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Results for “Molecular atmosphere”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

The effect of paleoatmospheric ozone on surface temperature

Photochemical and radiative-convective calculations are performed to evaluate the influence of ozone in determining the surface temperature of the paleoatmosphere prior to the buildup of molecular oxygen to its present atmospheric level. Possible effects of atmospheric dynamics on the photochemistry and thermal structure of the paleoatmosphere are neglected, and the present atmospheric values are assumed for the tropospheric water-vapor relative-humidity distribution and lapse rate as well as for the fractional cloud amount and cloud reflectivity. It is found that the radiative effects (at IR and solar wavelengths) of ozone for a molecular oxygen level of one-tenth the present atmospheric level resulted in a globally averaged surface-temperature increase of about 4.5 K for the present solar constant. Implications of the results for paleoclimate are briefly considered.

Levine, J. S.↗
NASA NTRS1969

Laser radar measurements of the aerosol content of the atmosphere

A summary of the results of laser radar observations of atmospheric aerosols is presented along with a description of the laser radar system devised during the study and of the data handling techniques utilized for the analysis of the data of the temporal and spatial distribution of atmospheric aerosols. Current research conducted by the group is directed toward the analysis of the frequency spectrum of laser radar echoes to obtain absolute measurements of the dust content of the atmosphere by resolving the molecular and aerosol contributions to the laser radar echoes.

Grams, G. W.↗
NASA NTRS1977

Infrared Observations of Late Type Stars

Substantive mass loss resulting in appreciable circumstellar dust envelopes is common in late-type stars. The evolutionary history and physical state of a cool star determine the chemistry within the outer stellar atmosphere mirrored by the molecular and particulate material present in the envelope. The observational consequences of this debris determined by moderate spectral resolution infrared spectrophotometry are reviewed. Significant information is provided by observations of the emergent energy flux of both the cool stellar photosphere and of the circumstellar dust envelope. The observation suggests that mass-loss occurs to some degree throughout late stellar evolutionary phases and that occasional periods of high mass loss are not uncommon.

Merrill, K. M.↗
NASA NTRS1978

A 1.3 centimeter wavelength interferometric study of Jupiter

Maps of the brightness distribution of Jupiter at 1.3 cm wavelength are reported for the two orthogonal linear polarizations; one approximately parallel to the equator and one approximately parallel to the pole. The synthesized beam is 6.0 arc sec by 12.0 arc sec, which provides about 55 picture elements over the visible disk. The two maps do not differ significantly. There are no small real features of the size of one resolution element with brightness greater than 6 K. The disk brightness is approximately uniform, which is consistent with saturated ammonia vapor as the source of opacity in the atmosphere. Uniformly mixed ammonia, molecular hydrogen, and methane are strongly excluded as major sources of the opacity. Forcing the maps to have symmetry about the pole, as expected for the rapidly rotating planet, reduces the residual noise level in the maps so that there appears to be a small amount of limb darkening along the equator and a small amount of brightening at the poles.

Valdes, F.↗
NASA NTRS1982

Spatially resolved reflectivities of Saturn - 3000-6000 A

Absolute reflectivity reductions are presented for spectrophotometric observations of seven spatially-resolved regions on the disk of Saturn in the 3000-6000 A region. An asymmetry is found between northern and southern hemisphere data, in the equivalent width of the CH4, 5430-A band and in the continuum reflectivity. In addition, the spectra are found not to include the 4700 A reflectivity peak found by Bergstralh et al (1981), and to exhibit general agreement with the Podolack and Danielson (1977) model. The blue and visual spectral region continuum reflectivity of a planetary atmosphere provides constraints for determining aerosol particle single-scattering albedo and vertical distribution, which are in turn important to an understanding of planetary energy balance, atmospheric dynamics, and planetary molecular absorption spectrum interpretation.

Cochran, W. D.↗
NASA NTRS1982

Conversion of para and ortho hydrogen in the Jovian planets

A mechanism is proposed which partially equilibrates the para and ortho rotational levels of molecular hydrogen in the atmospheres of Jupiter, Saturn, and Uranus. Catalytic reactions between the free-radical surface sites of aerosol particles and hydrogen modecules yield significant equilibration near 1 bar pressure, if the efficiency of conversion per collision is between 10 to the -8th and 10 to the -10th and the effective eddy mixing coefficient is 10,000 sq cm/sec. At lower pressures the ortho-para ratio retains the value at the top of the cloud layer, except for a very small effect from conversion in the thermosphere. The influence of conversion on the specific heat and adiabatic lapse rate is also investigated. The effect is found to be generally small, though is can rise to 10% inside the aerosol layer.

Massie, S. T.↗
NASA NTRS1982

Spaceborne lidar measurement accuracy - Simulation of aerosol, cloud, molecular density, and temperature retrievals

In connection with studies concerning the use of an orbiting optical radar (lidar) to conduct aerosol and cloud measurements, attention has been given to the accuracy with which lidar return signals could be measured. However, signal-measurement error is not the only source of error which can affect the accuracy of the derived information. Other error sources are the assumed molecular-density and atmospheric-transmission profiles, and the lidar calibration factor (which relates signal to backscatter coefficient). The present investigation has the objective to account for the effects of all these errors sources for several realistic combinations of lidar parameters, model atmospheres, and background lighting conditions. In addition, a procedure is tested and developed for measuring density and temperature profiles with the lidar, and for using the lidar-derived density profiles to improve aerosol retrievals.

Russell, P. B.↗
NASA NTRS1983

Photochemical reactions of water and carbon monoxide in earth's primitive atmosphere

The gas-phase photolysis of H2O at 1849 A in the presence of CO yields mainly CO2 and H2 and a variety of organic compounds, including C1-C3 hydrocarbons, alcohols, aldehydes, acetone, and acetic acid. The overall quantum yield for conversion of CO to organic compounds varies between 0.23 and 0.03 as a function of the CO abundance. These results indicate that even if primitive earth's atmosphere initially contained no molecular hydrogen and contained carbon only in the form of CO or a mixture of CO and CO2, the prebiotic environment would have become enriched with a variety of organic compounds produced by photochemical processes.

Bar-Nun, A.↗
NASA NTRS1984

Escape of sulfur and oxygen from Io

Charged particle sputtering is reexamined as a mechanism for escape of sulfur and oxygen from Io. Corotating ions and energetic ions are considered, using the best available determinations of ion fluxes and sputtering yields. It is unclear whether molecular SO2 is the dominant escaping neutral from Io or whether atomic O and S are dominant, but the Voyager detection of SO2(+) in the cold torus implies the presence of molecular SO2 there. Thin atmosphere models encounter serious difficulty in achieving adequate sulfur and oxygen escape rates, but they are not yet ruled out. Ionization and dissociation of SO2 in a sputter corona can dominate direct escape. In thick atmosphere models the neutral escape rates can be much higher, but the oxygen escape rate tends to be too high relative to the sulfur escape rate unless diffusive separation in the atmosphere is limited, perhaps by rapid mixing.

Cheng, A. F.↗
NASA NTRS1984

Lightning - Estimates of the rates of energy dissipation and nitrogen fixation

The nitrogen needed by plants can normally not be directly obtained from the nitrogen present in molecular form in the atmosphere. The reason for this situation is related to the great energy required to break the N-N bond. Only a few organisms, such as algae and certain bacteria, can 'fix' nitrogen. An abiological process for breaking the N-N bond is provided by lightning. The present investigation is concerned with this possibility. It is found that lightning produces approximately 2.6 x 10 to the 9th kg N per year. There are, however, uncertainties, which are mainly related to the energy of a lightning flash.

Borucki, W. J.↗
NASA NTRS1992

Oxygen supersaturation in ice-covered Antarctic lakes - Biological versus physical contributions

Lake Hoare is one of a number of ice-covered polar lakes in the Dry Valley Region of southern Victoria Land, Antarctica. Analysis of N2, O2, and Ar in bubbles from this lake's ice indicates that while O2 is about 2.4 times supersaturated in the water below the ice, only 11 percent of the O2 input to this lake is due to biological activity and the balance is derived from meltwater inflow. In Lake Hoare, as much as 70 percent of total gas loss may occur by advection through the ice cover; the remaining gas fractions are removed by respiration at the lower boundary in the case of O2, and by molecular exchange with the atmosphere in the peripheral summer moat around the ice.

Craig, H.↗
NASA NTRS1950

The gas kinetics of very high flight speeds

The aerodynamic forces on bodies of arbitrary shape were investigated under conditions such that the mean free path of the air molecule is greater than the dimensions of the body. Air pressures and friction forces were calculated from gas kinetic theory for surfaces facing both toward and away from the air stream at any angle. Air forces for an atmosphere of definite composition (molecular hydrogen) were calculated as a function of the flight velocity. The results indicate that the friction stresses between the air and the body surface are of the same magnitude as the dynamic pressure and as the air pressures normal to the surface. The application of the general method to the specific cases such as thin airfoils and projectiles leads to high drag coefficients and poor glide ratios even for the theoretically best wing sections.

AIR FLOW VELOCITY - MOLECULAR ENERGIES↗
NASA NTRS1995

Performance Of Perfluoropolyalkylether Lubricant System

Perfluoro-polyalkylethers (PFPAE) constitute class of fluids having characteristics of high thermal oxidative stability, good vicosity-temperature characteristics, good elastohydrodynamic film-forming capabilities, low volatility, and non-flammability. One unfortunate drawback PFPAE causes severe metal corrosion and fluid degradation when used in oxidizing atmosphere. Reports of interest deal with synthesis of PFPAE-type liquids and development of additive to reduce oxidizing atmosphere degradation. Properties and molecular structures reported in detail. Also lubricant performance over range of conditions.

Paciorek, K.↗
NASA NTRS2005

Retrieval of Atmospheric CO2 Column from Ground-based Near IR Spectra of the Sun

This grant has supported a graduate research assistant stipend for Zhonghua Yang, a geochemistry Ph.D. student at Caltech. In this project, we have significantly improved the retrieval of atmospheric column CO2 (and molecular oxygen) from ground-based, high resolution near-IR solar transmission spectra. This work has greatly benefited from interactions with Dr. Geoffrey Toon and Stan Sander of NASA's Jet Propulsion Laboratory and with James T. Randerson, University of California - Irvine. The results from this study are summarized in three publications, reprints of which are enclosed in with this report.

Wennberg, Paul↗
NASA NTRS2010

Extrasolar Planets Observed with JWST and the ELTs

The advent of cryogenic space-borne infrared observatories such as the Spitzer Space Telescope has lead to a revolution in the study of planets and planetary systems orbiting sun-like stars. Already Spitzer has characterized the emergent infrared spectra of close-in giant exoplanets using transit and eclipse techniques. The James Webb Space Telescope (JWST) will be able to extend these studies to superEarth exoplanets orbiting in the habitable zones of M-dwarf stars in the near solar neighborhood. The forthcoming ground-based Extremely Large Telescopes (ELTs) will playa key role in these studies, being especially valuable for spectroscopy at higher spectral resolving powers where large photon fluxes are needed. The culmination of this work within the next two decades will be the detection and spectral characterization of the major molecular constituents in the atmosphere of a habitable superEarth orbiting a nearby lower main sequence star.

Deming, L. Drake↗
NASA NTRS2012

Optimization of KINETICS Chemical Computation Code

NASA JPL has been creating a code in FORTRAN called KINETICS to model the chemistry of planetary atmospheres. Recently there has been an effort to introduce Message Passing Interface (MPI) into the code so as to cut down the run time of the program. There has been some implementation of MPI into KINETICS; however, the code could still be more efficient than it currently is. One way to increase efficiency is to send only certain variables to all the processes when an MPI subroutine is called and to gather only certain variables when the subroutine is finished. Therefore, all the variables that are used in three of the main subroutines needed to be investigated. Because of the sheer amount of code that there is to comb through this task was given as a ten-week project. I have been able to create flowcharts outlining the subroutines, common blocks, and functions used within the three main subroutines. From these flowcharts I created tables outlining the variables used in each block and important information about each. All this information will be used to determine how to run MPI in KINETICS in the most efficient way possible.

planetary atmospheres↗