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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

Current Concepts and Future Directions of CELSS

Bioregenerative life support systems for use in space were studied. Concepts of such systems include the use of higher plants and/or microalgae as sources of food, potable water and oxygen, and as sinks for carbon dioxide and metabolic wastes. Recycling of materials within the system will require processing of food organism and crew wastes using microbiological and/or physical chemical techniques. The dynamics of material flow within the system will require monitoring, control, stabilization and maintenance imposed by computers. Studies included higher plant and algal physiology, environmental responses, and control; flight experiments for testing responses of organisms to weightlessness and increased radiation levels; and development of ground based facilities for the study of recycling within a bioregenerative life support system.

Macelroy, R. D.↗

A review of shock waves around aeroassisted orbital transfer vehicles

Aeroassisted orbital transfer vehicles (AOTVs) are a proposed type of reusable spacecraft that would be used to transport cargoes from one Earth-bound orbit to another. Such vehicles could be based on the proposed space station and used to transport commercial satellites from the space station to geostationary orbits or to polar orbits and return. During a mission, AOTVs would fly through Earth's atmosphere, thus generating aerodynamic forces that could be used for decelerating the vehicles or changing their direction. AOTV research findings were concerned with the shock-wave-induced, high-temperature airflows that would be produced around these vehicles during atmospheric flight. Special emphasis was placed on the problems of: (1) the chemical physics of multitemperature, ionizing, nonequilibrium air flows, and (2) the dynamics of the flows in the base region of a blunt body with complex afterbody geometry.

Park, C.↗

Importance of formaldehyde in cloud chemistry

A physical-chemical model which is an extension of that of Hong and Carmichael (1983) is used to investigate the role of formaldehyde in cloud chemistry. This model takes into account the mass transfer of SO2, O3, NH3, HNO3, H2O2, CO2, HCl, HCHO, O2, OH and HO2 into cloud droplets and their subsequent chemical reactions. The model is used to assess the importance of S(IV)-HCHO adduct formation, the reduction of H2O2 by HCHO, HCHO-free radical interactions, and the formation of HCOOH in the presence of HCHO in cloud droplets. Illustrative calculations indicate that the presence of HCHO inhibits sulfate production rate in cloud droplets. The direct inhibition of sulfate production rate in cloudwater due to nucleophilic addition of HSO3(-) to HCHO(aq) to form hydroxymethanesulfonate is generally low for concentrations of HCHO typical of ambient air. However, inhibition of sulfate production due to formaldehyde-free radical interactions in solution can be important. These formaldehyde-free radical reactions can also generate appreciable quantities of formic acid.

Adewuyi, Y. G.↗

Balloon-borne three-meter telescope for far-infrared and submillimeter astronomy

Presented are scientific objectives, engineering analysis and design, and results of technology development for a Three-Meter Balloon-Borne Far-Infrared and Submillimeter Telescope. The scientific rationale is based on two crucial instrumental capabilities: high angular resolution which approaches eight arcseconds at one hundred micron wavelength, and high resolving power spectroscopy with good sensitivity throughout the telescope's 30-micron to 1-mm wavelength range. The high angular resolution will allow us to resolve and study in detail such objects as collapsing protostellar condensations in our own galaxy, clusters of protostars in the Magellanic clouds, giant molecular clouds in nearby galaxies, and spiral arms in distant galaxies. The large aperture of the telescope will permit sensitive spectral line measurements of molecules, atoms, and ions, which can be used to probe the physical, chemical, and dynamical conditions in a wide variety of objects.

Fazio, G. G.↗

Global change in the geosphere-biosphere: Initial priorities for an IGBP

Some of the factors are outlined that leads one to endorse the concept of focused, international geosphere-biosphere program, whose goal is to understand the interactive physical, chemical, and biological processes that regulate the Earth's unique environment for life, the changes that are occurring in this system, and the manner in which they are influenced by human actions. There is a pressing need to assess the consequence of human activities in the context of natural global change and to provide the body of knowledge necessary to chart a wise course to the future. A number of specific objectives were developed which leads to the conclusion that the need for new programs of observation of the Earth as a planet, a better understanding of the interactive processes that governs its changes, the development of a new generation of coupled modes, and the design of suitable tests to guide the development of these models and the understanding of the processes involved. Some general recommendations are summarized.

Source record↗

Present state of knowledge of the upper atmosphere: An assessment report; processes that control ozone and other climatically important trace gases

The state of knowledge of the upper atmosphere was assessed as of January 1986. The physical, chemical, and radiative processes which control the spatial and temporal distribution of ozone in the atmosphere; the predicted magnitude of ozone perturbations and climate changes for a variety of trace gas scenarios; and the ozone and temperature data used to detect the presence or absence of a long term trend were discussed. This assessment report was written by a small group of NASA scientists, was peer reviewed, and is based primarily on the comprehensive international assessment document entitled Atmospheric Ozone 1985: Assessment of Our Understanding of the Processes Controlling Its Present Distribution and Change, to be published as the World Meteorological Organization Global Ozone Research and Monitoring Project Report No. 16.

Watson, R. T.↗

Metallic glass as a temperature sensor during ion plating

The temperature of the interface and/or a superficial layer of a substrate during ion plating was investigated using a metallic glass of the composition Fe67Co18B14Si1 as the substrate and as the temperature sensor. Transmission electron microscopy and diffraction studies determined the microstructure of the ion-plated gold film and the substrate. Results indicate that crystallization occurs not only in the film, but also in the substrate. The grain size of crystals formed during ion plating was 6 to 60 nm in the gold film and 8 to 100 nm in the substrate at a depth of 10 to 15 micrometers from the ion-plated interface. The temperature rise of the substrate during ion plating was approximately 500 C. Discontinuous changes in metallurgical microstructure, and physical, chemical, and mechanical properties during the amorphous to crystalline transition in metallic glasses make metallic glasses extremely useful materials for temperature sensor applications in coating processes.

Miyoshi, K.↗

Stress-life interrelationships associated with alkaline fuel cells

A review is presented concerning the interrelationships between applied stress and the expected service life of alkaline fuel cells. Only the physical, chemical, and electrochemical phenomena that take place within the fuel cell stack portion of an overall fuel cell system will be discussed. A brief review will be given covering the significant improvements in performance and life over the past two decades as well as summarizing the more recent advances in understanding which can be used to predict the performance and life characteristics of fuel cell systems that have yet to be built.

Thaller, Lawrence H.↗

A review of shock waves around aeroassisted orbital transfer vehicles

Aeroassisted orbital transfer vehicles (AOTVs) are a proposed type of reusable spacecraft that would be used to transport cargoes from one earth-bound orbit to another. Such vehicles could be based on the proposed space station and used to transport commercial satellites from the space station to geostationary orbits or to polar orbits and return. During a mission, AOTVs would fly through earth's atmosphere, thus generating aerodynamic forces that could be used for decelerating the vehicles or changing their direction. AOTV research findings were concerned with the shock-wave-induced, high-temperature airflows that would be produced around these vehicles during atmospheric flight. Special emphasis was placed on the problems of: (1) the chemical physics of multitemperature, ionizing, nonequilibrium air flows, and (2) the dynamics of the flows in the base region of a blunt body with complex afterbody geometry.

Park, C.↗

Stress-life interrelationships associated with alkaline fuel cells

A review is presented concerning the interrelationships between applied stress and the expected service life of alkaline fuel cells. Only the physical, chemical, and electrochemical phenomena that take place within the fuel cell stack portion of an overall fuel cell system will be discussed. A brief review will be given covering the significant improvements in performance and life over the past two decades as well as summarizing the more recent advances in understanding which can be used to predict the performance and life characteristics of fuel cell systems that have yet to be built.

Thaller, Lawrence H.↗

U-Th-Pb, Sm-Nd, Rb-Sr, and Lu-Hf systematics of returned Mars samples

The advantage of studying returned planetary samples cannot be overstated. A wider range of analytical techniques with higher sensitivities and accuracies can be applied to returned samples. Measurement of U-Th-Pb, Sm-Nd, Rb-Sr, and Lu-Hf isotopic systematics for chronology and isotopic tracer studies of planetary specimens cannot be done in situ with desirable precision. Returned Mars samples will be examined using all the physical, chemical, and geologic methods necessary to gain information on the origin and evolution of Mars. A returned Martian sample would provide ample information regarding the accretionary and evolutionary history of the Martian planetary body and possibly other planets of our solar system.

Tatsumoto, M.↗

Novel nitrogen-based organosulfur electrodes for advanced intermediate temperature batteries

Advanced secondary batteries operating at intermediate temperatures (100 to 200 C) have attracted considerable interest due to their inherent advantages (reduced corrosion and safety risks) over higher temperature systems. Current work in this laboratory has involved research on a class of intermediate temperature Na/beta double prime- alumina/RSSR batteries conceptually similar to Na/S cells, but operating within a temperature range of 100 to 150 C, and having an organosulfur rather than inorganic sulfur positive electrode. The organosulfur electrodes are based on the reversible, two electron eduction of organodisulfides to the corresponding thiolate anions, RSSR + 2 electrons yield 2RS(-), where R is an organic moiety. Among the advantages of such a generic redox couple for battery research is the ability to tailor the physical, chemical, and electrochemical properties of the RSSR molecule through choice of the organic moiety. The viscosity, liquidus range, dielectric constant, equivalent weight, and redox potential can in fact be verified in a largely predictable manner. The current work concerns the use of multiple nitrogen organosulfur molecules, chosen for application in Na/RSSR cells for their expected oxidizing character. In fact, a Na/RSSR cell containing one of these materials, the sodium salt of 5-mercapto 1-methyltetrazole, yielded the highest open circuit voltage obtained yet in the laboratory; 3.0 volts in the charged state and 2.6 volts at 100 percent discharge. Accordingly, the cycling behavior of a series of multiple nitrogen organodisulfides as well as polymeric organodisulfides are presented in this manuscript.

Visco, S. J.↗

Space Station CMIF extended duration metabolic control test

The Space Station Extended Duration Metabolic Control Test (EMCT) was conducted at the MSFC Core Module Integration Facility. The primary objective of the EMCT was to gather performance data from a partially-closed regenerative Environmental Control and Life Support (ECLS) system functioning under steady-state conditions. Included is a description of the EMCT configuration, a summary of events, a discussion of anomalies that occurred during the test, and detailed results and analysis from individual measurements of water and gas samples taken during the test. A comparison of the physical, chemical, and microbiological methods used in the post test laboratory analyses of the water samples is included. The preprototype ECLS hardware used in the test, providing an overall process description and theory of operation for each hardware item. Analytical results pertaining to a system level mass balance and selected system power estimates are also included.

Schunk, Richard G.↗

Microbial trace fossils in Antarctica and the search for evidence of early life on Mars

It is possible to hypothesize that, if microbial life evolved on early Mars, fossil remnants of these organisms may be preserved on the surface. However, the cooling and drying of Mars probably resembled a cold desert and such an environment is not suitable for the process of fossilization. The frigid Ross Desert of Antarctica is probably the closest terrestrial analog to conditions that may have prevailed on the surface of the cooling and drying Mars. In this desert, cryptoendolithic microbial communities live in the airspaces of porous rocks, the last habitable niche in a hostile outside environment. The organisms produce characteristic chemical and physical changes in the rock substrate. Environmental changes (deterioration of conditions) may result in the death of the community. Although no cellular structures are fossilized, the conspicuous changes in the rock substrate are preserved as trace fossils. Likewise, microbial trace fossils (without cellular structures) may also be preserved on Mars: Discontinuities in structure or chemistry of the rock that are independent of physical or chemical gradients may be of biological origin. Ross Desert trace fossils can be used as a model for planning search strategies and for instrument design to find evidence of past Martian life.

Friedmann, E. Imre↗

Conceptual design of a piloted Mars sprint life support system

This paper presents the conceptual design of a life support system sustaining a crew of six in a piloted Mars sprint. The requirements and constraints of the system are discussed along with its baseline performance parameters. An integrated operation is achieved with air, water, and waste processing and supplemental food production. The design philosophy includes maximized reliability considerations, regenerative operations, reduced expendables, and fresh harvest capability. The life support system performance will be described with characteristics of the associated physical-chemical subsystems and a greenhouse.

Cullingford, H. S.↗

Bio-regenerative life support

The basis for and the potential uses of bio-regenerative life support are examined. Bio-regenerative life support systems are an alternative to physical-chemical regeneration techniques for use when resupply of a crew in space is expensive, or when the logistics of resupply are difficult. Many of the scientific studies required for bio-regenerative life support systems have been completed and preliminary development of some components will begin within the next 12 to 18 months. The focus of the work that lies ahead will be efficient power and mass use, long-term system stability, component function, systems integration, and extensive testing in the space environment. Because of the advantages of bio-regeneration, it is anticipated that human life support for long-term space missions will evolve to include increasingly large amounts of biologically-based regeneration.

Macelroy, Robert D.↗

Stability of genthelvite, Zn4(BeSiO4)3S - An exercise in chalcophilicity using exchange operators

Phase relations involving genthelvite are studied on the basis of physical-chemical principles and natural occurrences. Stability diagrams and exchange operators are considered as well as an extended system, natural associations, and solid state relations. It is noted that the extremely high chalcophilicity of Zn explains, in part, why genthelvite is such as rare mineral. It is only somewhat more stable than willemite and is therefore restricted to the extremely low-S environments provided by alkaline granites and syenites.

Burt, Donald M.↗