Fundamental effects of cold-work on some cobalt-chromium-nickel-iron base creep-resistant alloys
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A study of the effect of induction-vacuum-melting procedure on the high-temperature properties of a titanium-and-aluminum-hardened nickel-base alloy revealed that a major variable was the type of ceramic used as a crucible. Reactions between the melt and magnesia or zirconia crucibles apparently increased high-temperature properties by introducing small amounts of boron or zirconium into the melts. Heats melted in alumina crucibles had relatively low rupture life and ductility at 1,600 F and cracked during hot-working as a result of deriving no boron or zirconium from the crucible.
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Recent consideration of the use of permanent magnets in space power converters at heat rejection temperatures exceeding 250 C and in miniature high temperature actuators is supporting a search for permanent magnets resistant to demagnetizing forces at high temperature. The present paper investigates the short-term demagnetization resistance to applied bucking fields and at temperatures up to 300 C of SmCo5 type magnets, in the form of 1-cm cubes, from several commercial sources. Quasistatic, 2nd quadrant M-H data taken at selected temperatures are the source of derived plots which are then compared to similar data for previously tested Sm2Co17 type magnets. The 1-5 magnet remanence tends to be about 1.5 kG below that of the 2-17 magnets throughout the temperature range. However, the intrinsic coercivities and M-H curve 'knee-fields' seen in particular 1-5 magnets were considerably above those seen previously in the 2-17 magnets. This superior resistance to demagnetizing fields attainable in 1-5 magnets is also illustrated by safe operating area plots based on the knee-field, the magnetic induction swing and temperature. Comments are made on the possibility that a remanence versus knee-field tradeoff can make 1-5 material competitive with 2-17 in applications where a magnet has to withstand large bucking fields at high temperature.
Silicon and metal are coevaporated onto a silicon substrate in a molecular beam epitaxy system with a larger than stoichiometric amount of silicon so as to epitaxially grow particles of metal silicide embedded in a matrix of single crystal epitaxially grown silicon. The particles interact with incident photons by resonant optical absorption at the surface plasmon resonance frequency. Controlling the substrate temperature and deposition rate and time allows the aspect ratio of the particles to be tailored to desired wavelength photons and polarizations. The plasmon energy may decay as excited charge carriers of phonons, either of which can be monitored to indicate the amount of incident radiation at the selected frequency and polarization.
A structurally ordered cubic metal grain containing approximately 39 wt% Co, 61 wt% Fe, and less than 0.6 wt% Ni (approximately Fe3Co2) was found associated with troilite and pentlandite in the matrix of the Ningqiang carbonaceous chondrite. This mineral is similar to terrestrial wairauite. Experimental data in the Fe-Co system indicate that this CsCl-type Co-rich metal is stable below 700 C. Phase relations in the Fe-Co-Ni system show that Co cannot fractionate from Ni above 500 C. The dominant opaque minerals of awaruite, magnetite, and pentlandite in Ningqiang suggest relatively oxidizing conditions.
During the first several weeks after the explosion of SN 1987A, Fe/Co/Ni clumps, containing approx. 1% of the mass of the supernova envelope, absorbed most of the energy release by Ni-56 and Co-56 decay. As a result, the clumps expanded relative to the substrate, forming a 'nickel bubble' of low-density Fe/Co/Ni. Later the clumps captured approx. 10% of the radioactive luminosity of gamma rays and positrons. Assuming that these elements are not mixed microscopically with other elements, we find that the clumps must occupy approx. greater than 30% of the volume of the emitting region (radial velocity approx. less than 2500 km/s). The result indicates that the emission at late times is dominated by an extra source of heating and ionization, most likely photoionization by two-photon continuum from metastable helium in the gas surrounding the clumps. The resulting 'frothy' structure, consisting of bubbles of low-density Fe surrounded by higher-density filaments of H, He, and other elements, will persist and may be seen in the spectra and structure of supernova remnants.
The tribology of brush seals is of considerable interest to turbine engine designers because bristle wear continues to limit long term seal performance and life. To provide better materials characterization and foster the development of improved seals, NASA Lewis has developed a brush seal tuft tester. In this test, a 'paintbrush' sample tuft is loaded under constant contact pressure against the outside diameter of a rotating journal. With this configuration, load and friction are directly measured and accurate wear measurements are possible. Previously reported research using this facility showed excellent data repeatability and wear morphology similar to published seal data and dynamic rig tests. This paper is an update of the ongoing research into the tribology of brush seals. The effects of wire materials processing on seal wear and the tribological results for three journal coatings are discussed. Included in the materials processing were two nickel-chrome superalloys each processed to two different yield strengths. The results suggest that seal wear is dependent more on material composition than processing conditions.