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At least 253 records · Page 14

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NASA NTRS1991

The featureless continua and hydrogen lines of Seyfert 2 galaxies

Optical and ultraviolet spectra taken in similar sized large apertures for 15 Seyfert 2 galaxies are presented. Measurements of emission-line strengths of Ly-alpha, H-alpha, and H-beta are used together with measurements of the ultraviolet slopes to estimate the ratio of recombination photons to ionizing photons. The photon ratios indicate that the ionizing continuum is being emitted anisotropically for at least six of the eight objects with UV slope measurements. The median value of the UV slope is indistinguishable from the UV slope of Seyfert 1 galaxies. This result suggests that in the occultation/reflection picture of Seyfert nuclei, the reflecting particles are free electrons and not dust. Previous observations of variability in Mrk 477 are verified, and it is shown that this galaxy exhibits characteristics of both Seyfert 1 and Seyfert 2 galaxies.

Kinney, A. L.↗

NASA NTRS1986

Molecular ions in the circumstellar envelope of IRC + 10216

Assuming a steady and spherically symmetric mass loss, the spatial distribution of the ionization in a C-rich circumstellar envelope (CSE) is calculated, and it is shown that molecular ions dominate the ionization and chemistry of a large part of the CSE. Cosmic ray ionization of molecular hydrogen yields H3(+), and the photoionization of acetylene and neutral carbon yields C2H2(+) and C(+). In the system, the primary ions generate a series of heavier molecular ions by reactions with neutral molecules before being destroyed by dissociative recombination. The most promising candidate for mm-wavelength detection is found to be HCO(+), and IRC + 10216 antenna temperatures are calculated for different telescope sizes. Photoproduced C2H2(+), the most abundant intermediate distance CSE ion, may be responsible for the synthesis of various heavy hydrocarbon molecules at levels observed in IRC + 10216.

Glassgold, A. E.↗

NASA NTRS1991

Modeling arcjet space thrusters

The UTSI arcjet model is used to compare the performance of a hydrogen and an ammonia arcjet in the same configuration and at the same electrical power. The predicted specific impulse is 50 percent higher for the hydrogen propellant. Numerical studies made of the effect of transport properties on the performance of a hydrogen arcjet indicate that diffusive transport is very significant even in the supersonic part of the flow, and that relatively small changes in transport properties can have a significant effect on performance. These studies also show that nonequilibrium recombination chemistry can have a large effect on the transport coefficients. This leads to the conclusion that finite rate chemical calculations are necessary if accurate arcjet performance is to be calculated.

Rhodes, Robert↗

NASA NTRS1985

High-efficiency device research

Progress on research in high-efficiency silicon solar cells is presented. Topics addressed include: recombination measurement techniques, doped crystals, minority carrier transport, oxygen process in solar cells, solar cell models, loss mechanics in solar cells, high-efficiency metal insulators, dendritic web cells, and surface and bulk loss reduction by low-energy hydrogen doping.

Burger, D. R.↗

NASA NTRS1978

Global circulation and distribution of hydrogen in thermosphere of Venus

The global density distribution of atomic H in the upper atmosphere of Venus is determined in terms of a global circulation model. It is shown that H produced on the dayside is efficiently advected to the nightside by the major gas CO2 where it is then convected to lower altitudes and recombines. A maximum night/day H density ratio of about 5 is derived, in which case exospheric return flow from night to day strongly limits the nightside density enhancement. A previously postulated constraint connecting the eddy diffusion coefficient with the escape flux of H in one dimensional models is no longer required when global circulation of H is considered.

Hartle, R. E.↗

NASA NTRS1985

Bipolar nickel-hydrogen battery development

A comparison of the bipolar Ni-H2 battery with other energy systems to be used in future high-power space systems is presented. The initial design for the battery under the NASA-sponsored program is described and the candidate stack components are evaluated, including electrodes, separator, electrolyte reservoir plate, and recombination sites. The compressibility of the cell elements, electrolyte activation, and thermal design are discussed. Manufacturing and prototype test results are summarized.

Koehler, C. W.↗

NASA NTRS1992

Pathways of proton release in the bacteriorhodopsin photocycle

The pH dependencies of the rate constants in the photocycles of recombinant D96N and D115N/D96N bacteriorhodopsins were determined from time-resolved difference spectra between 70 ns and 420 ms after photoexcitation. The results were consistent with the model suggested earlier for proteins containing D96N substitution: BR hv----K----L----M1----M2----BR. Only the M2----M1 back-reaction was pH-dependent: its rate increased with increasing [H+] between pH 5 and 8. We conclude from quantitative analysis of this pH dependency that its reverse, the M1----M2 reaction, is linked to the release of a proton from a group with a pKa = 5.8. This suggests a model for wild-type bacteriorhodopsin in which at pH greater than 5.8 the transported proton is released on the extracellular side from this as yet unknown group and on the 100-microseconds time scale, but at pH less than 5.8, the proton release occurs from another residue and later in the photocycle most likely directly from D85 during the O----BR reaction. We postulate, on the other hand, that proton uptake on the cytoplasmic side will be by D96 and during the N----O reaction regardless of pH. The proton kinetics as measured with indicator dyes confirmed the unique prediction of this model: at pH greater than 6, proton release preceded proton uptake, but at pH less than 6, the release was delayed until after the uptake. The results indicated further that the overall M1----M2 reaction includes a second kinetic step in addition to proton release; this is probably the earlier postulated extracellular-to-cytoplasmic reorientation switch in the proton pump.

NASA Discipline Exobiology↗

NASA NTRS1975

The C/+/-CO transition in interstellar clouds

Ionized carbon recombines as the ultraviolet radiation field is attenuated inside interstellar clouds. It is proposed that C(+) is transformed into CO, the CO being formed by ion-molecule reactions of C(+) with OH and H2O. The characteristic column density of hydrogen required for the transition is approximately 3 sextillion per sq cm. The C(+)-CO transition has important implications for observations of CO and the thermal properties of sufficiently thick clouds.

Glassgold, A. E.↗

NASA NTRS1974

Effect of inelastic electron-atom collisions on the Balmer decrement

Calculation of the Balmer decrement in radiatively ionized hydrogen gas as a function of temperature and density, taking into account the effect of electron-atom collisions. It is found that once the electron density exceeds 10 to the 10th power per cu cm significant deviations from the normal radiative recombination decrement begin to occur. Implications of these results for the physical conditions in the line-emitting region of the Seyfert galaxy NGC 4151 are discussed briefly.

Adams, W. M.↗

NASA NTRS1999

In vitro activities of four xyloglucan endotransglycosylases from Arabidopsis

Xyloglucan endotransglycosylases (XETs) are encoded by a gene family in Arabidopsis thaliana. These enzymes modify a major structural component of the plant cell wall, xyloglucan, and therefore may influence plant growth and development. We have produced four Arabidopsis XETs (TCH4, Meri-5, EXGT and XTR9) using the baculovirus/insect cell system and compared their biochemical activities. TCH4, as previously demonstrated, and the other three proteins are capable of carrying out transglycosylation of xyloglucans. The K(m) for XLLGol acceptor oligosaccharide is in the range of 20-40 microM for all the XETs except XTR9, which has a Km of 5 microM and is significantly inhibited by high levels of XLLGol. All four enzymes are most active between pH 6.0 and 6.5. TCH4 and XTR9 have temperature optima of 18 degrees C, whereas Meri-5 and EXGT are most active at 28 and 37 degrees C, respectively. Although the activity levels of three of the XETs are not influenced by the presence of fucose on the xyloglucan polymer, XTR9 has a clear preference for non-fucosylated xyloglucan polymer. The four XETs show a marked preference for XLLGol over either XXFGol or XXXGol as acceptor oligosaccharide. All four XETs are glycosylated; however, only the activities of TCH4 and Meri-5 are affected by the removal of the N-glycan with PNGase F. These four enzymes most likely function solely as transglycosylases because xyloglucan endoglucanase activity was not apparent. Subtle differences in biochemical activities may influence the physiological functions of the distinct XETs in vivo.

Non-NASA Center↗

NASA NTRS2010

Selective Functionalization of Carbon Nanotubes: Part II

An alternative method of low-temperature plasma functionalization of carbon nanotubes provides for the simultaneous attachment of molecular groups of multiple (typically two or three) different species or different mixtures of species to carbon nanotubes at different locations within the same apparatus. This method is based on similar principles, and involves the use of mostly the same basic apparatus, as those of the methods described in "Low-Temperature Plasma Functionalization of Carbon Nanotubes" (ARC-14661-1), NASA Tech Briefs, Vol. 28, No. 5 (May 2004), page 45. The figure schematically depicts the basic apparatus used in the aforementioned method, with emphasis on features that distinguish the present alternative method from the other. In this method, one exploits the fact that the composition of the deposition plasma changes as the plasma flows from its source in the precursor chamber toward the nanotubes in the target chamber. As a result, carbon nanotubes mounted in the target chamber at different flow distances (d1, d2, d3 . . .) from the precursor chamber become functionalized with different species or different mixtures of species. In one series of experiments to demonstrate this method, N2 was used as the precursor gas. After the functionalization process, the carbon nanotubes from three different positions in the target chamber were examined by Fourier-transform infrared spectroscopy to identify the molecular groups that had become attached. On carbon nanotubes from d1 = 1 cm, the attached molecular groups were found to be predominantly C-N and C=N. On carbon nanotubes from d2 = 2.5 cm, the attached molecular groups were found to be predominantly C-(NH)2 and/or C=NH2. (The H2 was believed to originate as residual hydrogen present in the nanotubes.) On carbon nanotubes from d3 = 7 cm no functionalization could be detected - perhaps, it was conjectured, because this distance is downstream of the plasma source, all of the free ions and free radicals of the plasma had recombined into molecules.

Meyyappan, Meyya↗

NASA NTRS1982

Design of a 35-kilowatt bipolar nickel-hydrogen battery for low Earth orbit application

The needs of multikilowatt storage for low Earth orbit applications are featured. The modular concept, with projected energy densities of 20-24 W-hr/lb and 700-900 W-hr/ft3, has significant improvements over state of the art capabilities. Other design features are; active cooling, a new scheme for H2-O2 recombination, and pore size engineering of all cell components.

Cataldo, R. L.↗

NASA NTRS1984

Advanced designs for IPV nickel-hydrogen cells

Advanced designs for individual pressure vessel nickel-hydrogen cells have been concieved which should improve the cycle life at deep depths-of-discharge. Features of the designs which are new and not incorporated in either of the contemporary cells (Air Force/Hughes, Comsat) are: (1) use of alternate methods of oxygen recombination, (2) use of serrated edge separators to facilitate movement of gas within the cell while still maintaining required physical contact with the wall wick, and (3) use of an expandable stack to accommodate some of the nickel electrode expansion. The designs also consider electrolyte volume requirements over the life of the cells, and are fully compatible with the Air Force/Hughes design.

Smithrick, J. J.↗

NASA NTRS1984

Advanced designs for IPV nickel-hydrogen cells

Advanced designs for individual pressure vessel nickel-hydrogen cells have been conceived which should improve the cycle life at deep depths-of-discharge. Features of the designs which are new and not incorporated in either of the contemporary cells (Air Force/Hughes, Comsat) are: (1) use of alternate methods of oxygen recombination, (2) use of serrated edge separators to facilitate movement of gas within the cell while still maintaining required physical contact with the wall wick, and (3) use of an expandable stack to accommodate some of the nickel electrode expansion. The designs also consider electrolyte volume requirements over the life of the cells, and are fully compatible with the Air Force/Hughes design.

Smithrick, J. J.↗

NASA NTRS2003

Studies of Atomic Free Radicals Stored in a Cryogenic Environment

Impurity-Helium Solids are porous gel-like solids consisting of impurity atoms and molecules surrounded by thin layers of solid helium. They provide an ideal medium for matrix isolation of free radicals to prevent recombination and store chemical energy. In this work electron spin resonance, nuclear magnetic resonance, X-ray diffraction, and ultrasound techniques have all been employed to study the properties of these substances. Detailed studies via electron spin resonance of exchange tunneling chemical reactions involving hydrogen and deuterium molecular and atomic impurities in these solids have been performed and compared with theory. Concentrations of hydrogen approaching the quantum solid criterion have been produced. Structured studies involving X ray diffraction, ultrasound, and electron spin resonance have shown that the impurities in impurity helium solids are predominantly contained in impurity clusters, with each cluster being surrounded by thin layers of solid helium.

Lee, David M.↗

NASA NTRS1990

Preliminary plume characteristics of an arcjet thruster

An experimental program initiated to characterize the near field of an arcjet plume is described. The complete emission spectrum from 3200 to 7200 A at the nozzle exit plane detected the electronically excited species N2, N2(+), NH, and H, indicating excitation, dissociation, ionization, and recombination in the nozzle. Axial intensity profiles indicated an exponential decay in excited state population for H(alpha), H(beta), and NH. The rate of axial decay indicated lower velocities for NH than H in the plume and population of the third excited energy state of hydrogen from the decay of higher energy levels. Rotational temperatures ranged from 750 K for N2 to 2500 K for NH. Based on these results, the arcjet plume is found to be a highly nonequilibrium plasma. Anode electrical configuration is found to have a large effect on the spectral intensities measured in the plume.

Manzella, David H.↗

NASA NTRS1985

Initial performance of advanced designs for IPV nickel-hydrogen cells

Advanced designs for individual pressure vessel nickel hydrogen cells were conceived which should improve the life cycle at deep depths of discharge and improve thermal management. Features of the designs which are new and not incorporated in either of the contemporary cells (Air Force/Hughes, Comsat) are: (1) the use of alternate methods of oxygen recombination, (2) use of serrated edge separators to facilitate movement of gas within the cell while still maintaining required physical contact with the wall wick, and (3) use of an expandable stack to accommodate some of the nickel electrode expansion. The designs also consider electrolyte volume requirements over the life of the cells, and are fully compatible with the Air Force/Hughes design.

Smithrick, J. J.↗

NASA NTRS1985

Initial performance of advanced designs for IPV nickel-hydrogen cells

Smithrick, J. J.↗