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At least 253 records · Page 14

Merits of a lunar polar base location

There are no seasons on the moon, and its surface may include regions where the sun never fully sets. Permanent shadow regions may be very cold, and with continuous sunlight nearby, appear ideal sites for thermodynamic power systems. If located near a pole, a lunar base could have solar electric power and piped-in solar illumination continuously available. Habitat and agricultural conditions in underground facilities are easily kept constant. Such polar sites would furnish excellent opportunities for astronomical observation, since fully half of the sky is visible from each pole and cryogenic instruments are easily operated there.

Burke, J. D.↗

Evaluation of the Portable Instantaneous Display Analysis Spectrometer (PIDAS)

The Portable Instantaneous Display Analysis System (PIDAS) was evaluated by measuring 125 spectra of mineral specimens and rock samples under the following conditions: in the laboratory under artificial illumination and outdoors, on the building patio, while still using the line voltage electric power supplies. The PIDAS was compared and contrasted with the GEOSCAN PFS, Daedalus-Spectrafax 440, and the Geophysical Environmental Research (GER) IRIS Mark 4.

Lyon, R. J. P.↗

Evaluation of visual acuity with Gen 3 night vision goggles

Using laboratory simulations, visual performance was measured at luminance and night vision imaging system (NVIS) radiance levels typically encountered in the natural nocturnal environment. Comparisons were made between visual performance with unaided vision and that observed with subjects using image intensification. An Amplified Night Vision Imaging System (ANVIS6) binocular image intensifier was used. Light levels available in the experiments (using video display technology and filters) were matched to those of reflecting objects illuminated by representative night-sky conditions (e.g., full moon, starlight). Results show that as expected, the precipitous decline in foveal acuity experienced with decreasing mesopic luminance levels is effectively shifted to much lower light levels by use of an image intensification system. The benefits of intensification are most pronounced foveally, but still observable at 20 deg eccentricity. Binocularity provides a small improvement in visual acuity under both intensified and unintensified conditions.

Bradley, Arthur↗

In Situ ATR–SEIRAS of Carbon Dioxide Reduction at a Plasmonic Silver Cathode

Illumination of a voltage-biased plasmonic Ag cathode during CO 2 reduction results in a suppression of the H 2 evolution reaction while enhancing CO 2 reduction. This effect has been shown to be photonic rather than thermal, but the exact plasmonic mechanism is unknown. Here in this paper, we conduct an in situ ATR–SEIRAS (attenuated total reflectance–surface-enhanced infrared absorption spectroscopy) study of a sputtered thin film Ag cathode on a Ge ATR crystal in CO 2 -saturated 0.1 M KHCO 3 over a range of potentials under both dark and illuminated (365 nm, 125 mW cm –2 ) conditions to elucidate the nature of this plasmonic enhancement. We find that the onset potential of CO 2 reduction to adsorbed CO on the Ag surface is -0.25 V RHE and is identical in the light and the dark. As the production of gaseous CO is detected in the light near this onset potential but is not observed in the dark until -0.5 V RHE , we conclude that the light must be assisting the desorption of CO from the surface. Furthermore, the HCO 3 – wavenumber and peak area increase immediately upon illumination, precluding a thermal effect. We propose that the enhanced local electric field that results from the localized surface plasmon resonance (LSPR) is strengthening the HCO 3 – bond, further increasing the local pH. This would account for the decrease in H 2 formation and increase the CO 2 reduction products in the light.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Aircraft maneuver envelope warning system

A maneuver envelope warning system for an aircraft having operating limits, operating condition sensors and an indicator driver. The indicator driver has a plurality of visual indicators. The indicator driver determines a relationship between sensed operating conditions and the operating limits; such as, a ratio therebetween. The indicator driver illuminates a number of the indicators in proportion to the determined relationship. The position of the indicators illuminated represents to a pilot in an easily ascertainable manner whether the operational conditions are approaching operational limits of the aircraft, and the degree to which operational conditions lie within or exceed operational limits.

Bivens, Courtland C.↗

Low-background InSb array development

Photovoltaic indium antimonide (PV InSb) detector technology has matured over the past several years to enable a wide variety of applications to use this high-performance detector material to advantage. The operating conditions for most of the applications to date for back-side illuminated PV InSb arrays have encompassed focal plane temperatures ranging from 40 to approximately 95 K, with the majority in the narrower range between 60 and 80 K. Background flux conditions have ranged from 10 to the 10th power ph/sq cm/sec to 10 to the 16th power ph/sq cm/sec, most typically between 10 to the 12th power and 10 to the 14th power ph/sq cm/sec. Appropriately, the array parameters were optimized for maximum performance over these temperature and background ranges. The key parameters which were peaked in this process were the resistance-area product of the detectors and their quantum efficiency. The Space Infrared Telescope Facility (SIRTF) Infrared Array Camera requirements, however, present very low temperature and background operating conditions, plus the need for very high signal to noise ratios. Preliminary analysis indicates that back-side illuminated PV InSb arrays can be optimized for operation under these conditions, and some performance projections will be presented.

Thom, R. D.↗

Efficient and stable perovskite solar cells based on blade-coated CH 3 NH 3 PbI 3 thin films fabricated using “green” solvents under ambient conditions

Metal halide perovskites are considered the most promising candidates for solar cells of the decade due to their exceptional optical and electronic properties. The power conversion efficiency of metal halide perovskites, when incorporated as the active layer of solar cells, has become comparable to that observed for conventional silicon solar cells. However, the stability, scaleup, green solvent usage, and fabrication in ambient conditions of metal halide perovskites need to be solved for commercial applications. Here, in this work, we report the fabrication of blade-coated methylammonium lead iodide (MAPbI 3 ) perovskite thin films using methylamine and acetonitrile as “green” solvents under ambient conditions. Our perovskite films are initially prepared from low purity PbI2 (99%) and are blade-coated in dry air at relative humidity (RH) levels above 30%. A significant advantage of fabricating our perovskite thin films via blade-coating protocols is that there is a minimal amount of precursors (5 μL) used compared to spin-coating methods (50μL–60μL) for a 4 cm 2 substrate. With the addition of a small amount of an organic halide salt, namely, phenethylammonium chloride, the film crystallinity is improved and non-radiative recombination is suppressed, resulting in power conversion efficiencies over 20%. In addition, the device maintains more than 95% of its initial efficiency after 500 h under continuous light illumination of 1-sun at open circuit conditions, 50 °C and 60% RH. The above method leads a path towards the commercial fabrication of perovskite solar cells.

14 SOLAR ENERGY↗

Lighting and visual comfort performance of commercially available tubular daylight devices

Tubular daylight devices (TDDs) require a much smaller roof opening than conventional skylights and, because of their highly reflective tube, they can deliver daylight farther away from the building envelope. This can provide lighting energy savings, increasing resilience in new and existing buildings. Different types and configurations are available amongst commercially available TDDs, including domes/diffusers with varying optical properties and the diameter of the TDD. This paper presents a comprehensive experimental evaluation of the lighting and visual comfort performance of multiple configurations of commercially available TDDs, varying dome type (prismatic and clear), diffuser type (Fresnel and prismatic), and diameter (53 and 35 cm), under a range of environmental conditions (different times of day/year, sky cover). Based on illuminance measurements, estimated lighting energy use is also presented. Results indicate that, for clear sky, light levels increase and energy use decreases with solar altitude (e.g., 16 Wh/m 2 daily energy use intensity on a high maximum daily solar altitude (MDSA) day and 34 Wh/m 2 on a low MDSA day) and TDD diameter (e.g., 34 Wh/m 2 and 69 Wh/m 2 for 53 cm and 35 cm TDDs, respectively, for low MDSA). The daily illuminance profile is more rounded for prismatic domes and has higher peaks for clear domes; this translates into a somewhat higher average daily useful daylight illuminance (DUDI) for prismatic domes (86 %) when compared to clear domes (80 %). No clear impact of diffuser type was apparent. In conclusion, measurements indicated no discomfort glare for any of the conditions tested.

14 SOLAR ENERGY↗

Simulated space environment tests on cadmium sulfide solar cells

Cadmium sulfide (Cu2s - CdS) solar cells were tested under simulated space environmental conditions. Some cells were thermally cycled with illumination from a Xenon-arc solar simulator. A cycle was one hour of illumination followed immediately with one-half hour of darkness. In the light, the cells reached an equilibrium temperature of 60 C (333 K) and in the dark the cell temperature dropped to -120 C (153 K). Other cells were constantly illuminated with a Xenon-arc solar simulator. The equilibrium temperature of these cells was 55 C (328 K). The black vacuum chamber walls were cooled with liquid nitrogen to simulate a space heat sink. Chamber pressure was maintained at 0.000001 torr or less. Almost all of the solar cells tested degraded in power when exposed to a simulated space environment of either thermal cycling or constant illumination. The cells tested the longest were exposed to 10.050 thermal cycles.

Clarke, D. R.↗

Exploiting Lunar Natural and Augmented Thermal Environments for Exploration and Research

Near the poles of the Moon, there are permanently shadowed craters whose surface temperatures never exceed 100 K. Craters within craters, commonly referred to as double-shaded craters, have areas where even colder regions exist with, in many cases, temperatures that should never exceed 50 K. The presence of water ice possibly existing in permanently shaded areas of the moon has been hypothesized, discussed, and studied since Watson et al. [1] predicted the possibility of ice on the moon. Ingersoll et al. [2] estimated that the maximum sublimation rate for ice is less than 1 cm per billion years for these types of environments. These potential ice stores have many uses for lunar exploration, potentially providing precious water and rocket fuel for any human exploration or future colonization. The temperatures within these regions offer unprecedented high-vacuum cryogenic environments, which in their natural state could support cryogenic applications such as high-temperature superconductors and associated devices that could be derived. The potential application of naturally occurring cryogenic environments in conjunction with simple methods to augment these environments to achieve even colder temperatures opens the potential use of many additional cryogenic techniques. Besides ice stores and the potential for continuous solar illumination for power production, the unique cryogenic conditions at the lunar poles provide an environment that could reduce the power, weight, and total mass that would have to be carried from the Earth to the Moon for lunar exploration and research.

Ryan, Robert E.↗

Data Assimilation of Photosynthetic Light-use Efficiency using Multi-angular Satellite Data: II Model Implementation and Validation

Spatially explicit and temporally continuous estimates of photosynthesis will be of great importance for increasing our understanding of and ultimately closing the terrestrial carbon cycle. Current capabilities to model photosynthesis, however, are limited by accurate enough representations of the complexity of the underlying biochemical processes and the numerous environmental constraints imposed upon plant primary production. A potentially powerful alternative to model photosynthesis through these indirect observations is the use of multi-angular satellite data to infer light-use efficiency (ε) directly from spectral reflectance properties in connection with canopy shadow fractions. Hall et al. (this issue) introduced a new approach for predicting gross ecosystem production that would allow the use of such observations in a data assimilation mode to obtain spatially explicit variations in ε from infrequent polar-orbiting satellite observations, while meteorological data are used to account for the more dynamic responses of ε to variations in environmental conditions caused by changes in weather and illumination. In this second part of the study we implement and validate the approach of Hall et al. (this issue) across an ecologically diverse array of eight flux-tower sites in North America using data acquired from the Compact High Resolution Imaging Spectroradiometer (CHRIS) and eddy-flux observations. Our results show significantly enhanced estimates of ε and therefore cumulative gross ecosystem production (GEP) over the course of one year at all examined sites. We also demonstrate that ε is greatly heterogeneous even across small study areas. Data assimilation and direct inference of GEP from space using a new, proposed sensor could therefore be a significant step towards closing the terrestrial carbon cycle.

Hilker, Thomas↗

Power Hibernation for Low-Cost Solar Powered Lunar Missions

Because the surface of the Moon drops to cryogenic temperatures, no solar-powered lunar spacecraft have reliably operated beyond a single lunar day. Passive thermal control cannot keep a spacecraft sufficiently warm for the 354-hour lunar night, and active thermal control requires a dramatic increase in battery mass at the expense of payload mass. Extreme conditions seen on the lunar surface suggest a radioisotope solution is ideal, but mass, cost, and schedule are inconsistent with low-cost frequent flight intent of the commercial lunar payload services (CLPS) program. To solve the issue of lunar night survivability without radioisotope sources of power and heat, a lunar power hibernation approach is being developed at the Glenn Research Center, which exploits the ability of common 18650 Lithium-ion cells to passively survive cryogenic freeze-thaw cycles and recover without apparent performance degradation. A key aspect of this hibernation approach is the use of cryogenically operable electronics that safely manage the restoration of the battery thermal environment at lunar dawn. A spacecraft utilizing this strategy will operate into the lunar night on batteries until the state of charge or spacecraft temperature reaches a predetermined threshold. At this point, systems are shut down and the battery is isolated from the main bus to prevent charge or discharge during the freezing and thawing transitions. The system remains passive until lunar dawn, where temperatures can reach as low as 50 K. All electronics must be tolerant to these conditions. When the solar arrays are finally illuminated at lunar dawn, the main bus power electronics will initiate a “cold start” and begin regulating array power. The main bus electronics must be designed to operate at cryogenic temperatures. Array power is used to warm the battery and passive electronics back to operational temperatures. Once batteries are returned to normal temperatures, diagnostics and precharging is performed, as needed, and the battery is reconnected. The overall spacecraft system reboots and returns to nominal operations until lunar night returns. To assure that we can develop batteries suited for many hibernation freeze/thaw cycles, STMD Space Technology Research Grant Program (STRG) has selected two principal investigators that will thoroughly characterize of the Li-ion cell through the freeze-thaw process, investigate degradation mechanisms, and identify potential diagnostic techniques. STMD STRG is also funding an investigation of Gallium-Nitride semiconductors for cryogenic power applications. This work includes physics-informed modeling that considers cryogenic conductivity, carrier mobility, and quantum effects that govern semiconductor performance at cryogenic temperatures. These models can enable engineers to develop accurate cryogenic simulation models that assist in the design of power controls stable over the entire lunar surface temperature range. Meanwhile, Glenn is performing cryogenic testing of batteries and electronics, establishing design guidelines for power applications in extreme cold lunar environment, and potentially developing a hibernation technology demonstrator. The hibernation approach will enable low-cost lunar robotic missions to extend their operating lifetime to many months while minimizing development costs and impact on payload capacity. The need for cryogenically operable electronics is restricted to only main bus power and battery controls, as the majority of systems simply need to passively tolerate cryogenic temperatures. This allows developers to continue to exploit the cost savings of legacy and COTS hardware with minimum modification. For these reasons, lunar power hibernation is a viable near-term solution for lunar night survivability for solar powered commercial landers.

Space power↗

Photovoltaic Systems for Lunar Surface Survivability During the Lunar Day and Night

While photovoltaic systems will not be operating during the lunar night, it is still important to ensure that the cells, structure, and other components are able to survive the extreme low temperature conditions during times of low to no illumination. The Photovoltaics team at NASA GRC has expertise in low temperature solar cell operation, thermal cycling of solar cell coupons and array components, and the design of lunar solar arrays for long duration surface missions.

Solar power↗

Versatile recognition of graphene layers from optical images under controlled illumination through green channel correlation method

In this study, a simple yet versatile method is proposed for identifying the number of exfoliated graphene layers transferred on an oxide substrate from optical images, utilizing a limited number of input images for training, paired with a more traditional number of a few thousand well-published Github images for testing and predicting. Two thresholding approaches, namely the standard deviation-based approach and the linear regression-based approach, were employed in this study. The method specifically leverages the red, green, and blue color channels of image pixels and creates a correlation between the green channel of the background and the green channel of the various layers of graphene. This method proves to be a feasible alternative to deep learning-based graphene recognition and traditional microscopic analysis. The proposed methodology performs well under conditions where the effect of surrounding light on the graphene-on-oxide sample is minimum and allows rapid identification of the various graphene layers. Here, the study additionally addresses the functionality of the proposed methodology with nonhomogeneous lighting conditions, showcasing successful prediction of graphene layers from images that are lower in quality compared to typically published in literature. In all, the proposed methodology opens up the possibility for the non-destructive identification of graphene layers from optical images by utilizing a new and versatile method that is quick, inexpensive, and works well with fewer images that are not necessarily of high quality.

36 MATERIALS SCIENCE↗

Coronagraphic Observations of the Lunar Sodium Exosphere Near the Lunar Surface

The sodium exosphere of the Moon was observed using a solar coronagraph to occult the illuminated surface of the Moon. Exceptionally dust-free atmospheric conditions were required to allow the faint emission from sunlight scattered by lunar sodium atoms to be distinguished from moonlight scattered from atmospheric dust. At 0300 UT on April 22, 1994, ideal conditions prevailed for a few hours, and one excellent image of the sodium exosphere was measured, with the Moon at a phase angle of 51 deg, 81 % illuminated. Analysis of the image data showed that the weighted mean temperature of the exosphere was 1280 K and that the sodium column density varied approximately as cosine-cubed of the latitude. A cosine-cubed variation is an unexpected result, since the flux per unit area of solar photons and solar particles varies as the cosine of latitude. It is suggested that this can be explained by a temperature dependence for the sputtering of sodium atoms from the surface. This is a characteristic feature of chemical sputtering, which has been previously proposed to explain the sodium exosphere of Mercury. A possible interaction between chemical sputtering and solar photons is suggested.

Potter, A. E.↗

Characterization of Ice Roughness Variations in Scaled Glaze Icing Conditions

Because of the significant influence of surface tension in governing the stability and breakdown of the liquid film in flooded stagnation regions of airfoils exposed to glaze icing conditions, the Weber number is expected to be a significant parameter governing the formation and evolution of ice roughness. To investigate the influence of the Weber number on roughness formation, 53.3-cm (21-in.) and 182.9-cm (72-in.) NACA 0012 airfoils were exposed to flow conditions with essentially the same Weber number and varying stagnation collection efficiency to illuminate similarities of the ice roughness created on the different airfoils. The airfoils were exposed to icing conditions in the Icing Research Tunnel (IRT) at the NASA Glenn Research Center. Following exposure to the icing event, the airfoils were then scanned using a ROMER Absolute Arm scanning system. The resulting point clouds were then analyzed using the self-organizing map approach of McClain and Kreeger (2013) to determine the spatial roughness variations along the surfaces of the iced airfoils. The roughness characteristics on each airfoil were then compared using the relative geometries of the airfoil. The results indicate that features of the ice shape and roughness such as glaze-ice plateau limits and maximum airfoil roughness were captured well by Weber number and collection efficiency scaling of glaze icing conditions. However, secondary ice roughness features relating the instability and waviness of the liquid film on the glaze-ice plateau surface are scaled based on physics that were not captured by the local collection efficiency variations.

Roughness Formation↗

Redesigning Photoelectrodes So They Can Work in the Light and Dark

Unassisted photoelectrochemical (PEC) reactions, such as H2 generation and CO2 reduction, are limited by the durability of the immersed photoelectrode. Small band gap semiconductors, like Si, are efficient at utilizing a large portion of the solar spectrum but are not stable in aqueous environments without protection. While great strides have been made to improve stability under constant illumination, dark stability remains relatively unexamined and presents great challenges for durable PEC systems. Cathodic protection is an established electrochemical method for preventing metal electrode degradation in harsh conditions. Similar protection strategies cannot be applied to traditional two-terminal (2T) semiconductor photoelectrodes because of their inability to pass reverse bias current in the dark. New, three-terminal (3T) photovoltaic (PV) architectures introduce additional degrees of freedom in traditional 2T PEC operations by adding an extra electrical contact for an alternative low resistance path to protect the photoelectrode and drive electrochemical reactions, even in the dark. Here, we investigate bare 3T Si PV devices operating as photocathodes in aqueous methyl viologen electrolyte. The 3T architecture provides additional capabilities to PEC systems such as cathodic protection, the ability to drive reactions with or without illumination, and in situ switching between different operational modes. We show that 3T-based Si photocathodes maintain PEC activity after several hours of light/dark cycling. This work helps advance PEC use in real-world conditions where variable illumination must be considered.

cathodic protection↗

Efficiency of bulk perovskite-sensitized upconversion: Illuminating matters

Photon upconversion via triplet–triplet annihilation could allow for the existing efficiency limit of single junction solar cells to be surpassed. Indeed, efficient upconversion at subsolar fluences has been realized in bulk perovskite-sensitized systems. Many questions have remained unanswered, in particular, regarding their behavior under photovoltaic operating conditions. Here, we investigate the impact of repeated and continuous illumination on bilayer perovskite/rubrene upconversion devices. We find that variations of the underlying perovskite carrier recombination dynamics greatly impact the upconversion process. Trap filling and triplet sensitization are in direct competition: more saturated trap states in the perovskite and, thus, longer underlying perovskite photoluminescence lifetimes allow for an increased number of carriers to diffuse to the perovskite/rubrene interface and undergo charge extraction to the triplet state of rubrene. As a result, the upconversion efficiency is greatly influenced by the underlying trap density: the upconverted photoluminescence intensity increases by two orders of magnitude under continuous illumination for 4 h. This shows that the upconversion efficiency is difficult to define for this system. Importantly, these results indicate that perovskite-sensitized upconversion devices exhibit peak performance under continuous illumination, which is a requirement for their successful integration into photovoltaics to help overcome the Shockley–Queisser limit in single junction solar cells.

VanOrman, Zachary A. (ORCID:000000027773012X)↗