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Experimental studies on the composition of cosmic rays are reviewed. Studies of elemental composition and time variation, Fe and near-Fe nuclei, trans-iron, high-energy spectra, antiprotons, isotopes, and electrons and positrons are discussed. Some theoretical studies of electrons are also considered.
Iron troilite meteorites lead isotopic, Pb and U concentrations, considering fractionation and terrestrial contamination effects
The relative elemental and isotopic abundances of noble gases provide insights into a number of topics related to the solar system. Neon is in many ways the most diagnostic of the noble gases. The diagnostic character is mainly related to the variation in the relative abundance of the two most abundant neon isotopes, Ne-20 and Ne-22. The available evidence suggests that trapped neon found in meteorites and in lunar samples consists of as many as five isotopically distinct components, including neon A, B, C, D, and E. Neon B has been shown to be due to solar wind neon which has been directly implanted into the material found in a meteorite. It appears that neon E is extrasolar in origin. There exist ambiguities regarding the origins of the remaining three components. The present investigation is concerned with a reexamination of the existing data in an effort to eliminate or at least clarify these ambiguities. It is found that neon C is apparently due to directly implanted, low-energy solar flare neon nuclei.
Ion microprobe measurements of carbon isotope ratios were made in 30 specimens representing six fossil genera of microorganisms petrified in stromatolitic chert from the approximately 850 Ma Bitter Springs Formation, Australia, and the approximately 2100 Ma Gunflint Formation, Canada. The delta 13C(PDB) values from individual microfossils of the Bitter Springs Formation ranged from -21.3 +/- 1.7% to -31.9 +/- 1.2% and the delta 13C(PDB) values from microfossils of the Gunflint Formation ranged from -32.4 +/- 0.7% to -45.4 +/- 1.2%. With the exception of two highly 13C-depleted Gunflint microfossils, the results generally yield values consistent with carbon fixation via either the Calvin cycle or the acetyl-CoA pathway. However, the isotopic results are not consistent with the degree of fractionation expected from either the 3-hydroxypropionate cycle or the reductive tricarboxylic acid cycle, suggesting that the microfossils studied did not use either of these pathways for carbon fixation. The morphologies of the microfossils suggest an affinity to the cyanobacteria, and our carbon isotopic data are consistent with this assignment.
We will summarize the in situ measurements of atmospheric composition and the isotopic ratios of D/H in water, C-13/C-12, O-18/O-16, O-17 / O-16, and C-13 O-18 / C-12 O-16 in carbon dioxide, and Ar-38 / Ar-36, Kr-x / Kr-84, and N-15 / N-14 made in the martian atmosphere at Gale Crater from the Curiosity Rover using the Sample Analysis at Mars (SAM)'s Quadrupole Mass Spectrometer (QMS) and Tunable Laser Spectrometer (TLS). With data over 700 sols since the Curiosity landing, we will discuss evidence and implications for changes on seasonal and other timescales. We will also present results for continued methane and methane enrichment experiments over this time period. Comparison between our measurements in the modern atmosphere and those of martian meteorites like ALH 84001 implies that the martian reservoirs of CO2 and H2O were largely established approximately 4 billion years ago, but that atmospheric loss or surface interaction may be still ongoing.
Thirty oxygen analyses of a large (sub-millimetre) zircon grain from the lunar soil sample 14163 have been determined using CAMECA 1270 ion microprobe. The sample 14163 was returned form the Fra Mauro region by Apollo 14 mission. Zircon grain of 0.6-0.8 mm in size extracted from the sample was imaged using CL detector fitted to the Philips Electron Microscope in order to reveal internal structure. Oxygen isotopes have been analysed during two sessions. The first set of data was collected using the original mount where the grain was set in the resin attached to the glass slide. This resulted in the two complications: (i) standard zircon has to be analysed from the separate mount and (ii) the lunar zircon grain was rased in the holder compared to the standard. In order to investigate, if the elevated oxygen compositions observed during this session could have resulted from this difference in geometric configuration during the standard and sample analyses, the lunar zircon was extracted from the original mount, remounted with the standard chip in the new resin disk and reanalysed during the second session. All analyses made during the first session show delta O-18 values heavier than 6.0%. The second set of data has a wider spread of delta O-18 values with some values as low as 5.6%. Nevertheless, a half of observed delta O-18 values in this set is also higher than 6.0%. Slightly lighter oxygen compositions observed during the second session indicate possible dependence of measured delta O-18 values on the geometry of analysed samples. Presence of zircons with similar heavy oxygen isotope compositions on the Moon, which neither had liquid water or felic crust similar to that on the Earth nor ever developed regime similar to plate tectonics, suggests that other mechanisms can be responsible for elevated delta O-18 values in zircons. This implies that there is no support for the presence of an ocean on the surface of the early Earth and as the ocean appears to be an essential ingredient for the plate tectonics, there is no basis for belief that this mechanism was operating in the early history of the planet.
Carbon and sulfur concentration and isotopic variations in Apollo 11 fines, breccias and fine- grained basalts
The isotopes of cosmic-ray Li, Be, and B near 100 MeV per nucleon have been measured with cosmic-ray telescopes on board the IMP-7 and IMP-8 satellites during 1973 and 1974. The measured isotopic abundances provide a stringent test for models of interstellar propagation and solar modulation. It is found that the isotopic abundances can be explained using a steady-state interstellar propagation model with a 5-g/sq cm leakage mean free path. These results, taken along with Be-10 abundance measurements, indicate a longer lifetime for cosmic rays than that predicted by the usual assumption of an average interstellar density of 1 to 3 atoms per cu cm.
It is found that C, N, and O elemental and isotopic ratios in the galactic cosmic rays measured near the earth with the IMP 7 telescope of the University of Chicago have had the values N/O = 0.25 + or 0.02; C/O = 1.06 + or - 0.03; C-13/C = 0.04-0.10; N-15/N = 0.47 + or - 0.06; and O-18/O less than or equal to 0.03. It is noted that these results are confirmed by IMP 8 measurements. The measurements are extrapolated back to the cosmic ray source using exponential and truncated exponential path length distributions whose parameters have been determined by fitting cosmic ray B/C and sub-Fe/Fe ratios measured previously.
The development of cosmic ray telescopes to separate individual isotopes of heavy elements using the dE/dx-vs.-E technique depends on the incorporation of precise trajectory sensing elements into these systems. In typical implementations the particle trajectory is derived from a set of position measurements made prior to a particle's entering the first energy loss detector. The use of the trajectory obtained in this way to correct energy loss signals for the actual pathlengths through the detectors depends on the assumption that the particle trajectory is a straight line. In order to resolve iron isotopes the angles of incidence, theta the particle track must be known rather accurately.
A description is given of an experiment which was designed to measure the spectra and composition of cosmic-ray hydrogen and helium isotopes in the interval 120-280 MeV per nucleon to compare with the recent values observed at low energies and also with the only earlier measurement in this high-energy regime. The results presented were obtained during a high-altitude balloon flight from Thompson, Manitoba, in 1973 August. This flight occurred during the period in which the presence of the anomalous component in the helium spectrum became apparent, and provides the opportunity of determining whether this component extends to higher energies than those studied by satellite experiments. The results place an upper limit on the flux of 'anomalous' He-4 (which appeared at low energy in 1972) of at most 15% in the energy range of this experiment, and combined with the low-energy observations of the Chicago group, show an energy dependence of the average ratio of the helium isotopes in the modulated cosmic rays which is difficult to reconcile with current modulation models.
In this report, we present actinide isotopic and elemental data from fallout melt glass using high resolution inductively coupled plasma mass spectrometry (HR-ICP-MS). This is an analytical technique that requires minimal sample preparation. These data are directly compared to the results of high precision isotopic analyses and elemental assay by multi-collector (MC-) ICP-MS, which requires lengthy sample processing involving spiking and purifying aliquots of individual elements. The comparison shows broad overlap between the results of the two techniques. Thus, although the data obtained by HR-ICP-MS is of significantly lower precision, it is a viable method to obtain actinide elemental and isotopic data on a more rapid timeframe than traditional high-precision techniques.
The isotopes H-2 and He-3 have been identified in low-energy cosmic rays during solar-quiet periods from 1973 January to 1974 October. These observations, made with the electron/isotope spectrometer on IMP-7, cover the energy intervals 5-29 MeV per nucleon for H-2 and 7-50 MeV per nucleon for He-3. The energy spectra of H-1, H-2, and He-3 fall rapidly with decreasing energy, giving H-2/H-1 and He-3/H-1 ratios which are essentially independent of energy as expected from current theories of the solar modulation of galactic cosmic rays. The measured He-4 spectrum, however, is essentially flat below 40 MeV per nucleon, suggesting that there may be contributions from a local, nonsolar source of He-4. Comparisons of the H-1, H-2, and He-3 observations with calculated spectra at 1 AU imply a mean interstellar path length of 7 plus or minus 2 g/sq cm. However, present low-energy measurements of H and He isotopes at 1 AU do not discriminate between possible cosmic-ray source spectra.
Measurements of the abundances of three isotopes of magnesium in solar energetic particles are reported. Data were obtained from the Heavy Isotope Spectrometer Telescope on board the ISEE 3 spacecraft during a large solar particle event following the 2B solar flare of September 23, 1978. A two-dimensional maximum likelihood analysis of the mass determinations for each event, which were taken with a resolution of 0.23 amu, indicates a Mg-25/Mg-24 ratio of 0.14 (+0.05, -0.02) and a Mg-26/Mg-24 ratio of 0.15 (+0.04, -0.03) in the energy interval 12-36 MeV/n. The results are consistent with terrestrial magnesium isotope abundances.
Measurements of the isotopes of low energy cosmic ray He, C, N, O and Ne nuclei are analyzed, in concert with previous data, to examine relationships between galactic cosmic rays (GCR) and anomalous cosmic rays (ACR), which could arise from either extragalactic or interstellar sources. A ground-based heavy isotope spectrometer telescope was used for the survey, along with IMP-7 and IMP-8 data and ISEE-3 data. The data were recorded from 1973-78. Spectral and abundance data are provided for each element. Fragmentation was absent in the ACR data, unlike the GCR data. Differences were also observed in the Ne-22/Ne-20 ratios of ACR and GCR. It is suggested, therefore, that the low energy ACR isotopes have an interstellar origin and are useful for studies of the local interstellar medium.
Observations from the Cosmic Ray Isotope Spectrometer (CRIS) on ACE have been used to derive contraints on the locations, physical conditions, and time scales for cosmic-ray acceleration and transport.
Compound-specific carbon isotope analysis (delta(exp 13)C) of meteoritic organic compounds can be used to elucidate the abiotic chemical reactions involved in their synthesis. The soluble organic content of the Murchison carbonaceous chondrite has been extensively investigated over the years, with a focus on the origins of amino acids and the potential role of Strecker-cyanohydrin synthesis in the early solar system. Previous delta(exp 13)C investigations have targeted alpha-amino acid and alpha-hydroxy acid Strecker products and reactant HCN; however, delta(exp 13)C values for meteoritic aldehydes and ketones (Strecker precursors) have not yet been reported. As such, the distribution of aldehydes and ketones in the cosmos and their role in prebiotic reactions have not been fully investigated. Here, we have applied an optimized O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) derivatization procedure to the extraction, identification, and delta(exp 13)C analysis of carbonyl compounds in the Murchison meteorite. A suite of aldehydes and ketones, dominated by acetaldehyde, propionaldehyde, and acetone, were detected in the sample. delta(exp 13)C values, ranging from -10.0(0/00) to +66.4(0/00), were more (exp 13)C-depleted than would be expected for aldehydes and ketones derived from the interstellar medium, based on interstellar (exp 12)C/(exp 13)C ratios. These relatively (exp 13)C-depleted values suggest that chemical processes taking place in asteroid parent bodies (e.g., oxidation of the IOM) may provide a secondary source of aldehydes and ketones in the solar system. Comparisons between delta(exp 13)C compositions of meteoritic aldehydes and ketones and other organic compound classes were used to evaluate potential structural relationships and associated reactions, including Strecker synthesis and alteration-driven chemical pathways.
Carbonaceous chondrites primordial He and Ne isotopes variations