Search NASA⌕ Search

SEARCH · Search NASA

Results for “Dynamic phases”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
NASA NTRS1972

New considerations for pogo prevention on space shuttle

Recommendations for improving the methodology of pogo suppression for the space shuttle include: Consideration of inter-pump location for accumulator or active device, inclusion of tank outflow effects in dynamic structural analysis, the use of simplified transfer functions in systems studies, three phase dynamic testing program for turbopump with development of dynamic flowmeters, and the use of a linearized mathematical model for engine physics studies.

Rubin, S.↗
DOE OSTI2018

Improvement of Short-Circuit Current Density in GaInP Solar Cells Grown by Dynamic Hydride Vapor Phase Epitaxy

We demonstrate GaInP solar cells grown by dynamic hydride vapor phase epitaxy with improved efficiency through elimination of nonradiative recombination centers. We redesigned our reactor to eliminate unintentional impurities, which led to a reduction of nearly 30 x in dark current. This improvement led to a significantly improved open-circuit voltage of 1.41 V and a band gap-voltage offset of 0.47 V in a device with a rear reflector, achieved without front surface passivation. We demonstrate that the limiting factor toward achieving higher efficiency is control over the emitter thickness. Recombination is high in the unpassivated emitter, but losses can be minimized by designing it to be thin. We show that Se diffusion from the GaAs contact layer into the base is responsible for unintentional thickening of the emitter. Use of reduced contact doping reduces the penetration of Se into the p-GaInP base layer. With improved control of Se diffusion, we achieve 13.0 mA/cm 2 and 15.2% certified efficiency in a single-junction GaInP cell structure that is optically equivalent to the top cell in a GaInP/GaAs tandem.

14 SOLAR ENERGY↗
DOE OSTI2017

Direct evidence of atomic-scale structural fluctuations in catalyst nanoparticles

Rational catalyst design requires an atomic scale mechanistic understanding of the chemical pathways involved in the catalytic process. A heterogeneous catalyst typically works by adsorbing reactants onto its surface, where the energies for specific bonds to dissociate and/or combine with other species (to form desired intermediate or final products) are lower. Here, using the catalytic growth of single-walled carbon nanotubes (SWCNTs) as a prototype reaction, we show that the chemical pathway may in-fact involve the entire catalyst particle, and can proceed via the fluctuations in the formation and decomposition of metastable phases in the particle interior. We record in situ and at atomic resolution, the dynamic phase transformations occurring in a Cobalt catalyst nanoparticle during SWCNT growth, using a state-of-the-art environmental transmission electron microscope (ETEM). The fluctuations in catalyst carbon content are quantified by the automated, atomic-scale structural analysis of the time-resolved ETEM images and correlated with the SWCNT growth rate. We find the fluctuations in the carbon concentration in the catalyst nanoparticle and the fluctuations in nanotube growth rates to be of complementary character. These findings are successfully explained by reactive molecular dynamics (RMD) simulations that track the spatial and temporal evolution of the distribution of carbon atoms within and on the surface of the catalyst particle. We anticipate that our approach combining real-time, atomic-resolution image analysis and molecular dynamics simulations will facilitate catalyst design, improving reaction efficiencies and selectivity towards the growth of desired structure.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2021

Dynamic in situ imaging of methane hydrate formation in coal media

Fast 3D X-ray imaging has proved to provide crucial insights into multi-phase dynamic processes in various geomaterials. In particular, many in situ imaging experiments have been made to study gas-hydrate formation in porous sandy samples. Such imaging is challenging for the methane gas-hydrate formation in coal samples because of the coal micro-porosity structure and lower X-ray contrast. Here we present results of the first dynamic in situ micro-computed tomography experiment of methane-hydrate formation in coal samples. Synchrotron phase-contrast tomography techniques allowed to achieve necessary contrast levels to separate all the materials of interest (gas, water, coal, and gas hydrate) in reconstructed images with high spatial and temporal resolution. The imaging results are compared to the ones from a similar tomographic experiment with sand samples. Methane-hydrate formation is accompanied by the water movements caused by cryogenic water suction that happens in sequences of short fast movements with longer equilibrium states in between. Only one type of the hydrate formation was observed in coal (growth as shells on grain boundaries) as opposed to three types in sand (shells, growth into gas pockets, and inside water volumes). In particular, this leads to a slower hydrateformation speed in coal. For the coal sample, we also observed water extraction from grains, and interpreted it as competitive sorption of methane. Lastly, we visualized the dynamic behavior of this water extraction via microchannels inside the coal grains, and performed nano-tomography imaging of these channels for a better understanding of this phenomenon.

58 GEOSCIENCES↗
DOE OSTI2022

Random Quantum Circuits

Quantum circuits—built from local unitary gates and local measurements—are a new playground for quantum many-body physics and a tractable setting to explore universal collective phenomena far from equilibrium. These models have shed light on longstanding questions about thermalization and chaos, and on the underlying universal dynamics of quantum information and entanglement. In addition, such models generate new sets of questions and give rise to phenomena with no traditional analog, such as dynamical phase transitions in quantum systems that are monitored by an external observer. Quantum circuit dynamics is also topical in view of experimental progress in building digital quantum simulators that allow control of precisely these ingredients. Randomness in the circuit elements allows a high level of theoretical control, with a key theme being mappings between real-time quantum dynamics and effective classical lattice models or dynamical processes. Many of the universal phenomena that can be identified in this tractable setting apply to much wider classes of more structured many-body dynamics.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

NOVEL TECHNIQUE OF POWER CONTROL IN MAGNETRON TRANSMITTERS FOR INTENSE ACCELERATORS

A novel concept of a high-power magnetron transmitter allowing dynamic phase and power control at the frequency of locking signal is proposed. The transmitter compensating parasitic phase and amplitude modulations inherent in Superconducting RF (SRF) cavities within closed feedback loops is intended for powering of the intensity-frontier superconducting accelerators. The con- cept uses magnetrons driven by a sufficient resonant (in- jection-locking) signal and fed by the voltage which can be below the threshold of self-excitation. This provides an extended range of power control in a single magnetron at highest efficiency minimizing the cost of RF power unit and the operation cost. Proof-of-principle of the proposed concept demonstrated in pulsed and CW regimes with 2.45 GHz, 1kW magnetrons is discussed here. A conceptual scheme of the high-power transmitter allowing the dynamic wide-band phase and y power controls is presented and discussed.

Kazakevich, G.↗
DOE OSTI2016

Parity-time symmetry breaking in magnetic systems

The understanding of out-of-equilibrium physics, especially dynamic instabilities and dynamic phase transitions, is one of the major challenges of contemporary science, spanning the broadest wealth of research areas that range from quantum optics to living organisms. By focusing on nonequilibrium dynamics of an open dissipative spin system, we introduce a non-Hermitian Hamiltonian approach, in which non-Hermiticity reflects dissipation and deviation from equilibrium. The imaginary part of the proposed spin Hamiltonian describes the effects of Gilbert damping and applied Slonczewski spin-transfer torque. In the classical limit, our approach reproduces Landau-Lifshitz-Gilbert-Slonczewski dynamics of a large macrospin. Here, we reveal the spin-transfer torque-driven parity-time symmetry-breaking phase transition corresponding to a transition from precessional to exponentially damped spin dynamics. Micromagnetic simulations for nanoscale ferromagnetic disks demonstrate the predicted effect. These findings can pave the way to a general quantitative description of out-of-equilibrium phase transitions driven by spontaneous parity-time symmetry breaking.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2017

Velocity force curves, laning, and jamming for oppositely driven disk systems

Using simulations we examine here a two-dimensional disk system in which two disk species are driven in opposite directions. We measure the average velocity of one of the species versus the applied driving force and identify four phases as function of drive and disk density: a jammed state, a completely phase separated state, a continuously mixing phase, and a laning phase. The transitions between these phases are correlated with jumps in the velocity–force curves that are similar to the behavior observed at dynamical phase transitions in driven particle systems with quenched disorder such as vortices in type-II superconductors. In some cases the transitions between phases are associated with negative differential mobility in which the average absolute velocity of either species decreases with increasing drive. We also consider the situation where the drive is applied to only one species as well as systems in which both species are driven in the same direction with different drive amplitudes. We show that the phases are robust against the addition of thermal fluctuations. Finally, we discuss how the transitions we observe could be related to absorbing phase transitions where a system in a phase separated or laning regime organizes to a state in which contacts between the disks no longer occur and dynamical fluctuations are lost.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2022

Polariton-Based Quantum Memristors

Information processing and storage by the same physical system is emerging as a promising alternative to traditional computing platforms. In turn, this requires the realization of elementary units the memory content of which can be easily tuned and controlled. In this work, we introduce a polariton-based quantum memristor where the memristive nature arises from the intercavity polariton exchange and is controlled by a time-varying atom-cavity detuning. A dynamical hysteresis is characterized by the fluctuations in the instantaneous polariton number, where the history information is encoded into a dynamical phase. Using a Lindblad master-equation approach, we find that features of the quantum memristor dynamics, such as the area and circulation of the hysteresis loop, showcase a kind of “plasticity” controlled by quantum state initialization. This makes this quantum memristor very versatile for a wide range of applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Observation of η-Al41Sm5 reveals motif-aware structural evolution in Al-Sm alloys

Using an effective genetic algorithm, we uncover the structure of a metastable Al41Sm5 phase that supplements its family sharing similar short-range orders. The phase evolves upon heating an amorphous Al-9.7at.%Sm ribbon, produced by melt-spinning. The dynamical phase selection is discussed with respect to the structural connections between the short-range packing motifs in the amorphous precursor and those observed in the selected phases. This dataset includes information such as the crystal structure of Al41Sm5, the short-range packing motifs, experimental and calculated XRD, formation energy of stable and meta-stable phases in the Al-Sm system.

Ye, Zhou↗
DOE OSTI2012

THE LAST STAGES OF TERRESTRIAL PLANET FORMATION: DYNAMICAL FRICTION AND THE LATE VENEER

The final stage of terrestrial planet formation consists of the clean-up of residual planetesimals after the giant impact phase. Dynamically, a residual planetesimal population is needed to damp the high eccentricities and inclinations of the terrestrial planets to circular and coplanar orbits after the giant impact stage. Geochemically, highly siderophile element (HSE) abundance patterns inferred for the terrestrial planets and the Moon suggest that a total of about 0.01 M{sub Circled-Plus} of chondritic material was delivered as 'late veneer' by planetesimals to the terrestrial planets after the end of giant impacts. Here, we combine these two independent lines of evidence for a leftover population of planetesimals and show that: (1) a residual population of small planetesimals containing 0.01 M{sub Circled-Plus} is able to damp the high eccentricities and inclinations of the terrestrial planets after giant impacts to their observed values. (2) At the same time, this planetesimal population can account for the observed relative amounts of late veneer added to the Earth, Moon, and Mars provided that the majority of the accreted late veneer was delivered by small planetesimals with radii {approx}< 10 m. These small planetesimal sizes are required to ensure efficient damping of the planetesimal's velocity dispersion by mutual collisions, which in turn ensures sufficiently low relative velocities between the terrestrial planets and the planetesimals such that the planets' accretion cross sections are significantly enhanced by gravitational focusing above their geometric values. Specifically, we find that, in the limit that the relative velocity between the terrestrial planets and the planetesimals is significantly less than the terrestrial planets' escape velocities, gravitational focusing yields a mass accretion ratio of Earth/Mars {approx}({rho}{sub Circled-Plus }/{rho}{sub mars})(R{sub Circled-Plus }/R{sub mars}){sup 4} {approx} 17, which agrees well with the mass accretion ratio inferred from HSEs of 12-23. For the Earth-Moon system, we find a mass accretion ratio of {approx}200, which, as we show, is consistent with estimates of 150-700 derived from HSE abundances that include the lunar crust as well as the mantle component. We conclude that small residual planetesimals containing about {approx}1% of the mass of the Earth could provide the dynamical friction needed to relax the terrestrial planet's eccentricities and inclinations after giant impacts, and also may have been the dominant source for the late veneer added to Earth, Moon, and Mars.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

The nature of photoinduced phase transition and metastable states in vanadium dioxide

Photoinduced threshold switching processes that lead to bistability and the formation of metastable phases in photoinduced phase transition of VO 2 are elucidated through ultrafast electron diffraction and diffusive scattering techniques with varying excitation wavelengths. We uncover two distinct regimes of the dynamical phase change: a nearly instantaneous crossover into an intermediate state and its decay led by lattice instabilities over 10 ps timescales. The structure of this intermediate state is identified to be monoclinic, but more akin to M 2 rather than M1 based on structure refinements. The extinction of all major monoclinic features within just a few picoseconds at the above-threshold-level (~20%) photoexcitations and the distinct dynamics in diffusive scattering that represents medium-range atomic fluctuations at two photon wavelengths strongly suggest a density-driven and nonthermal pathway for the initial process of the photoinduced phase transition. These results highlight the critical roles of electron correlations and lattice instabilities in driving and controlling phase transformations far from equilibrium.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Plume dynamics and gas-phase molecular formation in transient laser-produced uranium plasmas

The dynamics of expansion, thermodynamics, and chemical reactions in laser-produced plasmas is of general interest for all laser ablation applications. This study investigates the complex morphology and behavior of reactive species in nanosecond laser-produced uranium plasmas. Comparing plasma morphology in various inert and reactive ambient gases provides information about the role of gas-phase chemistry in plume hydrodynamics. Background gases including nitrogen and argon foster collisional interactions leading to more significant plume confinement and the increase in persistence of uranium species. On the other hand, environments containing reactive gases such as oxygen promote chemical reactions between the plasma and ambient species. By comparing the expansion dynamics of uranium plumes in nitrogen, air, and argon, we discover that chemical reactions modify the hydrodynamics of the plume at later times of its evolution in the air background. Furthermore, we observe that varying the concentration of oxygen in the fill gas promotes different reaction pathways that lead to the formation of uranium oxides. The reaction pathways from atoms to diatomic to polyatomic molecules strongly vary with ambient oxygen concentration. Lower oxygen concentrations enhance the formation of uranium monoxide from atomic uranium, whereas higher oxygen concentrations tend to depopulate both atomic uranium and uranium monoxide concentrations through the formation of more complex uranium oxides.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

Analysis of GaAs Solar Cells Grown on 50 mm Wafers at 700 degrees C by Dynamic Hydride Vapor Phase Epitaxy

We grew and analyzed GaAs photovoltaics devices grown by dynamic hydride vapor phase epitaxy (D-HVPE) on 50 mm GaAs substrates. These were grown at 700 degrees C in a kinetically-limited growth regime. These devices exhibited nearly identical performance to our previous single-junction GaAs devices (>25% efficiency) that were grown at 650 degrees C in a transport-limited growth regime. We determined that the relatively low non-uniformity in device efficiency was not related to variations in structural characteristics, such as GaAs base thickness or Ga x In 1-x P composition or thickness, but rather uniformity of the absorber doping. These results show that growth of high quality material is possible in multiple growth regimes by D-HVPE.

14 SOLAR ENERGY↗
DOE OSTI2020

Detecting Phase-Resolved Magnetization Dynamics by Magneto-Optic Effects at 1550 nm Wavelength

We demonstrate the detection of phase-resolved magnetization dynamics with combinatorial magneto-optic Kerr and Faraday effects. The method uses a continuous-wave laser that is amplitude-modulated at the spin dynamic frequencies, and thus allows for coherent tracking of the spin dynamics, akin a “lock-in” type measurement. In particular, our method, using a single 1550-nmwavelength, probes simultaneously the ferromagnetic resonance of Y 3 Fe 5 O 12 (YIG) and Permalloy (Py = Ni 80 Fe 20 ) in a YIG-Pyhetero structure. The fiber-based magneto-optic components also have the advantage of being made into a compact, tabletop or even portable system with yet robust measurement performances. We believe that our method will be found useful in studying hybrid quantum magnonic systems and/or investigating phase-resolved spin dynamics in nanomagnet structures involving both ferromagnetic insulators and metals.

42 ENGINEERING↗