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250 records · Page 14

Integration of In-Flight and Post-Flight Water Monitoring Resources in Addressing the U.S. Water Processor Assembly Total Organic Carbon (TOC) Anomaly

Beginning in June of 2010, the total organic carbon (TOC) concentration in the U.S. Water Processor Assembly (WPA) product water started to increase. A surprisingly consistent upward TOC trend was observed through weekly ISS total organic carbon analyzer (TOCA) monitoring. As TOC is a general organic compound indicator, return of water archive samples was needed to make better-informed crew health decisions on the specific compounds of concern and to aid in WPA troubleshooting. TOCA-measured TOC was more than halfway to the health-based screening limit of 3,000 g/L before archive samples were returned. Archive samples were returned on 22 Soyuz in September 2010 and on ULF5 in November of 2010. The samples were subjected to extensive analysis. Although TOC was confirmed to be elevated, somewhat surprisingly, none of the typical target compounds were detected at high levels. After some solid detective work, it was confirmed that the TOC was associated with a compound known as dimethylsilanediol (DMSD). DMSD is believed to be a breakdown product of siloxanes which are thought to be ubiquitous in the ISS atmosphere. A toxicological limit was set for DMSD and a forward plan was developed for conducting operations in the context of understanding the composition of the TOC measured in flight. This required careful consideration of existing ISS flight rules, coordination with ISS stakeholders, and development of a novel approach for the blending of inflight TOCA data with archive results to protect crew health. Among other challenges, team members had to determine how to utilize TOCA readings when making decisions about crew consumption of WPA water. This involved balancing very real concerns associated with the assumption that TOC would continue to be comprised of only DMSD. Demonstrated teamwork, multidisciplinary awareness, and innovative problem-solving were required to respond effectively to this anomaly.

Straub, John E., II↗

Evaluating Greenland Surface-Mass-Balance and Firn-Densification Data Using ICESat-2 Altimetry

Surface-mass-balance (SMB) and firn-densification (FD) models are widely used in altimetry studies as a tool to separate atmospheric-driven from ice-dynamics-driven ice-sheet mass changes and to partition observed volume changes into ice-mass changes and firn-air-content changes. Until now, SMB models have been principally validated based on comparison with ice core and weather station data or comparison with widely separated flight radar-survey flight lines. Firn-densification models have been primarily validated based on their ability to match net densification over decades, as recorded in firn cores, and the short-term time-dependent component of densification has rarely been evaluated at all. The advent of systematic ice-sheet-wide repeated ice-surface-height measurements from ICESat-2 (the Ice Cloud, and land Elevation Satellite, 2) allows us to measure the net surface-height change of the Greenland ice sheet at quarterly resolution and compare the measured surface-height differences directly with those predicted by three FD–SMB models: MARv3.5.11 (Modèle Atmosphérique Régional version 3.5.11) and GSFCv1.1 and GSFCv1.2 (the Goddard Space Flight Center FD–SMB models version 1.1 and 1.2). By segregating the data by season and elevation, and based on the timing and magnitude of modelled processes in areas where we expect minimal ice-dynamics-driven height changes, we investigate the models' accuracy in predicting atmospherically driven height changes. We find that while all three models do well in predicting the large seasonal changes in the low-elevation parts of the ice sheet where melt rates are highest, two of the models (MARv3.5.11 and GSFCv1.1) systematically overpredict, by around a factor of 2, the magnitude of height changes in the high-elevation parts of the ice sheet, particularly those associated with melt events. This overprediction seems to be associated with the melt sensitivity of the models in the high-elevation part of the ice sheet. The third model, GSFCv1.2, which has an updated high-elevation melt parameterization, avoids this overprediction.

Benjamin E. Smith↗

Land management and climate change determine second‐generation bioenergy potential of the US Northern Great Plains

Bioenergy with carbon capture and storage (BECCS) has been proposed as a potential climate mitigation strategy raising concerns over trade‐offs with existing ecosystem services. We evaluate the feasibility of BECCS in the Upper Missouri River Basin (UMRB), a landscape with diverse land use, ownership, and bioenergy potential. We develop land‐use change scenarios and a switchgrass (Panicum virgatum L.) crop functional type to use in a land‐surface model to simulate second‐generation bioenergy production. By the end of this century, average annual switchgrass production over the UMRB ranges from 60 to 210 Tg dry mass/year and is dependent on the Representative Concentration Pathway for greenhouse gas emissions and on land‐use change assumptions. Under our simple phase‐in assumptions this results in a cumulative total production of 2,000–6,000 Tg C over the study period with the upper estimates only possible in the absence of climate change. Switchgrass yields decreased as average CO2 concentrations and temperatures increased, suggesting the effect of elevated atmospheric CO2 was small because of its C4 photosynthetic pathway. By the end of the 21st century, the potential energy stored annually in harvested switchgrass averaged between 1 and 4 EJ/year assuming perfect conversion efficiency, or an annual electrical generation capacity of 7,000–28,000 MW assuming current bioenergy efficiency rates. Trade‐offs between bioenergy and ecosystem services were identified, including cumulative direct losses of 1,000–2,600 Tg C stored in natural ecosystems from land‐use change by 2090. Total cumulative losses of ecosystem carbon stocks were higher than the potential ~300 Tg C in fossil fuel emissions from the single largest power plant in the region over the same time period, and equivalent to potential carbon removal from the atmosphere from using biofuels grown in the same region. Numerous trade‐offs from BECCS expansion in the UMRB must be balanced against the potential benefits of a carbon‐negative energy system.

climate change↗

Recent Ice Loss from the Fleming and Other Glaciers, Wordie Bay, West Antarctic Peninsula

Satellite radar interferometry data from 1995 to 2004, and airborne ice thickness data from 2002, reveal that the glaciers flowing into former Wordie Ice Shelf, West Antarctic Peninsula, discharge 6.8 +/- 0.3 km(exp 3)/yr of ice, which is 84 +/- 30 percent larger than a snow accumulation of 3.7 +/- 0.8 km(exp 3)/yr over a 6,300 km(exp 2) drainage basin. Airborne and ICESat laser altimetry elevation data reveal glacier thinning at rates up to 2 m/yr. Fifty km from its ice front, Fleming Glacier flows 50 percent faster than it did in 1974 prior to the main collapse of Wordie Ice Shelf. We conclude that the glaciers accelerated following ice shelf removal, and have been thinning and losing mass to the ocean over the last decade. This and other observations suggest that the mass loss from the northern part of the Peninsula is not negligible at present.

Sea level change↗

Atmospheric carbon dioxide concentrations before 2.2 billion years ago

The composition of the Earth's early atmosphere is a subject of continuing debate. In particular, it has been suggested that elevated concentrations of atmospheric carbon dioxide would have been necessary to maintain normal surface temperatures in the face of lower solar luminosity in early Earth history. Fossil weathering profiles, known as palaeosols, have provided semi-quantitative constraints on atmospheric oxygen partial pressure (pO2) before 2.2 Gyr ago. Here we use the same well studied palaeosols to constrain atmospheric pCO2 between 2.75 and 2.2 Gyr ago. The observation that iron lost from the tops of these profiles was reprecipitated lower down as iron silicate minerals, rather than as iron carbonate, indicates that atmospheric pCO2 must have been less than 10(-1.4) atm--about 100 times today's level of 360 p.p.m., and at least five times lower than that required in one-dimensional climate models to compensate for lower solar luminosity at 2.75 Gyr. Our results suggest that either the Earth's early climate was much more sensitive to increases in pCO2 than has been thought, or that one or more greenhouse gases other than CO2 contributed significantly to the atmosphere's radiative balance during the late Archaean and early Proterozoic eons.

NASA Discipline Exobiology↗

Recent Changes in the Greenland Ice Sheet as Seen from Space

Many changes in the Greenland Ice Sheet have been reported in the recent scientific literature and have been attributed to various responses of the ice sheet due to regional (and global) warming. Because melting of the ice sheet would contribute approximately 7 m to sea-level rise, the lives and habitat of hundreds of millions of people worldwide would be directly and indirectly affected if continued ice-sheet melting occurs. As mean-annual global temperatures have increased, there has been an increasing focus on studying the Greenland Ice Sheet using available satellite data, and numerous expeditions have been undertaken. Regional "clear-sky" surface temperature increases since the early 1980s in the Arctic, measured using Advanced Very High Resolution Radiometer (AVHRR) infrared data, range from 0.57+/-0.02 C to 0.72+/-0.10 C per decade. Arctic warming has important implications for ice-sheet mass balance because much of the periphery of the Greenland Ice Sheet is already near O C during the melt season, and is thus vulnerable to more extensive melting if temperatures continue to increase. An increase in melting of the ice sheet would accelerate sea-level rise, an issue of increasing concern to billions of people worldwide. The surface temperature of the ice sheet has been studied in even greater detail using Moderate-Resolution Imaging Spectroradiometer (MODIS) data in the six individual drainage basins as well as for the ice sheet as a whole. Surface temperature trends in the decade of the 2000s have not been strong, according to the MODIS measurements. In addition to surface-temperature increases over the last few decades as measured by AVHRR, other changes have been observed such as accelerated movement of many of Greenland's outlet glaciers and sudden draining of supraglacial lakes. Decreasing mass of the ice sheet since (at least) 2002 has been measured using Gravity Recovery and Climate Experiment (GRACE) data, along with an build-up of ice at the higher elevations and a decrease of ice at the lower elevations as measured using airborne Lidar and Ice, Cloud and Land Elevation Satellite (ICESat) data. The seminar will address the above issues using a variety of NASA satellite data and ground observations.

Hall, Dorothy K.↗

Mass Loss of Larsen B Tributary Glaciers (Antarctic Peninsula) Unabated Since 2002

Ice mass loss continues at a high rate among the large glacier tributaries of the Larsen B Ice Shelf following its disintegration in 2002. We evaluate recent mass loss by mapping elevation changes between 2006 and 201011 using differencing of digital elevation models (DEMs). The measurement accuracy of these elevation changes is confirmed by a null test, subtracting DEMs acquired within a few weeks. The overall 2006201011 mass loss rate (9.0 2.1 Gt a-1) is similar to the 2001022006 rate (8.8 1.6 Gt a-1), derived using DEM differencing and laser altimetry. This unchanged overall loss masks a varying pattern of thinning and ice loss for individual glacier basins. On Crane Glacier, the thinning pulse, initially greatest near the calving front, is now broadening and migrating upstream. The largest losses are now observed for the HektoriaGreen glacier basin, having increased by 33 since 2006. Our method has enabled us to resolve large residual uncertainties in the Larsen B sector and confirm its state of ongoing rapid mass loss.

remote sensing↗

Studies of Vestibular Neurons in Normal, Hyper- and Hypogravity

During the past year, pre-, in- and postflight studies were conducted in association with the Axon project for Bion 10 (Cosmos 2229). Recordings were made during pre- and postflight studies, from 118 horizontal semicircular canal afferents and 27 vestibular nucleus neurons in 7 rhesus monkeys; 137 pulse rotation protocols alone were executed (548 acceleration and deceleration responses were curve fit). Usable data was obtained from 127 horizontal afferents concerning their spontaneous discharge. Curve fits and analysis was made of sinusoidal and sum of sinusoidal responses from 42 and 35 horizontal afferents, respectively. Also recordings were made from neurons inflight from the two flight animals. The mean spontaneous rate varied from 128 spikes/sec. during preflight to 92 spikes/sec during postflight (day 5) - a change of 28%. In direct contrast to the results of Cosmos 2044, the best fitted neural adaptation operator (k) and the gain of the pulse response were decreased during post flight when compared to preflight. Surprisingly, the best fitted gain and k values for the sum of sines were slightly elevated during post flight tests. The gain and phase of single sine responses were compared for pre- and post flight tests and compared to a larger population of afferents. In contrast to Cosmos 2044 results where on the first day of post flight testing the gains of the best fitted sine response were skewed toward the higher values of the Miles and Braitman distribution, the gain of the best fitted sine responses during the first day of post flight testing (day 2) during Cosmos 2229 were exactly on the mode of the Miles and Braitman distribution. Thus, at least for the periodic stimuli, (pulses and sine waves) we found no change in gain and neural adaptation during post flight testing following Cosmos 2229. This conclusion is different from the one derived following the Cosmos 2044 flight. Cosmos flight 2229 differed from Cosmos flight 2044 in several significant ways: For example, during preflight, (1) The animals preflight training was different (less well trained on the gaze task) and (2) the animals were exposed to more experimental manipulations (surgical and rotational). Inflight, (1) the animals were required to make a pointing gesture (motor response) in association with eye movements to obtain reward, (2) the inflight diet was different (more balanced), (3) the feeder for one of the animals clogged following 9 days of flight resulting in evident dehydration and probably less head motion exposure in that monkey and (4) there was limited video taping of the monkeys in space. During postflight, (1) we were unable to test the flight animals until 26 hours postflight as compared to 14.5 hours during Cosmos 2044, (2) the animals received significantly more exposure to motion stimuli during postflight testing than during Cosmos 2044. These differences in the vestibular environment will require analysis of several parameters other than just neural and eye movement responses. For example, computer programs will have to be written and used to recover and quantify the number of head movements made by each animal during flight. This activity is critical to the production of neural adaptation and increased gain.

Correia, Manning J.↗

The Martian Dust Cycle: Observations and Modeling

The dust cycle is critically important for Mars' current climate system. Suspended atmospheric dust affects the radiative balance of the atmosphere, and thus greatly influences the thermal and dynamical state of the atmosphere. Evidence for the presence of dust in the Martian atmosphere can be traced back to yellow clouds telescopically observed as early as the early 19th century. The Mariner 9 orbiter arrived at Mars in November of 1971 to find a planet completely enshrouded in airborne dust. Since that time, the exchange of dust between the planet's surface and atmosphere and the role of airborne dust on Mars' weather and climate has been studied using observations and numerical models. The goal of this talk is to give an overview of the observations and to discuss the successes and challenges associated with modeling the dust cycle. Dust raising events on Mars range in size from meters to hundreds of kilometers. During some years, regional storms merge to produce hemispheric or planet encircling dust clouds that obscure the surface and raise atmospheric temperatures by tens of kelvin. The interannual variability of planet encircling dust storms is poorly understood. Although the occurrence and season of large regional and global dust storms are highly variable from one year to the next, there are many features of the dust cycle that occur year after year. A low-level dust haze is maintained during northern spring and summer, while elevated levels of atmospheric dust occur during northern autumn and winter. During years without global-scale dust storms, two peaks in total dust loading are generally observed: one peak occurs before northern winter solstice and one peak occurs after northern winter solstice. Numerical modeling studies attempting to interactively simulate the Martian dust cycle with general circulation models (GCMs) include the lifting, transport, and sedimentation of radiatively active dust. Two dust lifting processes are commonly represented in these models: wind-stress lifting (i.e., saltation) and dust devil lifting. Although the predicted patterns of dust lifting and atmospheric dust loading from these simulations capture some aspects of the observed dust cycle, there are many notable differences between the simulated and observed dust cycles. For example, it is common for models to predict one peak in global dust loading near northern winter solstice due to excessive dust lifting in the Hellas basin at this season. Additionally, it is difficult for models to realistically capture the observed interannual variability in global dust storms. New avenues of dust cycle modeling research include exploring the effects of finite surface dust reservoirs and the effects of coupling the dust and water cycles on the predicted dust cycle.

Kahre, Melinda A.↗

Crew Performance Support System to Aid in Anomaly Resolution: Concept of Operations

As missions progress into deep space, communication delays and disruptions will disenable the crew’s reliance on Earth experts. There are also limitations in the amount of data that can be downlinked to the ground. It is prudent to assume that critical, complex vehicle or habitat sub-systems will malfunction at a time when a lunar or Mars’ crew cannot rely on the Earth-Support team to detect, diagnose and resolve the problem and it is impractical to expect a small crew to step-in with the same level of expertise as 50+ authorities. The crew will need novel processes and advanced technological support to independently identify and resolve safety- and time-critical anomalies. That a self-reliant crew is unable to respond appropriately to time-critical anomalies is a significant risk to crew safety and mission success. This risk is driven by several factors; novel and unanticipated anomalies would not have been trained pre-flight, the crew could forget their pre-flight training or spaceflight stressors could impair the crew’s problem-solving ability. At last year’s IWS, Beard reported that a single spaceflight stressor (elevated CO2) could undermine the crew’s ability to independently respond to emergencies. Concept of Operations (ConOps) provide a common view of future system functions to all stakeholders. For the current project, a ConOps was developed that describes the operational processes, practices and capabilities needed by a crew of astronauts on deep space missions to autonomously respond to anticipated and unanticipated anomalies. It is crucial to recognize that, as of August 2018 existing technologies are unable to effectively support crew anomaly response to unanticipated events. “Intelligent technology” has not reached a maturity level that permits generalizing a solution to novel situations. For example, to train intelligent technology requires volumes of data that do not exist. The complexities involved in a manned mission to Mars cannot be compared to sending rovers to Mars using scripted software. This ConOps proposes a Crew Performance Support System (CPSS) that will push NASA and its industry partners toward what will be required for a safe and successful manned mission to Mars. Anomaly resolution during a deep space mission will take place within a dynamic, or changing, context. The figure to the left shows five broad contextual variables: the organizational culture, mission context, system characteristics, team characteristics and individual characteristics. The yellow arrow indicates that spaceflight and task-related stressors can affect system, team and individual crewmember characteristics and therefore anomaly response potential. The figure depicts a protective umbrella of Human-System Integration (HSI) principles that should be instituted during CPSS development including a balanced workload, shared situation awareness and building an appropriate level of trust in the automation. The figure also depicts two interrelated and cooperative components, an HSI Data System and other Enabling Capabilities will be required to support crew anomaly response and Earth-Support situation awareness. As we journey from ISS to Gateway to Mars, multiple, simultaneous and integrated research and development efforts (i.e., support systems co-evolution) must be implemented to meet the problem-solving challenges a self-reliant crew will face on a Mars’ mission. The crossovers between the capabilities are just as important as the discrete capabilities themselves. As the capabilities mature, the lines between the support subdomains will blur and an integrated system will emerge. The ConOps summarizes current knowledge about how highly trained people solve anomalies in safety- and time-critical situations, describes a group of capabilities that could help to reduce the extant risk and documents requirements levied on additional systems that provides critical inputs to the CPSS. Scenarios are used to promote a shared understanding of processes, practices and technological goals needed for safe and productive manned missions beyond LEO.

HSIA risk↗

Lumped Parameter Models of the Central Nervous System for VIIP Research

INTRODUCTION: Current long-duration missions to the International Space Station and future exploration-class missions beyond low-Earth orbit, such as to Mars and asteroids, expose astronauts to increased risk of Visual Impairment and Intracranial Pressure (VIIP) syndrome [1]. It has been hypothesized that the headward shift of cerebral spinal fluid (CSF) and blood in microgravity may cause significant elevation of intracranial pressure (ICP), which in turn induces VIIP syndrome through biomechanical pathways [1, 2]. However, there is insufficient evidence to confirm this hypothesis. In this light, we are developing lumped-parameter models of fluid transport in the central nervous system (CNS) as a means to simulate the influence of microgravity on ICP. The CNS models will also be used in concert with the lumped parameter and finite element models of the eye described in the realted IWS abstracts submitted by Nelson et al., Feola et al. and Ethier et al. METHODS: We have developed a nine compartment CNS model (Figure 1) capable of both time-dependent and steady state fluid transport simulations, based on the works of Stevens et al. [3]. The breakdown of compartments within the model includes: vascular (3), CSF (2), brain (1) and extracranial (3). The boundary pressure in the Central Arteries [A] node is prescribed using an oscillating pressure function PA(t) simulating the carotid pulsatile pressure wave as developed by Linninger et al. [4]. For each time step, pressures are integrated through time using an adaptive-timestep 4th and 5th order Runga-Kutta solver. Once pressures are found, constitutive equations are used to solve for flowrates (Q) between each compartment. In addition to fluid flow between the different compartments, compliance (C) interactions between neighboring compartments are represented. We are also developing a second CNS model based on the works of Linninger et al. [4] which takes a more granular approach to represent the interactions of the intracranial and spinal compartments with the inclusion of arteries, arterioles, capillaries, venules, veins, venous sinus, and ventricles. The flow through the arteries, veins and CSF compartments are governed by continuity, momentum and distensibility balance equations. Furthermore, unlike the Stevens et al. approach, the Monro-Kellie doctrine of constant cranial volume and the bi-phasic nature of the brain parenchyma are implemented. These features appear to be more consistent with the physiologic and anatomical behavior of the CNS, and follow a modeling philosophy similar to the lumped parameter eye model that is intended to be integrated with the CNS model. However, Linninger’s approach has never been implemented to include hydrostatic gradient and microgravity simulation capabilities. Therefore, we aim at implement this modeling approach for spaceflight simulations and assess its overall applicability to VIIP research. OBJECTIVES: We will present verification and validation test results for both models, as well as head-to-head comparison to explore their strengths and limitations with respect to mathematical implementation and physiological significance for VIIP research. In doing so, we hope to provide some guidance to the HRP research community on how to appropriately leverage lumped parameter models for space biomedical research.

Vera, J.↗

Platinum-group elements (PGE) and Rhenium in Marine Sediments across the Cretaceous-Tertiary Boundary: Constraints on Re-PGE Transport in the Marine Environment

The nature of Re-platinum-group element (PGE; Pt, Pd, Ir, Os, Ru) transport in the marine environment was investigated by means of marine sediments at and across the Cretaceous-Tertiary boundary (KTB) at two hemipelagic sites in Europe and two pelagic sites in the North and South Pacific. A traverse across the KTB in the South Pacific pelagic clay core found elevated levels of Re, Pt, Ir, Os, and Ru, each of which is approximately symmetrically distributed over a distance of approx. 1.8 m across the KTB. The Re-PGE abundance patterns are fractionated from chondritic relative abundances: Ru, Pt, Pd, and Re contents are slightly subchondritic relative to Ir, and Os is depleted by approx. 95% relative to chondritic Ir proportions. A similar depletion in Os (approx. 90%) was found in a sample of the pelagic KTB in the North Pacific, but it is enriched in Ru, Pt, Pd, and Re relative to Ir. The two hemipelagic KTB clays have near-chondritic abundance patterns. The approx. 1.8-m-wide Re-PGE peak in the pelagic South Pacific section cannot be reconciled with the fallout of a single impactor, indicating that postdepositional redistribution has occurred. The elemental profiles appear to fit diffusion profiles, although bioturbation could have also played a role. If diffusion had occurred over approx. 65 Ma, the effective diffusivities are approx. 10(exp -13)sq cm/s, much smaller than that of soluble cations in pore waters (approx. 10(exp -5) sq cm/s). The coupling of Re and the PGEs during redistribution indicates that postdepositional processes did not significantly fractionate their relative abundances. If redistribution was caused by diffusion, then the effective diffusivities are the same. Fractionation of Os from Ir during the KTB interval must therefore have occurred during aqueous transport in the marine environment. Distinctly subchondritic Os/Ir ratios throughout the Cenozoic in the South Pacific core further suggest that fractionation of Os from Ir in the marine environment is a general process throughout geologic time because most of the inputs of Os and Ir into the ocean have OsAr ratios greater than or = 1. Mass balance calculations show that Os and Re burial fluxes in pelagic sediments account for only a small fraction of the riverine Os (less than 10%) and Re (less than 0.1%) inputs into the oceans. In contrast, burial of Ir in pelagic sediments is similar to the riverine Ir input, indicating that pelagic sediments are a much larger repository for Ir than for Os and Re. If all of the missing Os and Re is assumed to reside in anoxic sediments in oceanic margins, the calculated burial fluxes in anoxic sediments are similar to observed burial fluxes. However, putting all of the missing Os and Re into estuarine sediments would require high concentrations to balance the riverine input and would also fail to explain the depletion of Os at pelagic KTB sites, where at most approx. 25% of the K-T impactor's Os could have passed through estuaries. If Os is preferentially sequestered in anoxic marine environments, it follows that the OsAr ratio of pelagic sediments should be sensitive to changes in the rates of anoxic sediment deposition. There is thus a clear fractionation of Os and Re from Ir in precipitation out of sea water in pelagic sections. Accordingly, it is inferred here that Re and Os are removed from sea water in anoxic marine depositional regimes.

Lee, Cin-Ty Aeolus↗

Mechanisms for vasopressin effects on intraocular pressure in anesthetized rats

Continuous intracameral infusions of a balanced salt solution (0.175 microliter min-1) have been reported to raise intraocular pressure (IOP) in anesthetized rats. Palm et al. (1995) previously reported that this effect was attenuated significantly by inclusion of arginine-vasopressin (AVP, 10 ng 0.175 microliter-1) in the infusate. This study used experimental and computer simulation methods to investigate factors underlying these changes in IOP. First, constant intracameral infusions of artificial cerebrospinal fluid (aCSF) at different fixed rates (0.049-0.35 microliter min-1) were used to estimate the outflow resistance. Secondly, IOP responses were measured during an 2 hr intracameral infusion of either aCSF or AVP that was the sum of a small constant component (0.05 microliter min-1) and a larger periodic component (0.25 microliter min-1, cycling for 4 min on, then 4 min off); the mean infusion rate was 0.175 microliter min-1. As shown previously for 0.175 microliter min-1 constant infusions, the periodic aCSF infusion induced a significant rise in IOP that was attenuated by AVP administration. Complex demodulation analysis and the estimated gain parameter of a second order transfer function fit to the periodic responses indicated that outflow resistance increased significantly during the infusions in both aCSF and AVP groups, but that the indices of resistance did not differ significantly between aCSF and AVP infused eyes. This finding implies that changes in outflow resistance do not explain the difference in IOP responses to intracameral aCSF and AVP. The two responses differed significantly, though, in damping factors, such that the aCSF responses were considerably more underdamped than the AVP responses. It is hypothesized that aCSF-induced increase in IOP reflects both (1) a small component reflecting increased outflow resistance and (2) a larger non-resistive component. Since the non-resistive component is insensitive to pretreatment with acetazolamide, it is suggested that the aCSF-induced elevation in IOP reflects primarily vascular perfusion changes that are reduced by local vasoconstrictor actions of AVP. The latter mechanism likely maintains vascular perfusion of the globe when intraocular hypertension develops.

NASA Discipline Cardiopulmonary↗

Depth and Distribution of CO2 Snow on Mars

The dynamic role of volatiles on the surface of Mars has been a subject of longstanding interest. In the pre-Viking era, much of the debate was necessarily addressed by theoretical considerations. A particularly influential treatment by Leighton and Murray put forth a simple model relying on solar energy balance, and led to the conclusion that the most prominent volatile exchanging with the atmosphere over seasonal cycles is carbon dioxide. Their model suggested that due to this exchange, atmospheric CO2 partial pressure is regulated by polar ice. While current thinking attributes a larger role to H2O ice than did the occasional thin polar coating this model predicted, the CO2 cycle appears to be essentially correct. There are a number of observational constraints on the seasonal exchange of surface volatiles with the atmosphere. The growth and retreat of polar CO2 frost is visible from Earth-based telescopes and from spacecraft in Mars orbit, both at visible wavelengths and in thermal IR properties of the surface. Recently, variations in Gamma ray and neutron fluxes have also been used to infer integrated changes in CO2 mass on the surface. Measurements made by Viking's Mars Atmospheric Water Detector experiment were sensitive to atmospheric H2O vapor abundance. Surface condensates and their transient nature were detected by the Viking landers. The study here is motivated by recent data collected by the Mars Global Surveyor, affording the opportunity to not only detect the lateral distribution of volatiles, but also to constrain the variable volumes of the reservoirs. We elaborate on a technique first employed by Smith et al. By examining averages of a large number of topographic measurements collected by the Mars Orbiter Laser Altimeter (MOLA), that study showed that the zonal pattern of deposition and sublimation of CO2 can be determined. In their first approach, reference surfaces were fit to all measurements in narrow latitude annuli, and the time dependent variations about those mean surfaces were examined. In their second approach, height measurements from pairs of tracks that cross on the surface were interpolated and differenced, forming a set of crossover residuals. These residuals were then examined as a function of time and latitude. The initial studies averaged over longitude to maximize signal and minimize noise in order to isolate the expected small signal. In this follow-up study we now attempt to extract the elevation change pattern also as a function of longitude, and we focus on the crossover approach.

Aharonson, Oded↗

Oxidation Behavior of GRCop-84 Copper Alloy Assessed

NASA's goal of safe, affordable space transportation calls for increased reliability and lifetimes of launch vehicles, and significant reductions of launch costs. The areas targeted for enhanced performance in the next generation of reusable launch vehicles include combustion chambers and nozzle ramps; therefore, the search is on for suitable liner materials for these components. GRCop-84 (Cu-8Cr-4Nb), an advanced copper alloy developed at the NASA Glenn Research Center in conjunction with Case Western Reserve University, is a candidate. The current liner of the Space Shuttle Main Engine is another copper alloy, NARloy-Z (Cu-3Ag-0.1Zr). It provides a benchmark against which to compare the properties of candidate successors. The thermomechanical properties of GRCop-84 have been shown to be superior, and its physical properties comparable, to those of NARloy-Z. However, environmental durability issues control longevity in this application: because copper oxide scales are not highly protective, most copper alloys are quickly consumed in oxygen environments at elevated temperatures. In consequence, NARloy-Z and most other copper alloys are prone to blanching, a degradation process that occurs through cycles of oxidation-reduction as the oxide is repeatedly formed and removed because of microscale fluctuations in the oxygen-hydrogen fuel systems of rocket engines. The Space Shuttle Main Engine lining typically degraded by blanching-induced hot spots that lead to surface roughening, pore formation, and coolant leakage. Therefore, resistance to oxidation and blanching are key requirements for second-generation reusable launch vehicle liners. The rocket engine ambient includes H2 (fuel) and H2O (combustion product) and is, hence, under reduced oxygen partial pressures. Accordingly, our studies were expanded to include oxygen partial pressures as low as 322 parts per million (ppm) at the temperatures likely to be experienced in service. A comparison of 10-hr weight gains of GRCop-84, NARloy-Z, and pure copper in 0.032, 2.2, and 100 percent oxygen from 550 to 750 C is shown. In 2.2 vol% and higher oxygen content, GRCop-84 oxidation was slower than that of NARloy-Z or Cu, but that advantage was lost or diminished in 322-ppm O2. Over longer (50-hr) exposures in 1.0 atm O2, however, the advantage of GRCop-84 increased significantly, its oxidation rate becoming approximately 10 times slower than those of Cu and NARloy-Z from 500 to 700 C. Weight gains were moderate and the kinetics parabolic for all three materials in 2.2 vol% and higher oxygen content; however, in 322-ppm O2, the scales were nonprotective below about 650 C, as reflected in linear kinetics and large weight gains. The superior oxidation resistance of GRCop-84 is likely related to the kinetics of extra oxygen consumption to form the additional oxides of Cr and Nb detected beneath the GRCop-84 oxide layer. While we continue to evaluate the blanching resistance of GRCop-84 in other tests, these oxidation results indicate that GRCop-84 is suitable as a reusable launch vehicle liner, and in applications where it is desired to use a copper alloy but without the risk of oxidative failure. Three bar charts comparing overall specific weight gains by each of the three materials studied. The top chart is for oxidation in 1.0 atm of oxygen, the middle is for 2.2% oxygen (balance argon), and the bottom is for 0.0322% oxygen. GRCop-84 outperforms the other two materials, showing the least weight gain in nearly all cases.

Thomas-Ogbuji, Linus U.↗

Derivation and Validation of Supraglacial Lake Volumes on the Greenland Ice Sheet from High-Resolution Satellite Imagery

Supraglacial meltwater lakes on the western Greenland Ice Sheet (GrIS) are critical components of its surface hydrology and surface mass balance, and they also affect its ice dynamics. Estimates of lake volume, however, are limited by the availability of in situ measurements of water depth,which in turn also limits the assessment of remotely sensed lake depths. Given the logistical difficulty of collecting physical bathymetric measurements, methods relying upon in situ data are generally restricted to small areas and thus their application to largescale studies is difficult to validate. Here, we produce and validate spaceborne estimates of supraglacial lake volumes across a relatively large area (1250 km(exp 2) of west Greenland's ablation region using data acquired by the WorldView-2 (WV-2) sensor, making use of both its stereo-imaging capability and its meter-scale resolution. We employ spectrally-derived depth retrieval models, which are either based on absolute reflectance (single-channel model) or a ratio of spectral reflectances in two bands (dual-channel model). These models are calibrated by usingWV-2multispectral imagery acquired early in the melt season and depth measurements from a high resolutionWV-2 DEM over the same lake basins when devoid of water. The calibrated models are then validated with different lakes in the area, for which we determined depths. Lake depth estimates based on measurements recorded in WV-2's blue (450-510 nm), green (510-580 nm), and red (630-690 nm) bands and dual-channel modes (blue/green, blue/red, and green/red band combinations) had near-zero bias, an average root-mean-squared deviation of 0.4 m (relative to post-drainage DEMs), and an average volumetric error of b1%. The approach outlined in this study - image-based calibration of depth-retrieval models - significantly improves spaceborne supraglacial bathymetry retrievals, which are completely independent from in situ measurements.

Spectrally-based depth-retrieval models↗