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Approximate variation principle for calculating energies and wave functions in electron impact experiments
Carbon dioxide electron impact cross sections, analyzing discrete excitation, autoionization, direct and dissociative ionization and use to aeronomy
The 3P - 1D electron-impact excitation cross section within the ground configuration of doubly ionized oxygen is calculated in the distorted-wave approximation. An essential element of the present treatment is that orthogonality is not assumed between core and scattering orbitals of the same angular symmetry. Resonance structures are included through the use of quantum-defect theory. Near threshold the effect of an isolated autoionization resonance in the dominant 2D(0) partial wave is found to be important, in agreement with previous close-coupling results.
The implications of a heavy ion plasma in the Jovian magnetosphere are discussed. The plasma electron density varies on time scales comparable with that of radial diffusion. This plasma can enhance a super-Alfvenic planetary wind by increasing the radial mass flux. A mechanism by which the heavy ion plasma can regenerate itself via self-sputtering from the surface of Io followed by ionization first by solar ultra-violet and later by electron impact is proposed. It is suggested that this long term variability can modulate the faster variations of the plasma-magnetosphere configuration of Jupiter.
The model for the Io oxygen cloud was improved and is now capable of calculating the two dimensional sky plane intensity for the 6300A, 1304A and 880A lines, where volume excitation and ionization rates are determined by impact collisions with Io plasma torus electrons. These three emission lines are those for which observations were performed by ground based, rocket, Earth orbiting satellites and Voyager spacecraft nstruments. Comparison of model results with observations at 6300A suggests an isotropic oxygen flux from Io of about (1.5 to 3.0) x 10 to the 9th power atoms cm/sec or an overall source rate of (0.6 to 1.2) x 10 to the 27th power atoms/sec. A model for the expected but yet undetected Io sulfur cloud was also developed and very preliminary results are discussed. Quantitative analysis of the Io sodium cloud focused upon the initial task of acquiring and preliminary evaluation of sodium cloud and Io plasma torus data.
Exploratory model calculations for the Io atomic oxygen cloud have provided two-dimensional sky-plane intensities for the 6300 A, 1304 A and 880 A lines, where volume excitation and ionization rates are determined by impact collisions with Io plasma torus electrons. Comparison of model results with observations at 6300 A suggests an isotropic oxygen flux from Io of about 1.5x109 atoms 1 sq cm/sec. The effects of including a neutral sulfur cloud and also of including charge exchange reactions between plasma torus ions and neutral OI and SI were evaluated to be significant and were roughly estimated to increase the required oxygen flux to 1.2 x 10 to the 10th atoms/sq cm/sec. In addition, increases in the estimates for the ion loading, cloud mass loss, plasma mass loading and ion energy input rates were also made. Model calculations for an Io sulfur cloud, excluding charge exchange reactions but assuming an SI flux of 7.5 x 10 to the 8th atoms/sq cm/sec (i.e., half of the oxygen flux), were also performed and provided sky plane intensities for a number of visible and IR emission lines.
The analysis of optically-thin far-ultraviolet and X-ray emission lines of multiply-charged ions is one of the basic methods for determining the temperatures and densities of laboratory and astrophysical plasmas. In addition, the energy balance in these plasmas can be significantly influenced by the emission of radiation from relatively low concentrations of multiple-charged atomic ions. Because the populations of the excited levels are expected to depart substantially from their local thermodynamic equilibrium values a detailed treatment of the elementary collisional and radiative processes must be employed in order to predict the emission line intensities. In this investigation the authors present the results of calculations based on a corona equilibrium model in which a detailed evaluation is made of the dielectronic recombination rate coefficients. The ionization and autoionization following inner-shell electron excitation from each ground state are balanced by direct radiative and dielectronic recombination. The spectral line intensities emitted by the low-lying excited states, which are assumed to undergo spontaneous radiative decay in times that are short compared with the collision time, are evaluated in terms of the corona ionization equilibrium distributions of the ground states and their electron-impact excitation states.
The methylene amidogen (H2CN) radical can be shown to be an important intermediate in models for the formation of HCN (via N + CH3) and the recombination of H to H2 (via H + HCN) on Titan as well as in models for the formation of HCN (via NH2 + C2H3) in the atmosphere of Jupiter. Experiments in our laboratory in a discharge flow system with mass spectrometric detection of both reactants and products have established that the major product channel (90 percent for the reaction N + CH3 is that leading to H2CN + H. The same result was obtained for N + CD3 yields D2CN + D. The rate constant for the reaction D + D2CN yields DCN + D2 was measured for the first time and k(298 K) greater than 7 x 10(exp -11) cu cm/s was found. The same result was obtained for the H atom reaction. This is the final step in the reaction sequence leading to HCN on both Titan and Jupiter and to formation of H2 from H on Titan. The first measurement of the ionization potentials for H2CN and D2CN was also made. From electron impact studies I.P. = (9.6 + or - 1.0) eV was obtained for both radicals. An upperlimit of I.P. less than 11.6 eV came from observations of the H2CN radical by photoionization mass spectrometry using an Ar resonance lamp (106.7 nm). Further photoionization experiments are planned using synchrotron radiation plus monochromator as a tunable vacuum UV light source.
During entry of a space craft into Earth atmosphere, the flow surrounding the vehicle becomes partially ionized leading to significant cation and free-electron production. Subsequently, electron impact excitation and dissociation form radiating excited state species that contribute to the heat load on the vehicle. While experimental data on selected total cross sections are available, few experiments address the need for accurate AI cross sections for metastable atomic states at the high temperatures realized in atmospheric re-entry. In order to maintain desired safety margins during atmospheric entry of a space vehicle, chemical reaction models need to accurately account for this process. For the present study, we have computed vibrationally resolved cross sections for the DR of NO+ for electron energies between 0.01 to 10 eV and apply microscopic reversibility to obtain the AI cross sections and rate coefficients. For the DR cross section calculations, we use state-of-the-art MRCI potential energy curves. The resulting adiabatic potential curves are transformed to a diabatic representation, which is used in time-dependent wave packet calculations to describe the nuclear motion of the dissociating cation upon collision with an electron. Based on the wave function evolution in time, these calculations provide T-matrix and cross sections for the DR including recombination into the low energy metastable atomic states. The DR and AI rate coefficients are compared with the available experimental data.
Ionization of multielectron atoms by fast charged particles and electron and proton impact
The production of magnetic fields was revealed by laboratory hypervelocity impacts in easily vaporized targets. As quantified by pressure measurements, high frame-rate photography, and electrostatic probes, these impacts tend to produce large quantities of slightly ionized vapor, which is referred to as impact-generated plasma. Nonaligned electron density and temperature gradients within this plasma may lead to production of the observed magnetic fields. Past experiments were limited to measuring a single component of the impact-generated magnetic fields at only a few locations about the developing impact crater and consequently gave little information about the field production mechanism. To understand this mechanism, the techniques were extended to map the three components of the magnetic field both in space and time. By conducting many otherwise identical experiments with arrayed magnetic detectors, a preliminary 3-D picture was produced of impact-generated magnetic fields as they develop through time.
In this paper, calculations of the hole initiated interband impact ionization rate in bulk silicon and GaAs are presented based on an ensemble Monte Carlo simulation with the inclusion of a wave-vector-dependent numerical transition rate formulation. The ionization transition rate is determined for each of the three valence bands, heavy, light, and split-off, using Fermi's golden rule with a two-body, screened Coulomb interaction. The dielectric function used within the calculation is assumed to be wave-vector-dependent. Calculations of the field-dependent impact ionization rate as well as the quantum yield are presented. It is found from both the quantum yield results and examination of the hole distribution function that the effective threshold energy for hole initiated impact ionization is relatively soft, similar to that predicted for the corresponding electron initiated ionization events occur more frequently than either heavy or split-offf initiated ionization events in bulk silicon over the applied electric field strengths examined here, 250-500 kV/cm. Conversely,in GaAs, the vast majority of hole initated ionization events originate from holes within the split-off band.
Direct and autoionization of H molecule by electron impact near threshold noting cross section, photoionization and vibrational and rotational energy changes
Propagation effects on telecommunications in a cometary environment include those due to dust, the inhomogeneous plasma of the coma and tail, and ionization generated by impact of neutral molecules and dust on the spacecraft. Attenuation caused by dust particles is estimated to be on the order of 10 to the minus 5th power dB for the Halley Intercept Mission. Ionization generated by impact on the spacecraft is estimated to result in an electron content of 10 to the 12th power to 10 to the 13th power el/sq meters (3 eV electrons) along the telecommunications path. An estimate of the electron content due to Comet Halley itself is 10 to the 16th power to 10 to the 17th power el/sq meters, compared to a content of 10 to the 16th power to 10 to the 18th power el/sq meters for the Earth's ionosphere and 10 to the 17th power to 10 to the 18th power el/sq meters for the interplanetary medium. The electron content of the plasma near Comet Halley will cause excess range delay, and a Doppler shift of the signal from the spacecraft will occur in propagation to the rate of change of the path electron content. It is recommended that S and X down-link frequencies by employed to monitor the path electron content and amplitude scintillation and spectral broadening of the received signals. These measurements will provide a quantitative base of knowledge that will be valuable for radio science and telecommunications system design purposes.
Theoretical studies using Franck-Condon and static-exchange approximations are reported for the complete dipole excitation and ionization spectrum in H2O, where (1) large Cartesian Gaussian basis sets are used to represent the required discrete and continuum electronic eigenfunctions at the ground state equilibrium geometry, and (2) previously devised moment-theory techniques are employed in constructing the continuum oscillator-strength densities from the calculated spectra. Comparisons are made of the calculated excitation and ionization profiles with recent experimental photoabsorption studies and corresponding spectral assignments, electron impact-excitation cross sections, and dipole and synchrotron-radiation studies of partial-channel photoionization cross sections. The calculated partial-channel cross sections are found to be atomic-like, and dominated by 2p-kd components. It is suggested that the latter transition couples with the underlying 1b(1)-kb(1) channel, accounting for a prominent feature in recent synchrotron-radiation measurements.
The threshold law for ionisation of atoms by positron impact is adduced in analogy with our approach to the electron-atom ionization. It is concluded the Coulomb-dipole region of the potential gives the essential part of the interaction in both cases and leads to the same kind of result: a modulated linear law. An additional process which enters positron ionization is positronium formation in the continuum, but that will not dominate the threshold yield. The result is in sharp contrast to the positron threshold law as recently derived by Klar on the basis of a Wannier-type analysis.
In molecular clouds of modest density and relatively high fractional ionization, the rotational excitation of CN is controlled by a competition among electron impact, neutral impact and the interaction with the cosmic background radiation. The degree of excitation can be measured through optical absorption lines and millimeter-wave emission lines. The available, accurate data on CN in diffuse and translucent molecular clouds are assembled and used to determine electron densities. The derived values, n(e) = roughly 0.02 - 0.5/cu cm, imply modest neutral densities, which generally agree well with determinations by other techniques. The absorption- and emission-line measurements of CN both exclude densities higher than n(H2) = roughly 10 exp 3.5/cu cm on scales varying from 0.001 to 60 arcsec in these clouds.
The behavior of the Venus nightside ionosphere at solar maximum and solar minimum is discussed based on Pioneer Venus radio occultation measurements. Although some solar maximum measurements are similar to those observed at minimum, which have an average peak density of about 7000/cu cm, others show much higher peak densities, reaching values of about 40,000/cu cm. These elevated peak densities also occur at higher altitudes. The integrated electron column densities for these measurements indicate the presence of substantial ionization above the main peak. The magnitudes of both the peak density and the integrated content above the peak are anticorrelated with the solar wind dynamic pressure, indicating that these enhancements during solar maximum are due to transterminator transport of O(+) ions from the dayside. The resulting ionization peak can be many times the concentration produced by energetic electron fluxes impacting the neutral atmosphere on the nightside.