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Results for “Frequency synthesizers”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
NASA NTRS1995

Metafitting: Weight optimization for least-squares fitting of PTTI data

For precise time intercomparisons between a master frequency standard and a slave time scale, we have found it useful to quantitatively compare different fitting strategies by examining the standard uncertainty in time or average frequency. It is particularly useful when designing procedures which use intermittent intercomparisons, with some parameterized fit used to interpolate or extrapolate from the calibrating intercomparisons. We use the term 'metafitting' for the choices that are made before a fitting procedure is operationally adopted. We present methods for calculating the standard uncertainty for general, weighted least-squares fits and a method for optimizing these weights for a general noise model suitable for many PTTI applications. We present the results of the metafitting of procedures for the use of a regular schedule of (hypothetical) high-accuracy frequency calibration of a maser time scale. We have identified a cumulative series of improvements that give a significant reduction of the expected standard uncertainty, compared to the simplest procedure of resetting the maser synthesizer after each calibration. The metafitting improvements presented include the optimum choice of weights for the calibration runs, optimized over a period of a week or 10 days.

Douglas, Rob J.↗
NASA NTRS1989

Aeroelastic analysis of prop fan blades with a semiempirical dynamic stall model

The time-history response of a propfan wind-tunnel model with dynamic stall was studied analytically. The response obtained from the analysis was compared with available experimental data. The governing equations of motion were formulated in terms of blade normal modes calculated using the COSMIC-NASTRAN computer code. The response analysis considered the blade plunging and pitching motions. The lift, drag, and moment coefficients for angles of attack below the static stall angle were obtained from a quasi-steady theory. For angles above static stall angles, a semiempirical dynamic stall model based on a correction to the angle of attack was used to obtain lift, drag, and moment coefficients. Using these coefficients, the aerodynamic forces were calculated at a selected number of strips, and integrated to obtain the total generalized forces. The combined momentum-blade element theory was used to calculate the induced velocity. The semiempirical stall model predicted a limit cycle oscillation near the setting angle at which large vibratory stresses were observed in an experiment. The predicted mode and frequency of oscillation also agreed with those measured in the experiment near this setting angle. The results also correlated well with the other published data that used a semiempirical dynamic stall model based on a synthesized procedure.

Reddy, T. S. R.↗
NASA NTRS1981

An error budget for the JPL hydrogen maser receiver

The hydrogen maser receiver is a synthesizer that converts the maser signal, at about 1420 MHz, to a set of output signals at 100, 20, 10, 5, 1, and 0.1 MHz. The contribution of the receiver and its component modules to the frequency instability and phase noise of each of its outputs is estimated, and these results are compared to published measurements of the 100-MHz output of the frequency standard, which consists of a maser plus its receiver. One can then assess how much the receiver degrades the performance of the frequency standard.

Greenhall, C. A.↗
NASA NTRS1980

Biomedical technology transfer. Applications of NASA science and technology

Ongoing projects described address: (1) intracranial pressure monitoring; (2) versatile portable speech prosthesis; (3) cardiovascular magnetic measurements; (4) improved EMG biotelemetry for pediatrics; (5) ultrasonic kidney stone disintegration; (6) pediatric roentgen densitometry; (7) X-ray spatial frequency multiplexing; (8) mechanical impedance determination of bone strength; (9) visual-to-tactile mobility aid for the blind; (10) Purkinje image eyetracker and stabilized photocoalqulator; (11) neurological applications of NASA-SRI eyetracker; (12) ICU synthesized speech alarm; (13) NANOPHOR: microelectrophoresis instrument; (14) WRISTCOM: tactile communication system for the deaf-blind; (15) medical applications of NASA liquid-circulating garments; and (16) hip prosthesis with biotelemetry. Potential transfer projects include a person-portable versatile speech prosthesis, a critical care transport sytem, a clinical information system for cardiology, a programmable biofeedback orthosis for scoliosis a pediatric long-bone reconstruction, and spinal immobilization apparatus.

Harrison, D. C.↗
NASA NTRS1984

Eigenspace design of an active flutter suppression system

An active control system is designed for the suppression of wing flutter in a flight test vehicle. Eigenvalue placement is used to synthesize a full state controller which satisfies performance specifications on control surface activity and which exhibits excellent gain and phase margins. The use of limited state feedback is examined; however, it is found that a simple frequency response matching technique can be used to design a realizable compensator which reproduces the feedback properties of the full state controller. The performance of the control system using this compensator is evaluated at various flight conditions and found to be satisfactory. In addition eigenvector shaping is used to enhance the gust load alleviation capabilities of the flutter control system.

Liebst, B. S.↗
NASA NTRS1994

Software for continuum modeling of controls-structures interactions

It is clear that computer software is needed to assist in the generation of the equations of motion for complex, flexible spacecraft. Daniel Poelaert of ESTEC has developed the software DISTEL with which he has modeled the structural dynamics for different satellites. He is interested in expanding the capabilities of DISTEL to include structural damping and control systems. Unfortunately, the software has not been released. The author has developed similar software, PDEMOD, which has been used to model the Spacecraft control Laboratory Experiment (SCOLE), the Solar Array Flight Experiment (SAFE), the Mini-MAST truss, and the LACE satellite. PDEMOD has been used also for optimal parameter estimation and integrated control-structures design. PDEMOD is also being extended to include structural damping and control systems which are imbedded into the same equations for the structural dynamics. This paper will address the formulation of the equations for the structural dynamics of spacecraft structures which are constructed of a 3-dimensional arrangement of rigid bodies and flexible beam elements. Control system dynamics are imbedded into the same equations so that model order reduction approximations are not necessary. The input data consists of the physical data of the elements and the topological information describing how the elements are connected. PDEMOD accomplishes the following: (1) automatically assembles the equations of motion for the entire structural model; (2) calculates the modal frequencies; (3) calculates the mode shapes; (4) generates perspective views of the mode shapes; and (5) forms selected transfer functions. The software PDEMOD continues to be developed to provide additional features to assist in analyzing and synthesizing control and structural systems for flexible spacecraft.

Taylor, Lawrence W., Jr.↗
NASA NTRS2002

An Implementation of a Tracking Filter

For Goddard's new Matlab-based data analysis system, a Hilbert transform is used to generate a quadrature signal directly from the COLA signal. This differs from the usual practice of synthesizing the sine and cosine components after determining the sweep characteristics from the COLA signal. The original and quadrature signals are in turn mixed with the signal to be analyzed and then filtered to determine the frequency spectrum. This new technique appears to be more accurate in determining frequency and is insensitive to variations in COLA amplitude.

Worth, Daniel B.↗
DOE OSTI2023

Large-scale synthesis of metal/nitrogen Co-doped carbon catalysts for CO 2 electroreduction

In this work, we report a facile approach for synthesizing M–N–C catalysts (M = Co, Fe, Ni) at a commercial scale without employing organic solvents. Our characterization efforts indicate that single atomic catalysts with high surface areas were successfully obtained. Electrochemical measurements demonstrate that, among the three synthesized catalysts, Ni–N–C exhibits the highest performance in the electrochemical CO2 reduction reaction (CO 2 RR) to carbon monoxide (CO), affording 80% Faradaic efficiency (FE) of CO production at –0.49 V RHE with a turnover frequency (TOF) of 57,379 h –1 . Large-scale synthesis coupled with high performance allows moving forward with the practical implementation of M–N–C catalysts for industrially relevant CO 2 RR.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1972

Encoding and decoding of color information using two-dimensional spatial filtering.

Spatial frequency encoding is described as it applies to both photographic and television systems. In each case, color separations amplitude modulate spatial frequency carriers. The photographic system separates the carriers in the two-dimensional Fourier transform plane using coherent optics; the television system employs a two-dimensional electrical filter to perform the same separation. These filters are synthesized so that the two-dimensional bandwidths of the television camera are used efficiently. Nonlinear processing techniques are also described to minimize crosstalk between channels.

Schaefer, L. F.↗
NASA NTRS1985

Forward and reverse transfer function model synthesis

A process for synthesizing a mathematical model for a linear mechanical system using the forward and reverse Fourier transform functions is described. The differential equation for a system model is given. The Bode conversion of the differential equation, and the frequency and time-domain optimization matching of the model to the forward and reverse transform functions using the geometric simplex method of Nelder and Mead (1965) are examined. The effect of the window function on the linear mechanical system is analyzed. The model is applied to two examples; in one the signal damps down before the end of the time window and in the second the signal has significant energy at the end of the time window.

Houghton, J. R.↗
NASA NTRS1989

Robust computer-aided synthesis and optimization of linear multivariable control systems with varying plant dynamics via AUTOCON

AUTOCON is an automated computer-aided design tool for the synthesis and optimization of linear multivariable control systems based upon user-defined control parameter optimization. Violations in stability and performance requirements are computed from constraints on Single Input/Single Output (SISO) open- and closed-loop transfer function frequency responses, and from constraints on the singular-value frequency responses of Multiple Input/Multiple Output (MIMO) transfer functions, for all critical plant variations. Optimum nonlinear programming algorithms are used in the search for local constrained solutions in which violations in stability and performance are caused either to vanish or be minimized for a proper selection of the control parameters. Classical control system stability and performance design can, in this way, be combined with modern multivariable robustness methods to offer general frequency response loop-shaping via a computer-aided design tool. Complete Nichols, Nyquist, Bode, singular-value Bode magnitude and transient response plots are produced, including user-defined boundary responses. AUTOCON is used to synthesize and optimize the lateral/directional flight control system for a typical high-performance aircraft.

Lefkowitz, C. P.↗
NASA NTRS2000

Robustness of Flexible Systems With Component-Level Uncertainties

Robustness of flexible systems in the presence of model uncertainties at the component level is considered. Specifically, an approach for formulating robustness of flexible systems in the presence of frequency and damping uncertainties at the component level is presented. The synthesis of the components is based on a modifications of a controls-based algorithm for component mode synthesis. The formulation deals first with robustness of synthesized flexible systems. It is then extended to deal with global (non-synthesized ) dynamic models with component-level uncertainties by projecting uncertainties from component levels to system level. A numerical example involving a two-dimensional simulated docking problem is worked out to demonstrate the feasibility of the proposed approach.

Maghami, Peiman G.↗
DOE OSTI2021

Deeper Understanding of Mononuclear Manganese(IV)–Oxo Binding Brønsted and Lewis Acids and the Manganese(IV)–Hydroxide Complex

Binding of Lewis acidic metal ions and Brønsted acid at the metal–oxo group of high-valent metal–oxo complexes enhances their reactivities significantly in oxidation reactions. However, such a binding of Lewis acids and proton at the metal–oxo group has been questioned in several cases and remains to be clarified. In this work, we report the synthesis, characterization, and reactivity studies of a mononuclear manganese(IV)–oxo complex binding triflic acid, {[(dpaq)Mn IV (O)]–HOTf} + (1–HOTf). First, 1–HOTf was synthesized and characterized using various spectroscopic techniques, including resonance Raman (rRaman) and X-ray absorption spectroscopy/extended X-ray absorption fine structure. In particular, in rRaman experiments, we observed a linear correlation between the Mn–O stretching frequencies of 1–HOTf (e.g., ν Mn–O at ~793 cm –1 ) and 1–M n+ (Mn + = Ca 2+ , Zn 2+ , Lu 3+ , Al 3+ , or Sc 3+ ) and the Lewis acidities of H + and M n+ ions, suggesting that H+ and Mn+ bind at the metal–oxo moiety of [(dpaq)Mn IV (O)] + . Interestingly, a single-crystal structure of 1–HOTf was obtained by X-ray diffraction analysis, but the structure was not an expected Mn(IV)–oxo complex but a Mn(IV)–hydroxide complex, [(dpaq)Mn IV (OH)](OTf) 2 (4), with a Mn–O bond distance of 1.8043(19) Å and a Mn–O stretch at 660 cm –1 . More interestingly, 4 reverted to 1–HOTf upon dissolution, demonstrating that 1–HOTf and 4 are interconvertible depending on the physical states, such as 1–HOTf in solution and 4 in isolated solid. The reactivity of 1–HOTf was investigated in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions and then compared with those of 1–Mn+ complexes; an interesting correlation between the Mn–O stretching frequencies of 1–HOTf and 1–M n+ and their reactivities in the OAT and HAT reactions is reported for the first time in this study.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Summary of GFL Inverter Capability and Performance: Malawi [Slides]

This presentation provides a comprehensive comparison of inverter-based resource (IBR) technical requirements across multiple international grid codes - including IEEE 2800, ESO, EirGrid, and Malawi's evolving regulatory framework - to support capacity building for electricity-sector institutions in Malawi. It highlights key performance expectations for grid-following (GFL) inverters across critical domains such as primary and fast frequency response, ramping behavior, frequency and voltage ride-through capabilities, reactive power and voltage control, ROCOF withstand, phase jump tolerance, system strength considerations, protection schemes, and dynamic modeling requirements. Emphasizing a "Do no harm, do something, do more" philosophy, the document synthesizes best practices and operational benchmarks to guide the integration and stability of inverter-based resources within Malawi's power system. The presentation forms part of the SABESS Center of Excellence initiative supported by the Global Energy Alliance for People and the Planet.

24 POWER TRANSMISSION AND DISTRIBUTION↗
NASA NTRS2019

Microphysical Retrievals from Simultaneous Measurements by Airborne and Ground Radars during OLYMPEX

The OLYMPEX field campaign took place over the Olympic Peninsula of Washington during winter 2015-2016. During the intensive observing period, several aircraft flights obtained multi-frequency airborne radar measurements at X-, Ku-, Ka, and W-band from radars aboard the ER-2 and DC-8 aircraft. In addition, ground radars at S- and X-band performed RHI scans under the aircraft ground tracks. These coincident datasets provide a wealth of complementary information about the hydrometeor particle sizes, shapes, and orientations.In order to synthesize these measurements and test the robustness of scattering models, an optimal estimation retrieval based upon a Hitschfeld-Bordan profiling algorithm has been developed. This algorithm retrieves profiles of the particle size distribution parameters Nw and Dm, and, in the ice phase, relative proportions of aggregate, pristine, and rimed particles, using scattering models with different size-density and size-aspect ratio relationships. Under this formulation, only the pristine particles are horizontally aligned and capable of producing non-zero ZDR and KDP.From the nadir-looking airborne multifrequency radars, we find that aggregates may be readily distinguished from rimed and pristine particles owing to their uniqueness in triple-frequency space. However, rimed and pristine particles occupy a similar region in this space and thus polarimetric measurements greatly enhance their identification in our retrieval framework. With these capabilities we will present analyses of three-dimensional hydrometeor mapping obtained during various OLYMPEX cases. Some features retrieved in these cases include a layer of enhanced aggregation about 2km above the melting layer, hypothesized to be maintained by orographic uplift. This layer is often situated above a layer of denser, aligned particles. Regions of riming and supercooled liquid water beneath generating cells are also identified by our retrieval algorithm. Comparisons to in-situ observations and evaluation of scattering models will be presented.

Munchak, S. Joseph↗
DOE OSTI2022

Investigating Deposition Sequence During Synthesis of Pd/Al2O3 Catalysts Modified with Organic Monolayers

Modification of supported metal catalysts with self-assembled monolayers (SAMs) has been shown to improve selectivity and turnover frequencies (TOFs) for many catalytic reactions. However, these benefits are often accompanied by a decrease in overall mass activity due to partial blocking of active sites by the monolayers. Therefore, a potential method for increasing site accessibility is to deposit the active metal (e.g., Pd) after deposition of a SAM modifier on the support material. In this work, Pd/Al2O3 catalysts were synthesized using both a conventional, "metal-first" sequence in which the phosphonic acid (PA) SAM was deposited on Pd/Al2O3 and a "SAM-first" technique in which the ligands were deposited onto the support prior to deposition of the metal. Although metal-first catalysts showed a significant increase in TOF during benzyl alcohol HDO, they exhibited only a modest increase in overall mass activity due to a decrease in the number of active sites. Meanwhile, SAM-first catalysts showed similar improvements in TOF and toluene selectivity but exhibited significantly improved HDO rates compared to metal-first catalysts. The rate increase was attributed to reduced site blocking as evidenced by CO chemisorption measurements. Additionally, analysis of catalysts having high Pd loadings using transmission electron microscopy (TEM) showed that SAM-first catalysts generally resulted in lower average particle sizes than traditionally modified and unmodified catalysts, suggesting that precoating the support surface with PAs changes the way that Pd is deposited during incipient wetness, leading here to improved activity.

catalytic reactions↗
DOE OSTI2024

Scalable Enrichment of 48 Ca at the Solid/liquid Interface by Chemical and Electrochemical Methods

This award targets to develop methods to enrich 48 Ca, which is a critical isotope for synthesizing superheavy elements and testing the standard model through neutrinoless double beta decay. The team first tested chemical exchange-based separation between solids and liquids, which is based on the free energy change due to the different vibrational frequencies caused by Ca isotopes in a material. However, the separation factor (alpha), which is defined as the ratio of 40 Ca/ 48 Ca ratios in the two phases, only reach ~1.01. The team then developed liquid centrifugation-based isotope separation, where a Ca salt aqueous solution is centrifuged at a speed of ~60 kRPM, and 48 Ca is enriched at the bottom of a centrifuge tube due to its larger mass. A high α of ~1.2-1.4 is achieved for 40 Ca/ 48 Ca at 40 °C. This method is further approved to be generic for any isotope that can be dissolved in a liquid solution or form liquid chemicals near room temperature. The experimental results also align well with modeling prediction. The team further develop a model to evaluate isotope separation in countercurrent liquid centrifugation. The team found that the countercurrent configuration can also enhance isotope separation in liquids, similar with gas centrifugation, which boost separation for isotopes which are difficult to be gasified near room temperature.

07 ISOTOPE AND RADIATION SOURCES↗
DOE OSTI2026

Toward Tunable Magnetic Dirac Semimetals: Mn Doping of Cd 3 As 2

Magnetic impurities provide a route toward increasing functionality in electronic materials, often enabling new device concepts and architectures. In the case of topological semimetals, dilute magnetic doping presents a particularly attractive approach for inducing a Dirac to Weyl phase change via time reversal symmetry breaking. However, efforts to realize changes in the electronic structure have been limited by challenges in incorporating magnetic impurities into crystals with sufficiently high electron mobilities to detect them via transport or spectroscopic techniques. Here, we demonstrate incorporation of Mn into Cd 3 ⁢As 2 Dirac semimetal thin films grown by molecular beam epitaxy (MBE). Using As-rich growth conditions and [001] oriented thin films, Mn compositions of >10% are achieved. Films contain uniform distributions of Mn with no evidence of secondary phases and exhibit electron mobilities greater than 10 000–30 000 cm 2 /Vs up to 5% Mn. An evolution in the magnetization behavior along with the emergence of a second quantum oscillation frequency at low Mn concentrations provide preliminary evidence of Mn-induced changes in the electronic structure that are consistent with a Weyl phase. This work demonstrates the potential of magnetically doping topological semimetal thin films and a pathway for synthesizing them.

36 MATERIALS SCIENCE↗