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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

Supersonic flow of chemically reacting gas-particle mixtures. Volume 1: A theoretical analysis and development of the numerical solution

A numerical solution for chemically reacting supersonic gas-particle flows in rocket nozzles and exhaust plumes was described. The gas-particle flow solution is fully coupled in that the effects of particle drag and heat transfer between the gas and particle phases are treated. Gas and particles exchange momentum via the drag exerted on the gas by the particles. Energy is exchanged between the phases via heat transfer (convection and/or radiation). Thermochemistry calculations (chemical equilibrium, frozen or chemical kinetics) were shown to be uncoupled from the flow solution and, as such, can be solved separately. The solution to the set of governing equations is obtained by utilizing the method of characteristics. The equations cast in characteristic form are shown to be formally the same for ideal, frozen, chemical equilibrium and chemical non-equilibrium reacting gas mixtures. The particle distribution is represented in the numerical solution by a finite distribution of particle sizes.

Penny, M. M.↗

Some applications of equilibrium thermodynamic properties to continuum gasdynamics

The speed of sound for the propagation of isentropic disturbances in a gas is developed, including corrections for chemical reaction. The term zero frequency is used to describe this isentropic limit sound speed; the term signifies that change in the gasdynamic variables are all very slow compared with the chemical rate changes in the gas. A faster, nonisentropic speed of propagation occurs for disturbances where the changes in gasdynamic variables are fast compared with the chemical rate changes. In the limit, this is known as the infinite frequency or frozen sound speed - the former term calling attention to the very high frequency of the disturbance, the latter term calling attention to the frozen character of the chemical reactions under such rapid changes of state. The true sound speed for a disturbance of finite frequency is shown to be between these two limits and is expressed in terms of the chemical relaxation time. The Riemann invariants that are useful in determining the changes in flow speed along characteristic directions in supersonic flow are derived in terms of integrations of acoustic impedance, and example results are given for air.

Source record↗

Nonhomologous contraction and equilibria of self-gravitating, magnetic interstellar clouds embedded in an intercloud medium: Star formation. II - Results

The paper studies the equilibrium of self-gravitating isothermal models of interstellar clouds with a frozen-in magnetic field linked smoothly to the field of a hot tenuous intercloud medium. Equilibrium states are determined which can be reached by clouds contracting nonhomologously from a spherical uniform initial state. Three free parameters characterize the problem: a dimensionless initial radius related to the Jeans length of the cloud, the initial ratio of the magnetic and gas pressures in the cloud, and the initial ratio of the intercloud and cloud pressures. The dependence of the solutions on each of these parameters is investigated. It is found that: (1) the frozen-in field causes the cloud to become oblate with its major axis normal to the field lines; (2) the flattening increases as the magnetic-field strength, gravitational forces, or intercloud pressure increases; (3) increasing intercloud pressure eventually leads to gravitational collapse; and (4) the cloud can reach equilibrium only if its radius does not exceed some critical value. The observed inefficiency of the star-formation process within massive clouds is examined and explained in terms of magnetic phenomena in a collapsing cloud.

Mouschovias, T. C.↗

The possible role of solid surface area in condensation reactions during chemical evolution - Reevaluation

Using surface concentration and reaction rate as the main criteria for the feasibility of condensation reactions, four types of prebiotic environments were analyzed: (1) an ocean-sediment system, (2) a dehydrated lagoon bed produced by evaporation, (3) the surface of a frozen sediment, and (4) a fluctuating system where hydration (rainstorms, tidal variations, flooding) and dehydration (evaporation) take place in a cyclic manner. With the possible exception of nucleotides, low adsorption of organomonomers on sediment surfaces of a prebiotic ocean (pH 8) is expected, and significant condensation is considered unlikely. In dehydrated and frozen systems, high surface concentrations are probable and condensation is more likely. In fluctuating environments, condensation rates will be enhanced and the size distribution of the oligomers formed during dehydration may be influenced by a 'redistribution mechanism' in which adsorbed oligomers and monomers are desorbed and redistributed on the solid surface during the next hydration-dehydration cycle.

Lahav, N.↗

Streamtube analysis of a hydrogen-burning scramjet exhaust and simulation technique

A scramjet/airframe integration program and a technique for simulating thermally perfect scramjet exhaust flows (freon/argon gas blends) is studied to extend the technique to more complicated flows approaching the actual exhaust flow in complexity. The state of the flow and the accuracy of the substitute gas simulation are analyzed in the case of a shock discontinuity present. Findings are: scramjet exhaust flow is essentially frozen throughout the expansion at Mach 6 and Mach 8; flow behind moderate shocks remains frozen; the technique can accurately track static distributions in scramjet exhaust flows (shocked or unshocked).

Talcott, N. A., Jr.↗

Stress intensity estimates by a computer assisted photoelastic method

Following an introductory history, the frozen stress photoelastic method is reviewed together with analytical and experimental aspects of cracks in photoelastic models. Analytical foundations are then presented upon which a computer assisted frozen stress photoelastic technique is based for extracting estimates of stress intensity factors from three-dimensional cracked body problems. The use of the method is demonstrated for two currently important three-dimensional crack problems.

Smith, C. W.↗

Differences in radar return from ice-covered North Slope Lakes

Comparisons are made between L and X band synthetic aperture radar images of frozen lakes on the North Slope of Alaska and ground truth observations of the nature of their ice covers. It is shown that the differences in radar backscatter observed on different areas of a lake can be correlated with whether or not the lake is frozen completely to the bottom at the site in question. This explanation is reasonable inasmuch as the reflection coefficient associated with the high-dielectric contrast ice/water interface is significantly higher than that associated with a low-contrast ice/soil interface. However, the presence of the ice/water interface cannot be the only condition required for the higher backscatter because the ice/water interface per se would be specular at X and L band frequencies, causing the energy returned from the interface to be reflected away from the radar receiver. The other principal factor contributing to the return of energy from the ice/water interface to the receiver is believed to be the presence in the ice of numerous vertically elongated air bubbles which would act as scatters.

Weeks, W. F.↗

The multiple nesting of mesoscale, submesoscale, and nonhydrostatic microscale numerical models for a case of mesocyclogenesis and severe storm development

A fundamental approach involving the integration of two different numerical models over several different spatial mesh lengths is considered. Model I is a hydrostatic, incompressible, and adiabatic primitive (Newtonian) equation set with no boundary layer forcing, i.e., surface heat or moisture flux or external frictional stresses. Typically this model is initialized from conventional radiosonde data and run for a 12-15 hour forecast period over a 40 km horizontal mesh. If phase I of the tornado developmental processes develops, the data is 'frozen' in space and time, interpolated to a 20 km mesh, and integrated for a shorter time period (3 hours) with a shorter time step. Model II is a nonhydrostatic compressible 18-level complement of model I. If model II indicates the development of the intensification of phase V dynamical processes, the data is frozen and interpolated to finer mesh lengths until the tornadic circulation system is approximated

Kaplan, M. L.↗

Is there liquid water on Europa

It is possible that tidal dissipation in an ice crust on Europa preserved a liquid water layer beneath it, provided that the three-body orbital resonance for Io, Europa, and Ganymede is ancient. The liquid water layer could be a continuing source of the observed surface frost. If Europa's water mantle were ever completely frozen, heating by tidal dissipation would not exceed that produced by radioactive elements, and the mantle would remain frozen.

Cassen, P.↗

Cryogenic machining of polyurethane foam

Low-density foam can be machined precisely while frozen. Liquid nitrogen cools foam and aluminum heat sink prior to machining. Heat sink keeps part frozen during entire machining operation.

Moshey, E. A.↗

Dynamic behavior of an unsteady trubulent boundary layer

Experiments on an unsteady turbulent boundary layer are reported in which the upstream portion of the flow is steady (in the mean) and in the downstream region, the boundary layer sees a linearly decreasing free stream velocity. This velocity gradient oscillates in time, at frequencies ranging from zero to approximately the bursting frequency. For the small amplitude, the mean velocity and mean turbulence intensity profiles are unaffected by the oscillations. The amplitude of the periodic velocity component, although as much as 70% greater than that in the free stream for very low frequencies, becomes equal to that in the free stream at higher frequencies. At high frequencies, both the boundary layer thickness and the Reynolds stress distribution across the boundary layer become frozen. The behavior at higher amplitude is quite similar. At sufficiently high frequencies, the boundary layer thickness remains frozen at the mean value over the oscillation cycle, even though flow reverses near the wall during a part of the cycle.

Parikh, P. G.↗

Observational data needs useful for modeling the coma

A computer model of comet comae is described; results from assumed composition of frozen gases are summarized and compared to coma observations. Restrictions on relative abundance of some frozen constituents are illustrated. Modeling, when tightly coupled to observational data, can be important for comprehensive analysis of observations, for predicting undetected molecular species and for improved understanding of coma and nucleus. To accomplish this, total gas production rates and relative elemental abundances of H:C:N:O:S are needed as a function of heliocentric distance of the comet. Also needed are relative column densitites and column density profiles with well defined diaphragm range and pointing position on the coma. Production rates are less desirable since they are model dependent. Total number (or upper limits) of molecules in the coma and analysis of unidentified spectral lines are needed also.

Huebner, W. F.↗

Possible applications of time domain reflectometry in planetary exploration missions

The use of a time domain reflectometer (TDR) for planetary exploration is considered. Determination of the apparent dielectric constant and hence, the volumetric water content of frozen and unfrozen soils using the TDR is described. Earth-based tests were performed on a New York state sandy soil and a Wyoming Bentonite. Use of both a cylindrical coaxial transmission line and a parallel transmission line as probes was evaluated. The water content of the soils was varied and the apparent dielectric constant measured in both frozen and unfrozen states. Advantages and disadvantages of the technique are discussed.

Heckendorn, S.↗

Theoretical studies of photodissociation of small molecules of astrophysical importance

The radicals and ions observed in comets result from photodissociation and photoionization of molecules. According to current models, a comet is composed chiefly of a large, solid nucelus of frozen gases (parent molecules) such as H2O, HCN, and NH3. It is believed comets were formed at the same time and in the same region of space as the major planets and that their chemical composition is the same as that of the early solar system. As the comet nears the Sun, the surface heats up, liberating the frozen gases as well as dust particles. Solar radiation photodissociates the parent molecules into fragments that are observed by resonance fluorescence. Both polyatomic molecules, present in the interstellar medium, and cometary radicals were observed. Using laboratory photo-dissociation data and computer models, astronomers are attempting to identify the parent molecules that account for all observed radicals and ions.

Saxon, R. P.↗

Chemical weathering and diagenesis of a cold desert soil from Wright Valley, Antarctica - An analog of Martian weathering processes

Weathering, diagenesis, and chemical alteration of a soil profile from the Dry Valleys of Antarctica are investigated as an analog to soil development within the Martian regolith. Soil samples from a soil pit one meter deep on Prospect Mesa, Wright Valley, are examined for their major element concentrations, water-soluble cations and anions, carbon, sulfur, and water concentrations, and related petrographic characteristics of weathering in a cold, dry environment. A petrographic study of the samples suggests that most silicate mineral and lithic fragments exhibit some degree of alteration. Chemical alteration occurs both in samples above and within the permanently frozen zone. The concentrations of water-soluble cations, for example, Na(+), K(+), Ca(2+), and anions, Cl(-), SO4(2-), NO3(-), are found to decrease significantly from the surface to the permanently frozen zone, suggesting a major movement of water-soluble species. It is also found that enrichments in secondary mineral abundances correlate with the water soluble ion concentrations. The formation of zeolites is seen throughout the soil column; these, it is thought, may be reservoirs for volatile storage within the regolith.

Gibson, E. K.↗

Dynamic behavior of an unsteady turbulent boundary layer

Experiments on an unsteady turbulent boundary layer are reported in which the upstream portion of the flow is steady (in the mean) and in the downstream region, the boundary layer sees a linearly decreasing free stream velocity. This velocity gradient oscillates in time, at frequencies ranging from zero to approximately the bursting frequency. For the small amplitude, the mean velocity and mean turbulence intensity profiles are unaffected by the oscillations. The amplitude of the periodic velocity component, although as much as 70 percent greater than that in the free stream for very low frequencies, becomes equal to that in the free stream at higher frequencies. At high frequencies, both the boundary layer thickness and the Reynolds stress distribution across the boundary layer become frozen. The behavior at higher amplitude is quite similar. At sufficiently high frequencies, the boundary layer thickness remains frozen at the mean value over the oscillation cycle, even though flow reverses near the wall during a part of the cycle. Previously announced in STAR as N81-28392

Parikh, P. G.↗

A new analysis of charge transfer and polarization for ligand-metal bonding - Model studies of Al4CO and Al4NH3

The nature of the bonding of CO and NH3 ligands to Al is analyzed, and the intra-unit charge polarization and inter-unit donation for the interaction of ligands with metals are studied. The consequences of metal-to-ligand and ligand-to-metal charge transfer are separately considered by performing a constrained space orbital variation (CSOV) with the electrons of the metal member of the complex in the field of frozen ligand. The electrons of the metal atoms are then frozen in the relaxed distribution given by the CSOV SCF wave function and the ligand electrons are allowed to relax. Quantitative measures of the importance of inter-unit charge transfers and intra-unit polarization are obtained using results of SCF studies of Al4CO and Al4NH3 clusters chosen to simulate the adsorption of the ligands at an on-top side of the Al(111) surface. The electrostatic attraction of the effective dipole moments of the metal and ligand units makes an important contribution to the bond.

Bagus, P. S.↗

Spring-Loaded Joule-Thomson Valve

Improved design reduces clogging and maintains constant pressure drop as flow rate varies. Spring-Loaded Joule-Thomson Valve pressure drop regulated by spring pushing stainless-steel ball against soft brass seat. Pressure drop remains nearly constant, regardless of helium flow rate and of any gas contaminants frozen on valve seat. Because springloaded J-T valve maintains constant pressure drop, upstream roomtemperature throttle valve adjusts flow rate precisely for any given upstream pressure. In addition, new valve relatively invulnerable to frozen gas contaminants, which clog fixed-orifice J-T valves.

Jones, J. A.↗