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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
NASA NTRS2010

Recent Improvements in Retrieving Near-Surface Air Temperature and Humidity Using Microwave Remote Sensing

Detailed studies of the energy and water cycles require accurate estimation of the turbulent fluxes of moisture and heat across the atmosphere-ocean interface at regional to basin scale. Providing estimates of these latent and sensible heat fluxes over the global ocean necessitates the use of satellite or reanalysis-based estimates of near surface variables. Recent studies have shown that errors in the surface (10 meter)estimates of humidity and temperature are currently the largest sources of uncertainty in the production of turbulent fluxes from satellite observations. Therefore, emphasis has been placed on reducing the systematic errors in the retrieval of these parameters from microwave radiometers. This study discusses recent improvements in the retrieval of air temperature and humidity through improvements in the choice of algorithms (linear vs. nonlinear) and the choice of microwave sensors. Particular focus is placed on improvements using a neural network approach with a single sensor (Special Sensor Microwave/Imager) and the use of combined sensors from the NASA AQUA satellite platform. The latter algorithm utilizes the unique sampling available on AQUA from the Advanced Microwave Scanning Radiometer (AMSR-E) and the Advanced Microwave Sounding Unit (AMSU-A). Current estimates of uncertainty in the near-surface humidity and temperature from single and multi-sensor approaches are discussed and used to estimate errors in the turbulent fluxes.

Roberts, J. Brent↗
NASA NTRS2013

It's the Heat AND the Humidity -- Assessment of Extreme Heat Scenarios to Enable the Assessment of Climate Impacts on Public Health

In the United States, extreme heat is the most deadly weather-related hazard. In the face of a warming climate and urbanization, which contributes to local-scale urban heat islands, it is very likely that extreme heat events (EHEs) will become more common and more severe in the U.S. In a NASA-funded project supporting the National Climate Assessment, we are providing historical and future measures of extreme heat to enable assessments of the impacts of heat on public health over the coterminous U.S. We use atmospheric temperature and humidity information from meteorological reanalysis and from Global Climate Models (GCMs) to provide data on past and future heat events. The project s emphasis is on providing assessments of the magnitude, frequency and geographic distribution of extreme heat in the U.S. to facilitate public health studies. In our approach, long-term climate change is captured with GCM output, and the temporal and spatial characteristics of short-term extremes are represented by the reanalysis data. Two future time horizons, 2040 and 2090, are the focus of future assessments; these are compared to the recent past period of 1981-2000. We are characterizing regional-scale temperature and humidity conditions using GCM output for two climate change scenarios (A2 and A1B) defined in the Special Report on Emissions Scenarios (SRES). For each future period, 20 years of multi-model GCM output have been analyzed to develop a heat stress climatology based on statistics of extreme heat indicators. Differences between the two future and past periods have been used to define temperature and humidity changes on a monthly time scale and regional spatial scale. These changes, combined with hourly historical meteorological data at a spatial scale (12 km) much finer than that of GCMs, enable us to create future climate realizations, from which we compute the daily heat stress measures and related spatially-specific climatological fields. These include the mean annual number of days above certain thresholds of maximum and minimum air temperatures, heat indices and a new heat stress variable that gives an integrated measure of heat stress (and relief) over the course of a day. Comparisons are made between projected (2040 and 2090) and past (1990) heat stress statistics. All output is being provided at the 12 km spatial scale and will also be aggregated to the county level, which is a popular scale of analysis for public health researchers. County-level statistics will be made available by our collaborators at the Centers for Disease Control and Prevention (CDC) via the Wide-ranging Online Data for Epidemiologic Research (WONDER) system. CDC WONDER makes the information resources of the CDC available to public health professionals and the general public. This addition of heat stress measures to CDC WONDER will allow decision and policy makers to assess the impact of alternative approaches to optimize the public health response to EHEs. It will also allow public health researchers and policy makers to better include such heat stress measures in the context of national health data available in the CDC WONDER system. The users will be able to spatially and temporally query public health and heat-related data sets and create county-level maps and statistical charts of such data across the coterminous U.S.

Crosson, William L↗
NASA NTRS2012

Role of Temperature, Humidity and Rainfall on Influenza Transmission in Guatemala, El Salvador and Panama

Worldwide, seasonal influenza causes about 500,000 deaths and 5 million severe illnesses per year. The environmental drivers of influenza transmission are poorly understood especially in the tropics. We aimed to identify meteorological factors for influenza transmission in tropical Central America. We gathered laboratory-confirmed influenza case-counts by week from Guatemala City, San Salvador Department (El Salvador) and Panama Province from 2006 to 2010. The average total cases per year were: 390 (Guatemala), 99 (San Salvador) and 129 (Panama). Meteorological factors including daily air temperature, rainfall, relative and absolute humidity (RH, AH) were obtained from ground stations, NASA satellites and land models. For these factors, we computed weekly averages and their deviation from the 5-yr means. We assessed the relationship between the number of influenza case-counts and the meteorological factors, including effects lagged by 1 to 4 weeks, using Poisson regression for each site. Our results showed influenza in San Salvador would increase by 1 case within a week of every 1 day with RH>75% (Relative Risk (RR)= 1.32, p=.001) and every 1C increase in minimum temperature (RR=1.29, p=.007) but it would decrease by 1 case for every 1mm-above mean weekly rainfall (RR=0.93,p<.001) (model pseudo-R2=0.55). Within 2 weeks, influenza in Panama was increased by 1 case for every 1% increase in RH (RR=1.04, p=.003), and it was increased by 2 cases for every 1C increase of minimum temperature (RR=2.01, p<.001) (model pseudo-R2=0.4). Influenza counts in Guatemala had 1 case increase for every 1C increase in minimum temperature in the previous week (RR=1.21, p<.001), and for every 1mm/day-above normal increase of rainfall rate (RR=1.03, p=.03) (model pseudo-R2=0.54). Our findings that cases increase with temperature and humidity differ from some temperate-zone studies. But they indicate that climate parameters such as humidity and temperature could be predictive of influenza activity and should be incorporated into country-specific influenza transmission models

Soebiyanto, Radina P.↗
NASA NTRS2017

Tack Measurements of Prepreg Tape at Variable Temperature and Humidity

NASA’s Advanced Composites Project has established the goal of achieving a 30 percent reduction in the timeline for certification of primary composite structures for application on commercial aircraft. Prepreg tack is one of several critical parameters affecting composite manufacturing by automated fiber placement (AFP). Tack plays a central role in the prevention of wrinkles and puckers that can occur during AFP, thus knowledge of tack variation arising from a myriad of manufacturing and environmental conditions is imperative for the prediction of defects during AFP. A full design of experiments was performed to experimentally characterize tack on 0.25-inch slit-tape tow IM7/8552-1 prepreg using probe tack testing. Several process parameters (contact force, contact time, retraction speed, and probe diameter) as well as environmental parameters (temperature and humidity) were varied such that the entire parameter space could be efficiently evaluated. Mid-point experimental conditions (i.e., parameters not at either extrema) were included to enable prediction of curvature in relationships and repeat measurements were performed to characterize experimental error. Collectively, these experiments enable determination of primary dependencies as well as multi-parameter relationships. Slit-tape tow samples were mounted to the bottom plate of a rheometer parallel plate fixture using a jig to prevent modification of the active area to be interrogated with the top plate, a polished stainless steel probe, during tack testing. The probe surface was slowly brought into contact with the pre-preg surface until a pre-determined normal force was achieved (2-30 newtons). After a specified dwell time (0.02-10 seconds), during which the probe substrate interaction was maintained under displacement control, the probe was retracted from the surface (0.1-50 millimeters per second). Initial results indicated a clear dependence of tack strength on several parameters, with a particularly strong dependence on temperature and humidity. Although an increase in either of these parameters reduces tack strength, a maximum in tack was predicted to occur under conditions of low temperature and moderate humidity.

Wohl, Christopher↗
NASA NTRS2015

Formation of Cirrus Clouds near the Tropical Tropopause and Their Implications for Stratospheric Humidity, Radiation Budgets, and Climate

Optically-thin cirrus clouds are a nearly ubiquitous feature of the transition layer between the tropical troposphere and stratosphere (known as the Tropical Tropopause Layer). Given their high occurrence frequency, these clouds have significant impacts on the Earth's radiation budget, with a particularly strong influence on the outgoing longwave radiation. Further, ice crystal growth and sedimentation in these clouds dehydrates air in the cold TTL to very low water vapor mixing ratios. Since transport from the troposphere into the stratosphere occurs primarily through the tropical tropopause and the Brewer-Dobson circulation transports air from the TTL throughout the stratosphere, cloud processes in the TTL cold trap essentially regulate the humidity of the entire stratosphere. It has been shown that even small changes in stratospheric humidity can have significant impacts on the Earth's radiation budget and climate, with magnitudes comparable to anthropogenic changes in greenhouse gases. The humidity of air crossing the TTL cold trap depends to first order on tropical tropopause temperatures, but also on deep convection reaching the TTL, large-scale transport (in balance with TTL radiative heating), atmospheric waves, and cloud microphysical processes. Gaps in our understanding of TTL transport and cloud processes motivated the NASA Airborne Tropical TRopopause EXperiment (ATTREX). ATTREX used the long-range (16,000 km), high-altitude (20 km) Global Hawk unmanned aircraft system equipped with twelve instruments measuring clouds, water vapor, meteorological conditions, chemical tracers, chemical radicals, and radiation. I will discuss the physics of TTL cirrus formation and the impact of these clouds on water vapor and radiation budgets, including new results emerging from the ATTREX measurements.

Jensen, Eric↗
NASA NTRS2024

Evaluation of a Combined Drought Indicator Against Crop Yield Estimations and Simulations Over the Argentine Humid Pampas

Droughts pose serious threats to the agricultural sector, especially in rainfed-dominated agricultural regions like those in Argentina’s Humid Pampas. This region was recently impacted by slow-evolving and long-lasting droughts as well as by flash droughts, resulting in losses reaching thousands of millions of US dollars. Improvements of drought early warning systems are essential, particularly given the projected increase in drought frequency and severity over southern South America. The spatial and temporal relationship between precipitation deficits, soil moisture and vegetation health anomalies are crucial for better understanding and representation of the agricultural droughts and their impacts. In this context, the Combined Drought Indicator (CDI) considers the causal and time-lagged relationship of these three variables. The study’s objective is twofold: (1) Analyze the time-lagged response between precipitation deficits, soil moisture and satellite fAPAR anomalies; and (2) Evaluate the CDI’s capability to characterize the severity of drought events on the Humid Pampas against agricultural yield estimations and simulations, as well as agricultural emergency declarations. The correlation among the variables shows strong spatial variability. The highest Pearson correlation values (r > 0.42) are observed over parts of the Humid Pampas for time lags of 0, 10, and 20 days between the variables. Although the CDI has limitations, such as its coarse spatial resolution and monthly temporal resolution of precipitation data, it effectively tracks the progression of major drought events in the region. The CDI’s performance aligns well with estimations and simulations of soybean and corn yields, as well as official declarations of agricultural emergencies. Insights from this study also provide a basis for discussing potential improvements to the CDI. This study highlights the global and regional significance of evaluating and enhancing the CDI for effective drought monitoring, emphasizing the role of collaborative efforts for future advancements in drought early warning systems.

Combined Drought Indicator↗
DOE OSTI2024

Multi-Parameter Optical Fiber Sensing of Humidity, CH4, CO2, and Corrosion

In this work, the previously demonstrated capability of the optical fiber sensor (OFS) for successful monitoring of humidity has been extended to monitor the humidity, CH4, and CO2 with different gas composition based on the strain produced along the single mode fiber (SMF) sensor. This is enabled by absorption of H2O/gases on to the commercially available polyacrylate coated jacketed portion of the fiber resulting a change in strain. Under equilibrium, a differential microstrain was observed along the jacketed portion of the SMF with N2, CH4, and CO2 at different humidity conditions, while the unjacketed portion of the fiber was used only for sensing pressure/temperature induced strain. In case of N2 at 800 psig pressure, the observed microstrain was approximately 80, 65, 50 and 35 µε at 100, 75.0, 46.8, and 23.4 RH% respectively. Comparatively, a microstrain of approximately 95 µε was observed with 100% RH CH4 which demonstrates that SMF produces a measurable CH4 response alongside water. Similarly, the observed microstrain with CO2 was approximately 105, 90, 85, 80, and 70 µε at 100, 75.0, 46.8, 23.4, and 0 RH% respectively. Linear regression and principal component analysis of these dataset provided deconvolution of the impact of strain from H2O, CH4, and CO2 enabling good cross sensitivity. Additionally, modified OFS comprising of Fe coated fiber section was employed to monitor corrosion, using Fe as corrosion proxy, under harsh corrosive environment.

Mainali, Badri↗
DOE OSTI2024

Multi-Parameter Optical Fiber Sensing of Humidity, CH4, CO2, and Corrosion

In this work, the previously demonstrated capability of the optical fiber sensor (OFS) for successful monitoring of humidity has been extended to monitor the humidity, CH4, and CO2 with different gas composition based on the strain produced along the single mode fiber (SMF) sensor. This is enabled by absorption of H2O/gases on to the commercially available polyacrylate coated jacketed portion of the fiber resulting a change in strain. Under equilibrium, a differential microstrain was observed along the jacketed portion of the SMF with N2, CH4, and CO2 at different humidity conditions, while the unjacketed portion of the fiber was used only for sensing pressure/temperature induced strain. In case of N2 at 800 psig pressure, the observed microstrain was ~80, ~65, ~50 and ~35 µε at 100, 75.0, 46.8, and 23.4 RH% respectively. Comparatively, a microstrain of ~95 µε was observed with 100% RH CH4 which demonstrates that SMF produces a measurable CH4 response alongside water. Similarly, the observed microstrain with CO2 was ~105, ~90, ~85, ~ 80, and ~70 µε at 100, 75.0, 46.8, 23.4, and 0 RH% respectively. Linear regression and principal component analysis of these dataset provided deconvolution of the impact of strain from H2O, CH4, and CO2 enabling good cross sensitivity. Additionally, modified OFS comprising of Fe coated fiber section was employed to monitor corrosion based on the increase in backscattered intensity amplitude of the light being passed once corrosion occurs.

Mainali, Badri↗
DOE OSTI2024

Modeling Ni Coarsening under Humid Atmosphere in the Electrode of Solid Oxide Cells

Ni coarsening is an important degradation mechanism in solid oxide cells. It is reported that Ni coarsening is faster under a humid atmosphere experimentally, but the underline mechanism is not well understood. In this work, Ni coarsening through Ni(OH)x surface diffusion was investigated by a combination of density-functional theory (DFT) and phase-field modeling (PFM). DFT is used to evaluate the surface coverage and diffusivity of Ni(OH)x on Ni (111) surface and the results are used as an input to the PFM to simulate Ni coarsening under humid atmospheres on both reconstructed and synthetic microstructures. It is found that steam partial pressure and microstructure effect alone cannot explain the faster Ni coarsening under a humid atmosphere observed experimentally. Large local overpotential in fuel cell mode is needed to explain the fast Ni coarsening.

Lei, Yinkai↗
DOE OSTI2025

Simulated Moving Bed Process for CO 2 Capture from Humid Postcombustion Flue Gases Using MUF-16

Simulated moving bed (SMB) designs are increasingly being adapted for the separation of multicomponent gaseous mixtures. In this work, we develop a modified SMB process for capturing CO 2 from humid postcombustion flue gas using MUF-16 (MUF = Massey University Framework). MUF-16 shows excellent selectivity for CO 2 over N 2 , moderate heats of adsorption for CO 2 and H 2 O, and no competitive sorption of CO 2 over water at relative humidities relevant to postcombustion capture. We utilize these characteristics to propose a continuous process that uses N 2 from the feed as the desorbent for the water, eliminating the need for a separate desiccant bed and allowing for localized heating during desorption for H 2 O-saturated MOF beds. Single-component isotherms, single-column breakthrough experiments, and SO 2 stability tests suggest the excellent suitability of MUF-16 to this separation via the proposed SMB design.

CO2 capture from humid flue gas↗
DOE OSTI2016

Comfort in High-Performance Homes in a Hot-Humid Climate

TO5 2.3.2: Large-Scale Temperature Study Although space-conditioning systems are required to meet standards such as those in the Air Conditioning Contractors of America (ACCA) Manual RS (Rutkowski 1997) and the ASHRAE Standard 55 (ASHRAE 2013) comfort criteria, little is known about how space-conditioning systems are actually operating in the field and if these systems are meeting those standards. Unconventional space-conditioning systems may be necessary for low-load homes in the future. It is important to know how current systems are functioning in existing homes and to what temperatures occupants typically set the thermostats in their homes. The U.S. Department of Energy's Building America research team IBACOS set out to find some answers. By using low-cost data loggers and occupant surveys to monitor 37 single-family homes that have standard heating, ventilating, and air-conditioning (HVAC) equipment, the team gained insight into how sensitive occupants are to comfort in their homes relative to the ACCA and ASHRAE standards. This study focused on one climate zone (hot-humid); however, future studies may find differences among occupants- ideas of thermal comfort in other climate zones. Data were collected from installed sensors during a 2-month period from late August 2014 through late October 2014. The final aspect of this project was to review the business metrics associated with builders involved in a comfort and performance guarantee program. The results of this study-taken as an aggregate-show that the homes provided room-to-room temperature differences less than 6 degrees F 95% of the time. Temperature differences were less than 4 degrees F 80% of the time. Some homes showed better or worse performance. On average, two-story homes had a 3.3 degrees F temperature difference between rooms; single-story homes had an average of a 2.2 degrees F temperature difference between rooms. Occupants who did not use programmable thermostats had an average set point of 75 degrees F. Homes in which the thermostats were programmed with a setback schedule showed a median baseline temperature value of 74 degrees F and had a median afternoon setback of 75 degrees F. System runtime was analyzed and showed that the room-to-room temperature uniformity in some homes worsened during an on cycle, whereas the uniformity improved in other homes. That is, when the system was running, some rooms were receiving too much or too little air relative to the rest of the house, and the temperatures in those rooms were moving away from the temperatures of the other rooms in the house. Finally, analysis of the thermostat data shows a wide degree of variability among homes in the study. Interpretation of the measured data suggests that 21 occupants made no regular adjustments to the thermostats in their homes, seven had regular setbacks, seven showed varying setbacks, and 10 appeared to follow no pattern (with random adjustments). Ultimately, the data show that current systems are maintaining expected levels of comfort. As expected, it is more challenging to maintain a uniform temperature in all rooms of two-story homes, and future systems should address this issue. Furthermore, the data show that the majority of homes maintained relative humidity levels below 60% without any supplemental dehumidification

ACCA Manual RS↗
DOE OSTI2016

Evaluation of the Performance of Houses With and Without Supplemental Dehumidification in a Hot-Humid Climate

Understanding indoor humidity conditions in low energy homes in hot-humid climates is critical to promoting long term occupant comfort, indoor air quality and building durability. The results of this study were expected to inform the residential building community on whether supplemental dehumidification is a needed and effective investment to promote these long term standards. Data logging equipment was installed at eight test homes in July, 2012 and later at two more test homes in January, 2013. Interior conditions and various end-use loads were monitored until November 7th, 2013. The mechanical systems at each of the 10 homes were commissioned by BSC to ensure consistent operation between each of the homes and to fully comply with the intended mechanical design. PHA-1 to 8 - Energy Savings: 21.8-18.9%, Company: Project Home Again (PHA); Address New Orleans, LA 70112, House Count: 8 BDC-1 - Energy Savings: 28.8%, Company: Broadmoor Development Corporation (BDC); Address New Orleans, LA 70112, House Count: 2

Array↗
DOE OSTI2019

Comparative performance analysis of relative humidity sensor based on intermodal interference using tapered square no-core optical fiber and tapered cylindrical optical fiber

This work presents the computational evaluation of a new model for relative humidity sensor based on the principle of intermodal interference using a square-section no-core tapered optical fiber compared to a classical cylindrical tapered optical fiber sensor. Attempting at a new application of this type of sensor, simulations were carried out in the range of up to 60% of relative humidity, the main interest range of the pharmaceutical industry. Several materials were used in its modeling and an analysis was developed in its constructive dimensions, in order to verify the influence of each of them on the sensor performance.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2023

New coal char-based bricks: Effects of curing temperature, humidity, pressing pressure, and addition of superplasticizer on the physical, mechanical, and thermal properties

Coal char, as a sustainable and eco-friendly material, holds significant potential for use in new construction materials, specifically, coal char-based bricks. This study employed the pre-pressing method to create char bricks containing high char content of 70%. The impact of various curing temperatures (20, 40, 60 °C), humidity levels (15% and 90%), and pressing pressures (3.5, 7, and 10 MPa) on the density, X-ray diffraction, compressive strength, and thermal conductivity of char-based samples were examined. The addition of superplasticizer and the performance of char bricks were assessed by comparing them to traditional clay bricks and corresponding standards. The study discovers that the temperature of 40 °C enhances the early 7-day strength of char brick samples, while the highest 28-day strength is observed in char bricks at a temperature of 20 °C and humidity of 90%. Compared to conventional clay bricks (with density of 1.9 g/cm3, thermal conductivity of 0.39-0.63 W/mK, compressive strength of 10-20 MPa), the proposed char bricks exhibit lower density (~0.8 g/cm 3 ), lower thermal conductivity (0.26-0.35 W/mK), and good performance in compressive strength (up to 15 MPa). Lastly, coal char-based bricks with high char content demonstrate significant advantages over traditional clay bricks, making them a sustainable and environmentally friendly building material option.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Fabrication of high efficiency perovskite solar cells based on mesoporous TiO2 nanofibrous film under high humidity conditions

Highlights: • 1D TiO{sub 2} nanofibrous film was prepared by electrospinning technique as mesoporous of PSCs. • PSCs were fabricated under ambient conditions even with a high humidity condition more than 40%. • The 1D TiO{sub 2} nanofiber-based PSCs achieved a power conversion efficiency (PCE) about 11.6% compared with 7.5% whereas the 0D TiO{sub 2} nanoparticle-based PSCs only has 7.5%. - Abstract: One-dimensional (1D) TiO{sub 2} nanofibrous film with good morphology and electrical characteristics was prepared by electrospinning technique. And then perovskite solar cells (PSCs) were fabricated based on 2-μm-thick mesoporous TiO{sub 2} nanofibrous film under ambient conditions even with a high humidity condition more than 40%. The devices show high power conversion efficiency (PCE) due to high porosity that is beneficial to the loading of CH{sub 3}NH{sub 3}PbI{sub 3} perovskite layer. This high-porosity 1D TiO{sub 2} nanofibrous film also acts as a protection layer which can enhance the moisture stability of CH{sub 3}NH{sub 3}PbI{sub 3}. As a result, conversion efficiency of 11.6% and short-circuit current density (J{sub sc}) of 17.3 mA were achieved under 100 mW cm{sup −2} AM 1.5 G solar illumination. These two values are both higher than those of zero-dimensional (0D) TiO{sub 2} nanoparticulate film-based devices.

14 SOLAR ENERGY↗
DOE OSTI2017

New insights on electro-optical response of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) film to humidity

Understanding the relative humidity (RH) response of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is critical for improving the stability of organic electronic devices and developing selective sensors. In this work combined gravimetric sensing, nanoscale surface probing, and mesoscale optoelectronic characterization are used to directly compare the RH dependence of electrical and optical conductivities and unfold connections between the rate of water adsorption and changes in functional properties of PEDOT:PSS film. We report three distinct regimes where changes in electrical conductivity, optical conductivity, and optical bandgap are correlated with the mass of adsorbed water. At low (RH < 25%) and high (RH > 60%) humidity levels dramatic changes in electrical, optical and structural properties occur, while changes are insignificant in mid-RH (25% < RH < 60%) conditions. We associate the three regimes with water adsorption at hydrophilic moieties at low RH, diffusion and swelling throughout the film at mid-RH, and saturation of the film by water at high RH. Optical film thickness increased by 150% as RH was increased from 9% to 80%. Low frequency (1 kHz) impedance increased by ~100% and film capacitance increased by ~30% as RH increased from 9% to 80% due to an increase in the film dielectric constant. Finally, changes in electrical and optical conductivities concomitantly decrease across the full range of RH tested.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Observationally Constrained Modeling of the Reactive Uptake of Isoprene-Derived Epoxydiols under Elevated Relative Humidity and Varying Acidity of Seed Aerosol Conditions

Isoprene is the non-methane volatile organic compound (VOC) emitted in largest amounts to the atmosphere, and it is a significant source of secondary organic aerosol (SOA) mass. The uptake of isoprene oxidation products followed by multiphase chemistry in fine particles is the key pathway to form isoprene epoxydiol-derived SOA (IEPOX-SOA). However, many parameters that relate to diffusion and reaction of IEPOX in the particle phase remain uncertain, since reaction kinetics previously measured in bulk aqueous phase solutions might be different from atmospheric aerosols. Here, we use simultaneous environmental chamber measurements of multiple parameters governing IEPOX-SOA formation at timescales of ~hours: particle size distribution, composition, and volatility of IEPOX-SOA to constrain the key parameters governing IE-POX-SOA formation under humid (i.e., 50% relative humidity, RH) and varying seed aerosol acidity conditions. Reducing the 2-methyltetrol (tetrol) reaction rate constants by a factor of 4 brings the model predictions in agreement with the IEPOX-SOA measurements with acidified ammonium bisulfate seed aerosols. For less acidic ammonium sulfate aerosols both the organo-sulfate (OS) and tetrol reaction rate constants need to be reduced to bring model predictions closer to chamber observations. Using the measured non-volatile content of IEPOX-SOA we constrain the oligomerization timescale of 2-methyltetrols. We find that the oligomerization timescale is 4 hours with acidified seed aerosols, but a much longer time scale of 24 hours is needed for non-acidified seed aerosols, indicating that the aerosol acidity greatly affects the oligomerization rate of tetrols. Here we show that the actual kinetics of IEPOX-SOA formation rate on aerosol seeds consisting of both ammonium bisulfate and ammonium sulfate are a factor of 4~5 slower under 50-60% RH conditions compared to their application in previous models, which were based on bulk aqueous solution measurements.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗