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At least 253 records · Page 14

First Global Observations of Atmospheric COCIF from the Atmospheric Chemistry Experiment Mission

Carbonyl chlorofluoride (COCIF) is an important reservoir of chlorine and fluorine in the Earth's atmosphere. Satellite-based remote sensing measurements of COCIF, obtained by the Atmospheric Chemistry Experiment (ACE) for a time period spanning February 2004 through April 2007, have been used in a global distribution study. There is a strong source region for COCIF in the tropical stratosphere near 27 km. A layer of enhanced COCIF spans the low- to mid-stratosphere over all latitudes, with volume mixing ratios of 40-100 parts per trillion by volume, largest in the tropics and decreasing toward the poles. The COCIF volume mixing ratio profiles are nearly zonally symmetric, but they exhibit a small hemispheric asymmetry that likely arises from a hemispheric asymmetry in the parent molecule CCl3 F. Comparisons are made with a set of in situ stratospheric measurements from the mid-1980s and with predictions from a 2-D model.

Fu, Dejian↗

Observation of absorbing aerosols above clouds over the south-east Atlantic Ocean from the geostationary satellite SEVIRI – Part 1: Method description and sensitivity

High-temporal-resolution observations from satellites have a great potential for studying the impact of biomass burning aerosols and clouds over the south-east Atlantic Ocean (SEAO). This paper presents a method developed to simultaneously retrieve aerosol and cloud properties in aerosol above-cloud conditions from the geostationary instrument Meteosat Second Generation/Spinning Enhanced Visible and Infrared Imager (MSG/SEVIRI). The above-cloud aerosol optical thickness (AOT), the cloud optical thickness (COT) and the cloud droplet effective radius (CER) are derived from the spectral contrast and the magnitude of the signal measured in three channels in the visible to shortwave infrared region. The impact of the absorption from atmospheric gases on the satellite signal is corrected by applying transmittances calculated using the water vapour profiles from a Met Office forecast model. The sensitivity analysis shows that a 10 % error on the humidity profile leads to an 18.5 % bias on the above-cloud AOT, which highlights the importance of an accurate atmospheric correction scheme. In situ measurements from the CLARIFY-2017 airborne field campaign are used to constrain the aerosol size distribution and refractive index that is assumed for the aforementioned retrieval algorithm. The sensitivities in the retrieved AOT, COT and CER to the aerosol model assumptions are assessed. Between 09:00 and 15:00 UTC, an uncertainty of 40 % is estimated on the above-cloud AOT, which is dominated by the sensitivity of the retrieval to the single-scattering albedo. The absorption AOT is less sensitive to the aerosol assumptions with an uncertainty generally lower than 17 % between 09:00 and 15:00 UTC. Outside of that time range, as the scattering angle decreases, the sensitivity of the AOT and the absorption AOT to the aerosol model increases. The retrieved cloud properties are only weakly sensitive to the aerosol model assumptions throughout the day, with biases lower than 6 % on the COT and 3 % on the CER. The stability of the retrieval over time is analysed. For observations outside of the backscattering glory region, the time series of the aerosol and cloud properties are physically consistent, which confirms the ability of the retrieval to monitor the temporal evolution of aerosol above-cloud events over the SEAO.

cloud properties↗

Irradiation stratigraphy and depositional history of the Apollo 16 double drive tube 60009/10

We report track density frequency distributions, the fraction of high density grains and minimum track densities for 63, 1 mm wide locations in the Apollo 16 double drive tube 60009/10. From these data we conclude that there are seven irradiation strata in the core. Only one buried reworking zone extending from 50-52 cm was found and it was exposed near the surface from 4.5-9 times 10 to the 6th y with a most probable exposure period of 6 times 10 to the 6th y. There is lack of conclusive data that this zone represents a reworking zone in which case the material below 52 cm most probably was exposed in situ for 4.5 times 10 to the 6th y and developed a reworking zone approximately less than 0.5 cm. The present surface of the core has a reworking zone of 12-13 cm which was exposed from 1.3 times 10 to the 7th to 2.5 times 10 to the 8th y. The best estimate for this exposure period remains the value of approximately less than 1.25 times 10 to the 8th y determined by Bogard and Hirsch (1976). The other strata in the core appear to contain mixtures of various soil types and are not related to in situ depositional events.

Blanford, G. E.↗

Meteorites, Microfossils and Exobiology

The discovery of evidence for biogenic activity and possible microfossils in a Martian meteorite may have initiated a paradigm shift regarding the existence of extraterrestrial microbial life. Terrestrial extremophiles that live in deep granite and hydrothermal vents and nanofossils in volcanic tuffs have altered the premise that microbial life and microfossils are inconsistent with volcanic activity and igneous rocks. Evidence for biogenic activity and microfossils in meteorites can no longer be dismissed solely because the meteoritic rock matrix is not sedimentary. Meteorite impact-ejection and comets provide mechanisms for planetary cross-contamination of biogenic chemicals, microfossils, and living microorganisms. Hence, previously dismissed evidence for complex indigenous biochemicals and possible microfossils in carbonaceous chondrites must be re-examined. Many similar, unidentifiable, biological-like microstructures have been found in different carbonaceous chondrites and the prevailing terrestrial contaminant model is considered suspect. This paper reports the discovery of microfossils indigenous to the Murchison meteorite. These forms were found in-situ in freshly broken, interior surfaces of the meteorite. Environmental Scanning Electron Microscope (ESEM) and optical microscopy images indicate that a population of different biological-like forms are represented. Energy Dispersive Spectroscopy reveals these forms have high carbon content overlaying an elemental distribution similar to the matrix. Efforts at identification with terrestrial microfossils and microorganisms were negative. Some forms strongly resemble bodies previously isolated in the Orgueil meteorite and considered microfossils by prior researchers. The Murchison forms are interpreted to represent an indigenous population of the preserved and altered carbonized remains (microfossils) of microorganisms that lived in the parent body of this meteorite at diverse times during the past 4.5 billion years (Gy).

Hoover, Richard B.↗

"One-Stop Shopping" for Ocean Remote-Sensing and Model Data

OurOcean Portal 2.0 (http:// ourocean.jpl.nasa.gov) is a software system designed to enable users to easily gain access to ocean observation data, both remote-sensing and in-situ, configure and run an Ocean Model with observation data assimilated on a remote computer, and visualize both the observation data and the model outputs. At present, the observation data and models focus on the California coastal regions and Prince William Sound in Alaska. This system can be used to perform both real-time and retrospective analyses of remote-sensing data and model outputs. OurOcean Portal 2.0 incorporates state-of-the-art information technologies (IT) such as MySQL database, Java Web Server (Apache/Tomcat), Live Access Server (LAS), interactive graphics with Java Applet at the Client site and MatLab/GMT at the server site, and distributed computing. OurOcean currently serves over 20 real-time or historical ocean data products. The data are served in pre-generated plots or their native data format. For some of the datasets, users can choose different plotting parameters and produce customized graphics. OurOcean also serves 3D Ocean Model outputs generated by ROMS (Regional Ocean Model System) using LAS. The Live Access Server (LAS) software, developed by the Pacific Marine Environmental Laboratory (PMEL) of the National Oceanic and Atmospheric Administration (NOAA), is a configurable Web-server program designed to provide flexible access to geo-referenced scientific data. The model output can be views as plots in horizontal slices, depth profiles or time sequences, or can be downloaded as raw data in different data formats, such as NetCDF, ASCII, Binary, etc. The interactive visualization is provided by graphic software, Ferret, also developed by PMEL. In addition, OurOcean allows users with minimal computing resources to configure and run an Ocean Model with data assimilation on a remote computer. Users may select the forcing input, the data to be assimilated, the simulation period, and the output variables and submit the model to run on a backend parallel computer. When the run is complete, the output will be added to the LAS server for

Li, P. Peggy↗

Tracking Nonradial Outflows in Extreme Ultraviolet and White Light Solar Images

Understanding the solar corona requires knowledge of its dynamics through its various layers and subsequent connectivity to the heliosphere. This requires understanding the nature of the outflows and the physical transitions through the middle corona (∼1.5–6.0 Rs). While this region is still inaccessible to in situ measurements, remote sensing observations are available, but their interpretation can be controversial due to line-of-sight effects and the nonradial motion of outflowing structures close to the Sun (≤3.0 Rs). In this work, we describe a method to mitigate these challenges by generating nonradial height–time profiles of outflows by using advanced image processing techniques. The northern and southern boundaries of a large equatorial streamer during the 2008 solar minimum were identified in STEREO/SECCHI solar images, using two different methodologies based on thresholds of brightness and piecewise polynomial function fitting. To address line-of-sight issues, we used tomographic reconstruction of the 3D distribution of the coronal electron density based on SECCHI/COR2 images. Spectral analysis of the time series of the position angle of the streamer boundary revealed its oscillatory nature at some heights at 36–48 and 10.5–14.6 hr. Dividing the distance between the northern and southern streamer boundaries in equal parts at each height, we obtained nonradial height–time paths from which we generated nonradial profiles of corona/solar wind plasma outflow. We tracked outflows as they moved uninterruptedly from the Sun in EUVI, through COR1 and into COR2. Finally, we discuss the preliminary results of nonradial plane-of-sky velocities for a coronal mass ejection and two small-scale features.

Nathalia Alzate↗

Appendix C: First Global Observations of Atmospheric COClF from the Atmospheric Chemistry Experiment Mission

Carbonyl chlorofluoride (COCIF) is an important reservoir of chlorine and Fluorine in the Earth's atmosphere. Satellite-based remote sensing measurements of COCIF, obtained by Received in revised form the Atmospheric Chemistry Experiment (ACE) for a time period spanning February 2004 through April 2007, have been used in a global distribution study. There is a strong Accepted 18 February 2009 source region for COCIF in the tropical stratosphere near 27 km. A layer of enhanced COCIF spans the low- to mid-stratosphere over all latitudes, with volume mixing ratios of 40-100 parts Per trillion by volume, largest in the tropics and decreasing toward the poles. The COCIF volume mixing ratio profiles are nearly zonally symmetric, but they exhibit a small hemispheric asymmetry that likely arises from a hemispheric asymmetry in the parent molecule CCl3F. Comparisons are made with a set of in situ stratospheric measurements from the mid-1980s and with predictions from a 2-D model.

Fu, Djian↗

The Normalization of Surface Anisotropy Effects Present in SEVIRI Reflectances by Using the MODIS BRDF Method

A modified version of the MODerate resolution Imaging Spectroradiometer (MODIS) bidirectional reflectance distribution function (BRDF) algorithm is presented for use in the angular normalization of surface reflectance data gathered by the Spinning Enhanced Visible and InfraRed Imager (SEVIRI) aboard the geostationary Meteosat Second Generation (MSG) satellites. We present early and provisional daily nadir BRDFadjusted reflectance (NBAR) data in the visible and near-infrared MSG channels. These utilize the high temporal resolution of MSG to produce BRDF retrievals with a greatly reduced acquisition period than the comparable MODIS products while, at the same time, removing many of the angular perturbations present within the original MSG data. The NBAR data are validated against reflectance data from the MODIS instrument and in situ data gathered at a field location in Africa throughout 2008. It is found that the MSG retrievals are stable and are of high-quality across much of the SEVIRI disk while maintaining a higher temporal resolution than the MODIS BRDF products. However, a number of circumstances are discovered whereby the BRDF model is unable to function correctly with the SEVIRI observations-primarily because of an insufficient spread of angular data due to the fixed sensor location or localized cloud contamination.

SEVIRI↗

Formation and transformation of iron oxy-hydroxide precursor clusters to ferrihydrite

Iron (Fe) oxy-hydroxide minerals such as ferrihydrite (Fh) are ubiquitous in Earth-surface environments and important in biogeochemical element cycling. Recent research has suggested that their formation is preceded by the precipitation of ultrasmall (~1 nm) Keggin-like Fe oxy-hydroxide clusters. However, relatively little is understood about the structure of the precursor clusters and the impacts of pH and time on their growth and transformation to more stable phases. Here, we used a new method that involves mixed flow reactors (MFR) to synthesize these Fe oxy-hydroxide precursor clusters at pH 1.0, 1.5, 2.5, and 4.5. In situ and ex situ synchrotron scattering measurements and laboratory small-angle X-ray scattering (SAXS) were used to study the structure and size of Fe oxy-hydroxide clusters and their transformation products, respectively. Results show that with increasing pH, the particle size and structural order of samples increase, forming solids that resemble 2-line Fh at pH 4.5. The experimental data were compared with X-ray pair distribution functions (PDF) calculated for a range of Fe(III) oxyhydroxide clusters, including Fe 13 Keggin isomers computed previously using density functional theory (DFT), which yielded at best only partial agreement at short range (<5 Å). Aging of the clusters synthesized at pH 1.5 and 2.5 results in growth and transformation via Ostwald ripening to mixtures of goethite (Gt) and lepidocrocite (Lp). This process was inhibited by immediately reacting the early-formed clusters with phosphate (PO 4 3– ), suggesting that oxyanion surface complexes can stabilize the initial clusters by preventing growth and crystallization to more stable phases.

58 GEOSCIENCES↗

Development and Validation of The SMAP Enhanced Passive Soil Moisture Product

Since the beginning of its routine science operation in March 2015, the NASA SMAP observatory has been returning interference-mitigated brightness temperature observations at L-band (1.41 GHz) frequency from space. The resulting data enable frequent global mapping of soil moisture with a retrieval uncertainty below 0.040 cu m/cu m at a 36 km spatial scale. This paper describes the development and validation of an enhanced version of the current standard soil moisture product. Compared with the standard product that is posted on a 36 km grid, the new enhanced product is posted on a 9 km grid. Derived from the same time-ordered brightness temperature observations that feed the current standard passive soil moisture product, the enhanced passive soil moisture product leverages on the Backus-Gilbert optimal interpolation technique that more fully utilizes the additional information from the original radiometer observations to achieve global mapping of soil moisture with enhanced clarity. The resulting enhanced soil moisture product was assessed using long-term in situ soil moisture observations from core validation sites located in diverse biomes and was found to exhibit an average retrieval uncertainty below 0.040 cu m/cu m. As of December 2016, the enhanced soil moisture product has been made available to the public from the NASA Distributed Active Archive Center at the National Snow and Ice Data Center.

SMAP Enhanced↗

First-Principles Modeling Of Electromagnetic Scattering By Discrete and Discretely Heterogeneous Random Media

A discrete random medium is an object in the form of a finite volume of a vacuum or a homogeneous material medium filled with quasi-randomly and quasi-uniformly distributed discrete macroscopic impurities called small particles. Such objects are ubiquitous in natural and artificial environments. They are often characterized by analyzing theoretically the results of laboratory, in situ, or remote-sensing measurements of the scattering of light and other electromagnetic radiation. Electromagnetic scattering and absorption by particles can also affect the energy budget of a discrete random medium and hence various ambient physical and chemical processes. In either case electromagnetic scattering must be modeled in terms of appropriate optical observables, i.e., quadratic or bilinear forms in the field that quantify the reading of a relevant optical instrument or the electromagnetic energy budget. It is generally believed that time-harmonic Maxwell's equations can accurately describe elastic electromagnetic scattering by macroscopic particulate media that change in time much more slowly than the incident electromagnetic field. However, direct solutions of these equations for discrete random media had been impracticable until quite recently. This has led to a widespread use of various phenomenological approaches in situations when their very applicability can be questioned. Recently, however, a new branch of physical optics has emerged wherein electromagnetic scattering by discrete and discretely heterogeneous random media is modeled directly by using analytical or numerically exact computer solutions of the Maxwell equations. Therefore, the main objective of this Report is to formulate the general theoretical framework of electromagnetic scattering by discrete random media rooted in the Maxwell- Lorentz electromagnetics and discuss its immediate analytical and numerical consequences. Starting from the microscopic Maxwell-Lorentz equations, we trace the development of the first principles formalism enabling accurate calculations of monochromatic and quasi-monochromatic scattering by static and randomly varying multiparticle groups. We illustrate how this general framework can be coupled with state-of-the-art computer solvers of the Maxwell equations and applied to direct modeling of electromagnetic scattering by representative random multi-particle groups with arbitrary packing densities. This first-principles modeling yields general physical insights unavailable with phenomenological approaches. We discuss how the first-order-scattering approximation, the radiative transfer theory, and the theory of weak localization of electromagnetic waves can be derived as immediate corollaries of the Maxwell equations for very specific and well-defined kinds of particulate medium. These recent developments confirm the mesoscopic origin of the radiative transfer, weak localization, and effective-medium regimes and help evaluate the numerical accuracy of widely used approximate modeling methodologies.

Michael I Mishchenko↗

Interpreting the spatial distribution of soil properties with a physically-based distributed hydrological model

Digital soil maps are commonly data-driven as the development of physically-based models for soil mapping is difficult due to the complexity of soils. However, physically-based hydrologic models have been successful in simulating water dynamics. Since water movement is a major driver of pedogenesis, the physical rules that govern water movement might help explain and predict the spatial variation of soil properties. Here, we demonstrate the novel use of a physically-based, distributed hydrologic model to inform the spatial distribution of soil properties. The Distributed Hydrology Soil Vegetation Model (DHSVM) was utilized to simulate soil moisture content (SM) and water table depth (WTD) in two hillslope catchments under pasture and forest management wherein hydrologic model outputs were then compared with soil properties measured in situ. SM sensors and wells were installed in both catchments to validate simulations of soil water movement via Nash-Sutcliffe Efficiency (E). In-situ observations were made at 87 sites within both catchments to study the connection between simulated water movement (SM and WTD) and observed soil properties, namely the depth and thickness of the argillic (Bt), fragic (Btx), and C horizons, and the depth of redoximorphic features. The simulated time series of SM and WTD were also clustered per season using Dynamic Time Warping (DTW), which identified similarity among time series at varying timescales. Model validation suggested that simulations of surficial SM (0–20 cm) were reasonable (E = 0.45), however, simulated subsurface SM (45–60 cm) and WTD were not sufficiently accurate. The thickness of Btx horizons were spatially grouped into different populations by SM clusters from every season except spring. For the other properties, only SM dynamics of specific seasons grouped into significantly different populations, suggesting that the explanatory power of simulated water movement varies seasonally and was greater during winter. Here, we show clusters of simulated SM separated soil properties into statistically different populations, showing that hydrologic models could inform areas that followed different water dynamics related to pedogenic trajectories and related biogeochemical processes not necessarily simulated by the model. As such, physically-based modeling of water dynamics can, therefore, inform and advance digital soil mapping by linking water movement patterns stemming from hydrologic model outputs to spatial patterns of soil properties and pedogenesis.

54 ENVIRONMENTAL SCIENCES↗

Venus nighttime hydrogen bulge

The concentration of atomic hydrogen in the Venus thermosphere near 165 km altitude and approximately 18 deg north latitude has been derived from Pioneer Venus in situ measurements of H(+), O(+), O and CO2 concentrations, under the assumption of chemical equilibrium. Altitude profiles of derived H concentration suggest that chemical equilibrium prevails to an altitude of at least 200 km on the dayside and to 165 km on the nightside. Measurements below these limits were made by the ion and neutral mass spectrometers on the orbiter spacecraft between December 1978 and July 1979, while periapsis traversed a complete diurnal cycle. The hydrogen concentration is found to rise sharply at both terminators from a dayside value of approximately 50,000/cu cm, and to exhibit an asymmetric nightside distribution with a peak density in the predawn sector approximately 400 times greater than the dayside value. Analysis suggests that wind-induced diffusion, combined with exospheric return flow, can account for the observed hydrogen behavior. The large day-night temperature contrast enhances advective transport, which produces the large H concentration diurnal variation; the shift of the H concentration nighttime maximum toward dawn is caused by atmospheric superrotation.

Brinton, H. C.↗

Aura Atmospheric Data Products and Their Availability from NASA Goddard Earth Sciences DAAC

NASA's EOS-Aura spacecraft was launched successfully on July 15, 2004. The four instruments onboard the spacecraft are the Microwave Limb Sounder (MLS), the Ozone Monitoring Instrument (OMI), the Tropospheric Emission Spectrometer (TES), and the High Resolution Dynamics Limb Sounder (HBDLS). The Aura instruments are designed to gather earth sciences measurements across the ultraviolet, visible, infra-red, thermal and microwave regions of the electromagnetic spectrum. Aura will provide over 70 distinct standard atmospheric data products for use in ozone layer and surface UV-B monitoring, air quality forecast, and atmospheric chemistry and climate change studies (http://eosaura.gsfc.nasa.gov/). These products include earth-atmosphere radiances and solar spectral irradiances; total column, tropospheric, and profiles of ozone and other trace gases, surface W-B flux; clouds and aerosol characteristics; and temperature, geopotential height, and water vapor profiles. The MLS, OMI, and HIRDLS data products will be archived at the NASA Goddard Earth Sciences (GES) Distributed Active Archive Center (DAAC), while data from TES will be archived at NASA Langley Research Center DAAC. Some of the standard products which have gone through quick preliminary checks are already archived at the GES DAAC (http://daac.nsfc.nasa.gov/) and are available to the Aura science team and data validation team members for data validation; and to the application and visualization software developers, for testing their application modules. Once data are corrected for obvious calibration problems and partially validated using in-situ observations, they would be made available to the broader user community. This presentation will provide details of the whole suite of Aura atmospheric data products, and the time line of the availability of the rest of the preliminary products and of the partially validated provisional products. Software and took available for data access, visualization, and data mining will also be discussed.

Ahmad, S.↗

Ground-Based Network and Supersite Observations to Complement and Enrich EOS Research

Since 1997 NASA has been successfully launching a series of satellites - the Earth Observing System (EOS) - to intensively study, and gain a better understanding of, the Earth as an integrated system. Space-borne remote sensing observations, however, are often plagued by contamination of surface signatures. Thus, ground-based in-situ and remote-sensing measurements, where signals come directly from atmospheric constituents, the sun, and/or the Earth-atmosphere interactions, provide additional information content for comparisons that confirm quantitatively the usefulness of the integrated surface, aircraft, and satellite datasets. Through numerous participations, particularly but not limited to the EOS remote-sensing/retrieval and validation projects over the years, NASA/GSFC has developed and continuously refined ground-based networks and mobile observatories that proved to be vital in providing high temporal measurements, which complement and enrich the satellite observations. These are: the AERO NET (AErosol RObotic NETwork) a federation of ground-based globally distributed network of spectral sun-sky photometers; the MPLNET (Micro-Pulse Lidar NETwork, a similarly organized network of micro-pulse lidar systems measuring aerosol and cloud vertical structure continuously; and the SMART-COMMIT (Surface-sensing Measurements for Atmospheric Radiative Transfer - Chemical, Optical & Microphysical Measurements of In-situ Troposphere, mobile observatories, a suite of spectral radiometers and in-situ probes acquiring supersite measurements. Most MPLNET sites are collocated with those of AERONET, and both networks always support the deployment of SMART-COMMIT worldwide. These data products follow the data structure of EOS conventions: Level-0, instrument archived raw data; Level-1 (or 1.5), real-time data with no (or limited) quality assurance; Level-2, not real high temporal and spectral resolutions. In this talk, we will present NASA/GSFC groundbased facilities, serving as network or supersite observations, which have been playing key roles in major international research projects over diverse aerosol regimes to complement and enrich the EOS scientific research.

Tsay, Si-Chee↗

Impacts of NASA's Earth Observations on Subseasonal and Seasonal Forecasts

NASA's suite of Earth-observing satellites provides a unique view of many processes on Earth, with relevance on timescales ranging from hours to weeks and even years. NASA's observations span all parts of the Earth system: atmospheric, ocean, land and cryosphere, and include physical, chemical and biological components. This presentation explores use of NASA observations in extended-range prediction, from many days to months, using the Goddard Earth Observing System (GEOS) assimilation and predictive modeling capabilities. The skill of a weather forecast is linked to the fidelity of the initialization process (data assimilation) and the realistic representation of "fast" physical processes in the model. At longer time horizons, the slower "feedback" processes in the Earth System begin to take a more prominent role in the accuracy of the forecast. Simultaneously, forecast-skill attribution transitions away from feature-based metrics that emphasize smaller scales (e.g., representations of fronts and vortices) to metrics that emphasize the statistical distributions of large-scale features (e.g., ENSO diagnostics and teleconnections). This presentation will summarize studies performed using the GEOS-S2S (subseasonal to seasonal) system that explore the impacts of NASA observations on the fidelity of the forecasts. The GEOS-S2S system is configured for the atmosphere-ocean-land-ice model and is initialized using in-situ and space-based observations, including atmospheric aerosols and ozone which are not typically analyzed in such systems. The GEOS-S2S model routinely includes aerosol feedbacks, which systematically impact the realism of the forecasts, providing a first example of how suitable NASA observations impact the performance of the GEOS-S2S system. Studies in which a stratospheric chemistry module is activated in the GEOS-S2S system allow the impacts of ozone radiative feedbacks to be isolated. Space-based observations of sea-surface temperature and altimetry are routinely analyzed for the initialization of the GEOS-S2S system; recent advances allow the use of NASA's sea-surface salinity data, which are shown to impact the long-range skill of the forecasts.

Pawson, Steven↗

Managing and Servicing Physical Oceanographic Data at a NASA Distributed Active Archive Center

The NASA Earth Science Data Information Systems Project funds and operates 12 Distributed Active Archive Center(s) (DAAC) throughout the United States. Of these 12 centers, the Physical Oceanography DAAC (PO.DAAC) is committed to providing long term archival, distribution and stewardship for NASA physical oceanographic data, primarily derived from space-born satellite systems, but also including a growing set of recent and future in situ observations from the SPURS-1 and SPURS-2 campaigns. Notable NASA missions supported include: Seasat, TOPEX/Poseidon, NSCAT, QuikSCAT, ISS-RapidScat, Jason-1, Jason-2/OSTM, GRACE, Aquarius, GHRSST, and MODIS. The following interagency and international missions are also supported by PO.DAAC: AVHRR, Coriolis, DMSP, MetOp-A, MetOp-B, Oceansat-2. The PO.DAAC currently holds 525 datasets in public distribution, spanning the following observational parameters: sea surface temperature, sea surface salinity, ocean color, ocean surface currents, ocean surface wind speed, ocean surface wind direction, sea surface height, significant wave height, ocean water mass/thickness, and sea ice age. A hundred of these datasets are available in near-real-time. Datasets are distributed through a variety of open-source access protocols including FTP, OPeNDAP, and THREDDS. FTP will soon be phased out in favor of a recently introduced HTTPS PO.DAAC Drive interface that supports WebDAV and interoperable machine-to-machine communication. OPeNDAP supports remote data/metadata query, subset, and download. THREDDS provides the features of OPeNDAP with the additional feature of temporal aggregation. PO.DAAC also offers proprietary tools and services to further enhance the data discovery, visualization and analysis experience, including but not limited to: State of the Ocean, Web Services (data/metadata discovery and extraction), HiTIDE Level-2 subsetter, Live Access Server (LAS), Webification (w10nsci), and Rich Site Summary (RSS) Datacasting. To assist with provenance of datasets, PO.DAAC has implemented DOIs for the data it distributes so that they can be properly cited. There is a user forum and helpdesk that contains data recipes and via which users can get guidance. In summary, this presentation aims to provide a general overview of PO.DAAC’s web portal and data holdings along with a set of illustrative examples leading prospective data users into the practical utility of its tools and services.

Moroni, David F.↗

Observations of Ocean Primary Productivity Using MODIS

Measuring the magnitude and variability of oceanic net primary productivity (NPP) represents a key advancement toward our understanding of the dynamics of marine ecosystems and the role of the ocean in the global carbon cycle. MODIS observations make two new contributions in addition to continuing the bio-optical time series begun with Orbview-2's SeaWiFS sensor. First, MODIS provides weekly estimates of global ocean net primary productivity on weekly and annual time periods, and annual empirical estimates of carbon export production. Second, MODIS provides additional insight into the spatial and temporal variations in photosynthetic efficiency through the direct measurements of solar-stimulated chlorophyll fluorescence. The two different weekly productivity indexes (first developed by Behrenfeld & Falkowski and by Yoder, Ryan and Howard) are used to derive daily productivity as a function of chlorophyll biomass, incident daily surface irradiance, temperature, euphotic depth, and mixed layer depth. Comparisons between these two estimates using both SeaWiFS and MODIS data show significant model differences in spatial distribution after allowance for the different integration depths. Both estimates are strongly dependence on the accuracy of the chlorophyll determination. In addition, an empirical approach is taken on annual scales to estimate global NPP and export production. Estimates of solar stimulated fluorescence efficiency from chlorophyll have been shown to be inversely related to photosynthetic efficiency by Abbott and co-workers. MODIS provides the first global estimates of oceanic chlorophyll fluorescence, providing an important proof of concept. MODIS observations are revealing spatial patterns of fluorescence efficiency which show expected variations with phytoplankton photo-physiological parameters as measured during in-situ surveys. This has opened the way for research into utilizing this information to improve our understanding of oceanic NPP variability. Deriving the ocean bio-optical properties places severe demands on instrument performance (especially band to band precision) and atmospheric correction. Improvements in MODIS instrument characterization and calibration over the first 16 mission months have greatly improved the accuracy of the chlorophyll input fields and FLH, and therefore the estimates of NPP and fluorescence efficiency. Annual estimates now show the oceanic NPP accounts for 40-50% of the global total NPP, with significant interannual variations related to large scale ocean processes. Spatial variations in ocean NPP, and exported production, have significant effects on exchange of CO2 between the ocean and atmosphere. Further work is underway to improve both the primary productivity model functions, and to refine our understanding of the relationships between fluorescence efficiency and NPP estimates. We expect that the MODIS instruments will prove extremely useful in assessing the time dependencies of oceanic carbon uptake and effects of iron enrichment, within the global carbon cycle.

Esaias, Wayne E.↗