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At least 253 records · Page 14

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NASA NTRS1979

Chemical processing of lunar materials

The paper highlights recent work on the general problem of processing lunar materials. The discussion covers lunar source materials, refined products, motivations for using lunar materials, and general considerations for a lunar or space processing plant. Attention is given to chemical processing through various techniques, including electrolysis of molten silicates, carbothermic/silicothermic reduction, carbo-chlorination process, NaOH basic-leach process, and HF acid-leach process. Several options for chemical processing of lunar materials are well within the state of the art of applied chemistry and chemical engineering to begin development based on the extensive knowledge of lunar materials.

Criswell, D. R.↗

NASA NTRS1979

Chemical processes involved in the initiation of hot corrosion of B-1900 and NASA-TRW VIA

Sodium surface-induced hot corrosion of B-1900 and NASA-TRW VIA alloys at 900 C has been studied, with special attention to the chemical reactions during and immediately after the induction period. Thermogravimetric tests were run and data were obtained by chemical analysis of water soluble metal salts and of residual sulfate. Surface analyses of hot corroded samples were obtained by spectroscopic techniques (ESCA). A chemical mechanism for elucidating Na2SO4-induced hot corrosion is proposed indicating that hot corrosion is initiated by basic fluxing of the protective Al2O3 scale. The sequential, catastrophic corrosion results from molybdenum content. The self-sustaining feature is a consequence of the cyclic nature of the acidic fluxing. It is believed that the mechanism is applicable not only to laboratory results, but also to the practical problem of hot corrosion encountered in gas turbine engines.

Fryburg, G. C.↗

NASA NTRS1980

Environmental analysis of the chemical release module

The environmental analysis of the Chemical Release Module (a free flying spacecraft deployed from the space shuttle to perform chemical release experiments) is reviewed. Considerations of possible effects of the injectants on human health, ionosphere, weather, ground based optical astronomical observations, and satellite operations are included. It is concluded that no deleterious environmental effects of widespread or long lasting nature are anticipated from chemical releases in the upper atmosphere of the type indicated for the program.

Heppner, J. P.↗

NASA NTRS1980

Chemicals from biomass - The U.S. prospects for the turn of the century

Historically, chemicals from biomass have been and are expected to be economical in three major areas: byproducts, specialty items and polymers. Assessments of producing major chemicals from biomass in a processing plant based on the available conversion techniques indicate that they are not economically attractive, with the possible exception of conversion to ammonia and ethanol. The deterrents are the heavy capital investments, dependability of raw material supply and transportation costs for large plants, lack of operation experience, inadaptability of market variations, and competition from petroleum and coal. More importantly, it is also shown that even if chemicals from biomass were economical today, the resultant savings in petroleum would be far less than those achieved through other options available for the utilization of biomass as fuel and structural material. Thus, it is concluded that near-term research and development must be toward improved conversion processes, recovery of valuable products from waste streams at existing plants, more efficient use of biomass of energy and more efficient production of superior material products.

Sarbolouki, M. N.↗

NASA NTRS1981

Chemical composition of the SiO2/InSb interface as determined by X-ray photoelectron spectroscopy

In connection with the relatively poor insulating characteristics of the native oxides of most III-V compound semiconductors, there has been interest in the development of deposited dielectric layers for surface passivation and MOS device fabrication on III-V compound semiconductor substrates. The chemical system of SiO2 deposited on single-crystal InSb substrates has been proposed for the fabrication of IR CCD. The considered investigation is concerned with a detailed examination of the chemical nature of the interactions between deposited and native oxides using X-ray photoelectron spectroscopy (XPS) in conjunction with a chemical-etching technique for depth profiling. The compositional structure of the interfaces obtained in the SiO2/native oxide/InSb system is derived on the basis of an intensity analysis of XPS spectra. Thermal oxidation of the InSb substrate is found to result in an In-rich native oxide and excess elemental Sb at the native oxide/substrate interface.

Vasquez, R. P.↗

NASA NTRS1981

Io - Thermal models and chemical evolution

A combined thermal and chemical evolution model of Io is presented, outlining limits on the possible starting materials, heating history, chemical history, and present state of Io. Our best scenario starts with Io being accreted from material in a proto-Jovian nebula which condensed between 400-600 K. Radionuclides and tidal heating would lead to large-scale convection within Io and chemical reactions leading to the outgassing of water and methane. Reactions between Fe(0)-FeS and water, at least near the surface, go to completion, resulting in all Fe being oxidized with elemental sulfur producing a low-conductivity crust. In the deep interior, these reactions may not completely exhaust Fe metal, and an FeS-rich core may be formed.

Consolmagno, G. J.↗

NASA NTRS1982

Regional chemical setting of the Apollo 16 landing site and the importance of the Kant Plateau

Orbital X-ray data from the Apollo 16 region indicate that physiographic units identified before the lunar mission can be classified as chemical units as well. The Descartes Mountains, however, appear to be an extension of the Kant Plateau composition that is unusually anorthositic and resembles farside terra. The Cayley Plains have closer affinities to basaltic materials than terra materials, physically, spectrally and chemically. The Theophilus impact, 330 km east of the landing site, excavated magnesium-rich basalts from below less-magnesian flows in Mare Nectaris; but, mafic ejecta was substantially blocked from the Apollo 16 site by the Kant Plateau that rises 5 km above the level of the mare. Apollo 16 soil samples from stations selected to collect either Descartes Mountains material or Cayley Plains material were surprisingly similar. However, they do, indeed, show the chemical trends indicative of the two units as defined by the orbiting geochemistry detectors. The Kant Plateau and Descartes Mountains material may be among the rare nearside examples of a plagioclase-rich cumulate of the primordial magma ocean.

Andre, C. G.↗

NASA NTRS1982

The possible role of soluble salts in chemical evolution

A model for a prebiotic environment in which concentration, condensation, and chemical evolution of biomolecules could have occurred is proposed. The principal reactions expected of proteins, nucleic acids, lipids, and some of their precursors in this environment are discussed. The model is based on the concept of a fluctuating system in which hydration and dehydration processes occur in a cyclic manner, with allowance for high concentrations of soluble salts, such as chlorides and sulfates. It is concluded that the proposed prebiotic environment with its dynamical characteristics is a plausible model for the chemical evolution from biomonomers through random oligomers toward self-replicating chemical systems.

Lahav, N.↗

NASA NTRS1983

Acoustic imaging for diagnostics of chemically reacting systems

The concept of local diagnostics, in chemically reacting systems, with acoustic imaging is developed. The elements of acoustic imaging through ellipsoidal mirrors are theoretically discussed. In a general plan of the experimental program, the first system is chosen in these studies to be a simple open jet, non premixed turbulent flame. Methane is the fuel and enriched air is the oxidizer. This simple chemically reacting flow system is established at a Reynolds number (based on cold viscosity) of 50,000. A 1.5 m diameter high resolution acoustic mirror with an f-number of 0.75 is used to map the acoustic source zone along the axis of the flame. The results are presented as acoustic power spectra at various distances from the nozzle exit. It is seen that most of the reaction intensity is localized in a zone within 8 diameters from the exit. The bulk reactions (possibly around the periphery of the larger eddies) are evenly distributed along the length of the flame. Possibilities are seen for locally diagnosing single zones in a multiple cluster of reaction zones that occur frequently in practice. A brief outline is given of the future of this work which will be to apply this technique to chemically reacting flows not limited to combustion.

Ramohalli, K.↗

NASA NTRS1983

Chemical evolution and the origin of life

A review is presented of recent advances made in the understanding of the formation of carbon compounds in the universe and the occurrence of processes of chemical evolution. Topics discussed include the principle of evolutionary continuity, evolution as a fundamental principle of the physical universe, the nuclear synthesis of biogenic elements, organic cosmochemistry and interstellar molecules, the solar nebula and the solar system in chemical evolution, the giant planets and Titan in chemical evolution, and comets and their interaction with the earth. Also examined are carbonaceous chondrites, environment of the primitive earth, energy sources available on the primitive earth, the synthesis of biochemical monomers and oligomers, the abiotic transcription of nucleotides, unified prebiotic and enzymatic mechanisms, phospholipids and membranes, and protobiological evolution.

Oro, J.↗

NASA NTRS1984

Opportunities for the chemical industry in space, part 1

The chemical/petrochemical industry devotes a large percentage of its gross income to research and development, with much of its R and D of a long-term nature. As the chemical industry is examined as a candidate for space investigations, it is readily apparent that research and development in the space environment may lead to attractive commercial opportunities. The advantages of low gravity manufacturing, with a particular emphasis on chemical catalysts, are presented herein specifically for the chemical industry. Research from the Skylab program and Apollo Soyuz test project is reviewed, including acoustic levitation, crystal growth, and container less melts. Space processing of composite materials, alloys, and coatings is also discussed.

Source record↗

NASA NTRS1983

An investigation of sulfate production in clouds using a flow-through chemical reactor model approach

A flow-through chemical reactor model is developed to describe the mass transfer and chemical processes that atmospheric gases undergo in clouds. The model includes the simultaneous absorption of SO2, NH3, O3, NO(x), HNO3, CO2 and H2O2, the accompanying dissociation and oxidation reactions in cloud water, considers electrical neutrality, and includes qualitative parameterization of cloud microphysics. The model is used to assess the importance of the oxidation reactions H2O2-S(IV), O3-S(IV), and S(IV)-Mn(2+) catalysis, and the effects of cloud parameters such as drop size, rain intensity, liquid water content, and updraft velocity. Both precipitating and nonprecipitating clouds are studied. Model results predict sulfate production rates varying from 3 percent/hr to 230 percent/hr. The actual rate is highly dependent on the chemical composition of the uptake air and the physical conditions of the cloud. Model results also show that both the H2O2 and the O3 oxidation reactions can be significant.

Hong, M. S.↗

NASA NTRS1984

Chemical kinetic reaction mechanism for the combustion of propane

A detailed chemical kinetic reaction mechanism for the combustion of propane is presented and discussed. The mechanism consists of 27 chemical species and 83 elementary chemical reactions. Ignition and combustion data as determined in shock tube studies were used to evaluate the mechanism. Numerical simulation of the shock tube experiments showed that the kinetic behavior predicted by the mechanism for stoichiometric mixtures is in good agrement with the experimental results over the entire temperature range examined (1150-2600K). Sensitivity and theoretical studies carried out using the mechanism revealed that hydrocarbon reactions which are involved in the formation of the HO2 radical and the H2O2 molecule are very important in the mechanism and that the observed nonlinear behavior of ignition delay time with decreasing temperature can be interpreted in terms of the increased importance of the HO2 and H2O2 reactions at the lower temperatures.

Jachimowski, C. J.↗

NASA NTRS1984

Role of fuel chemical properties on combustor radiative heat load

In an attempt to rigorously study the fuel chemical property influence on combustor radiative heat load, UTRC has conducted an experimental program using 25 test fuels. The burner was a 12.7-cm dia cylindrical device fueled by a single pressure-atomizing injector. Fuel physical properties were de-emphasized by selecting injectors which produced highly-atomized, and hence rapidly-vaporizing sprays. The fuels were specified to cover the following wide ranges of chemical properties: hydrogen, 9.1 to 15- (wt) pct; total aromatics, 0 to 100 (vol) pct; and naphthalene, 0 to 30 (vol) pct. They included standard fuels, specialty products and fuel blends. Fuel naphthalene content exhibited the strongest influence on radiation of the chemical properties investigated. Smoke point was a good global indicator of radiation severity.

Rosfjord, T. J.↗

NASA NTRS1985

Direct numerical simulations of a reacting mixing layer with chemical heat release

In order to study the coupling between chemical heat release and fluid dynamics, direct numerical simulations of a chemically reacting mixing layer with heat release are performed. The fully compressible equations as well as an approximate set of equations that is asymptotically valid for low-Mach-number flows are treated. These latter equations have the computational advantage that high-frequency acoustic waves have been filtered out, allowing much larger time steps to be taken in the numerical solution procedure. A detailed derivation of these equations along with an outline of the numerical solution technique is given. Simulation results indicate that the rate of chemical product formed, the thickness of the mixing layer, and the amount of mass entrained into the layer all decrease with increasing rates of heat release.

Mcmurtry, P. A.↗

NASA NTRS1985

A finite volume method for the calculation of compressible chemically reacting flows

Several efficient pseudo time techniques have been developed for calculating steady state chemically reacting flows. The techniques include the implicit treatment of the chemical source term, point implicit multiple grid accelerator and a constant CFL condition. It turns out that these methods can be viewed as ways of rescaling the equations in time such that all chemical and convective phenomena evolve at comparable pseudo time scales. Consequently the number of iterations needed to solve reacting problems is approximately the same as for non-reacting problems. The techniques are demonstrated for a simple dissociation model and a nontrivial H2 - Air combustion model.

Bussing, T. R. A.↗

NASA NTRS1985

On convergence of computation of chemically reacting flows

The computational problems associated with high-temperature flows undergoing finite-rate ionization reactions is investigated. The conservation equations governing chemical species and vibrational and electron energies are solved simultaneously with those for overall mass, momentum, and energy for a one-dimensional subsonic flow, through a constant-area duct, originating behind a normal shock wave, using an implicit time-marching technique. Boundary conditions are imposed in the form of characteristic wave variables accounting for the effects of chemical reactions on the speed of sound. Converging solutions are obtained for cases in which chemical reactions are weak, but difficulty is encountered in other cases. The cause of the difficulty is investigated and shown to be the sharp pressure disturbances produced by such reactions.

Park, C.↗

NASA NTRS1983

Chemical state of pre-solar matter

Consideration is given to several features of the chemical state of interstellar matter that may be relevant to the observed properties of chondrules if they are formed from aggregates of pre-existing particles. First, a brief summary of the numbers and types of interstellar particles as indicated by the extinction of starlight is given. Second, a model of the free decay interval required by the low solar abundance of 129-I is advanced. This model can support variations in the 129-I/127-I ratio that are larger than typical isotopic anomalies. Third, a new steady-state model of the chemical state of the interstellar medium is presented as a first step toward a quantitative distribution of the abundances among different chemical forms. Last, the advantages of fusing chondrules from aggregates of pre-solar dust by the action of exothermic chemistry are enumerated.

Clayton, D. D.↗