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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
NASA NTRS1980

Venus nighttime hydrogen bulge

The concentration of atomic hydrogen in the Venus thermosphere near 165 km altitude and approximately 18 deg north latitude has been derived from Pioneer Venus in situ measurements of H(+), O(+), O and CO2 concentrations, under the assumption of chemical equilibrium. Altitude profiles of derived H concentration suggest that chemical equilibrium prevails to an altitude of at least 200 km on the dayside and to 165 km on the nightside. Measurements below these limits were made by the ion and neutral mass spectrometers on the orbiter spacecraft between December 1978 and July 1979, while periapsis traversed a complete diurnal cycle. The hydrogen concentration is found to rise sharply at both terminators from a dayside value of approximately 50,000/cu cm, and to exhibit an asymmetric nightside distribution with a peak density in the predawn sector approximately 400 times greater than the dayside value. Analysis suggests that wind-induced diffusion, combined with exospheric return flow, can account for the observed hydrogen behavior. The large day-night temperature contrast enhances advective transport, which produces the large H concentration diurnal variation; the shift of the H concentration nighttime maximum toward dawn is caused by atmospheric superrotation.

Brinton, H. C.↗
NASA NTRS1986

Mode and mechanism of fatigue fracture of a pearlitic steel in hydrogen

It is presently suggested that there are two mechanisms that cause fatigue crack initiation in a specimen subjected to a hydrogen environment: either a critical concentration of hydrogen is attained within the specimen, causing Mode I crack initiation, or the presence of some hydrogen (below critical concentration) promotes the early onset of plastic instability at the sites of maximum strain. It is further suggested that in the static loading condition, a high hydrogen concentration may be attained by way of mechanical factors, causing Mode I crack initiation. While cyclic fatigue specimens exhibited Mode II crack initiation in air, only Mode I crack initiation emerged in a hydrogen environment.

Lo, S. H.↗
DOE OSTI2023

Charge Concentration Limits the Hydrogen Evolution Rate in Organic Nanoparticle Photocatalysts

Colloidal organic nanoparticles have proven to be a promising class of photocatalyst for performing the Hydrogen Evolution Reaction (HER) due to their dispersibility in aqueous environments, their strong absorption within the visible region, and the tunabilty of their component materials' redox potentials. Currently, there is little understanding of how charge generation and accumulation in organic semiconductors change when these materials are formed into nanoparticles that share a high interfacial area with water, nor is it known what mechanism limits the hydrogen evolution efficiency in recent reports on organic nanoparticle photocatalysts. Herein, we use Time-Resolved Microwave Conductivity to study aqueous-soluble organic nanoparticles and bulk thin films composed of various blend ratios of the non-fullerene acceptor EH-IDTBR and conjugated polymer PTB7-Th and examine the relationship between composition, interfacial surface area, charge carrier dynamics, and photocatalytic activity. We quantitatively measure the rate of Hydrogen Evolution Reaction by nanoparticles composed of various donor:acceptor blend ratio compositions and find that the most active blend ratio displays a Hydrogen Quantum Yield of 0.83% per photon. Moreover, we find that nanoparticle photocatalytic activity corresponds directly to charge generation, and that nanoparticles have 3x more long-lived accumulated charges relative to bulk samples of the same material composition. Here these results suggest that, under our current reaction conditions, with approximately 3x solar flux, catalytic activity by these nanoparticles is limited by the concentration of electrons and holes in operando and not a finite number of active surface cites or the catalytic rate at the interface. This provides a clear design goal for the next generation of efficient photocatalytic nanoparticles.

08 HYDROGEN↗
NASA NTRS1972

Cost analysis of carbon dioxide concentrators

A methodology is developed to predict the relevant contributions of the more intangible cost elements encountered in the development of flight-qualified hardware and is used to predict the costs of three carbon dioxide concentration systems. The cost and performance data from Gemini, Skylab, and other programs are utilized as a basis for establishing the cost estimating relationships. The concentration systems analyzed are the molecular sieves C02 concentrator, the hydrogen-depolarized concentrator, and the regenerable solid desiccant concentrator. Besides the cost estimates for each system, their comparative criteria including relative characteristics, operational differences, and development status are considered.

Yakut, M. M.↗
NASA NTRS1976

Electrochemical performance investigations on the hydrogen depolarized CO2 concentrator

An extensive investigation of anode and cathode polarization in complete cells and half cells was conducted to determine the factors affecting HDC electrode polarization and the nature of this polarization. Matrix-electrolyte-electrode interactions and cell electrolyte composition were also investigated. The electrodes were found to have normal performance capabilities. The HDC anode polarization characteristics were correlated with a theoretical kinetic analysis; and, except for some quantitative details, a rather complete understanding of the causes for HDC electrode polarization was formulated. One of the important finding resulting from the kinetic analysis was that platinum appears to catalyze the decomposition of carbonic acid to carbon dioxide and water. It was concluded that the abnormal voltage performance of the One Man ARS HDC cells was caused by insufficient cell electrolyte volume under normal operating conditions due to deficiencies in the reservoir to cell interfacing.

Aylward, J. R.↗
NASA NTRS1995

Hydrogen-Detection Apparatus

Apparatus continuously monitors concentration of hydrogen, at level ranging from few parts per million to several percent, in mixture of gases. Simple and fast, providing high sensitivity and linear response. Used to alert technicians to potentially explosive concentrations of residual hydrogen.

Ross, H. Richard↗
NASA NTRS2010

South Pole Hydrogen Distribution for Present Lunar Conditions: Implications for Past Impacts

It has been known since the Lunar Prospector mission that the poles of the Moon evidently harbor enhanced concentrations of hydrogen [1,2]. The physical and chemical form of the hydrogen has been much debated. Using imagery from Clementine it was possible to roughly estimate permanently-shadowed regions (PSRs), and to perform image reconstructions of the Lunar Prospector epithermal neutron flux maps [3,4]. The hydrogen concentrations resulting from these reconstructions were consistent with a few weight percent water ice in selected locations. With the LCROSS impact, we now know that hydrogen in the form of ice does exist in lunar polar cold traps [5]. Armed with this information, and new data from LRO/Diviner, we can examine whether the pre-sent-day distribution of hydrogen in the form of water ice is consistent with a past large impact that delivered a large mass of volatiles to the lunar surface. These volatiles, mixed with solid impact ejecta, would then be lost from locations having high mean temperatures but would otherwise remain trapped in locations with sufficiently low mean annual temperatures [6]. The time scales for loss would depend on the location-dependent temperatures as well as impact history.

Elphic, R. C.↗
NASA NTRS1977

Evaluation of a hydrogen chloride detector for environmental monitoring

The paper describes a hydrogen chloride detector designed to monitor concentrations of hydrogen chloride gas in the ambient environment. The detector was developed for NASA for use in launch vehicle effluent monitoring. The detector operates on chemiluminescence principles with a lower detection limit of less than 5 x 10 to the -3rd ppm (by volume). The hydrogen chloride in the air sample reacts with a bromide-bromate coating in the inlet tube of the instrument producing bromine. Bromine is then quantitated by chemiluminescent oxidation of luminol. The visible light generated in the chemiluminescent reaction is proportional to the hydrogen chloride concentration of the sampled airstream. The detector is most suited to laboratory or field studies where hydrogen chloride is the dominant pollutant, as compared to the interfering species. Interferences include strong acids, acid-forming gases, and halogen gases. Of the interferences investigated the most serious in these groups are hydrochloric and sulfuric acid, sulfur dioxide, and chlorine, respectively. The detector has been in use since 1974 and has been found to be highly portable, rugged, and stable under extreme environmental conditions.

Gregory, G. L.↗
NASA NTRS1980

Direct thermal water splitting by concentrated solar radiation for hydrogen production. Phase O: Proof of concept experiment

The direct production of hydrogen from water and solar energy concentrated into a high temperature aperture is described. A solar powered reactor able to dissociate water vapor and to separate the reaction product at high temperature was developed, and direct water splitting has been achieved in a laboratory reactor. Water vapor and radiative heating from a carbon dioxide laser are fed into the reactor, and water vapor enriched in hydrogen and water vapor enriched in oxygen are produced. The enriched water vapors are separated through a separation membrane, a small disc of zirconium dioxide heated to a range of 1800 k to 2800 k. To avoid water vapor condensation within the reactor, the total pressure within the reactor was limited to 0.15 torr. A few modifications would enable the reactor to be operated at an increased pressure of a few torrs. More substantial modifications would allow for a reaction pressure of 0.1 atmosphere.

Genequand, P.↗
NASA NTRS2018

Background and Lunar Neutron Populations Detected by LEND and Average Concentration of Near-Surface Hydrogen near the Moon's Poles

Neutron flux measurements by the Lunar Exploration Neutron Detector (LEND) on the Lunar Reconnaissance Orbiter (LRO) enable quantifying hydrogen-bearing volatiles in the lunar surface from orbit. Accurately determining hydrogen abundance requires discriminating between the instrument background detection rate and the population of lunar-sourced neutrons that are sensitive to surficial hydrogen. We have investigated the detection rate for lunar and non-lunar (spacecraft-sourced) neutrons in LEND by modeling maps of measured count rate in three LEND detector systems using linear combinations of maps compiled from LEND detectors and from the Lunar Prospector Neutron Spectrometer. We find that 30% of the global-average 24.926 0.020 neutron counts per second (cps) detected by the LEND STN3 thermal-energy neutron sensor are lunar-sourced neutrons in the thermal energy range (E < 0.4 eV), 65% are lunar-sourced neutrons in the epithermal and fast energy range (E > 0.4 eV), and 5% are from spacecraft-sourced background signal. In the SETN epithermal neutron detector, 90% of the 10.622 0.002 neutron detections per second are consistent with a lunar source of epithermal and fast neutrons combined (E > 0.4 eV), with 3% due to lunar-sourced thermal neutron leakage into the detector (E < 0.4 eV), and background signal accounting for 7% of total detections. Background signal due to spacecraft-derived neutrons is substantial in the CSETN collimated detector system, accounting for 57% of the global average detection rate of 5.082 0.001 cps, greater than the 48% estimated from cruise-phase data. Lunar-sourced epithermal and fast neutrons account for 43% of detected neutrons, including neutrons in collimation as well as neutrons that penetrate the collimator wall to reach the detector. We estimate a lower limit of 17% of lunar-sourced neutrons detected by CSETN are epithermal neutrons in collimation (0.37 cps), with an upper limit estimate of 54 11% of lunar-sourced neutrons received in collimation, or 1.2 0.2 cps global average. The pole-to-equator contrast ratio inepithermal and high-energy epithermal neutron flux indicates that the average concentration of hydrogen in the polar regolith above 80 north or south latitude is ~105 ppmw (parts per million by weight), or 0.095 0.01 wt% water-equivalent hydrogen. Above 88 north or south, the concentration increases to ~140 ppmw, or 0.13 0.02 wt% water-equivalent hydrogen. The similar pattern of neutron flux suppression at both poles suggests that hydrogen concentration generally increases nearer the pole and is not closely associated with a specific feature such as Shackleton Crater at the lunar south pole that has no northern counterpart. Epithermal neutron flux decreases with increasing latitude outside the polar regions, consistent with surface hydration that increases with latitude if that hydration extends to ~13-40 cm into the surface.

Livengood, Timothy A.↗
NASA NTRS2017

Background and Lunar Neutron Populations Detected by LEND and Average Concentration of Near-Surface Hydrogen near the Moon's Poles

Neutron flux measurements by the Lunar Exploration Neutron Detector (LEND) on the Lunar Reconnaissance Orbiter (LRO) enable quantifying hydrogen-bearing volatiles in the lunar surface from orbit. Accurately determining hydrogen abundance requires discriminating between the instrument background detection rate and the population of lunar-sourced neutrons that are sensitive to surficial hydrogen. We have investigated the detection rate for lunar and non-lunar (spacecraft-sourced) neutrons in LEND by modeling maps of measured count rate in three LEND detector systems using linear combinations of maps compiled from LEND detectors and from the Lunar Prospector Neutron Spectrometer. We find that 30% of the global-average 24.926 +/- 0.020 neutron counts per second (cps) detected by the LEND STN3 thermal-energy neutron sensor are lunar-sourced neutrons in the thermal energy range (E < 0.4 eV), 65% are lunar-sourced neutrons in the epithermal and fast energy range (E > 0.4 eV), and 5% are from spacecraft-sourced background signal. In the SETN epithermal neutron detector, 90% of the 10.622 +/- 0.002 neutron detections per second are consistent with a lunar source of epithermal and fast neutrons combined (E > 0.4 eV), with 3% due to lunar-sourced thermal neutron leakage into the detector (E < 0.4 eV), and background signal accounting for 7% of total detections. Background signal due to spacecraft-derived neutrons is substantial in the CSETN collimated detector system, accounting for 57% of the global average detection rate of 5.082 +/- 0.001 cps, greater than the 48% estimated from cruise-phase data. Lunar-sourced epithermal and fast neutrons account for 43% of detected neutrons, including neutrons in collimation as well as neutrons that penetrate the collimator wall to reach the detector. We estimate a lower limit of 17% of lunar-sourced neutrons detected by CSETN are epithermal neutrons in collimation (0.37 cps), with an upper limit estimate of 54 +/- 11% of lunar-sourced neutrons received in collimation, or 1.2 +/- 0.2 cps global average. The pole-to-equator contrast ratio in epithermal and high-energy epithermal neutron flux indicates that the average concentration of hydrogen in the polar regolith above 80deg north or south latitude is ∼105 ppmw (parts per million by weight), or 0.095 +/- 0.01 wt% water-equivalent hydrogen. Above 88deg north or south, the concentration increases to ∼140 ppmw, or 0.13 +/- 0.02 wt% water-equivalent hydrogen. The similar pattern of neutron flux suppression at both poles suggests that hydrogen concentration generally increases nearer the pole and is not closely associated with a specific feature such as Shackleton Crater at the lunar south pole that has no northern counterpart. Epithermal neutron flux decreases with increasing latitude outside the polar regions, consistent with surface hydration that increases with latitude if that hydration extends to ∼13-40 cm into the surface.

T A Livengood↗
NASA NTRS1978

Summary of airborne chlorine and hydrogen chloride gas measurements for August 20 and September 5, 1977 Voyager launches at Air Force Eastern Test Range, Florida

Airborne chlorine and hydrogen chloride measurements were made in the tropospheric ground cloud following the Voyager launches of August 20 and September 5, 1977. The maximum observed hydrogen chloride concentration for both launches was about 25 to 30 parts per million (ppm) occurring typically 2 to 6 minutes after launch. By completion of the sampling mission (1-1/2 hours for August, 4-1/2 hours for September), the maximum in-cloud concentration decayed to about 1 to 2 ppm. Maximum observed chlorine concentrations were about 40 to 55 parts per billion (ppb) about 2 to 8 minutes after launch; by about 15 minutes after launch, chlorine concentrations were less than 10 ppb (detection limit). In-cloud chlorine concentrations were well below 1 percent of hydrogen chloride concentrations. The appendix of the report discusses the chlorine instrument and the laboratory evaluation of the detector.

Gregory, G. L.↗
NASA NTRS1973

Hydrogen depolarized carbon dioxide concentrator performance improvements and cell pair structural tests

The investigations and testing associated with the CO2 removal efficiency and voltage degradation of a hydrogen depolarized carbon oxide concentrator are reported. Also discussed is the vibration testing of a water vapor electrolysis cell pair. Performance testing of various HDC cell pairs with Cs2CO3 electrolyte provided sufficient parametric and endurance data to size a six man space station prototype CO2 removal system as having 36 HDC cell pairs, and to verify a life capability exceeding six moths. Testing also demonstrated that tetramethylammonium carbonate is an acceptable HDC electrolyte for operating over the relative humidity range of 30 to 90 percent and over a temperature range of 50 to 80 F.

Huddleston, J. D.↗
DOE OSTI2023

Non-equilibrium molecular dynamics studies of thermal diffusion of hydrogen isotopes in low concentration zirconium hydrides

Tritium permeability in zirconium-based tritium getter critically impacts tritium storage and environmental safety during operation of tritium-producing burnable absorber rods (TPBARs). Previous experiments indicated that during irradiation operation, the hydrogen equilibrium pressured is increased. Further experimental and modeling studies suggested that the enhanced tritium release observed for reactor scale assemblies might be related to a thermal diffusion known as the Soret effect. A direct measurement of the Soret factor, however, has not been performed. To improve TPBAR and other nuclear applications, here we have applied two non-equilibrium molecular dynamics methods to study thermal diffusion of hydrogen isotopes in low-concentration zirconium hydrides. One of the methods produces sufficiently converged results to distinguish crystal orientation, isotope type, and concentration effects. In conclusion, with this method, crystal orientation, isotope type, and concentration effects are discussed.

36 MATERIALS SCIENCE↗
NASA NTRS1993

Compact Raman Spectrometers Would Detect Hydrogen

Compact Raman spectrometers developed to measure concentrations of hydrogen as low as hundreds of parts per million in air, nitrogen, or other carrier gases. Advantages include speed, dynamic range, and ease of calibration. Design concept incorporates Raman-scattering apparatus into compact instrument of hydrogen leaking into stream of gas or into gas enclosed in small space. Should hydrogen-fueled cars and trucks come into widespread use, instruments used to detect leaks from vehicles and supply equipment, to help prevent explosions. Similar spectrometers developed to detect other gases emitting characteristic Raman spectra.

Helms, William R.↗