced Fouling of Heater Tubes in the First-ever Polymer Flood Pilot on Alaska North Slope

Polymer flooding has been validated in the lab and by successful applications in other countries, such as Canada and China, to be an effective EOR technique for heavy oil reservoirs. Currently, polymer flooding is being pilot tested for the first time in the Schrader Bluff viscous oil reservoir at Milne Point field on Alaska North Slope (ANS). One of the major concerns of the operator is the impact of polymer on the oil production system after polymer breakthrough, especially the polymer induced fouling issues in the heat exchanger. This study investigates the propensity of polymer fouling on the heater tubes as a function of different variables, with the ultimate goal of determining safe and efficient operating conditions. A unique experimental set-up was indigenously designed and developed to simulate the fouling process on the heating tube. The influence of heating tube skin temperature, tube material, and polymer concentration on fouling tendency was investigated. Under each test condition, the test was run five times with the same tube, and in each run, the freshly prepared synthetic brine and polymer solution were heated from 77°F to 122°F to mimic field operating conditions. The heating time and fouling amount were recorded for each run. The morphology and composition of the deposit samples were analyzed by environmental scanning electron microscopy (ESEM) and X-ray diffraction (XRD), respectively. It has been found that, in general, the presence of polymer in produced fluids would aggravate the fouling issues on both carbon steel and stainless steel surfaces at all tested skin temperatures (165°F, 250 °F and 350°F), but only higher skin temperatures of 250°F and 350°F could cause polymer induced fouling issues on the copper tube surface and the fouling tendency increased with polymer concentration. At the lower skin temperatures of 165°F, no polymer-induced fouling was identified on the copper tube. A critical temperature that is related to the cloud point of the polymer solution was believed to exist, below which polymer induced fouling would not occur and only mineral scale deposited, but above which the polymer would obviously aggravate the fouling issue. The heating efficiency of the tube would be reduced gradually as more fouling material accumulates on its surface. The ESEM results indicate that if polymer precipitated and deposited on the surface, it would bond to the mineral crystals to form a stronger three- dimensional network structure, and that is why the polymer induced fouling was tougher and more difficult to be removed from the tube surface. The XRD analysis results confirm that the presence of polymer in the fluids can enhance the mineral scale propensity. Overall, the study results have provided practical guidance to the field operator for the ongoing polymer flooding pilot test on ANS. This study may also prove to be valuable for other chemical EOR projects around the world.

Alaska North Slope↗

DOE OSTI2024

Reservoir Simulations and Accuracy Measures for CO 2 and Pressure Plumes for the Broom Creek Formation in Central North Dakota

Conference paper presented at 17th International Conference on Greenhouse Gas Control Technologies (GHGT-17), Calgary, Alberta, Canada, October 20–24, 2024. This study estimated the accuracy of the predicted 5-year carbon dioxide (CO 2 ) and pressure plumes for a hypothetical geological storage project injecting CO 2 into the Broom Creek Formation near central North Dakota.

01 COAL, LIGNITE, AND PEAT↗

DOE OSTI2024

Utilizing 3D Mechanical Earth Models for Calibration and Validation in a Large-Scale Carbon Capture and Storage Project in North Dakota

Conference paper presented at 17th International Conference on Greenhouse Gas Control Technologies (GHGT-17), Calgary, Alberta, Canada, October 20–24, 2024. Three-dimensional (3D) mechanical earth models (MEMs) are pivotal in assessing geological sites for carbon dioxide (CO 2 ) storage and mitigating potential risks associated with storage and injection. The Energy & Environmental Research Center is exploring innovative carbon storage monitoring techniques at a CO 2 storage site near Beulah, North Dakota. These methods aim to provide lower-impact, faster feedback for commercial carbon capture and storage (CCS) projects. The research includes monitoring CO 2 injection using various approaches: 1) an automated, integrated modular monitoring station; 2) time-lapse electromagnetic (EM) field surveys; 3) drone-based surveillance; 4) time-lapse seismic techniques; and 5) advanced wellbore monitoring.

02 PETROLEUM↗

DOE OSTI2024

Potential for Combined Heat and Power with Carbon Capture and Storage at U.S. Ethanol Facilities

Conference paper presented at 17th International Conference on Greenhouse Gas Control Technologies (GHGT-17), Calgary, Alberta, Canada, October 20–24, 2024. Economic conditions in the United States have positioned ethanol producers as early adopters of industrial CO 2 capture and storage (CCS) from fermentation processes, creating an opportunity to further reduce emissions. Replacing fossil fired energy with biogenic combined heat and power (CHP) coupled with CCS could enable ethanol production to achieve net negative CO 2 emissions, with gasification based CHP better matching ethanol facilities’ heat and power needs than combustion based systems. Pilot scale testing showed that while 100% biomass gasification increased tar formation, cofeeding corn stover with coal and optimizing gasifier configurations offered promising pathways to reduce tar and improve operational performance.

09 BIOMASS FUELS↗

DOE OSTI2024

PCOR Partnership: A Catalyst for Commercial CCUS Deployment

Conference paper presented at 17th International Conference on Greenhouse Gas Control Technologies (GHGT-17), Calgary, Alberta, Canada, October 20–24, 2024. This paper presents an overview of the Plains CO 2 Reduction (PCOR) Partnership Initiative and the current commercial carbon capture, utilization, and storage (CCUS) activity in the region, discusses challenges facing CCUS in the region, and highlights important challenges that have recently been overcome to enable CCUS deployment in the region.

01 COAL, LIGNITE, AND PEAT↗

DOE OSTI2024

Quantifying the Potential Atmospheric Leakage Risks Associated With the Geologic Storage of CO 2 in Saline Aquifers for Use in Voluntary Carbon Market Buffer Account Determination

Conference paper presented at 17th International Conference on Greenhouse Gas Control Technologies (GHGT-17), Calgary, Alberta, Canada, October 20–24, 2024. This paper presents the results of a detailed study into the potential atmospheric leakage risks associated with the geologic storage of CO 2 in saline aquifers. This study included a detailed literature review, a re-creation of existing CO 2 leakage models put forth by other authors and, lastly, the development of an enhanced model that can be utilized for assessing the potential losses to the atmosphere of stored CO 2 across a variety of potential project parameters. The results of this study indicate that, across broad ranges of input parameters for mechanisms that have the potential for CO 2 loss from the storage complex to the atmosphere, there is an extremely low risk of CO 2 leakage to the atmosphere, with the median leakage risk estimated to be 0.1% of total injected CO 2 . The risk of leakage from real-world storage projects is likely to be even lower than those estimated through this study.

01 COAL, LIGNITE, AND PEAT↗

DOE OSTI2024

Demonstration of Plume Stability for Carbon Storage Projects

Conference paper presented at 17th International Conference on Greenhouse Gas Control Technologies (GHGT-17), Calgary, Alberta, Canada, October 20–24, 2024. A technical approach has been developed to demonstrate CO 2 plume stabilization: 1) construct a geologic model, 2) perform numerical simulations, and 3) estimate the rate of change in circumferential area of the CO 2 plume with respect to time (dA/dt). Demonstration of the technical approach for plume stabilization is presented using a North Dakota case study.

01 COAL, LIGNITE, AND PEAT↗

DOE OSTI2020

XXVIIth International Conference on Supersymmetry and Unification of Fundamental Interactions (SUSY 2019) (Final Report)

Supersymmetry (SUSY) is one of most elegant extensions of the Standard Model (SM) and explains the puzzles of the SM by providing a candidate to explain the dark matter content of the universe, allowing scientists to understand the origin of the electroweak scale requiring the top mass to be around 170 GeV and leading to the unification of forces at a grand unified scale. Further the minimal supersymmetric standard model (MSSM) predicts the Higgs boson mass to be less than 135 GeV. The discovery of the Higgs Boson with mass around 125 GeV at the LHC has provided a major support to SUSY ideas. Searches for SUSY are ongoing at the Large Hadron Collider (LHC). Direct and indirect dark matter experiments are searching for a particle dark matter candidate which arises most naturally in SUSY models. Proton decay predicted by SUSY grand unified theories is being searched for at deep underground experiments. In addition, recent advances in neutrino and dark matter physics, observational astrophysics, precision cosmology and the promising new window into the cosmos opened by the direct detection of gravitational waves, have brought new ideas on the potential connections between new fundamental particles and our understanding of their impact on the early universe and its evolution. At present, the major questions include: Is SUSY still the best candidate for models beyond the SM? Do we have any well motivated alternative to SUSY? Have we exhausted all possibilities to search for new physics at high and low energy scales? XXVIIth International Conference on Supersymmetry and Unification of Fundamental Interactions (SUSY 2019), hosted by Texas A&M University – Corpus Christi during May 20-24, 2019, provided a unique venue to discus and understand the status of SUSY, connection between particle physics and cosmology, supersymmetry and its alternative, Higgs sector, neutrino sector, flavor sector, dark matter, electroweak phase transition, astroparticle physics, gravitational waves and string theory. Discussion of results from the LHC, recent neutrino experiments and observations, direct and indirect dark matter detection experiments, detection of gravitational waves, data from particle colliders, as well as measurements of the CMB and Large Scale Structure were an integral part of SUSY 2019. To ensure the younger participants will benefit from the conference the most, the conference was preceded by the 4 day long pre-SUSY summer school for graduate students and postdocs. The invited speakers were leading scientists in the fields of SUSY interest. The school took place on Texas A&M University – Corpus Christi campus during the week prior the SUSY 2019 conference (May 15 – 18, 2019). Since its inception in 1993, SUSY has become one of the most important and widely attended international meetings in high energy physics, devoted to new ideas in fundamental particle physics. SUSY 2019 brought together approximately 250 scientists, theorists, phenomenologists, experimentalists and cosmologists, (including over 60 graduate students and 70 postdocs) representing 22 nations: Australia, Belgium, Canada, Chile, China, Colombia, France, Germany, India, Italy, Japan, Mexico, Peru, Portugal, Romania, South Korea, Spain, Sweden, Switzerland, Taiwan, United Kingdom and United States. SUSY 2019 provided a stimulating venue for the exchange of scientific ideas among experts in dark matter, neutrino physics, particle physics, astrophysics and cosmology. The following scientific topics were delivered during SUSY 2019 in form of 44 plenary talks and over 200 parallel talks: Unification of Forces; Electroweak, Top and Higgs Physics; Precision Calculations and MC tools; BSM in Flavor Physics; Neutrino Masses: Models and Phenomenology; Cosmology and Gravitational Waves; Dark Matter, Astroparticle Physics; Formal Field Theory and Strings; Alternatives to Supersymmetry; Quantum Information: Machine Learning/Big Data. 28 talks were given during the pre-SUSY program related to the following topics: Neutrino Physics; Big Data; Collider Physics & SUSY; String Phenomenology; Cosmology; Dark Matter; SUSY Models and Phenomenology

43 PARTICLE ACCELERATORS↗

DOE OSTI2020

A Scintillating Xenon Bubble Chamber for Dark Matter Detection. Final Report

This report describes the progress in the search for particle dark matter achieved under DOE award DE-SC0012161, as well as the invention of a new dark matter and neutrino detection technique. Work supported by this award follows in three distinct thrusts: (1) the successful completion of the Generation-1 Direct Detection experiment PICO-60, which set the world-leading limit on the spin-dependent coupling of dark matter to protons and achieved a precise understanding of the response of bubble chambers to nuclear-recoil signals and electron-recoil backgrounds; (2) the construction of the Generation-2 Direct Detection experiment LZ, which will soon be the world's most sensitive dark matter detector; and (3) the demonstration of the first scintillating bubble chamber. The development of a scintillating liquid noble bubble chamber was the primary goal of the proposed work, with the aim of combining the excellent background rejection of a PICO-style bubble chamber with the event-by-event energy resolution of a liquid-noble detector such as LZ. This work produced the first ever observation of coincident scintillation and bubble nucleation by a nuclear recoil in a superheated fluid and also revealed an unexpected benefit to the use of noble liquids in a bubble chamber, namely the ability to increase the degree of superheat by an order of magnitude beyond that achievable in PICO-style detectors while maintaining PICO's world-leading background rejection. This discovery has led to new projects in the US and Canada, developing noble liquid bubble chambers both as detectors for low-mass dark matter and as detectors of coherent elastic neutrino-nucleus scattering (CEvNS) by neutrinos produced at nuclear reactors.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2020

Biomass Combustion in a Circulating Fluidized Bed Combustor

Interest in circulating fluidized bed (CFB) boilers as a power generation technology has skyrocketed in recent years because of several advantages this technology offers over conventional boilers, such as increased gas-solid mixing resulting in higher combustion efficiency and the ability to use lower quality fuels. CFB combustors are operated at lower temperatures than conventional thermal power generation combustors, thus reducing NO x emissions. SO 2 emissions are conveniently controlled through the addition of Ca-based sulphur sorbents within the combustor. This report summarizes the current modeling effort on a 50 kW th CFB combustor with a diameter of 10 cm and a height of 5 m; designed, built, and operated at CanmetENERGY in Ottawa, Canada employing the multiphase particle-in-cell (PIC) approach in the open-source Multiphase Flow with Interphase eXchanges (MFiX) Software Suite. The MFiX-PIC model parameters for the simulation are tuned against cold-flow experiments from CanmetENERGY using 9 kg of olivine sand as the inert bed material. It is shown that for the relatively coarse fluid meshes and large parcel sizes necessitated by the scale of the simulation, filter size dependent corrections to the drag law must be incorporated to ensure accuracy of the simulation results. The validated cold flow model is extended to simulate reacting flow with torrefied hardwood as the feedstock and to validate the combustion reaction scheme. The species concentrations at the riser outlet are compared against CanmetENERGY’s experiments and show satisfactory agreement. The simulations demonstrate the ability of MFiX-PIC to accurately capture the physics and chemistry of a circulating fluidized bed combustor at bench scales, which can be further extended to pilot- and industrial-scale systems.

20 FOSSIL-FUELED POWER PLANTS↗

DOE OSTI2020

Electric Vehicle Charging Infrastructure Trends from the Alternative Fueling Station Locator (Q1 2020)

The US. Department of Energy’s (DOE’s) Alternative Fueling Station Locator contains information on public and private non-residential alternative fueling stations in the United States and Canada and currently tracks ethanol (E85), biodiesel, compressed natural gas, electric vehicle (EV) charging, hydrogen, liquefied natural gas, and propane stations. Of these fuels, EV charging continues to experience rapidly changing technology and growing infrastructure. This report provides a snapshot of the state of EV charging infrastructure in the United States in the first calendar quarter of 2020 (Q1). Using data from the Station Locator, this report breaks down the growth of public and private charging infrastructure by charging level, network, and location. Additionally, this report measures the current state of charging infrastructure compared with the amount projected to meet charging demand by 2030. This information is intended to help transportation planners, policymakers, researchers, infrastructure developers, and others understand the rapidly changing landscape for EV charging.

33 ADVANCED PROPULSION SYSTEMS↗

DOE OSTI2020

Cultivation and Use of Acidithiobacillus ferrooxidans in Tellurium Biorecovery

The use of Acidithiobacillus ferrooxidans, Thiobacillus thiooxidans, and other chemoautotrophic microbes in bioleaching have been implemented in a variety of processes.1 In industry, bioleaching has been studied for its potential to extract valuable metals from low grade ores that would otherwise be cost prohibitive to recover.2 Other applications of bioleaching include the ability of certain microbes to detoxify waste products and even heavy metal contaminated soils.3 Another potential application for such bio-oxidative microbial activity is the extraction of tellurium (Te) from mine tailings, a low-cost abundant resource. Tellurium is one of the least common elements on Earth; it is found in the planetary crust at about 1 µg/kg, a rarity most comparable to that of platinum.4 A major use of Te in the U.S. is in cadmium-telluride (CdTe) solar panels5. Te is primarily imported into the U.S. from Canada, and it is usually recovered as a byproduct of copper refining.6 Since CdTe photovoltaic (PV) cells are the most efficient, cost-effective, and environmentally friendly PV chemistry, the renewables market has seen an increased demand for CdTe PV cells causing some concerns about sustainability and the limited global availability of Te. Acidithiobacillus ferroxidans is a microorganism that can oxidize iron and sulfur to produce ferric iron and sulfuric acid, and it is possible that it could also solubilize Te from sulfidic mine tailings. In this project, different media for growth of A. ferroxidans were evaluated, and a plan for testing the ability of A. ferroxidans to leach Te from mine tailings was developed. Initial characterization of A. ferroxidans cultures grown in the presence of copper tailings suggests that conditions suitable for Te bioleaching can be established.

60 APPLIED LIFE SCIENCES↗

DOE OSTI2020

Decovalex-2019 (Executive Summary)

The DECOVALEX Project is an on-going international research collaboration, established in 1992, to advance the understanding and modeling of coupled Thermal (T), Hydrological (H), Mechanical (M) and Chemical (C) processes in geological in geological systems. DECOVALEX was initially motivated by the recognition that prediction of these coupled effects is an essential part of the performance and safety assessment of geologic disposal systems for radioactive waste and spent nuclear fuel. Later it was realized that these processes also play a critical role in other subsurface engineering activities, such as subsurface CO 2 storage, enhanced geothermal systems, and unconventional oil and gas production through hydraulic fracturing. Research teams from many countries (e.g., Canada, China, Czech Republic, Finland, France, Germany, Japan, Republic of Korea, Spain, Sweden, Switzerland, Taiwan, United Kingdom, and the United States) various institutions have participated in the DECOVALEX Project over the years, providing a wide range of perspectives and solutions to these complex problems. These institutions represent radioactive waste management organizations, national research institutes, regulatory agencies, universities, as well as industry and consulting groups. The overall aim of DECOVALEX-2019 was to increase the understanding of various thermo-hydro-mechanical-chemical processes of importance for radionuclide release and transport from a repository to the biosphere and how they can be described and modelled using mathematical models. The scientific and technical objectives are: to increase the basic understanding of T-H-M-C coupled processes in fractured rocks (crystalline, sedimentary, argillaceous) and buffer materials; to investigate the predictive capabilities of different codes to field experiments and to perform verification of codes; to exchange experimental data, and improve the understanding of the constitutive behavior of crystalline and argillaceous rock masses and buffer materials; and to perform THMC calculations in a performance/safety assessment context.

58 GEOSCIENCES↗

DOE OSTI2020

DECOVALEX-2019 (Task E Final Report)

The DECOVALEX Project is an on-going international research collaboration, established in 1992, to advance the understanding and modeling of coupled Thermal (T), Hydrological (H), Mechanical (M) and Chemical (C) processes in geological in geological systems. DECOVALEX was initially motivated by the recognition that prediction of these coupled effects is an essential part of the performance and safety assessment of geologic disposal systems for radioactive waste and spent nuclear fuel. Later it was realized that these processes also play a critical role in other subsurface engineering activities, such as subsurface CO 2 storage, enhanced geothermal systems, and unconventional oil and gas production through hydraulic fracturing. Research teams from many countries (e.g., Canada, China, Czech Republic, Finland, France, Germany, Japan, Republic of Korea, Spain, Sweden, Switzerland, Taiwan, United Kingdom, and the United States) various institutions have participated in the DECOVALEX Project over the years, providing a wide range of perspectives and solutions to these complex problems. These institutions represent radioactive waste management organizations, national research institutes, regulatory agencies, universities, as well as industry and consulting groups. This document is the final report of Task E which was proposed and coordinated by Andra, the National Radioactive Waste Management Agency in France, presenting the technical definitions of the problems studied, approaches applied, achievements made and outstanding issues for future research. The purpose of Task E of the DECOVALEX-2019 project is to investigate upscaling THM modelling from small-scale experiments (some cubic meters) to full-scale experiments (some ten cubic meters) and finally to the scale of the waste repository (cubic kilometers). To achieve this aim, the data of two in-situ heating experiments performed by Andra (the French National Radioactive Waste Management Agency) in the Meuse/Haute-Marne Underground Research Laboratory (MHM URL) have formed the basis for the understanding of the THM behavior of the COx at different scales. The first experiment provided the reference values of the THM parameters by means of a calibration exercise and they were used for a blind prediction and an interpretative analysis of the second one.

58 GEOSCIENCES↗

DOE OSTI2021

Electric Vehicle Charging Infrastructure Trends from the Alternative Fueling Station Locator: Second Quarter 2020

The U.S. Department of Energy’s Alternative Fueling Station Locator contains information on public and private non-residential alternative fueling stations in the United States and Canada and currently tracks ethanol (E85), biodiesel, compressed natural gas, electric vehicle (EV) charging, hydrogen, liquefied natural gas, and propane stations. Of these fuels, EV charging continues to experience rapidly changing technology and growing infrastructure. This report provides a snapshot of the state of EV charging infrastructure in the United States in the second calendar quarter of 2020. Using data from the Station Locator, this report breaks down the growth of public and private charging infrastructure by charging level, network, and location. Additionally, this report measures the current state of charging infrastructure compared with the amount projected to meet charging demand by 2030. This information is intended to help transportation planners, policymakers, researchers, infrastructure developers, and others understand the rapidly changing landscape for EV charging. This is the second report in a new series. The first report for the first calendar quarter of 2020 can be found in the publication databases of the Alternative Fuels Data Center and the National Renewable Energy Laboratory.

24 POWER TRANSMISSION AND DISTRIBUTION↗

DOE OSTI2021

Modeling Explosive Dispersal of Radiological Material: A Nonparametric Analysis

The National Atmospheric Release Advisory Center (NARAC) is a Department of Energy (DOE) asset that provides guidance on the potential effects of atmospherically released hazards based on dispersion simulation results. Numerical simulation results are compared to well-characterized experimental measurements whenever possible to validate and refine the model predictions. In 2012, such measurements were obtained by Defence Research and Development Canada (DRDC) and collaborating organizations for the case of explosively released 140 La – a radioactive isotope with a half-life of 1.6781 days.

42 ENGINEERING↗

DOE OSTI2021

Bifacial Photovoltaic Modules and Systems: Experience and Results from International Research and Pilot Applications

Within the framework of IEA PVPS, Task 13 aims to provide support to market actors working to improve the operation, the reliability and the quality of PV components and systems. Operational data from PV systems in different climate zones compiled within the project will help provide the basis for estimates of the current situation regarding PV reliability and performance. The general setting of Task 13 provides a common platform to summarize and report on technical aspects affecting the quality, performance, reliability and lifetime of PV systems in a wide variety of environments and applications. By working together across national boundaries we can all take advantage of research and experience from each member country and combine and integrate this knowledge into valuable summaries of best practices and methods for ensuring PV systems perform at their optimum and continue to provide competitive return on investment. Task 13 has so far managed to create the right framework for the calculations of various parameters that can give an indication of the quality of PV components and systems. The framework is now there and can be used by the industry who has expressed appreciation towards the results included in the high-quality reports. The IEA PVPS countries participating in Task 13 are Australia, Austria, Belgium, Canada, Chile, China, Denmark, Finland, France, Germany, Israel, Italy, Japan, the Netherlands, Norway, Spain, Sweden, Switzerland, Thailand, and the United States of America.

14 SOLAR ENERGY↗

DOE OSTI2021

Designing New Materials for Photovoltaics: Opportunities for Lowering Cost and Increasing Performance through Advanced Material Innovations

14 SOLAR ENERGY↗