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At least 253 records · Page 14

Phase Separation, Capillarity, and Odd-Surface Flows in Chiral Active Matter

Active phase separations evade canonical thermodynamic descriptions and have thus challenged our understanding of coexistence and interfacial phenomena. Considerable progress has been made towards a nonequilibrium theoretical description of these traditionally thermodynamic concepts. Spatial parity symmetry is conspicuously assumed in much of this progress, despite the ubiquity of chirality in experimentally realized systems. Here, in this Letter, we derive a theory for the phase coexistence and interfacial fluctuations of a system that microscopically violates spatial parity. We find suppression of the phase separation as chirality is increased as well as the development of steady-state currents tangential to the interface dividing the phases. These odd flows are irrelevant to stationary interfacial properties, with stability, capillary fluctuations, and surface area minimization determined entirely by the capillary surface tension. Using large-scale Brownian dynamics simulations, we find excellent agreement with our theoretical scaling predictions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Lattice Strain Measurement of Core@Shell Electrocatalysts with 4D Scanning Transmission Electron Microscopy Nanobeam Electron Diffraction

Strain engineering enables the direct modification of atomic bonding and is currently an active area of research aimed at improving electrocatalytic activity. However, directly measuring the lattice strain of individual catalyst nanoparticles is challenging, especially at the scale of a single unit cell. In this study, we quantitatively map the strain present in rhodium@platinum (core@shell) nanocube electrocatalysts using conventional aberration-corrected scanning transmission electron microscopy (STEM) and the recently developed technique of 4D-STEM nanobeam electron diffraction. We demonstrate that 4D-STEM combined with data preconditioning allows for quantitative lattice strain mapping with subpicometer precision and without the influence of scan distortions. When combined with multivariate curve resolution, 4D-STEM allows us to distinguish the nanocube core from the shell and to quantify the unit cell size as a function of distance from the core–shell interface. Our results demonstrate that 4D-STEM has significant precision and accuracy advantages in strain metrology of catalyst materials compared to aberration-corrected STEM imaging and is beneficial for extracting information about the evolution of strain in catalyst nanoparticles.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Buckling Imperfection Sensitivity of Conical Sandwich Composite Structures for Launch-Vehicles

Structural stability can be an important consideration in the design of large composite shell structures and therefore it is important to understand the buckling response of such structures. It is well known that geometric imperfections can significantly influence the buckling response of such structures by causing the buckling loads to be significantly lower than the theoretical buckling load of a geometrically perfect shell structure. Results are presented of an analytical study on the buckling imperfection sensitivity of large-scale conical sandwich structures for launch vehicles. In particular, representative structures from the Space Launch System launch-vehicle development activities will be considered. The study considered composite sandwich conical structures with multiple sandwich core thicknesses and facesheet layups consisting of tape and fabric composite layups. The results of this analytical study indicate that there is conservatism in the NASA current buckling knockdown factor of 0.33 for conical shell structures. Therefore, it is suggested that the buckling response of composite sandwich cones be further investigated through buckling tests and analytical predictions to potentially revise the buckling design recommendations for conical composite structures.

Sleight, David W.↗

Theoretical Study of C-H Bond Cleavage via Concerted Proton-Coupled Electron Transfer in Fluorenyl-Benzoates

Developing new strategies to activate and cleave C-H bonds is important for a broad range of applications. Recently a new approach for C-H bond activation using multi-site concerted proton-coupled electron transfer (PCET) involving intermolecular electron transfer to an oxidant coupled to intramolecular proton transfer was reported. For a series of oxidants reacting with 2-(9H-fluoren-9-yl)benzoate, experimental studies revealed an atypical Brønsted a, defined as the slope of the logarithm of the PCET rate constant versus the logarithm of the equilibrium constant or the scaled driving force. Herein this reaction is modeled with a vibronically nonadiabatic PCET theory. Hydrogen tunneling, thermal sampling of the proton donor-acceptor mode, solute and solvent reorganization, and contributions from excited vibronic states are found to play important roles. The calculations qualitatively reproduce the experimental observation of a Brønsted a significantly less than 0.5 and explain this shallow slope in terms of exoergic processes between pairs of electron-proton vibronic states. These fundamental mechanistic insights may guide the design of more effective strategies for C-H bond activation and cleavage.

Sayfutyarova, Elvira R.↗

Materials for Advanced Ultra-Supercritical (A-USC) Steam Turbines --- A-USC Component Demonstration

The U.S. Advanced Ultra-Supercritical (A-USC) Consortium was formed in 2001 as a government/industry program, sponsored by the U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) and cost shared by industrial and not-for-profit partners. The purpose of the consortium was to advance the state of the art for power generation by evaluating and developing materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 1400°F (760°C), can increase the efficiency of coal-fired boilers from an average of 35% (current U.S. fleet) to more than 45% higher heating value (HHV) (>49% lower heating value [LHV]). The increase in a plant’s efficiency is limited unless new materials able to withstand these higher operating temperatures and pressures are identified and approved for use. The A-USC Consortium identified these needed materials during earlier phases of the program. It developed the welding and joining techniques along with manufacturing processes for casting and wrought products made from these new high-nickel alloys. It subjected these materials to extensive laboratory and steam loop testing. It then obtained ASME code approval for their use in U.S. boiler systems. The program’s successes leave this last remaining activity (ComTest Phase 2) that the U.S. utility industry has recommended to be accomplished prior to commercialization. The focus of the activity is the evaluation and demonstration of commercial readiness for “full scale” components to be made from these nickel-based alloy materials and provided by a U.S. domestic supply chain that is new to working with these alloys. According to studies completed by the Electric Power Research Institute (EPRI), the cost of an A-USC plant is approximately 20% higher than a non-A-USC plant because of its use of nickel-based alloys needed for the high temperature operating conditions. However, CO 2 reductions of approximately 30% from the current fleet average provide a strong incentive for its consideration. The actual costs and perceived value for CO 2 abatement will determine whether new or retrofitted plants are undertaken, although decisions to build A-USC plants in India would indicate its economic feasibility while also being part of a global carbon emissions strategy. The work by the A-USC Consortium, prior to the start of the ComTest project, has included lab scale and pilot scale materials testing, both in air and oxy-combustion. This testing has included air-cooled and steam-cooled “loops” that were installed into existing operating utility boilers to gain exposure of these materials to realistic conditions of high temperature and corrosion caused by the constituents in the coal ash. The A-USC Consortium also gained ASME Code approval of the Inconel 740 material, has cast and extruded the largest high nickel precipitation hardened alloys, and developed unique welding techniques to avoid problems identified by the competing European program. However, as valuable as these material test loops and accomplishments have been for obtaining information, their scale is below that required to minimize the risk associated for a U.S. utility to build a multibillion-dollar A-USC power plant. To reduce the final identified risk barrier to full-scale commercialization of these advanced materials and systems, the A-USC Consortium (guided by a utility industry advisory committee) has identified the key areas of the technology they desire to see as being capable of full-scale manufacturing and/or fabrication from an identified, capable U.S. domestic supplier base. A significant amount of work was accomplished during Phase 1 to identity the components, as well as the component size, that would be manufactured from advanced alloys such as Inconel 740H or Haynes 282 alloys. Pathways to supply these components for ComTest have been identified, as well as any further development that would be required. The Phase 2 effort used Phase 1 findings for designing these key full-scale components for A-USC boilers and turbines to include large castings; extrusions, forgings, fabrication of water walls and steam loops with headers from advanced materials, raw material (such as pipe extrusion billets) are at the commercial readiness level to permit advancement to a demonstration project. The Phase 2 work scope was addressed by a diverse team, including government, industry, and not-for-profit partners. The work scope under Phase 2 addressed fabrication of components identified as being outside of the proven capabilities of the existing supply chain, including the following: Steam turbine rotor forging and Haynes 282 nozzle carrier casting Superheater and reheater header and tube assemblies Large-diameter pipe extrusions and forgings Test valve articles to support ASME Code approval. In addition, key fabrication steps were completed, including boiler weld overlays and simulated field repairs. Throughout, extensive inspection and quality assurance testing of the components were performed. The team worked to advance ASME Code approval for key components and processes. Although much of the focus of ComTest Phase 2 was the high-temperature nickel-based alloy materials, a broader range of materials were incorporated, which would be representative of the materials used in full-scale A-USC power plant applications and have cross-cutting applicability on other high-temperature power generation options, such as advanced nuclear, supercritical CO 2 cycles, and central solar receivers. This report that has been submitted is organized in the following manner: Section 1 contains an Executive Summary. Section 2 discusses the ComTest project background and organization. Section 3 discusses project management and reporting. Section 4 discusses the procurement of nickel-based alloy and other A-USC materials and components. Section 5 discusses the fabrication of procurement of nickel-based alloy and other A-USC materials and components. Section 6 discusses the fabrication of cast nickel-based A-USC steam turbine components. Section 7 discusses the fabrication of forged nickel-based A-USC steam turbine piping and steam pipe components. Section 8 discusses the qualification of pressure relieve valves (PRVs) for A-USC power plants. Section 9 discusses proposed plans for future evaluation of A-USC components. Section 10 contains the summary and conclusion.

01 COAL, LIGNITE, AND PEAT↗

Materials dispersion and biodynamics project research

The Materials Dispersion and Biodynamics Project (MDBP) focuses on dispersion and mixing of various biological materials and the dynamics of cell-to-cell communication and intracellular molecular trafficking in microgravity. Research activities encompass biomedical applications, basic cell biology, biotechnology (products from cells), protein crystal development, ecological life support systems (involving algae and bacteria), drug delivery (microencapsulation), biofilm deposition by living organisms, and hardware development to support living cells on Space Station Freedom (SSF). Project goals are to expand the existing microgravity science database through experiments on sounding rockets, the Shuttle, and COMET program orbiters and to evolve,through current database acquisition and feasibility testing, to more mature and larger-scale commercial operations on SSF. Maximized utilization of SSF for these science applications will mean that service companies will have a role in providing equipment for use by a number of different customers. An example of a potential forerunner of such a service for SSF is the Materials Dispersion Apparatus (MDA) 'mini lab' of Instrumentation Technology Associates, Inc. (ITA) in use on the Shuttle for the Commercial MDAITA Experiments (CMIX) Project. The MDA wells provide the capability for a number of investigators to perform mixing and bioprocessing experiments in space. In the area of human adaptation to microgravity, a significant database has been obtained over the past three decades. Some low-g effects are similar to Earth-based disorders (anemia, osteoporosis, neuromuscular diseases, and immune system disorders). As new information targets potential profit-making processes, services and products from microgravity, commercial space ventures are expected to expand accordingly. Cooperative CCDS research in the above mentioned areas is essential for maturing SSF biotechnology and to ensure U.S. leadership in space technology. Currently, the MDBP conducts collaborative research with investigators at the Rockefeller University, National Cancer Institute, and the Universities of California, Arizona, and Alabama in Birmingham. The growing database from these collaborations provides fundamental information applicable to development of cell products, manipulation of immune cell response, bone cell growth and mineralization, and other processes altered by low-gravity. Contacts with biotechnology and biopharmaceutical companies are being increased to reach uninformed potential SSF users, provide access through the CMDS to interested users for feasibility studies, and to continue active involvement of current participants. We encourage and actively seek participation of private sector companies, and university and government researchers interested in biopharmaceuticals, hardware development and fundamental research in microgravity.

Lewis, Marian L.↗

A Summary of NASA Related Contributions for the Remote Sensing of Evapotranspiration in Support of Water Management and Agriculture

The amount of evapotranspiration (ET) to the atmosphere can account for 60% or more of the water loss in many semi-arid locations, and can critically affect local economies tied to agriculture, recreation, hydroelectric power, ecosystems, and numerous other water-related areas. NASA supports many activities using satellite and Earth science data to more accurately and cost effectively estimate ET. NASA ET related work includes the research, development and application of techniques. The free and open access of NASA satellite data and products now permits a much wider application of ET mapping. Typically the NASA supported approaches ranges from large regional and continental ET mapping using MODIS (also with AIRS and CERES), GRACE (gravimetric water balance), geostationary (e.g., GOES and Meteosat for near continental sca|e), land surface modeling (i.e, Land Data Assimilation Systems) to fine scale mapping such as provided bvLandsatdata(<100 m). Usually satellite or airborne thermal imagery are used as input to an ET estimated surface energy balance based approach. There are currently several of these ET approaches under development and implementation including 'METRIC', 'SEBS', 'ALEXI/DisALEXI', etc.. One exception is an approach using GRACE satellite data that estimates the terrestrial water storage using gravimetric data over large areas and estimates ET indirectly. Also land surface modeling within the context of data assimilation and integration schemes provides the capability to integrate in situ, ancillary and satellite together to provide a spatially and synoptic estimates of ET also for use to provide for short-term ET predictions. We will summarize NASA related activities contributing to the improved estimation of ET for water management and agriculture with an emphasis on the Western U3.. This summary includes a description of ET projects in the Middle Rio Grande, Yakima, North Platte and other selected basins in the western US. We will also discuss plans to further address ET applications through working with the USDA and the Group on Earth Observations (GEO) to extend and evaluate western U.S. ET mapping to other parts of the U.S. and internationally.

Toll, David↗

Relations between the Birkeland currents, the auroral electrojet indices and high latitude Joule heating

Field-aligned currents were postulated by Birkeland (1908) to explain the magnetic perturbations in the auroral zone. Theoretical models have been developed to examine the effect of these currents on the ionosphere. These models, in general, involve very extensive computer programs, and it is difficult to see how their very complicated boundary conditions and assumptions affect the relationships between the Birkeland currents and magnetic activity. In the present investigation, a simplified analysis is used to study the average behavior of the large-scale ionospheric current paths and to examine the interrelationships of various parameters. The relationship of the parameters of the current deposition regions to the magnetic indices is investigated along with the polar cap potential. Attention is given to the experimental values of coefficients, and relations between the Birkeland current densities, current intensities, currents, and the AL, AU, AE indices are discussed.

Nisbet, J. S.↗

Roadmap on exsolution for energy applications

Over the last decade, exsolution has emerged as a powerful new method for decorating oxide supports with uniformly dispersed nanoparticles for energy and catalytic applications. Due to their exceptional anchorage, resilience to various degradation mechanisms, as well as numerous ways in which they can be produced, transformed and applied, exsolved nanoparticles have set new standards for nanoparticles in terms of activity, durability and functionality. In conjunction with multifunctional supports such as perovskite oxides, exsolution becomes a powerful platform for the design of advanced energy materials. In the following sections, we review the current status of the exsolution approach, seeking to facilitate transfer of ideas between different fields of application. We also explore future directions of research, particularly noting the multi-scale development required to take the concept forward, from fundamentals through operando studies to pilot scale demonstrations.

25 ENERGY STORAGE↗

Deploying Automation Technology Supporting Packaging and Transportation Operations

Various United States Department of Energy (DOE) sites are investigating the deployment of robotics to provide safer, effective, and more efficient operations. By implementing robotics in packaging and transportation operations, improvements toward production efficiency, worker ergonomics, radiological dose reduction, and security assurance can be realized. Robotic Systems must be designed and implemented in concert with a facility’s safety basis, classification, and security constraints, while improving overall operational effectiveness. The desired robotic implementation should provide a path to potential long-term cost savings, reduce/eliminate hazardous conditions and radiological exposure, while improving quality and reliability of an operation process. The Savannah River Site (SRS), a DOE Site located in Aiken South Carolina, has initiated several large scale projects supporting future nuclear material disposition activities. Incorporation of automation and robotic equipment in system designs will support effective and efficient material handling operations, including container movements and packaging activities. Robotic systems will execute tasks that are precise, procedural and integrated with control systems to verify and record data for material inventory and historical archiving. An overview of the current robotic system development to perform receipt inspection, packaging, storage and shipment preparation activities of designated Type A and B shipping packages will be presented.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Reinforcements: The key to high performance composite materials

Better high temperature fibers are the key to high performance, light weight composite materials. However, current U.S. and Japanese fibers still have inadequate high temperature strength, creep resistance, oxidation resistance, modulus, stability, and thermal expansion match with some of the high temperature matrices being considered for future aerospace applications. In response to this clear deficiency, both countries have research and development activities underway. Once successful fibers are identified, their production will need to be taken from laboratory scale to pilot plant scale. In such efforts it can be anticipated that the Japanese decisions will be based on longer term criteria than those applied in the U.S. Since the initial markets will be small, short term financial criteria may adversely minimize the number and strength of U.S. aerospace materials suppliers to well into the 21st century. This situation can only be compounded by the Japanese interests in learning to make commercial products with existing materials so that when the required advanced fibers eventually do arrive, their manufacturing skills will be developed.

Grisaffe, Salvatore J.↗

Shaping of the magnetotail from the mantle - Global and local structuring

Kinetic modeling of the properties of magnetotail formation from a plasma mantle source are discussed, and a unified view of the structure of the central part of the magnetotail plasma sheet as well as the structure of its boundary layer is developed. The Tsyganenko magnetic field model for quiet periods of magnetospheric activity is used to trace trajectories of mantle protons in the presence of a uniform dawn-dusk electric field. The present model shows the evolution of the global structure of the tail with a clearly defined central plasma sheet and plasma sheet boundary layer developing from its beginnings as a plasma 'nucleus' in the distant tail current sheet. This large-scale restructuring is accompanied by the creation of small-scale features in the particle distribution functions. It is also shown that complementary ring distribution structures should also exist in the central plasma sheet. The ion distribution functions in the central plasma sheet should take a rather specific form in velocity space with loss regions oriented predominantly orthogonal to the magnetic field.

Ashour-Abdalla, Maha↗

Detecting Spacecraft Anomalies Using LSTMs and Nonparametric Dynamic Thresholding

As spacecraft send back increasing amounts of telemetry data, improved anomaly detection systems are needed to lessen the monitoring burden placed on operations engineers and reduce operational risk. Current spacecraft monitoring systems only target a subset of anomaly types and often require costly expert knowledge to develop and maintain due to challenges involving scale and complexity. We demonstrate the effectiveness of Long Short-Term Memory (LSTMs) networks, a type of Recurrent Neural Network (RNN), in overcoming these issues using expert-labeled telemetry anomaly data from the Soil Moisture Active Passive (SMAP) satellite and the Mars Science Laboratory (MSL) rover, Curiosity. We also propose a complementary unsupervised and nonparametric anomaly thresholding approach developed during a pilot implementation of an anomaly detection system for SMAP, and offer false positive mitigation strategies along with other key improvements and lessons learned during development.

Soderstrom, Tom↗

Modern Scientific Data Governance Framework

Science has entered the era of Big Data with new challenges related to data governance, stewardship, and management. The existing data governance practices must catch up to ensure proper data management. Existing data governance policies and stewardship best practices tend to be disconnected from operational data management practices and enforcement and mainly exist in well-meaning documents or reports. These governance policies are, at best, partially implemented and rarely monitored or audited. In addition, existing governance policies keep adding additional data management steps that require a human, ‘a data steward’, in the loop, and the cost of data management can no longer scale proportionately with the current and future increased data volume and complexity. The goal for developing an updated data governance framework is to modernize scientific data governance to the reality of Big data and align it with the current technology trends such as cloud computing and AI. The goals of this framework are two folds. One is to ensure thoroughness that the governance adequately covers the entire data life cycle. Two, provide a practical approach that offers a consistent and repeatable process for different projects. Three core principles ground this framework. First, focus on just enough governance and prevent data governance from becoming a roadblock toward the scientific process. Remove any unnecessary processes and steps. Second, automate data management steps where possible. Actively remove steps that require ‘human in the loop’ within the management process to be efficient and scale with increasing data. Third, all the processes should continually be optimized using quantified metrics to streamline the monitoring and auditing workflows.

Rahul Ramachandran↗

Underground Hydrogen Storage: Transforming Subsurface Science into Sustainable Energy Solutions

As the global economy moves toward net-zero carbon emissions, large-scale energy storage becomes essential to tackle the seasonal nature of renewable sources. Underground hydrogen storage (UHS) offers a feasible solution by allowing surplus renewable energy to be transformed into hydrogen and stored in deep geological formations such as aquifers, salt caverns, or depleted reservoirs, making it available for use on demand. This study thoroughly evaluates UHS concepts, procedures, and challenges. This paper analyzes the most recent breakthroughs in UHS technology and identifies special conditions needed for its successful application, including site selection guidelines, technical and geological factors, and the significance of storage characteristics. The integrity of wells and caprock, which is important for safe and efficient storage, can be affected by the operating dynamics of the hydrogen cycle, notably the fluctuations in pressure and stress within storage formations. To evaluate its potential for broader adoption, we also examined economic elements such as cost-effectiveness and the technical practicality of large-scale storage. We also reviewed current UHS efforts and identified key knowledge gaps, primarily in the areas of hydrogen–rock interactions, geochemistry, gas migration control, microbial activities, and geomechanical stability. Resolving these technological challenges, regulatory frameworks, and environmental sustainability are essential to UHS’s long-term and extensive integration into the energy industry. This article provides a roadmap for UHS research and development, emphasizing the need for further research to fully realize the technology’s promise as a pillar of the hydrogen economy.

25 ENERGY STORAGE↗

Current and Future Rocket Propulsion Testing at NASA Stennis Space Center

Year 2000 has been an active one for large-scale propulsion testing at the NASA John C. Stennis Space Center. This paper highlights several of the current-year test programs conducted at the Stennis Space Center (SSC) including the X-33 Aerospike Engine, Ultra Low Cost Engine (ULCE) program, and the Hybrid Sounding Rocket (HYSR) program. Future directions in propulsion test are also introduced including the development of a large-scale Rocket Based Combined Cycle (RBCC) test facility.

Ryan, H. M.↗

Firesense: Supporting Operational Partners Through Co-Development

Fire is a natural disturbance and fundamental to many ecosystems, but, across the United States and many areas globally, fires have become more common, larger and more likely to occur at the same time. This has the potential to challenge resource allocation and response and requires coordinated integration of technology and tools at the spatial and temporal scales required by practitioners who make wildland fire management decisions. In the US wildfire is currently managed across state, federal, and tribal agencies who leverage various datasets to guide management decisions. FireSense, a NASA Science Mission Directorate project, aims to develop and deliver trailblazing technology and tools for use before, during, and after wildland fires by working together with land managers and practitioners. FireSense is focused on turning information into solutions by expanding partnerships and collaborations with operational agencies to inform and deliver data and technology to support decisions for wildland fire management. Through implementation across the US and with campaign activities in a variety of landscapes, coordinated research and development work will build upon adaptive and use-inspired approaches that can be put into operation. By leveraging and complementing partner activities through coordinated investment, we support a more comprehensive and cohesive response that can advance fire science to better understand fire behavior and effects through integrated measurement, monitoring and modeling. We present updates from in-progress technology development and field campaigns within the US which include sampling and application across scales with information from multiple sensors collocated with field measurements and highlighting the importance of cross-scale observations during the fire lifecycle. Coordinated investment in new science and technology for the complete fire lifecycle supports a comprehensive and cohesive fire response that help to overcome barriers and anticipate and manage the new reality of extreme fires in a warming world.

Jacquelyn Shuman↗