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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Defect–Concentration–Mediated T–Nb 2 O 5 Anodes for Durable and Fast–Charging Li–Ion Batteries

Metastable orthorhombic niobium pentoxide (T-Nb 2 O 5 ) is a promising anode to fulfill the requirements for high-rate Li-ion batteries (LIBs). Stoichiometric T-Nb 2 O 5 is plagued by low electric conductivity and particle pulverization after repeated charge/discharge processes. In this work, oxygen vacancies are implanted into T-Nb 2 O 5 particles via acid immersion of Nb 2 O 5 ·nH 2 O with the formation of Lewis acid sites. The multiple characterizations and simulations reveal the lengthening of Nb–O bonds, and the transformation from NbO 7 pentagonal bipyramids and NbO 6 tetragonal bipyramids in T-Nb 2 O 5–x . The enrichment of oxygen vacancies endows T-Nb 2 O 5–x with higher electric conductivity, better electrochemical kinetics, larger pseudocapacitive contribution. O-doped graphitic C 3 N 4 is creatively proposed as a trace oxygen pump to repair excessive oxygen vacancies, and it also serves as a sacrifice template for Nb 2 O 5–x growth to construct a porous and monolithic electrode network. Defect-modulated Nb 2 O 5–x displays extraordinary cycling stability (164 mAh g –1 at 5 C after 1100 cycles), high capacity retention (104 mAh g –1 ) at an ultrahigh rate (25 C), and large areal capacity (0.74 mAh cm –2 ) under high mass loading (4 mg cm –2 ). The practical prospect is proved by Nb 2 O 5–x /LiNi 0.8 Co 0.1 Mn 0.1 O 2 full cells with high average platform (2.12 V) and high specific capacity (229 mAh g –1 ). Finally, the oxygen-defect modulation strategy on oxide anodes provides an alternative solution to fast-charging and durable LIBs.

25 ENERGY STORAGE↗
DOE OSTI2020

Preliminary Criticality and Radiation Shielding Analysis for the Storage and Transfer of MARVEL Reactor Spent Nuclear Fuel

This report documents the results of preliminary nuclear criticality and radiation shielding assessments during transfer and dry storage of irradiated Microreactor Applications Research Validation and Evaluation (MARVEL) reactor fuel at Idaho National Laboratory (INL). The assessments focus on transfer casks and storage canisters that are currently in use at INL, which may be compatible with the irradiated MARVEL reactor fuel. The criticality assessments were performed using the radiation transport code MCNP6 with 37 MARVEL reactor fuel elements in various configurations and scenarios. All transfer and storage configurations under dry conditions were below the assumed criticality safety limit of 0.93. Some storage and transfer configurations under wet conditions exceeded the criticality safety limit. This suggests that the appropriate administrative and engineering controls, in addition to reducing the number of MARVEL reactor fuel elements per transfer cask or storage canister, can be expected to ensure criticality safety under all scenarios. The radiation shielding assessments were performed by generating conservative neutron and photon source terms using the ORIGEN module in the SCALE suite of codes. These source spectra were used to estimate the dose equivalent rates using the radiation transport code MCNP6, both on contact and 1 m away from the fuel and transfer casks. The maximum estimated dose equivalent rate of 37 unshielded MARVEL reactor fuel elements on contact is approximately 42000 R/hr. The maximum estimated dose equivalent rates on contact to the ATR transfer cask, HFEF-5 transfer cask, and high load charger were approximately 233 mR/hr, 171 mR/hr, and 201 mR/hr, respectively. This suggests that with the appropriate administrative and engineering controls, all three transfer casks analyzed can be expected to provide sufficient radiation shielding to workers during transfer of irradiated MARVEL reactor fuel. These calculations are performed to support the planning and strategy for the MARVEL project and will demonstrate the technical viability of the different configurations discussed and help identify where engineered or administrative controls may be necessary. A complete criticality safety analysis and radiation shielding analysis, including validation and contingency and accident analysis must be completed by licensed and authorized personnel before any transfer or storage of MARVEL reactor nuclear fuel.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS1973

Role of plastic deformation in wear of copper and copper - 10-percent-aluminum alloy in cryogenic fuels

High-purity copper specimens and a copper-aluminum (10%) alloy specimen were subjected to sliding against Type 440 C in cryogenic fuel environments. It was found that virtually all wear occurred by the plastic deformation of a recrystallized layer extending to about 10 micrometers below the wear scar surface of the copper or copper alloy. The wear debris was in the form of a layered structure adhering to the exit region of the wear scar. Measurements on the high purity copper specimens indicated that the wear rate was proportional to the applied load and to the sliding velocity squared. A physical model of the wear process is proposed to account for these observations.

Bill, R. C.↗
NASA NTRS1973

Influence of gaseous hydrogen on metals

Tensile, fracture toughness, threshold stress intensity for sustained-load crack growth, and cyclic and sustained load crack growth rate measurements were performed on a number of alloys in high-pressure hydrogen and helium environments. The results of tensile tests performed in 34.5 MN/m2 (5000 psi) hydrogen indicated that Inconel 625 was considerable embrittled at ambient temperature but was not embrittled at 144 K (-200 F). The tensile properties of AISI 321 stainless steel were slightly reduced at ambient temperature and 144 K (-200 F). The tensile properties of Ti-5Al-2.5 Sn ELI were essentially unaffected by hydrogen at 144 K (-200 F). OFHC copper was not embrittled by hydrogen at ambient temperature or at 144 K (-200 F).

Walter, R. J.↗
NASA NTRS1974

Techniques for aerothermal tests of large, flightweight thermal protection panels in a Mach 7 wind tunnel

Recently developed experimental techniques permit evaluating thermal performance and structural integrity of full-scale panel concepts applicable to reentry and hypersonic vehicles in the Langley 8-foot high-performance structures tunnel. Rate and magnitude of surface heating and differential-pressure loading are independently controlled. Realistic temperature distributions are radiantly preheated into the panel prior to aerodynamic heating, and stream conditions are preselected to sustain the preheat surface heating input during aerodynamic exposure. During tunnel start and shutdown, panels are shielded outside the stream from potentially damaging transient acoustics and buffeting and are then rapidly inserted into the hypersonic flow. Infrared radiometry provides detailed surveys of surface temperatures.

Deveikis, W. D.↗
NASA NTRS1991

The use of carboranes as oxidation inhibitors for carbon-carbon composites

Carbon-carbon composites have many beneficial properties for use in aerospace applications, including their high specific strength and modulus at elevated temperatures. However, they share with all carbon based substances a strong tendency to burn when heated in air. In order to exploit their good qualities, it is necessary to slow or prevent their oxidation during use. Molecular inhibiters offer protection with the advantage of being able to form a homogeneous solution with the resin. Since boron oxides are known to provide the desired kind of protection, molecular compounds based on boron seem reasonable candidates to test as inhibitors. Performance tests indicated that carboranes are excellent materials for obtaining high uniform loadings of boron inhibitors in glassy carbon materials and thus reducing their rates of oxidation. Further, there is evidence that the use of substituted derivatives could provide more complete and thorough forms of protection.

Petty, John T.↗
NASA NTRS2001

Iogenic Plasma and its Rotation-Driven Transport in Jupiter's Magnetosphere

Model calculations are reported for the Iogenic plasma source created by atomic oxygen and sulfur above Io's exobase in the corona and extended clouds (Outer Region). On a circumplanetary scale, two-dimensional distributions produced by integrating the proper three dimensional rate information for electron impact and charge exchange processes along the magnetic field lines are presented for the pickup ion rates, the net-mass and total-mass loading rates, the mass per unit magnetic flux rate, the pickup conductivity, the radial pickup current, and the net-energy loading rate for the plasma torus. All of the two-dimensional distributions are highly peaked at Io's location and hence highly asymmetric about Jupiter. The Iogenic plasma source is also calculated on a much smaller near-Io scale to investigate the structure of the highly peak rates centered about lo's instantaneous location. The Iogenic plasma source for the Inner Region (pickup rates produced below Io's exobase) is, however, expected to be the dominant source near lo for the formation of the plasma torus ribbon and to be a comparable source, if not a larger contributor, to the energy budget of the plasma torus, so as to provide the necessary power to sustain the plasma torus radiative loss rate.

Smyth, William H.↗
NASA NTRS2016

System Level Aerothermal Testing for the Adaptive Deployable Entry and Placement Technology (ADEPT)

The Adaptive Deployable Entry and Placement Technology (ADEPT), a mechanically deployable entry vehicle technology, has been under development at NASA since 2011. As part of the technical maturation of ADEPT, designs capable of delivering small payloads (10 kg) are being considered to rapidly mature sub 1 m deployed diameter designs. The unique capability of ADEPT for small payloads comes from its ability to stow within a slender volume and deploy to achieve a mass efficient drag surface with a high heat rate capability. The low ballistic coefficient results in entry heating and mechanical loads that can be met by a revolutionary three-dimensionally woven carbon fabric supported by a deployable skeleton structure. This carbon fabric has test proven capability as both primary structure and payload thermal protection system. In order to rapidly advance ADEPTs technical maturation, the project is developing test methods that enable thermostructural design requirement verification of ADEPT designs at the system level using ground test facilities. Results from these tests are also relevant to larger class missions and help us define areas of focused component level testing in order to mature material and thermal response design codes. The ability to ground test sub 1 m diameter ADEPT configurations at or near full-scale provides significant value to the rapid maturation of this class of deployable entry vehicles. This paper will summarize arc jet test results, highlight design challenges, provide a summary of lessons learned and discuss future test approaches based upon this methodology.

Hypersonic↗
NASA NTRS1970

Electronically controlled motor drive system has ultra-high reliability and long lifetime

Direct drive electromechanical system is composed of brushless dc torque motor, offset-tooth magnetic sensor that derives position and rate information directly from output shaft, and rotary power transformer that transfers electrical power from external source to proper load. System has high servo loop stiffness and minimum power consumption.

Veillette, L. J.↗
DOE OSTI2021

Thermal Charging Rate of Composite Wax-Expanded Graphite Phase Change Materials

Phase change materials (PCMs) are valuable for their ability to store heat nearly isothermally around their phase transition temperature. PCMs are at the core of latent heat thermal energy storage (LHTES) systems, which provide the ability to buffer high thermal loads or decouple the time when heating or cooling is needed from when it is produced. Thermal charging and discharging of LHTES systems often employ a constant temperature source, and the rate at which heat can be exchanged is dependent on the thermophysical properties of the PCM. For graphite composite PCMs, the high thermal conductivity of the graphite enables an increased heat transfer rate through the material, but its presence displaces PCM which reduces the effective volumetric latent heat of the composite relative to the pure PCM. This results in a tradeoff between thermal power and volumetric energy storage capacity. The thermal charging rate is the average thermal energy stored in the material for some elapsed time. In this study, composite PCMs of compressed expanded natural graphite (CENG) and n-Octadecane are studied. Samples with varying CENG mass fractions were synthesized and the thermal charging rate was measured under a constant temperature boundary condition. For evaluation of the expanded graphite-PCM composite, one boundary of the material was exposed to a 50°C constant temperature plate, above the 27.5°C melting temperature of the PCM. The melting front progression [mm-s-1] and the thermal charging rate [W-cm-2] of the PCM were determined, and the results were compared with analytical predictions for the 1-D semi-infinite phase change. For CENG addition up to 5.75% mass fraction, a 450% thermal conductivity increase was observed with a 5% decrease in volumetric energy density as compared to pure octadecane. The average thermal charging rate was increased by over 430% for the melt to penetrate a depth of 22 mm. The experimental results matched analytical predictions, indicating that higher CENG fractions can be evaluated using analytical approaches.

Hirschey, Jason↗
DOE OSTI2023

Aqueous buffer solution-induced crystallization competes with enzymatic depolymerization of pre-treated post-consumer poly (ethylene terephthalate) waste

In this paper, the complex relationship between kinetics and substrate morphology during enzymatic depolymerization of melt processed poly(ethylene terephthalate) (PET) is explored and the effects of competing transformations are analyzed. Extruded PET substrates from post-consumer recycled PET (RPET) bottles flakes subjected to enzymatic depolymerization are examined to reveal increases in crystallinity from ~10% post-extrusion to >30% after 3 days of depolymerization as well as increases in glass transition temperature (T g ) from ~66°C to > 80°C. Further investigation into this behavior shows that post-extrusion RPET substrates do not exhibit changes in crystallinity when subjected to dry annealing at 65°C in an oven over 7 days, but they do experience annealing in depolymerization buffer solution with no enzymes at 65°C within 3 days. This difference may be attributed to plasticization of PET in the presence of water, also known as solvent induced crystallization. The impact of this plasticized annealing behavior is demonstrated by subjecting RPET substrates to increasing enzyme-to-substrate loads. As enzyme load increases, overall conversion of substrates increases despite crystallinity also increasing to similar levels regardless of the initial enzyme loading. The competition between depolymerization and crystallization suggests that the rate at which PET substrates are depolymerized at the operational temperature is integral to achieving high conversion to monomeric product. This, in turn, also suggests that savings from lowered enzyme loadings may be more detrimental than helpful in pursuing the most cost-effective recycling systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1989

Prediction of fatigue-crack growth in a high-strength aluminum alloy under variable-amplitude loading

The present paper is concerned with the application of an analytical crack-closure model to study crack growth under various load histories. The model was based on a concept like the Dugdale model, but modified to leave plastically deformed material in the wake of the advancing crack tip. The thickness effect was accounted for by using a 'constraint' factor on tensile yielding at the crack tip. The model was used to correlate crack-growth rates under constant-amplitude loading, and to predict crack growth under variable-amplitude loading on a high-strength aluminum alloy (7475-T7351) sheet material. The experimental data was obtained from Zhang et al. Predicted crack-growth lives agreed well with experimental data. For ten crack-growth tests subjected to various variable-amplitude load histories, the ratio of predicted-to-experimental lives ranged from 0.54 to 1.19. The mean value of predicted-to-experimental lives was 0.95 with a standard error of 0.2 for a constraint factor of 1.9.

Newman, J. C., Jr.↗
DOE OSTI2023

High strain rate nanoindentation testing: Recent advancements, challenges and opportunities

Recent advancements in electronics have renewed the interest in high strain rate nanoindentation testing, resulting in the development of new high strain rate nanoindentation test equipment and test methodologies. Here, in this work, the current state-of-the-art in high strain rate nanoindentation testing is critically reviewed, with focus on three key aspects - the testing equipment's dynamic mechanical and electronic response, test methodology, and post-processing of raw data to obtain hardness and strain rate. The challenges in instrument hardware design and post-test data analysis are discussed, along with optimal strain rate window for accurate high strain rate measurements. Specific focus will be on instrumented high strain rate testing using self-similar indenters at strain rates in excess of 100 s -1 , wherein load and depth of penetration into the sample are both measured or applied.

36 MATERIALS SCIENCE↗
NASA NTRS1988

Alterations in crack-tip deformation during variable-amplitude fatigue crack growth

Fatigue crack growth rate changes caused by single overloads and an overload followed by an underload have been studied in the high-strength aluminum alloy 7091. Crack-tip plasticity parameters were measured at each step in the loading sequence using the stereoimaging technique. Effective stress-intensity factor was measured with high resolution immediately at the crack tip both before an overload and during the subsequent growth rate retardation period. Crack-tip opening displacement and strain were altered in the same way as growth rate following the overload/underload events, and similitude with respect to crack-tip plasticity was preserved during the growth retardation period. Effective stress-intensity factor was found to correlate well with crack growth rate. Strains within the plastic zone were converted to stress at each step in load change. These stresses were then summed to determine the zone of residual stress caused by the overload. The region of compressive residual stress ahead of the crack tip was found to increase with overload severity but was limited to yield stress in magnitude. An underload shrank the spatial extent of the residual stresses caused by the overload.

Davidson, David L.↗
NASA NTRS1998

Creep Strain and Strain Rate Response of 2219 Al Alloy at High Stress Levels

As a result of high localized plastic deformation experienced during proof testing in an International Space Station connecting module, a study was undertaken to determine the deformation response of a 2219-T851 roll forging. After prestraining 2219-T851 Al specimens to simulate strains observed during the proof testing, creep tests were conducted in the temperature range from ambient temperature to 107 C (225 F) at stress levels approaching the ultimate tensile strength of 2219-T851 Al. Strain-time histories and strain rate responses were examined. The strain rate response was extremely high initially, but decayed rapidly, spanning as much as five orders of magnitude during primary creep. Select specimens were subjected to incremental step loading and exhibited initial creep rates of similar magnitude for each load step. Although the creep rates decreased quickly at all loads, the creep rates dropped faster and reached lower strain rate levels for lower applied loads. The initial creep rate and creep rate decay associated with primary creep were similar for specimens with and without prestrain; however, prestraining (strain hardening) the specimens, as in the aforementioned proof test, resulted in significantly longer creep life.

Taminger, Karen M. B.↗
DOE OSTI2023

Relative humidity threshold for oxygen generation by high-purity plutonium dioxides in 3013 containers

High-purity plutonium dioxide with adsorbed water in a sealed container can generate oxygen, but oxygen will not be generated in low water loading conditions. A threshold for oxygen generation has been observed in the hydrogen generation rate normalized by the specific power for high-purity plutonium dioxide. Normalized hydrogen generation rates above this threshold generate oxygen and below the threshold consume oxygen. The threshold rate is determined by the amount of water adsorbed onto the surface of the oxide. The relative humidity of the atmosphere that the oxide is in equilibrium with determines the amount of physisorbed water adsorbed on the surface. We calculate the relative humidity corresponding to the threshold rate as a function of mass and specific surface area of material stored in 3013 containers. Exceeding the calculated relative humidity may result in flammable gas mixtures of hydrogen and oxygen at some time during storage.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS1989

Prediction of fatigue-crack growth in a high-strength aluminum alloy under variable-amplitude loading

The present paper is concerned with the application of an analytical crack-closure model to study crack growth under various load histories. The model was based on a crack-tip plasticity concept like the Dugdale model, but modified to leave plastically deformed material in the wake of the advancing crack tip. The effect of material thickness on plasticity was accounted for by using a constraint factor on tensile yielding at the crack tip. The model was used to correlate crack-growth rates under constant-amplitude loading, and to predict crack growth under variable-amplitude loading on a high-strength aluminum alloy (7475-T7351) sheet material. The experimental data were obtained from Zhang et al. Predicted crack-growth lives agreed well with experimental data. For ten crack-growth tests subjected to various variable-amplitude load histories, the ratio of predicted-to-experimental lives ranged from 0.54 to 1.19. The mean value of the ratio of predicted-to-experimental lives was 0.95 and the standard error was 0.2 using a constraint factor of 1.9 in the model. Crack-opening stresses calculated from the model were significantly different from those determined by Zhang et al. using a striation-based experimental method.

Newman, J. C., Jr.↗
DOE OSTI2021

Mechanical characterization of 304L-VAR stainless steel in tension with a full coverage of low, intermediate, and high strain rates

A 304L-VAR stainless steel is mechanically characterized in tension over a full range of strain rates from low, intermediate, to high using a variety of apparatuses. While low- and high-strain-rate tests are conducted with a conventional Instron and a Kolsky tension bar, the tensile tests at intermediate strain rates are conducted with a fast MTS and a Drop-Hopkinson bar. The fast MTS used in this study is able to obtain reliable tensile response at the strain rates up to 150 s -1 , whereas the lower limit for the Drop-Hopkinson bar is 100 s -1 . Combining the fast MTS and the Drop-Hopkinson bar closes the gap within the intermediate strain rate regime. Using these four apparatuses, the tensile stress-strain curves of the 304L-VAR stainless steel are obtained at strain rates on each order of magnitude ranging from 0.0001 to 2580 s -1 . All tensile stress-strain curves exhibit linear elasticity followed by significant work hardening prior to necking. After necking occurrs, the specimen load decreases, and the deformation becomes highly localized until fracture. The tensile stress-strain response of the 304L-VAR stainless steel exhibits strain rate dependence. The flow stress increases with increasing strain rate and is described with a power law. The strain-rate sensitivity is also strain-dependent, possibly due to thermosoftening caused by adiabatic heating at high strain rates. The 304L-VAR stainless steel shows significant ductility. The true strains at the onset of necking and at failure are determined. The results show that the true strains at both onset of necking and failure decrease with increasing strain rate. The true failure strains are approximately 200% at low strain rates but are significantly lower (~100%) at high strain rates. The transition of true failure strain occurs within the intermediate strain rate range between 10 -2 and 10 2 s -1 . A Boltzmann description is used to present the effect of nominal strain rate on true failure strain.

304L-VAR stainless Steel↗