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NASA NTRS2014

Vesta's Elemental Composition

Many lines of evidence (e.g. common geochemistry, chronology, O-isotope trends, and the presence of different HED rock types in polymict breccias) indicate that the howardite, eucrite, and diogenite (HED) meteorites originated from a single parent body. Meteorite studies show that this protoplanet underwent igneous differentiation to form a metallic core, an ultramafic mantle, and a basaltic crust. A spectroscopic match between the HEDs and 4 Vesta along with a plausible mechanism for their transfer to Earth, perhaps as chips off V-type asteroids ejected from Vesta's southern impact basin, supports the consensus view that many of these achondritic meteorites are samples of Vesta's crust and upper mantle. The HED-Vesta connection was put to the test by the NASA Dawn mission, which spent a year in close proximity to Vesta. Measurements by Dawn's three instruments, redundant Framing Cameras (FC), a Visible-InfraRed (VIR) spectrometer, and a Gamma Ray and Neutron Detector (GRaND), along with radio science have strengthened the link. Gravity measurements by Dawn are consistent with a differentiated, silicate body, with a dense Fe-rich core. The range of pyroxene compositions determined by VIR overlaps that of the howardites. Elemental abundances determined by nuclear spectroscopy are also consistent with HED-compositions. Observations by GRaND provided a new view of Vesta inaccessible by telescopic observations. Here, we summarize the results of Dawn's geochemical investigation of Vesta and their implications.

Prettyman, T. H.↗
NASA NTRS2010

Thermal Infrared Emission Spectroscopy of Synthetic Allophane and its Potential Formation on Mars

Allophane is a poorly-crystalline, hydrous aluminosilicate with variable Si/Al ratios approx.0.5-1 and a metastable precursor of clay minerals. On Earth, it forms rapidly by aqueous alteration of volcanic glass under neutral to slightly acidic conditions [1]. Based on in situ chemical measurements and the identification of alteration phases [2-4], the Martian surface is interpreted to have been chemically weathered on local to regional scales. Chemical models of altered surfaces detected by the Mars Exploration Rover Spirit in Gusev crater suggest the presence of an allophane-like alteration product [3]. Thermal infrared (TIR) spectroscopy and spectral deconvolution models are primary tools for determining the mineralogy of the Martian surface [5]. Spectral models of data from the Thermal Emission Spectrometer (TES) indicate a global compositional dichotomy, where high latitudes tend to be enriched in a high-silica material [6,7], interpreted as high-silica, K-rich volcanic glass [6,8]. However, later interpretations proposed that the high-silica material may be an alteration product (such as amorphous silica, clay minerals, or allophane) and that high latitude surfaces are chemically weathered [9-11]. A TIR spectral library of pure minerals is available for the public [12], but it does not contain allophane spectra. The identification of allophane on the Martian surface would indicate high water activity at the time of its formation and would help constrain the aqueous alteration environment [13,14]. The addition of allophane to the spectral library is necessary to address the global compositional dichotomy. In this study, we characterize a synthetic allophane by IR spectroscopy, X-ray diffraction (XRD), and transmission electron microscopy (TEM) to create an IR emission spectrum of pure allophane for the Mars science community to use in Martian spectral models.

Rampe, E. B.↗
NASA NTRS2018

Air Quality Satellite Monitoring by TROPOMI on Sentinel-5P

The recently launched Sentinel satellite mission, the Sentinel-5 Precursor (Sentinel-5P), is one of the European Space Agency's (ESA) new mission family – Sentinels. The sole payload on Sentinel-5P is the TROPOspheric Monitoring Instrument (TROPOMI), a nadir-viewing 108⁰ field-of-view push-broom grating hyperspectral spectrometer, covering the wavelengths of ultraviolet-visible (270 nm - 495 nm), near infrared (675 nm - 775 nm), and shortwave infrared (2305 nm - 2385 nm). Sentinel-5P is the first of the Atmospheric Composition Sentinels, and is providing measurements of atmospheric chemistry, aerosols, and clouds at high spatial, temporal, and spectral resolution. The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) supports over a thousand data collections in the focus areas of Atmospheric Composition, Water & Energy Cycles, and Climate Variability. Sentinel-5P TROPOMI Level-1B (L1B) and Level-2 (L2) products are curated at the GES DISC. Sentinel-5P data are provided by the European Union and the European Space Agency (ESA) through an agreement between ESA and NASA. Through its convenient and enhanced tools/services, such as OPeNDAP and L2 Subsetting, GES DISC offers the air quality remote sensing user community facile solutions for using complex Earth science data and applications. This presentation will demonstrate up-to-date TROPOMI products including EarthView (EV) radiance, solar irradiance, Aerosol Index, Carbon Monoxide, Total column Ozone, Nitrogen Dioxide, and cloud, as well as easy ways to access, visualize and subset TROPOMI data.

TROPOMI↗
NASA NTRS2011

Dawn Maps the Surface Composition of Vesta

By 7-October-2011, the Dawn mission will have completed Survey orbit and commenced high altitude mapping of 4-Vesta. We present a preliminary analysis of data acquired by Dawn's Framing Camera (FC) and the Visual and InfraRed Spectrometer (VIR) to map mineralogy and surface temperature, and to detect and quantify surficial OH. The radiometric calibration of VIR and FC is described. Background counting data acquired by GRaND are used to determine elemental detection limits from measurements at low altitude, which will commence in November. Geochemical models used in the interpretation of the data are described. Thermal properties, mineral-, and geochemical-data are combined to provide constraints on Vesta s formation and thermal evolution, the delivery of exogenic materials, space weathering processes, and the origin of the howardite, eucrite, and diogenite (HED) meteorites.

Prettyman, T.↗
NASA NTRS1990

Fiber-coupled high resolution infrared array spectrometer for the Kuiper Airborne Observatory

A novel cryogenic grating spectrometer (FCAS) is being designed for observations of volatiles in cometary and planetary atmospheres, and in newly forming planetary systems. The instrument features two-dimensional detector arrays coupled to a high-dispersion echelle by infrared fibers, and will achieve a spectral resolving power of about 40,000. The primary observational platform for this instrument will be the Kuiper Airborne Observatory, but it will also be configured for use at ground-based observatories. Initially, the spectrometer will use a 58 x 62, 1- to 5-micron InSb array. Larger-format IR arrays and arrays of different composition, will later be incorporated as they become available. The instrument will be used in two modes. The first uses a large format IR array in the spectral image plane for the customary one-dimensional spectral-one-dimensional spatial coverage. In the second mode, a massive, coherent bundle of infrared transmitting ZrF4 fibers will be installed after the dispersive element, to reformat the two-dimensional array into an elongated one-dimensional array for wide spectral coverage, allowing multiple lines to be measured in a single integration with high sensitivity. The overall instrument design is discussed, and the system sensitivity is estimated.

Glenar, D. A.↗
NASA NTRS2014

Compositional Diversity of the Vestan Regolith Derived from Howardite Compositions and Dawn VIR Spectra

Howardite, eucrite and diogenite meteorites likely come from asteroid 4 Vesta [1]. Howardites - physical mixtures of eucrites and diogenites - are of two subtypes: regolithic howardites were gardened in the true regolith; fragmental howardites are simple polymict breccias [2]. The Dawn spacecraft imaged the howarditic surface of Vesta with the visible and infrared mapping spectrometer (VIR) resulting in qualitative maps of the distributions of distinct diogenite-rich and eucrite-rich terranes [3, 4]. We are developing a robust basis for quantitative mapping of the distribution of lithologic types using spectra acquired on splits of well-characterized howardites [5, 6]. Spectra were measured on sample powders sieved to <75 μm in the laboratories of the Istituto di Astrofisica e Planetologia Spaziali and Brown University. Data reduction was done using the methods developed to process Dawn VIR spectra [4]. The band parameters for the ~1 and ~2 μm pyroxene absorption features (hereafter BI and BII) can be directly compared to Dawn VIR results. Regolithic howardites have shallower BI and BII absorptions compared to fragmental howardites with similar compositions. However, there are statistically significant correlations between Al or Ca contents and BI or BII center wavelengths regardless of howardite subtype. Diogenites are poor in Al and Ca while eucrites are rich in these elements. The laboratory spectra can thus be directly correlated with the percentage of eucrite material contained in the howardites. We are using these correlations to quantitatively map Al and Ca distributions, and thus the percentage of eucritic material, in the current regolith of Vesta.

Mittlefehldt, D. W.↗
NASA NTRS1992

Geologic remote sensing - New technology, new information

Results of geologic studies using data collected by the NASA/JPL Thermal Infrared Imaging Spectrometer (TIMS), Airborne Visible/Infrared Imaging Spectrometer (AVIRIS), and the Airborne Synthetic Aperture Radar (AIRSAR) are discussed. These instruments represent prototypes for the Earth Observing System (EOS) satellite instruments ASTER, High Resolution Imaging Spectrometer (HIRIS), and EOS SAR. Integrated analysis of this data type is one of the keys to successful geologic research using EOS. TIMS links the physical properties of surface materials in the 8-12-*mm region to their composition. Calibrated aircraft data make direct lithological mapping possible. AVIRIS, an analog for HIRIS, provides quantitative information about the surface composition of materials based on their detailed visible and infrared spectral signatures (0.4-2.45 mm). Calibrated AVIRIS data make direct identification of minerals possible. The AIRSAR provides additional complementary information about the surface morphology of rocks and soils.

Kruse, F. A.↗
NASA NTRS1992

A high-resolution atlas of the infrared spectrum of the Sun and the Earth atmosphere from space. Volume 3: Key to identification of solar features

During the period April 29 through May 2, 1985, the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment was operated as part of the Spacelab-3 (SL-3) payload on the shuttle Challenger. The instrument, a Fourier transform spectrometer, recorded over 2000 infrared solar spectra from an altitude of 360 km. Although the majority of the spectra were taken through the limb of the Earth's atmosphere in order to better understand its composition, several hundred of the 'high-sun' spectra were completely free from telluric absorption. These high-sun spectra recorded from space are, at the present time, the only high-resolution infrared spectra ever taken of the Sun free from absorptions due to constituents in the Earth's atmosphere. Volumes 1 and 2 of this series provide a compilation of these spectra arranged in a format suitable for quick-look reference purposes and are the first record of the continuous high-resolution infrared spectrum of the Sun and the Earth's atmosphere from space. In the Table of Identifications, which constitutes the main body of this volume, each block of eight wavenumbers is given a separate heading and corresponds to a page of two panels in Volume 1 of this series. In addition, three separate blocks of data available from ATMOS from 622-630 cm(exp -1), 630-638 cm(exp -1) and 638-646 cm(exp -1), excluded from Volume 1 because of the low signal-to-noise ratio, have been included due to the certain identification of several OH and NH transitions. In the first column of the table, the corrected frequency is given. The second column identifies the molecular species. The third and fourth columns represent the assigned transition. The fifth column gives the depth of the molecular line in millimeters. Also included in this column is a notation to indicate whether the line is a blend or lies on the shoulder(s) of another line(s). The final column repeats a question mark if the line is unidentified.

Geller, Murray↗
NASA NTRS2015

Characterization of Synthetic and Natural Manganese Oxides as Martian Analogues

Recent discoveries of highly concentrated manganese oxides in Gale Crater and on the rim of Endeavour Crater by the Mars Science Laboratory Curiosity and Mars Exploration Rover Opportunity, respectively, imply more highly oxidizing aqueous conditions than previously recognized. Manganese oxides are a significant environmental indicator about ancient aqueous conditions, provided the phases can be characterized reliably. Manganese oxides are typically fine-grained and poorly crystalline, making the mineral structures difficult to determine, and they generally have very low visible reflectance with few distinctive spectral features in the visible to near infrared, making them a challenge for interpretation from remote sensing data. Therefore, these recent discoveries motivate better characterization using methods available on Mars, particularly visible to near infrared (VNIR) spectroscopy, X-ray diffractometry (XRD), and compositional measurements. Both rovers have complementary instruments in this regard. Opportunity is equipped with its multispectral visible imager, Pancam, and an Alpha Particle X-ray Spectrometer (APXS), and Curiosity has the multispectral Mastcam, ChemCam (laser-induced breakdown spectroscopy and passive spectroscopy), and APXS for in situ characterization, and ChemMin (XRD) for collected samples.

Fox, V. K.↗
NASA NTRS2018

Using Mineralogy of the Bagnold Dune Field in Gale Crater to Interpret Eolian Sediment Sorting on the Martian Surface

The Mars Science Laboratory Curiosity rover landed in Gale crater in August 2012 to characterize modern and ancient surface environments. Curiosity executed a two-phase campaign to study the morphology, activity, physical properties, and chemical and mineralogical composition of the Bagnold Dune Field, an active eolian dune field on the lower slopes of Aeolis Mons (Mount Sharp). Detectable aspects of dune sand mineralogy have been examined from orbit with the visible/short-wave infrared spectrometer CRISMand the thermal-infrared spectrometers THEMIS and TES. CRISM data demonstrate variations in plagioclase, pyroxene, and olivine abundances across the dune field. Curiosity analyzed sediments from two locations in the dune field to evaluate the causes of the mineralogical differences observed from orbit. The Gobabeb sample was collected from Namib Dune, a barchanoidal dune on the upwind margin of the dune field, and the Ogunquit Beach sample was collected from the Mount Desert Island sand patch located downwind from Namib. These samples were sieved to <150 μm and delivered to the CheMin X-ray diffraction instrument for quantitative mineralogical analysis. CRISM-derived mineralogy of the Namib Dune and Mount Desert Island and CheMin-derived mineralogy of the Gobabeb and Ogunquit Beach samples can be used in a value-added manner to interpret grain segregation at the bedform to dune-field scale and evaluate contributions from local sediment sources. Models of CRISM data demonstrate that Mount Desert Island is more enriched in olivine and less enriched in plagioclase than Namib dune, suggesting that fine-grained mafic sediments are preferentially mobilized downwind. Curiosity data indicate olivine also forms a coarse lag on the lee sides of barchanoidal dunes. Minor abundances of hematite, quartz, and anhydrite and small differences in the crystal chemistry of plagioclase and pyroxene derived from CheMin data suggest that sediments from the underlying lacustrine rocks also contribute to the Bagnold sands.

Rampe, E. B.↗
NASA NTRS1984

A search for the 10-micron silicate feature in periodic Comet Grigg-Skjellerup

A 10-micron spectrum of periodic Comet Grigg-Skjellerup was obtained on 22 June 1982 with the UCL array spectrometer at the United Kingdom Infrared Telescope, Mauna Kea. No emission feature is obvious in the spectrum. The observed spectrum can be fit equally well by a model of small hot absorbing grains or by a composite model with less than or equal to 30 percent (3sigma) warm, 'dirty' silicate grains. The latter model is consistent with the silicate abundance in Comet Kohoutek, which did display an emission feature at 10 microns.

Hanner, M.↗
NASA NTRS1993

The Pluto fast flyby mission: Completing the reconnaissance of the solar system

The concept of a fast flyby mission to Pluto has been advanced as a means to complete the reconnaissance of the known solar system. In order to acquire data on the Pluto system at the earliest possible time, and within the professional lifetime of investigators now active in the field, concepts are being developed for relatively small spacecraft in the mass range of 70 Kg to 350 Kg with flight times to Pluto of 7 to 13 years. Necessarily, the science complement on such a mission will be very mass and power limited. The challenge will be to define a spacecraft and an instrument package that will maximize the scientific return within these limitations. Cost, of course, will be a major consideration, and funds for new technology development specific to this mission will not be extensive. Consequently, innovative ways to incorporate elegant simplicity into the designs must be found. In order to facilitate exploration of the Pluto-Charon system, fully integrated science payloads must be developed. Two proposed mission designs involving limited mass and power science payloads have been presented to the Outer Planets Science Working Group (OPSWG). These payload mass allocations range from 5 to 30 kilograms with power allocations as low as 5 watts. The drivers behind these low mass and power allocations are that they enable developing missions to fit within the moderate mission cost profile and allow fast flight times to Pluto (7 to 13 years). The OPSWG has prioritized science goals for this class of reconnaissance mission. Three specific science objectives were identified as the highest priority required for the first Pluto mission. These goals were: (1) study of the neutral atmosphere, (2) geology and morphology, and (3) surface compositional mapping. In order to achieve these science goals within the constraints of low mass, power and cost, it may be necessary to combine the functions of 3 conventional instruments (CCD camera, Ultra-Violet Spectrometer, and Infrared Spectrometer) into one fully integrated payload. Where possible, this payload would share optics, mechanisms, electronics and packaging.

Henry, Paul K.↗
NASA NTRS1991

Stratospheric profiles of heavy water vapor isotopes and CH3D from analysis of the ATMOS Spacelab 3 infrared solar spectra

The isotopic composition of stratospheric water vapor and methane was investigated. Stratospheric profiles of HDO, (H-18)2O, (H-17)2O, and CH3D were derived from solar occultation spectra recorded on April 30 - May 1, 1985 by the Atmospheric Trace Molecule Spectroscopy Fourier transform spectrometer aboard Spacelab 3. The profiles of the three water-vapor isotopes showed an increase in the volume mixing ratio with altitude. The measured profiles of D/H in water vapor showed a large depletion in the lower stratosphere (about 63 percent relative to standard mean ocean water, SMOW, at 20 km) and a small increase in D/H with altitude at higher altitudes, up to 34 km. The D/H ratio in stratospheric methane was close to the corresponding isotopic ratio in SMOW.

Rinsland, C. P.↗
NASA NTRS2000

NASA Participation in the ISAS MUSES C Asteroid Sample Return Mission

NASA and Japan's Institute of Space and Astronautical Science (ISAS) have agreed to cooperate on the first mission to collect samples from the surface of an asteroid and return them to Earth for in-depth study. The MUSES-C mission will be launched on a Japanese MV launch vehicle in January 2002 from Kagoshima Space Center, Japan, toward a touchdown on the asteroid Nereus in September 2003. A NASA-provided miniature rover will conduct in-situ measurements on the surface. The asteroid samples will be returned to Earth by MUSES-C via a parachute-borne recovery capsule in January 2006. NASA and ISAS will cooperate on several aspects of the mission, including mission support and scientific analysis. In addition to providing the rover, NASA will arrange for the testing of the MUSES-C re-entry heat shield at NASA/Ames Research Center, provide supplemental Deep Space Network tracking of the spacecraft, assist in navigating the spacecraft and provide arrangements for the recovery of the sample capsule at a landing site in the U. S. Scientific coinvestigators from the U.S. and Japan will share data from the instruments on the rover and the spacecraft. They will also collaborate on the investigations of the returned samples. With a mass of about I kg, the rover experiment will be a direct descendant of the technology used to build the Sojourner rover. The rover will carry three science instruments: a visible imaging camera, a near-infrared point spectrometer and an alpha X ray spectrometer. The solarpowered rover will move around the surface of Nereus collecting imagery data which are complimentary to the spacecraft investigation. The imaging system will be capable of making surface texture, composition, and morphology measurements at resolutions better than 1 cm. The rover will transmit this data to the spacecraft for relay back to Earth. Due to the microgravity environment on Nereus, the rover has been designed to right itself in case it flips over. Solar panels on all sides of the rover will ensure that enough power will always be available to the rover to activate the motors needed to turn over. Posable struts will allow the rover to position its chassis such that the camera can be pointed straight down at the surface or straight up at the sky. The presentation will describe the mission, scientific objectives and current state of the rover in detail.

Jones, Ross↗
NASA NTRS1973

A composite study of cloud, ozone and other data from recent satellite experiments

Pictorial data from the Image Dissector Camera System (IDCS) and Temperature-Humidity Infrared Radiometer (THIR) experiments on Nimbus 4 satellite are analyzed along with: (a) global total ozone maps prepared from Infrared Interferometer Spectrometer (IRIS) data and (b) total ozone and its vertical distribution as derived from Backscatter Ultraviolet (BUV) spectrometer data. A close relationship is generally observed between centers of high ozone and vortices in the IDCS and THIR montages. This is also confirmed by low centers in the 200 mb Northern Hemisphere charts. The vertical distribution of ozone indicates that the enhancement in ozone in these cases occurs in the lower stratosphere (and possibly to a minor extent in the troposphere) rather than in the upper stratosphere and mesosphere.

Rao, M. S. V.↗
NASA NTRS1990

Thermal Infrared Imaging Spectrometer - An advanced optics technology instrument

Through the use of a special optical filter, the Thermal Infrared Imaging Spectrometer, an airborne multispectral IR imaging instrument operating in the thermal emission region (7.5-14 microns), will achieve signal-to-noise ratios greater than 600 with ambient temperature optics. This instrument will be used to do compositional surface mapping of the terrain, and will refine the ability to categorize rock families and types by providing much higher spectral resolution in the emission region than was previously available. Details of the optical system, the detector, the cooler system, and the support electronics are described.

Mahoney, Colin↗
NASA NTRS2013

Constraints on the Compositions of Phobos and Deimos from Mineral Absorptions

The compositions of Phobos and Deimos have remained controversial despite multiple Earth- and space-based observations acquired during the last 40 years. Phobos is composed of at least two spectral units that are both dark yet distinct at visible to near infrared wavelenghts; a spectrally red-sloped "red" unit covers most of the moon and a less red-sloped "blue" unit is present in the ejecta of the approximately 9-km diameter impact crater Stickney [1,2]. Deimos is similar spectrally to Phobos' "red" unit [2]. Here we report results from mapping mineral absorptions on Phobos and Deimos using visible/near infrared observations from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM). We find evidence for an absorption feature at 0.65 m in the Phobos red unit and Deimos that is reproducible in observations from other instruments. The phase responsible is uncertain but may be a Fe-bearing phyllosilicate and/or graphite, consistent with the notion that Phobos and Deimos have compositions similar to CM carbonaceous chondrites [3].

Fraeman, A. A.↗
NASA NTRS2003

Analysis of Multispectral Galileo SSI Images of the Conamara Chaos Region, Europa

Multispectral imaging of Europa s surface by Galileo s Solid State Imaging (SSI) camera has revealed two major surface color units, which appear as white and red-brown regions in enhanced color images of the surface (see figure). The Galileo Near- Infrared Mapping Spectrometer (NIMS) experiment suggests that the whitish material is icy, almost pure water ice, while the spectral signatures of the reddish regions are dominated by a non-ice material. Two endmember models have been proposed for the composition of the non-ice material: magnesium sulfate hydrates [1] and sulfuric acid and its byproducts [2]. There is also debate concerning whether the origin of this non-ice material is exogenic or endogenic [3].Goals: The key questions this work addresses are: 1) Is the non-ice material exogenic or endogenic in origin? 2) Once emplaced, is this non-ice material primarily modified by exogenic or endogenic processes? 3) Is the non-ice material within ridges, bands, chaos, and lenticulae the same non-ice material across all such geological features? 4) Does the distribution of the non-ice material provide any evidence for or against any of the various models for feature formation? 5) To what extent do the effects of scattered light in SSI images change the spectral signatures of geological features?

Spaun, N. A.↗