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At least 253 records · Page 14

Morphological Evolution and Weak Interface Development within CVD-Zirconia Coating Deposited on Hi-Nicalon Fiber

The phase contents and morphology of a ZrO2 fiber coating deposited at 1050 C on Hi-Nicalon(Tm) by chemical vapor deposition were examined as a function of deposition time from 5 to 120 min. The morphological evolution in the ZrO2 coating was correlated to the development of delamination within the ZrO2 coating. The delamination appears to occur as a result of: (1) continuous formation of tetragonal ZrO2 nuclei on the deposition surface; (2) martensitic transformation of the tetragonal phase to a monoclinic phase upon reaching a critical grain size; and (3) development of significant compressive hoop stresses due to the volume dilation associated with the transformation. Our observations suggest that it will be of critical importance to further understand and eventually control the nucleation and grain growth behavior of CVD ZrO2 and its phase transformation behavior for its potential applications for composites.

Li, Hao↗

SIMS Studies of Allende Projectiles Fired into Stardust-type Aluminum Foils at 6 km/s

We have explored the feasibility of C-, N-, and O-isotopic measurements by NanoSIMS and of elemental abundance determinations by TOF-SIMS on residues of Allende projectiles that impacted Stardust-type aluminum foils in the laboratory at 6 km/s. These investigations are part of a consortium study aimed at providing the foundation for the characterization of matter associated with micro-craters that were produced during the encounter of the Stardust space probe with comet 81P/Wild 2. Eleven experimental impact craters were studied by NanoSIMS and eighteen by TOF-SIMS. Crater sizes were between 3 and 190 microns. The NanoSIMS measurements have shown that the crater morphology has only a minor effect on spatial resolution and on instrumental mass fractionation. The achievable spatial resolution is always better than 200 nm, and C- and O-isotopic ratios can be measured with a precision of several percent at a scale of several 100 nm, the typical size of presolar grains. This clearly demonstrates that presolar matter, provided it survives the impact into the aluminum foil partly intact, is recognizable even if embedded in material of Solar System origin. TOF-SIMS studies are restricted to materials from the crater rim. The element ratios of the major rockforming elements in the Allende projectiles are well characterized by the TOF-SIMS measurements, indicating that fractionation of those elements during impact can be expected to be negligible. This permits information on the type of impactor material to be obtained. For any more detailed assignments to specific chondrite groups, however, information on the abundances of the light elements, especially C, is crucial.

Hoppe, Peter↗

Morphology and types of particles of regolith sample from the Sea of Fertility

A brief description of the morphology of lunar surface material returned by Luna 16 automatic lunar station is given. Adhesiveness of the surface material and its ability to be electrified is noted. Two main genetic groups of regolith particles are differentiated: primary, represented mainly by fragments of magmatic rocks of the basalt and gabbro types, as well as mineralized grains of their constituent minerals, and secondary, particles subjected to appreciable exogenic transformation on the surface of the Moon. The second group, representing more than 70 percent of the material in coarse fractions, includes particles of breccias, sintered aggregates of complex dendritic form, and glass and vitrified particles of varied composition.

Florenskiy, K. P.↗

Stability of Y-Ba-Cu-oxide phases in salt flux

The results of an investigation into the possibility of growing YBa2Cu3O7 (or Y123) single crystals from a NaCl-KCl flux (salt flux) are presented. They are compared with results for Y123 crystals grown from a Ba-Cu-oxide flux system. The chosen salt flux composition was 1:1 (NaCl:KCl). The preparation method of the solutes is presented, with particular attention given to the compounds surrounding the Y123 phase, such as Y2BaCuO6 (Y211). Optical microscopy was introduced to study the morphology of the sample; X-ray diffraction was used for phase identification; and a chemical analysis was effected. The Y123, Y211, and BaCuO2 phases were shown to be dissociated in the NaCl-KCl flux, and could not be recrystallized. A small amount of the flux could be added to create large-grain Y123 crystals, but single-crystal growth was not possible in a top-seeded NaCl-KCl solution. This is attributed to significant differences in solubility of the crystal elements, and phase separation caused by CuO crystal formation.

Tao, Y. K.↗

A quantitative study of factors influencing lamellar eutectic morphology during solidification

The factors that influence the shape of the solid-liquid interface of a lamellar binary eutectic alloy are evaluated. Alloys of carbon tetrabromide and hexachloroethane which serve as a transparent analogue of lamellar metallic eutectics are used. The observed interface shapes are analyzed by computer-aided methods. The solid-liquid interfacial free energies of each of the individual phases comprising the eutectic system are measured as a function of composition using a 'grain boundary groove' technique. The solid-liquid interfacial free energy of the two phases are evaluated directly from the eutectic interface. The phase diagram for the system, the heat of fusion as a function of composition, and the density as a function of composition are measured. The shape of the eutectic interface is controlled mainly by the solid-liquid and solid-solid interfacial free energy relationships at the interface and by the temperature gradient present, rather than by interlamellar diffusion in the liquid at the interface, over the range of growth rates studied.

Kaukler, W. F. S.↗

The embedded young stars in the Taurus-Auriga molecular cloud. II - Models for scattered light images

We describe NIR imaging observations of embedded young stars in the Taurus-Auriga molecular cloud. We find a large range in J-K and H-K colors for these class I sources. The bluest objects have colors similar to the reddest T Tauri stars in the cloud; redder objects lie slightly above the reddening line for standard ISM dust and have apparent K extinctions of up to 5 mag. Most of these sources also show extended NIR emission on scales of 10-20 arcsec which corresponds to linear sizes of 1500-3000 AU. The NIR colors and nebular morphologies for this sample and the magnitude of linear polarization in several sources suggest scattered light produces most of the NIR emission in these objects. We present modeling results that suggest mass infall rates that agree with predictions for cold clouds and are generally consistent with rates estimated from radiative equilibrium models. For reasonable dust grain parameters, the range of colors and extinctions require flattened density distributions with polar cavities evacuated by bipolar outflows. These results support the idea that infall and outflow occur simultaneously in deeply embedded bipolar outflow sources. The data also indicate fairly large centrifugal radii and large inclinations to the rotational axis for a typical source.

Kenyon, Scott J.↗

Hypervelocity Dust Impact in Olivine: Fib/Tem Characterization and Comparison of Experimental and Natural Microcraters

The flux of objects impacting the surfaces of solar system airless bodies is dominated by micrometeoroids less than 1 mm diameter whose impact effects play a major role in the space weathering of airless body surfaces. To obtain better understanding of how small scale impact effects vary as a function of impact speed in an important lunar and asteroidal mineral, we produced artificial microcraters in San Carlos olivine using Fe metal dust particles 0.10 to 5 µm in diameter electrostatically accelerated to speeds between 0.35 to 25 km s-1. The crater morphologies, size distrrubiton and microstruc-tures were characterized by field-emission SEM (FE-SEM) and also by FIB cross sectioning of selected craters for field-emission scanning transmission electron microscopy (FE-STEM). These same techniques were also applied to study a natural 20 µm-diameter microcrater in a olivine grain on the surface of lunar rock 12075. Measured microcrater diameters in the experimental sample range between 0.20 to 5 µm with larger craters having more irregular outlines dominated by spallation fractures. FE-SEM and FE-STEM imaging docu-ment the formation of shock melt in the size population of experimental craters below approximately 1 µm in diameter, corresponding to particle impact speeds in the 10-25 km s-1 range. The natural olivine crater exhibits similar shock melt features along the perimeter of its cavity, but the shock melt also contains nanophase Fe metal particles, something not observed in the experimental samples. FE-STEM imaging of the experimental craters reveals complex shock-generated dislocation and nanofracture microstructures in zones extend-ing 1-2 µm into the olivine from the crater cavity. The natural microcrater shows a lower density of shock-generated disloca-tions that extends a factor of 2 deeper into the the olivine than in the experimental samples.

Roy Gray Christoffersen↗

Endolithic algae and micrite envelope formation in Bahamian oolites as revealed by scanning electron microscopy.

Examination of Holocene Bahamian ooelites by scanning electron and light microscopy has revealed the morphology and orientation of aragonite crystals in the lamellar ooelitic envelope, and their modification by the boring activities of endolithic algae. The voids produced by these algae are found in progressive stages of being lined and filled with precipitated microcrystalline aragonite, which is similar to the process of micrite envelope formation in molluscan and other skeletal carbonate grains.

Margolis, S.↗

CCD observations of additional interstellar lines in stars associated with the Vela Remnant and Eta Carinae nebulosity

Nine stars from the Vela Remnant and seven stars in the Eta Carinae complex are examined with CCD spectrograms with high signal-to-noise ratios for data regarding the optical interstellar lines. These data are supplemented by observations of objects with known high-velocity components and substantial interstellar Ti II lines. The CCD spectrograms have signal-to-noise ratios of 100-300, a 2-pixel resolving power of 20,000, and cover features of Na I, Ti II, Ca I, CH(+), and CH in the 3200-4400-A range. The Ca I line confirms the high H density in Vela, and the Ti II lines show evidence of shock-induced grain evaporation. Weak shocks are thought to contribute to the CH(+) component, and a high H I density in some clouds is inferred from the CH line. The high H I density is supported by IUE data on Ca I and on the fine-structure carbon lines. The data point to a significant difference in spectroscopic morphology between the two groups of stars, and the need for theoretical support is underscored.

Wallerstein, George↗

Mineral Biomarkers in Martian Meteorite Allan Hills 84001?

The occurrence of fine-grained magnetite in the Fe-rich rims surrounding carbonate globules in the martian meteorite ALH84001, originally described in , have been proposed as fossil remains of primitive martian organisms. Here we report observations on size and shape distributions of magnetites from ALH84001 and compare them to biogenic and inorganic magnetite crystals of terrestrial origin. While some magnetite morphology is not unequivocally diagnostic for its biogenicity, such as cubodial forms of magnetite, which are common in inorganically formed magnetites, other morphologies of magnetite (parallel-epiped or elongated prismatic and arrowhead forms) are more likely signatures of biogenic activity. Some ALH 84001 magnetite particles described below have unique morphology and length-to-width ratios that are indistinguishable from a variety of terrestrial biogenic magnetite and distinct from all known inorganic forms of magnetite.

Thomas-Keprta, K. L.↗

Constraining the Origin of Impact Craters on Al Foils from the Stardust Interstellar Dust Collector

Preliminary examination (PE) of the aerogel tiles and Al foils from the Stardust Interstellar Dust Collector has revealed multiple impact features. Some are most likely due to primary impacts of interstellar dust (ISD) grains, and others are associated with secondary impacts of spacecraft debris, and possibly primary impacts of interplanetary dust particles (IDPs) [1, 2]. The current focus of the PE effort is on constraining the origin of the individual impact features so that definitive results from the first direct laboratory analysis of contemporary ISD can be reported. Because crater morphology depends on impacting particle shape and composition, in addition to the angle and direction of impact, unique particle trajectories are not easily determined. However, elemental analysis of the crater residues can distinguish real cosmic dust from the spacecraft debris, due to the low cosmic abundance of many of the elements in the spacecraft materials. We present here results from the elemental analysis of 24 craters and discuss the possible origins of 4 that are identified as candidate ISD impacts

Stroud, Rhonda M.↗

Lunar and Planetary Science XXXV: Carbonaceous Chondrites

The titles in this section include: 1) A Quantitative NMR Analysis of Phosphorus in Carbonaceous and Ordinary Chondrites; 2) An Infrared Study of the Matrices of CI1 and CM2 Chondrites; 3) A Study of the Morphology, Composition and Mineral Associations of Fe-Ni Sulphides in CM Carbonaceous Chondrites; 4) Aqueous Alteration Mineralogy in CM Carbonaceous Chondrites; 5) In Situ Location and Characterization of Carbon-bearing Phases in Carbonaceous; 6) Chondrites: Insights from Yamato 791198, a Weakly-altered CM2 Chondrite; 7) Unique Texture in EET 83389: Clues to Formation of Fine Grained Rims in CM Chondrites; 8) Amoeboid Olivine Aggregates in the NWA 760 CV3 Chondrite; 9) Petrologic Type of CV3 Chondrites as Revealed by Raman Spectroscopy of Organic Matter; 10) A First Look at Acfer 324: Evidence for Another CR 3 Chondrite? 11) Hydrogen Isotopic Composition of the Bencubbin Meteorite; 12) The Fountain Hills Meteorite: A New CBa Chondrite from Arizona; 13) Shock Effects in the Metal-rich Chondrites QUE 94411, Hammadah al Hamra 237 and Bencubbin; 14) Mineralogy and Petrology of Al-rich Objects in the CH Carbonaceous Chondrite North West Africa 739.

Source record↗

Diagnosing the Structure of the HD 163296 Protoplanetary Disk Via Coronagraphic Imaging Polarimetry

Coronagraphic imaging polarimetry is a high contrast imaging technique which can diagnose both the spatial distribution and size distribution of dust grains which comprise primordial protoplanetary disks. It can therefore be a useful tool to test our understanding of how the structure of young disks evolves through the era of gas giant planet formation. We report our initial analysis of the H-band polarized and total intensity of the nearby Herbig Ae star HD 163296, and characterize the morphology of the scattered light disk in the context of previous optical HST coronagraphic imagery. Our observations were obtained as part of a multi-epoch campaign designed to diagnose and correlate the behavior of the inner and outer regions of select protoplanetary disks. This campaign will help test recent suggestions (Sitko et al. 2008; Wisniewski et al. 2008) that that HD 163296 dis experiences the novel phenomenon of time-variable self-shadowing, whereby occasional changes in the scale height of the inner disk wall induces changes in the illumination of the outer disk.

Kowalski, Adam F.↗

Fomalhaut's Debris Disk and Planet: Constraining the Mass of Formalhaut B from Disk Morphology

Following the optical imaging of exoplanet candidate Fomalhaut b (Fom b), we present a numerical model of how Fomalhaut's debris disk is gravitationally shaped by a single interior planet. The model is simple, adaptable to other debris disks, and can be extended to accommodate multiple planets. If Fom b is the dominant perturber of the belt, then to produce the observed disk morphology it must have a mass M(sub pl) < 3M(sub J), an orbital semimajor axis a(sub pl) > 101.5AU, and an orbital eccentricity e(sub pl) = 0.11 - 0.13. These conclusions are independent of Fom b's photometry. To not disrupt the disk, a greater mass for Fom b demands a smaller orbit farther removed from the disk; thus, future astrometric measurement of Fom b's orbit, combined with our model of planet-disk interaction, can be used to determine the mass more precisely. The inner edge of the debris disk at a approximately equals 133AU lies at the periphery of Fom b's chaotic zone, and the mean disk eccentricity of e approximately equals 0.11 is secularly forced by the planet, supporting predictions made prior to the discovery of Fom b. However, previous mass constraints based on disk morphology rely on several oversimplifications. We explain why our constraint is more reliable. It is based on a global model of the disk that is not restricted to the planet's chaotic zone boundary. Moreover, we screen disk parent bodies for dynamical stability over the system age of approximately 100 Myr, and model them separately from their dust grain progeny; the latter's orbits are strongly affected by radiation pressure and their lifetimes are limited to approximately 0.1 Myr by destructive grain-grain collisions. The single planet model predicts that planet and disk orbits be apsidally aligned. Fomalhaut b's nominal space velocity does not bear this out, but the astrometric uncertainties are difficult to quantify. Even if the apsidal misalignment proves real, our calculated upper mass limit of 3 M(sub J) still holds. Parent bodies are evacuated from mean-motion resonances with Fom b; these empty resonances are akin to the Kirkwood gaps opened by Jupiter. The belt contains at least 3M(sub Earth) of solids that are grinding down to dust, their velocity dispersions stirred so strongly by Fom b that collisions are destructive. Such a large mass in solids is consistent with Fom b having formed in situ.

Chiang, E.↗

Exocometary Gas in the HD 181327 Debris Ring

An increasing number of observations have shown that gaseous debris discs are not an exception. However, until now, we only knew of cases around A stars. Here we present the first detection of 12CO (2-1) disc emission around an F star, HD 181327, obtained with the Atacama Large Millimeter/submillimeter Array (ALMA) observations at 1.3 mm. The continuum and CO emission are resolved into an axisymmetric disc with ring-like morphology. Using a Markov chain Monte Carlo method coupled with radiative transfer calculations, we study the dust and CO mass distribution. We find the dust is distributed in a ring with a radius of 86.0 +/- 0.4 au and a radial width of 23.2 +/- 1.0 au. At this frequency, the ring radius is smaller than in the optical, revealing grain size segregation expected due to radiation pressure. We also report on the detection of low-level continuum emission beyond the main ring out to approximately 200 au. We model the CO emission in the non-local thermodynamic equilibrium regime and we find that the CO is co-located with the dust, with a total CO gas mass ranging between 1.2 x 10(exp -6) solar mass and 2.9 x 10(exp -6) solar mass, depending on the gas kinetic temperature and collisional partners densities. The CO densities and location suggest a secondary origin, i.e. released from icy planetesimals in the ring. We derive a CO+CO2 cometary composition that is consistent with Solar system comets. Due to the low gas densities, it is unlikely that the gas is shaping the dust distribution.

exocometary gas↗

Preliminary Analyses of Asteroid Bennu Samples Returned by NASA’s OSIRIS-REx Mission

NASA’s OSIRIS-REx mission returned ~122 g of pristine carbonaceous regolith from Bennu on September 24, 2023. The science team is performing analyses of the mineralogy, chemical and isotopic compositions, and physical properties of the samples. The returned samples consist of particles ranging up to 3.5 cm in size with angular and hummocky morphologies predominating. Reflectance spectra over the visible and infrared wavelengths collected during the spacecraft encounter contained features indicating abundant hydrated phyllosilicates, carbonates, magnetite, organic matter, and rare anhydrous silicates. Laboratory analyses confirmed these detections and identified several other major and minor phases including abundant FeNi sulfides, minor hydrated Mg-rich phosphates as encrustations and in veins, and presolar grains. The Bennu samples show evidence for extensive aqueous alteration and resemble the rare and chemically primitive CI carbonaceous chondrites and samples returned from Ryugu by JAXA’s Hayabusa2 mission. Samples of Bennu’s uppermost surface, collected by contact pads, help us to understand how recent impacts and irradiation processes have changed the optical properties of Bennu surface materials measured by remote sensing. The analyses thus far highlight the value of sample return by illustrating the pristine nature of the samples compared to meteorites that have been compromised and altered by exposure to the terrestrial environment.

Lindsay P Keller↗

Physical Properties of Volcanic Deposits on Venus from Radar Polarimetry

Studies of the morphology and radar properties of volcanic deposits can aid in understanding their differences and formation. On Venus, volcanoes range in size from large highland edifices, such as Theia Mons, to small shields and domes which are often found in groups of tens to hundreds. In plains regions, windstreaks are sometimes found near shield fields, suggesting that there may be fine grained deposits associated with the volcanoes. Previous studies of Bell Regio suggest the presence of fine-grained material in a low dielectric constant triangular shaped region on the flank of Tepev Mons, which may be crater ejecta or a pyroclastic deposit spread westward by wind. The eastern caldera on Tepev Mons shows a steep trend in backscattered power with incidence angle and has high RMS-slopes, implying a finegrained covering such as ash. Radar waves can easily penetrate smooth mantling layers such as ash and aeolian deposits. If a radar system can measure two orthogonal polarizations, it is possible to detect subsurface scattering and infer the presence of surficial deposits. The Magellan spacecraft could only measure one polarization and was therefore not able to fully characterize the polarization state of the radar echoes. We compare Arecibo dual-polarization data for Venus to Magellan images and emissivity data to investigate the physical properties of volcanic deposits.

Carter, Lynn M.↗

The dust in the hydrogen-poor ejecta of Abell 30

We present new optical and near-infrared images of the hydrogen-poor planetary nebula Abell 30 and produce detailed models that account for the major observed morphological and IR properties. By imaging the nebula in the K band, we confirm the presence of hot dust in an expanding equatorial ring of H-poor gas. No emission was detected from the H-poor polar knots, suggesting a dust deficiency htere relative to the equatorial ring. The near-IR emission is attributed to small carbonaceous dust grains which are stochastically heated by stellar ultraviolet photons. Using an adaptive version of a matrix method devised by Guhathakurta & Draine (1989) to model stochastic heating, we find that the near-IR spectrum observed by Dinerstein & Lester (1984) requires the presence of dust grains down to approximately 0.0007 microns in radius. This minimum grain radius is in excellent agreement with our calculations of the grain destruction by energetic stellar UV photons: we find that carbon clusters with less than approximately 140 atoms (0.0007 microns in radius) are destroyed by stellar UV photons in approximately 1000 yr, the kinematic age of H-poor ejecta. Modeling of the far-IR dust emission implies that the bulk of the dust mass in A30 must reside at distances several times greater than the distance of the equatorial ring from the central star. This spatial dust distribution is attributed to the interaction of the stellar wind with the inhomogeneous H-poor ejecta. Most of the H-poor gas and dust has been apparently carried outward by the stellar wind, leaving behing dense, H-poor knots with prominent wind-blown tails in the equatorial ring and in the polar knots. This picture is supported by the presence of a stellar wind-blown bubble within the H-rich envelope in our optical images.

Borkowski, Kazimierz J.↗