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NASA NTRS1972

Thermal scale modeling of radiation-conduction-convection systems.

Investigation of thermal scale modeling applied to radiation-conduction-convection systems with particular emphasis on the spacecraft cabin atmosphere/cabin wall thermal interface. The 'modified material preservation,' 'temperature preservation,' 'scaling compromises,' and 'Nusselt number preservation' scale modeling techniques and their inherent limitations and problem areas are described. The compromised scaling techniques of mass flux preservation and heat transfer coefficient preservation show promise of giving adequate thermal similitude while preserving both gas and temperature in the scale model. The use of these compromised scaling techniques was experimentally demonstrated in tests of full scale and 1/4 scale models. Correlation of test results for free and forced convection under various test conditions shows the effectiveness of these scaling techniques. It is concluded that either mass flux or heat transfer coefficient preservation may result in adequate thermal similitude depending on the system to be modeled. Heat transfer coefficient preservation should give good thermal similitude for manned spacecraft scale modeling applications.

Shannon, R. L.↗

NASA NTRS1978

Magnetic loops, downflows, and convection in the solar corona

Optical and extreme-ultraviolet observations of solar loop structures show that flows of cool plasma from condensations near the loop apex are a common property of loops associated with radiations whose maximum temperature is greater than approximately 7000 K and less than approximately 3,000,000 K. It is suggested that the mass balance of these structures indicates reconnection by means of plasma motion across field lines under rather general circumstances (not only after flares). It is shown that the cool material has lower gas pressure than the surrounding coronal medium. The density structure of the bright extreme ultraviolet loops suggests that downflows of cool gas result from isobaric condensation of plasma that is either out of thermal equilibrium with the local energy deposition rate into the corona, or is thermally unstable. The evidence is thought to indicate that magnetic fields act to induce a pattern of forced convection.

Foukal, P.↗

NASA NTRS1994

Forecast skill of a high-resolution real-time mesoscale model designed for weather support of operations at Kennedy Space Center and Cape Canaveral Air Station

NASA funded Mesoscale Environmental Simulations and Operations (MESO), Inc. to develop a version of the Mesoscale Atmospheric Simulation System (MASS). The model has been modified specifically for short-range forecasting in the vicinity of KSC/CCAS. To accomplish this, the model domain has been limited to increase the number of horizontal grid points (and therefore grid resolution) and the model' s treatment of precipitation, radiation, and surface hydrology physics has been enhanced to predict convection forced by local variations in surface heat, moisture fluxes, and cloud shading. The objective of this paper is to (1) provide an overview of MASS including the real-time initialization and configuration for running the data pre-processor and model, and (2) to summarize the preliminary evaluation of the model's forecasts of temperature, moisture, and wind at selected rawinsonde station locations during February 1994 and July 1994. MASS is a hydrostatic, three-dimensional modeling system which includes schemes to represent planetary boundary layer processes, surface energy and moisture budgets, free atmospheric long and short wave radiation, cloud microphysics, and sub-grid scale moist convection.

Taylor, Gregory E.↗

DOE OSTI2022

Challenge Problem 1: Preliminary Model Development and Assessment of Flexible Heat Transfer Modeling Approaches

This report presents the modeling progress of a university consortium studying flexible modeling for turbulent heat transfer. In the context of advanced nuclear reactor design, where challenges include non-unity Prandtl fluids, free and mixed convection, and transitional flow, computational fluid dynamics methods are underutilized due to low confidence in modeling approaches and high computational cost. This report evaluates the performance of engineering CFD models in diabatic, buoyant turbulent flow. It finds that all turbulence models including several variants of the k-ε and k-ω models struggle to predict accurate turbulent momentum and heat transfer in such flows. The Nusselt numbers have been compared between the models and the DNS data, where calculations have been performed for each case and trends have shown a good agreement between DNS estimated Nusselt numbers and available correlations as well as experimental data. A novel DNS correlation for high Pr cases as they are transitioning from mixed convection to natural convection has been proposed. While Nusselt number errors relative to DNS range from 20% to 50%, the models capture similar trends to DNS with respect to Nusselt suppression and amplification under varying levels of buoyancy effect. This report also highlights model form error as a significant contributor to CFD predictions and proposes a framework for quantifying model error and improving confidence in CFD calculations. To improve the predictive capability of engineering CFD models, data-driven approaches for turbulence models are investigated. Theoretical frameworks based on the invariant tensor / vector basis neural networks for prediction of Reynolds stresses and turbulent heat fluxes are employed. The models are developed using direct numerical simulations data for forced convection flows of different fluids in vertical planar channel domain. The framework is implemented in spectral element solvers Nek5000 / nekRS and has shown a potential for future development and consideration of mixed convection flows.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

NASA NTRS1994

Miniature Convection Cooled Plug-type Heat Flux Gauges

Tests and analysis of a new miniature plug-type heat flux gauge configuration are described. This gauge can simultaneously measure heat flux on two opposed active surfaces when heat flux levels are equal to or greater than about 0.2 MW/m(sup 2). The performance of this dual active surface gauge was investigated over a wide transient and steady heat flux and temperature range. The tests were performed by radiatively heating the front surface with an argon arc lamp while the back surface was convection cooled with air. Accuracy is about +20 percent. The gauge is responsive to fast heat flux transients and is designed to withstand the high temperature (1300 K), high pressure (15 MPa), erosive and corrosive environments in modern engines. This gauge can be used to measure heat flux on the surfaces of internally cooled apparatus such as turbine blades and combustors used in jet propulsion systems and on the surfaces of hypersonic vehicles. Heat flux measurement accuracy is not compromised when design considerations call for various size gauges to be fabricated into alloys of various shapes and properties. Significant gauge temperature reductions (120 K), which can lead to potential gauge durability improvement, were obtained when the gauges were air-cooled by forced convection.

Liebert, Curt H.↗

NASA NTRS1995

The USML-1 wire insulation flammability glovebox experiment

Flame spreading tests have been conducted using thin fuels in microgravity where buoyant convection is suppressed. In spacecraft experiments flames were ignited in quiescent atmospheres with an elevated oxygen content, demonstrating that diffusional mechanisms can be sufficient alone to sustain flame spreading. In ground-based facilities (i.e. drop towers and parabolic aircraft) low-speed convection sustains flames at much lower concentrations of atmospheric oxygen than in quiescent microgravity. Ground-based experiments are limited to very thin fuels (e.g., tissue paper); practical fuels, which are thicker, require more test time than is available. The Glovebox Facility provided for the USML 1 mission provided an opportunity to obtain flame spreading data for thicker fuel Herein we report the results from the Wire Insulation Flammability (WIF) Experiment performed in the Glovebox Facility. This experiment explored the heating, ignition and burning of 0.65 mm thick polyethylene wire insulation in low-speed flows in a reduced gravity environment. Four tests were conducted, two each in concurrent flow (WIF A and C) and opposed flow (WIF B and D), providing the first demonstration of flame spreading in controlled forced convection conducted in space.

Greenberg, Paul S.↗

NASA NTRS1995

Dynamics of Vapour Bubbles in Nucleate Boiling: Basic Equations of Bubble Evolution - 1

We consider the behaviour of a vapour bubble formed at a nucleation site on a heated horizontal wall. There is no forced convection of an ambient liquid, and the bubble is presumably separated from the wall by a thin liquid microlayer. The energy conservation law results in a variational equation for the mechanical energy of the whole system consisting of the bubble and liquid. It leads to a set of two strongly nonlinear equations which govern bubble expansion and motion of its centre of mass. A supplementary equation to find out the vapour temperature follows from consideration of heat transfer to the bubble, both from the bulk of surrounding liquid and through the microlayer. The average thickness of the microlayer is shown to increase monotonously with time as the bubble meniscus spreads along the wall. Bubble expansion is driven by the pressure head between vapour inside and liquid far away from the bubble, with due allowance for surface tension and gravity effects. It is resisted by inertia of liquid being placed into motion as the bubble grows. The inertia originates also a force that presses the bubble to the wall. This force is counteracted by the buoyancy and an effective surface tension force that tends to transform the bubble into a sphere. The analysis brings about quite a new formulation of the familiar problem of bubble growth and detachment under conditions of nucleate pool boiling.

Buyevich, Yu A.↗

DOE OSTI2021

Tritium Transport Phenomena in Molten-Salt Reactors: Molten Salt Tritium Transport Experiment Design

Tritium is produced from neutron interactions with both lithium and beryllium. Large quantities of tritium are generated in Molten Salt Reactors (MSRs) which use LiF/BeF2 (FLiBe) as the fuel salt. Tritium is unique among the radionuclide hazards as it readily permeates through metal structural materials at high temperatures. All metal surfaces are potential release paths for tritium. For adequate safety analysis and eventual licensing of new reactors, predictive models for tritium transport and release from MSRs must be developed. These models must account for the multiple transport phenomena involved with tritium: fuel salt phase mass transport, dissociation/recombination reactions on metal surfaces, interstitial diffusion through the metal structure, and salt or gas phase mass transport in the downstream fluid. These models also must also be validated with representative experiments. Our previous report outlined tritium transport phenomena involved in MSRs, made suggestions on gaps in the transport dataset, and proposed an experimental test stand to test combined transport effects – tritium transport through pipe walls in a convective salt flow. In this report, we summarize an updated analysis framework for tritium transport in MSRs, report our results on hydrogen and deuterium permeation through Hastelloy N, and describe the final design of the Molten Salt Tritium Transport Experiment (MSTTE, pronounced “misty”). The MSRE provides the only wholistic experimental data set for tritium transport in MSRs and understanding the transport phenomena involved in the MSRE is crucial for future model development. One set of parameters in our analysis framework was unknown for the MSRE—surface reaction rates for tritium on Hastelloy N. This warranted our hydrogen and deuterium permeation campaign to assess the permeability, diffusivity, and solubility of hydrogen isotopes in clean Hastelloy N. Surface reaction rate constants were probed by low pressure measurements, however, no surface effects were observed in the limits of our permeation apparatus. Permeation experiments on oxidized Hastelloy N were not performed for this report but are planned in future work. The experimental test stand, MSTTE, measures combined transport properties of the salt-metal system. MSTTE is a forced convection FLiBe loop with custom designed test section to measure tritium transport through candidate structural materials. We use MSRE relevant dimensionless numbers to design and scale the test section. Hastelloy N is a candidate loop and test section material due to the relevance for the MSRE and related designs, however, other metals are being considered (e.g. 316H SS) which may better align with current vendor concepts.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2022

Large-scale reactive thermoset printing: Complex interactions between temperature evolution, viscosity, and cure shrinkage

Thermoset composites are strong candidates for large-scale material extrusion additive manufacturing (AM). However, uncured thermoset composites become unstable as print height increases. Here, chemical initiation of vinyl ester immediately before deposition was used to suppress collapse and enable large-scale thermoset printing. Structural stability was assessed by printing thin walls at various layer times and monitoring thermal gradients with an infrared camera. Stable printing was observed at a layer time of 4.50 min, approximately half the gel time of the material (8 min). Self-weight collapse occurred at short layer time (0.68 min), whereas warpage occurred at long layer time (6.50 min). Here, a new behavior was discovered at intermediate layer time (2.25 min) where the heat generated by the reaction causes new, un-gelled layers to flow. Forced convection eliminates this behavior, stabilizing the 2.25-min layer time print. These findings motivated development of a less exothermic material system, which was used to print a large-scale mold and demonstrate the value of this understanding. By presenting these challenges of large-scale reactive thermoset AM for the first time, this work motivates focused studies of the complex interplay between rheological, thermal, and chemical behaviors to improve the feasibility of large-scale thermoset AM. Tensile properties of the printed material were also measured. Longitudinal and transverse elastic moduli are 3.79 and 2.95 GPa, respectively, and corresponding tensile strengths are 36.11 and 18.83 MPa. The glass transition temperature is 93.13 °C.

36 MATERIALS SCIENCE↗

DOE OSTI2025

The molten salt tritium transport experiment: A pumped fluoride salt loop for hydrogen isotope experimentation

Molten salt reactors (MSRs) and fusion reactors propose to use molten salts as coolants and breeder blanket materials, respectively. Tritium, however, poses safety concerns in both reactor types due to its ability to permeate through reactor materials and potential for environmental release. This manuscript addresses the tritium transport phenomena in molten salts and presents the design and analysis of the Molten Salt Tritium Transport Experiment (MSTTE). MSTTE is a forced-convection fluoride salt loop intended to measure hydrogen isotope permeation through structural materials in a flowing salt system. In the first phase, MSTTE will use FLiNaK salt and deuterium as surrogates for FLiBe and tritium, with future plans to utilize tritium and FLiBe. MSTTE couples a Copenhagen Atomics pumped salt loop with an external test section that introduces hydrogen isotopes into the loop and measures transport phenomena. The Hydrogen Injection System (HIS) controls hydrogen isotope introduction into the molten salt loop. Here, the permeation test section measures the permeation rate through stainless steel tubing in contact with flowing salt. Computational fluid dynamics (CFD) analysis ensures fully developed salt flow in the permeation test section. MSTTE is modeled with MELCOR-TMAP to predict the permeation rate as a function of experimental variables such as source term, salt flow rate, and salt temperature. Results indicate that the source term is the only parameter with a significant effect on the permeation rate. Pressure drop analysis suggests that the loop should operate below 200 LPM to maintain a pressure drop below 200 kPa. Additionally, finite-element analysis assesses thermal stress during loop operation to ensure the experiment's safe design. MSTTE will provide semi-integral data on tritium transport phenomena in molten salts and serve as a testbed for advancing molten salt technology.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

DOE OSTI2022

Effect of PVD-coated chromium on the subcooled flow boiling performance of nuclear reactor cladding materials

Here we elucidate the separate effect of a thin Cr coating deposited by physical vapor deposition (PVD) on the subcooled flow boiling performance of zircaloy-4. First, we run flow boiling experiments on prototypical zircaloy-4 surfaces mimicking the scratch pattern and surface roughness of nuclear reactor claddings. Then, we PVD-coat a 0.3 µm thick chromium layer on the same exact surface and repeat the same flow boiling investigations. All experiments are run using deionized water at atmospheric pressure, flowing on a 1 × 3 cm 2 rectangular cross section channel at a rate of 1000 kg/m 2 /s and a subcooling of 10 K. We measure the average temperature of the boiling surface at increasing surface heat fluxes, covering a wide range of heat transfer regimes, from single-phase forced convection to the boiling crisis. We also record high-speed videos of the boiling process, which we postprocess to measure bubble nucleation site density, growth time, departure diameter and frequency. The surface analysis reveals that, while the chromium coating does not seem change the surface roughness and morphology, it improves surface wettability. However, it decreases the critical heat flux. The chromium coating causes an increase of nucleation temperature, bubble departure diameter and growth time, and a reduction of the nucleation site density. The concurrence of these observations indicates that a size reduction of the nucleation sites, conformally covered by the chromium coating, may be the cause of the boiling performance deterioration. We confirm this hypothesis repeating the same analysis on a FeCrAl sample prepared and tested using the same protocol as the zircaloy-4 sample, but with a different initial surface texture.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2025

Energy performance of an operational government building retrofitted with ceiling phase change material tiles in a mixed-humid climate

The aging U.S. building stock requires various retrofit measures to enhance their energy efficiency. Here, this study explores the integration of thermal energy storage and advanced building controls as viable retrofit solutions for load flexibility and peak demand response while maintaining the occupants' comfort. A detailed assessment is conducted on the energy use of an administrative building in Sumner County, Kansas, focusing on the implementation of phase change materials (PCMs) in the ceiling of occupied zones. First, a time-resolved, whole-building energy model is developed in EnergyPlus, incorporating complex thermal behaviors such as air exchange between the plenum space and occupied zones, envelope leakage, and operational schedules. The model is then validated using experimental field test data, and subsequently a parametric assessment of key PCM properties and application strategies is performed to evaluate cooling electricity demand benefits. The parametric study shows that the optimal retrofit strategy, comprising a PCM with 23°C peak melting temperature, 0.125 in. (3.17 mm) thickness, and 150 kJ/kg latent heat, combined with active controls that include 8 h of precooling, forced convection under the ceiling, and a 2°C thermostat setback during peak hours, can result in a maximum load shift during the peak period of 99.6 % and the total electricity savings during the peak period of 98.9 % for the optimum case and thus provide significant cost savings under time-of-use pricing scenarios.

24 POWER TRANSMISSION AND DISTRIBUTION↗

DOE OSTI2022

Generalized Analysis of Dynamic Flow Fouling on Heat Transfer Surfaces

Several energy applications involve flow of untreated heat transfer fluids that contain trace amounts of mineral salts, such as calcium carbonate and calcium sulfate, which show reverse solubility with temperature. The gradual accretion of these salts onto the heat transfer surfaces causes fouling that degrades thermal performance over time. While fouling of bare surfaces has been extensively studied, fouling of nonwetting superhydrophobic or liquid-infused surfaces is less understood, especially under dynamic flow conditions. This study presents a systematic experimental analysis to elucidate dynamic flow fouling of calcium carbonate and calcium sulfate on smooth, superhydrophobic and liquid-infused surfaces in a generalized manner. Here, copper tubes with modified inner surface wettability are fabricated and subjected to forced convection at different flow rates and fouling salt concentrations. Fouling characteristics of the two salts on the different surfaces are examined through microstructural analysis, and quantified in terms of asymptotic fouling resistance that measures the total extent of fouling, and a threshold time, which correlates to the onset of significant fouling. Using Taguchi design of experiments, the study reports, for the first time, closed-form analytical relationships for the asymptotic fouling thermal resistance and threshold time on the Reynolds number, dimensionless concentration of fouling agent and dimensionless infused liquid viscosity that represents the different surface types in a unified manner. It is shown that the analytical model accurately predicts the fouling characteristics in up to about 97% of the data, based on which contour maps of optimum surface designs for minimizing fouling resistance are presented. The results provide information on designing surfaces for reduced fouling or for estimating the fouling characteristics for a given surface in applications.

36 MATERIALS SCIENCE↗

DOE OSTI2022

Wire-coil insert optimization for high-heat-load/flux synchrotron components

Many synchrotron components require high levels of internal-flow, forced-convection heat transfer to minimize surface temperatures, thermal gradients, and thermally induced stress on high-power beam-interacting surfaces. Wire-coil inserts, physically similar to a common spring, are mechanically fitted inside of component cooling passages to optimize heat transfer performance. They are routinely used in Advanced Photon Source (APS) front end and beamline high-heat-load/flux components to significantly enhance convection heat transfer-up to 400% compared to plain open passages. This has the additional benefit of greatly reducing coolant flow requirements for these components. Using several cooling passage sizes, five different wire sizes, and a range of pitch values, an experimental investigation conducted at the APS has determined the average heat transfer coefficient and resulting pressure loss as a function of water flow rate for 65 different wire-coil inserts. Data from this study have been non-dimensionalized and generalized to yield relationships that can be used to determine the heat transfer performance and resulting pressure loss for any given wire-coil insert that may be used at the APS. Through data reduction, the wire-coil insert characteristic dimensions have also been optimized to yield the highest heat transfer enhancement while minimizing the coolant flow requirements. These generalized expressions for wirecoil inserts will be presented, and they can be used by scientists and engineers during the component design process to evaluate achievable heat transfer performance and associated pressure loss, aiding in the establishment of optimized operating parameters and cooling passage flow distribution schemes.

43 PARTICLE ACCELERATORS↗

DOE OSTI2022

Carburization and decarburization behavior of Grade 91 ferritic-martensitic steel in liquid sodium environments

Here, this paper presents a study of carbon transfer and its effect on microstructure and tensile properties of Grade 91 (G91) ferritic-martensitic steel exposed to sodium at 550–650 °C. Sodium exposure tests were conducted in Argonne's forced convection sodium loops up to exposure times of ~40,000 h. Thermal aging study of G91 steel was conducted in parallel to isolate the thermal aging effect from the sodium effect. It was found that sodium exposures at 650 °C dissolved M 23 C 6 carbides, eliminated the martensite subgrain structure resulting in excessive grain growth and reduced the tensile strength by >50%, while sodium exposures at 550 and 600 °C had an insignificant effect on its microstructure and tensile properties. These effects were attributed to the carburization/decarburization process of G91 steel in sodium environments. Carbon concentrations in sodium were determined by a foil equilibration method. The estimated carbon concentration was in the range of 0.8–1.2 ppm in the SMT-1 loop and 0.3–0.7 ppm in the SMT-2 loop. Thermodynamic analysis of the carburization – decarburization process was conducted for G91 steels exposed in sodium environments. The carbon activity-concentration relationship for G91 was evaluated by considering four phases in G91, i.e. bcc ferrite, M 23 C 6 , NbC and VC carbides. It was found that the carburization-decarburization process in G91 steel was dictated by M 23 C 6 carbides at high carbon activities, while NbC and VC carbides dominated the process at low carbon activities. The calculated carburization-decarburization boundary showed that G91 would undergo decarburization at 650 °C and carburization at 550 °C in the sodium loop environments, which was consistent with our experimental observations. This experimental and theoretical analysis provided a basis for predicting the effect of carbon transfer on the integrity of reactor components in sodium environments and for the design of new alloys used in sodium-cooled fast reactors.

36 MATERIALS SCIENCE↗

DOE OSTI2024

Strength stability at high temperatures for additively manufactured alumina forming austenitic alloy

Several fast-spectrum nuclear reactors designed to generate high power (~450 MWe) rely on forced convection of media such as supercritical CO 2 , sodium, or liquid lead to cool the nuclear core, operating at temperatures up to 600 °C. Cost-effective, high-strength Fe-based alumina forming austenitic (AFA) alloys are a promising candidate for the fabrication of critical nuclear components. This study investigated laser powder bed fusion (LPBF) processing of an AFA alloy composition optimized for improved creep resistance. Electron microscopy revealed an elongated grain structure along the build direction with a fine sub-grain cellular structure decorated with (Cr,Fe,Nb) 23 C 6 carbide precipitates at the intercellular boundaries. Finally, at temperatures of 20–900 °C, the LPBF alloy's superior tensile properties compared to its arc-melted counterpart and other advanced steels (e.g., SS316) were attributed to the distribution of nano-sized carbide precipitates, whereas the high ductility was attributed to the LPBF alloy's elongated grain structure.

36 MATERIALS SCIENCE↗

DOE OSTI2022

Effects of Temperature on Flow Fouling of Smooth and Nonwetting Surfaces

Mineral fouling (scaling) of heat transfer surfaces is a pervasive problem in heat exchangers, chemical reactors, and other equipment in energy, environmental, and process industrial applications. Many of the applications involve dynamic flow of fluids with the impurity minerals and, furthermore, operate at elevated temperature. Strategies to mitigate fouling under these conditions are of much value in industrial applications. This paper presents a comparative study of temperature-dependent mineral fouling deposition on smooth surfaces and nonwetting superhydrophobic and lubricant-infused surfaces under dynamic flow conditions. The surfaces are represented in a unified manner using the viscosity ratio of the infused material within the porous asperities on a surface to that of the flowing fluid such that the spectrum of surfaces from superhydrophobic to smooth is captured by the range of viscosity ratios from 0 to ∞. Using a forced convection experimental setup, deposition of calcium sulfate on the surfaces is quantified in terms of asymptotic fouling resistance over a range of temperature, Reynolds number, and mineral foulant supersaturation. Through a systematic set of accelerated fouling experiments, an empirical relationship for the asymptotic fouling resistance is developed in terms of Reynolds number, foulant concentration, temperature, and surface type. The empirical model is validated with a comprehensive set of experimental data from this study as well as from the literature. Optimum nonwetting surface designs for minimizing fouling resistance compared to conventional smooth surfaces are developed as a function of temperature. The results of the study offer insight into the temperature-dependent fouling of surfaces under flow conditions and a rational design of fouling-resistant nonwetting surfaces that can be readily translated to practice.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2024

Microgravity effects on nonequilibrium melt processing of neodymium titanate: thermophysical properties, atomic structure, glass formation and crystallization

The relationships between materials processing and structure can vary between terrestrial and reduced gravity environments. As one case study, we compare the nonequilibrium melt processing of a rare-earth titanate, nominally 83TiO 2 -17Nd 2 O 3 , and the structure of its glassy and crystalline products. Density and thermal expansion for the liquid, supercooled liquid, and glass are measured over 300–1850 °C using the Electrostatic Levitation Furnace (ELF) in microgravity, and two replicate density measurements were reproducible to within 0.4%. Cooling rates in ELF are 40–110 °C s -1 lower than those in a terrestrial aerodynamic levitator due to the absence of forced convection. X-ray/neutron total scattering and Raman spectroscopy indicate that glasses processed on Earth and in microgravity exhibit similar atomic structures, with only subtle differences that are consistent with compositional variations of ~2 mol. % Nd 2 O 3 . The glass atomic network contains a mixture of corner- and edge-sharing Ti-O polyhedra, and the fraction of edge-sharing arrangements decreases with increasing Nd 2 O 3 content. X-ray tomography and electron microscopy of crystalline products reveal substantial differences in microstructure, grain size, and crystalline phases, which arise from differences in the melt processes.

36 MATERIALS SCIENCE↗