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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

Recovery of terephthalic acid from solar PV backsheets using waste solvent from distilled spirits production

Current research on solar photovoltaic (PV) recycling mainly focuses on recovering valuable metals and glass, often neglecting the polymeric components, particularly the backsheets, which are typically landfilled or thermally decomposed. This study explores an innovative approach to upcycle PV backsheets into value-added products, specifically terephthalic acid (TPA), using waste ethanol solvent from the distilled spirits industry. Experimental results show that increasing both exposure time and ethanol concentration significantly enhances backsheet delamination efficiency. Using waste ethanol, a maximum delamination efficiency of 80% was achieved at room temperature after 24 hours. In decomposition trials, both sodium hydroxide (NaOH) and potassium hydroxide (KOH) demonstrated comparable efficiencies (96.6–97.5%) over 8 and 24 hour reactions. With virgin ethanol, NaOH yielded 94–97.5% TPA recovery. Notably, using waste ethanol achieved a TPA recovery efficiency of 96.8%, underscoring the process's economic viability and sustainability. Analytical characterization of TPA recovered after 8 hours showed consistent spectral patterns across both alkalis and solvents, indicating a similar chemical environment and functional groups. The recovered TPA can be repolymerized into high-purity PET, suitable for manufacturing new PV backsheets. This work advances polymer-recycling by demonstrating that an industrial waste solvent (distilled-spirits ‘heads’) can replace virgin ethanol without loss in delamination performance or TPA yield. While PV backsheet PET is a modest share of global PET, using waste ethanol to upcycle this currently under-recycled stream demonstrates a transferable solvent-reuse pathway that can extend to higher-volume PET sources.

Nain, Preeti [Michigan State Univ., East Lansing, ↗

Behavior of Multiple PV Plants in Future Power Grids During Events

As the integration of multiple photovoltaic (PV) plants into power grids grows, the dynamic response of each plant and their interactions during transient events demands a deeper understanding. In this paper, the dynamic behavior of multiple PV plants connected to future power grids is comprehensively explored using site-specific high-fidelity electromagnetic transient (EMT) PV plant models and generic high-fidelity EMT PV plant models. This research demonstrates the need to employ multiple high-fidelity EMT PV plant models to understand the intricate interactions between multiple PV plants during grid events. These models, developed in Fortran within the PSCAD environment, encompass a range of operational scenarios and plant configurations, offering invaluable insights crucial for future system planning with multiple PV plants to enhance grid stability.

Marthi, Phani Ratna Vanamali [ORNL] (ORCID:0000000↗

Nondestructive Characterization of Antireflective Coatings on PV Modules

Antireflective coatings (ARCs) are used on the vast majority of solar photovoltaic (PV) modules to increase power production. However, ARC longevity can vary from less than 1 to over 15 years depending on coating quality and deployment conditions. A technique that can quantify ARC degradation nondestructively on commercial modules would be useful both for in-field diagnostics and accelerated aging tests. In this article, we demonstrate that accurate measurements of ARC spectral reflectance can be performed using a modified commercially available integrating-sphere probe. The measurement is fast, accurate, nondestructive, and can be performed outdoors in full-sun conditions. We develop an interferometric model that estimates coating porosity, thickness, and fractional area coverage from the measured reflectance spectrum for a uniform single-layer coating. We demonstrate the measurement outdoors on an active PV installation, identify the presence of an ARC, and estimate the properties of the coating.

14 SOLAR ENERGY↗

Characterization of Real-World and Accelerated Exposed PV Module Backsheet Degradation

Backsheet degradation is key to maintaining the lifetime of photovoltaic (PV) modules. Cracking, delamination, bubbling, and discoloration are main types of degradation. PV modules were collected from PV installations in multiple climatic zones. Multiple types of backsheets were obtained with poly(ethylene teraphlate) (PET) and polyamide air side layers being the largest number of backsheets retrieved. Multiple commercial PV backsheets were exposed to multiple accelerated exposures and key degradation mechanisms were identified. Polyamide backsheets showed cracking in retrieved modules and under accelerated exposures. Poly(vinylidene fluoride) (PVDF) and poly(vinyl fluoride) (PVF) showed the highest stability in retrieved and accelerated exposures. While polyamide had the largest amount of large scale degradation.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Data for Validating Models for PV Module Performance

This data encompasses performance data measured for flat-plate photovoltaic (PV) modules installed in Cocoa, Florida; Eugene, Oregon; and Golden, Colorado. The data include PV module current-voltage curves and associated meteorological data for approximately one-year periods. The data was acquired with the NREL Performance and Energy Rating Testbed (PERT) and the mobile Performance and Energy Rating Testbed (mPERT).

PV, Validation, IV Curves, Field performance, mPER↗

Thermally Conductive Backsheets (TCB) of PV Modules: Positive Impacts on Performance, Lifetime and LCOE

The operating temperatures of photovoltaic (PV) modules can be impacted by the selection of specific packaging materials, e.g., backsheets and encapsulants. This research focuses on the evaluation of operating temperature reduction of one-cell modules by comparing conventional Tedlar/polyester/Tedlar (TPT) backsheet with novel thermally conductive backsheets (TCBs) materials. A large number of one-cell modules with two TCB types (TCB_A and TCB_B) and baseline TPT type were fabricated and installed in three different climatic conditions of the hot-dry desert in Arizona (high and low wind speed locations) and North Carolina (temperate with low wind speed location). In this study, these two TCBs were compared with conventional TPT backsheet in terms of performance, lifetime and levelized cost of energy (LCOE). The field results were analyzed for thermal performance of TCBs compared to TPT at three sites for two and half years. This study concludes that the thermal and electrical performances of the PV modules can be improved by using TCB_A in hot and dry climate sites and TCB_B at temperate climate sites. Therefore, the lifetime of TCB-based modules is expected to be higher than TPT-based modules. Using backsheet-specific power degradation levels and assuming the same cost for both types of backsheets, the LCOE of modules using TCBs is estimated to be lower than that of TPT.

14 SOLAR ENERGY↗

Device Performance of Emerging Photovoltaic Materials (Version 2)

Following the 1st release of the "Emerging photovoltaic (PV) reports", the best achievements in the performance of emerging photovoltaic devices in diverse emerging photovoltaic research subjects are summarized, as reported in peer-reviewed articles in academic journals since August 2020. Updated graphs, tables, and analyses are provided with several performance parameters, e.g., power conversion efficiency, open-circuit voltage, short-circuit current density, fill factor, light utilization efficiency, and stability test energy yield. These parameters are presented as a function of the photovoltaic bandgap energy and the average visible transmittance for each technology and application and are put into perspective using, e.g., the detailed balance efficiency limit. The 2nd installment of the "Emerging PV reports" extends the scope toward tandem solar cells and presents the current state-of-the-art in tandem solar cell performance for various material combinations.

36 MATERIALS SCIENCE↗

Flat-plate solar array project. Volume 1: Executive summary

In 1975, the U.S. Government contracted the Jet Propulsion Lab. to develop, by 1985, in conjunction with industry, the photovoltaics (PV) module and array technology required for widespread use of photovoltaics as a significant terrestrial energy source. As a result, a project that eventually became known as the Flat Plate Solar Array (FSA) Project was formed to manage an industry, university, and Government team to perform the necessary research and development. The original goals were to achieve widespread commercial use of PV modules and arrays through the development of technology that would allow them to be profitably sold for $1.07/peak watts (1985 dollars). A 10% module conversion efficiency and a 20 year lifetime were also goals. It is intended that the executive summary provide the means by which one can gain a perspective on 11 years of terrestrial photovoltaic research and development conducted by the FSA Project.

Callaghan, W.↗

An Investigation on the Pollen-Induced Soiling Losses in Utility-Scale PV Plants

Soiling, the accumulation of dust and other contaminants on the surface of photovoltaic (PV) modules, is a common factor that can negatively impact the performance of PV systems. In this study, the authors aim to analyze the impact of pollen on soiling losses in PV systems located in North Carolina, USA, particularly during the spring season. The performance data of two utility-scale PV plants was collected and analyzed using the two soiling extraction methods. Environmental data, including croplands and vegetation was also collected and analyzed to identify correlations with soiling losses. The results of the study may help improve understanding of necessary operation and maintenance activities for PV plants and provide new insights into the phenomenon of pollen deposition on PV systems.

correlation↗

Industry Facing PV Degradation Prediction Tool and Database to Enable a 50-Year Life Module

The Photovoltaic (PV) industry constantly aims for lower costs, higher-efficiency cells, and improved module designs. These trends lead to using new materials, designs, and manufacturing processes, resulting in a continually changing technological landscape. These changes can potentially introduce new, unknown degradation mechanisms and failure modes that are difficult to diagnose, analyze, test, and model. This introduces uncertainty into the expected lifetime of PV modules of 25 years. Furthermore, research efforts aim for up to 50 years of service life while keeping performance degradation at a minimum for decades of outdoor weathering - putting additional pressure on improving the accuracy of long-term durability and reliability assessments. Here there is a need to organize the existing degradation data into an accessible format and to provide industry relevant tools for extrapolation from laboratory to field conditions. Because the core of this type of analysis involves calculations that are complicated but ubiquitous for many degradation processes, an enhanced predictive modeling framework will facilitate the analysis to help researchers keep up with the rapid pace of technological changes. In this work, we present an online tool that can be used to search for and analyze degradation information and extrapolate PV module performance and durability to field exposure. A graphical user interface will aid in the understanding of the results. The prediction tool will be built modular and published as open source, enabling users to expand on the existing framework. We use an integration pipeline approach that allows us to leverage weather data from the National Solar Radiation Database to perform geospatial degradation analysis in the US and worldwide. Our repository will contain various degradation models and material parameters suitable for the reliability and durability assessment of materials and components deployed outdoors. We hope to become a repository that can be used for weathering and degradation analysis for various applications beyond the PV industry.

degradation↗

Loss Factor Assessment in the 8GW PV Fleet Performance Data Initiative

This presentation is divided into the following sections: (1) photovoltaics (PV) current and future deployment; (2) the PV Fleet Performance Data Initiative; (3) fleet degradation trends; (4) high-efficiency module performance; (5) other system loss factors; and (6) conclusions.

deployment↗

PV Degradation Modeling: Applying Geospatial Workflows with "PVDeg"

Accurate degradation modeling is essential for predicting photovoltaic (PV) module performance, estimating longevity and informing design decisions. With degradation rates varying significantly by location, geospatial analysis is critical for PV and broader applications, such as agrivoltaics, weathering and environmental data analysis. This work presents PVDeg, an open-source tool designed for geospatial degradation analysis. PVDeg integrates meteorological data from global sources, including the National Solar Radiation Database (NSRDB) and Photovoltaic Geographical Information System (PVGIS), with degradation models. The toolkit enables users to customize geospatial workflows by integrating weather data, material parameters, and user-defined Python functions. It facilitates accelerated downloads of NSRDB and PVGIS datasets and optimizes geospatial point selection to preserve data density in regions of interest. Additionally, PVDeg provides a local database for storage and spatial queries, supporting large-scale analyses without the need for high-performance computing (HPC) resources. PVDeg provides a foundational workflow that extends its utility beyond PV applications, enabling researchers to analyze geospatial processes across discipline.

14 SOLAR ENERGY↗

Novel Approach to PV Inverter Modeling and Simulation Leveraging Experiments, Learning Based Modeling and Co-Simulation

Photovoltaic (PV) inverter manufacturers use custom, proprietary control approaches and topologies in their inverter design. The proprietary nature of these approaches makes it challenging to share electromagnetic transients (EMT) domain models for system studies. This research work presents an approach to develop EMT models from experimental data. We use novel approach in experimental design, high fidelity data collection, use of learning-based modeling, and co-simulation to reduce the time taken to develop an EMT model for an inverter under test (IUT). We used a 20 kW off-the-shelf grid following PV inverter and subjected the inverter to controlled tests. The tests include voltage and frequency step changes, as well as solar irradiance variations. The recorded high frequency data were used to train a neural network model representing the dynamic behavior of the IUT. The model was subsequently imported into an EMT tool using co-simulation techniques, and thus completing the modeling effort.

black box inverter modeling↗

A Method for Estimating Time-Series PV Production Loss From Solar Tracking Failures

Solar tracking system failures can dramatically reduce photovoltaic (PV) system energy output through suboptimal irradiance capture and self-shading loss. Detecting tracker failures is not always straightforward; unlike other common PV system failures like inverter outages and blown fuses which take portions of a system completely offline, tracker failures only partially reduce output power and can go unnoticed as a result. Additionally, tracker failures can take one of several forms, each with their own loss characteristics. Here we present two methods of detecting tracker failure events from time-series production data and a method for estimating the associated production loss. Compared with existing detection methods, the proposed power-based detection method showed 0-17% reductions in Type I error rate depending on weather conditions. Here, the loss model estimated production loss with low error (mean bias error = -2.3 %, root-mean-squared error = 6%) in a rudimentary validation.

14 SOLAR ENERGY↗

Hands-On PV Experience (HOPE) Workshop, Final Technical Report FY22-FY24

The Hands-On Photovoltaics Experience, or HOPE, is a one-week school held at NLR each summer to educate graduate student photovoltaic researchers in the fundamentals of photovoltaics (PV) as well as specific cell technologies and measurement & characterization techniques. The program brings students from universities across the U.S. and their faculty advisors to spend a week in an in-depth, intensive program, including hands-on lab experiences in solar cell fabrication and testing. This program is intended to educate the students and increase collaboration among the students, their advising faculty, and staff at NLR. Our survey results consistently indicate high satisfaction with this program and good student outcomes post-HOPE. HOPE is a selective program with a competitive application process and is limited to 12-20 students each year. Keeping the program small enables a high level of interaction among the students and individualized attention from the faculty and staff.

14 SOLAR ENERGY↗

Ultra-Compact High Efficiency Multi-Level Gan-Based PV Inverter

This project developed the key technology for a scalable, high-density photovoltaic (PV) inverter, based on gallium-nitride (GaN) power semiconductors, and advanced digital control. Specifically, we explored the feasibility of a flying-capacitor multi-level inverter for 1.5 kV PV installations, through the development of hardware prototypes utilizing low-inductance commutation loop designs, robust digital control and signaling, and low-cost heatsink integration.

14 SOLAR ENERGY↗

Operations, maintenance, and cost considerations for PV+Storage in the United States

Battery storage systems are increasingly being installed at photovoltaic (PV) sites to address supply-demand balancing needs. Although there is some understanding of costs associated with PV operations and maintenance (O&M), costs associated with emerging technologies such as PV plus storage lack details about the specific systems and/or activities that contribute to the cost values. This study aims to address this gap by exploring the specific factors and drivers contributing to utility-scale PV plus storage systems (UPVS) O&M activities costs, including how technology selection, data collection, and related and ongoing challenges. Specifically, we used semi-structured interviews and questionnaires to collect information and insights from utility-scale owners and operators. Data was collected from 14 semi-structured interviews and questionnaires representing 51.1 MW with 64.1 MWh of installed battery storage capacity within the United States (U.S.). Differences in degradation rate, expected life cycle, and capital costs are observed across different storage technologies. Most O&M activities at UPVS related to correcting under-performance. Fires and venting issues are leading safety concerns, and owner operators have installed additional systems to mitigate these issues. There are ongoing O&M challenges due the lack of storage-specific performance metrics as well as poor vendor reliability and parts availability. Insights from this work will improve our understanding of O&M consideration at PV plus storage sites.

14 SOLAR ENERGY↗

PV Fleet Performance Data Initiative Final Technical Report (FTR)

Improved analysis and reporting of photovoltaic (PV) field performance increases the certainty of owners and financiers that systems will perform as expected. Advanced module technologies (e.g., PERC, HJT, and bifacial) introduce new degradation mechanisms and performance characteristics. This project will leverage data from the ever-increasing PV fleet to develop models and understanding of the field performance of existing and new technologies. Please see our list of public reports at https://www.nrel.gov/pv/fleet-performance-data-initiative.html. Objective 1: Support the global PV industry with scalable, robust data analysis tools that reduce the uncertainty of PV system performance and loss calculation. Objective 2: Reduce perceived risk arising from degradation rate, soiling loss, and system availability by publishing detailed statistics on U.S. fleet performance. Objective 3: Highlight factors leading to system underperformance including module type, climate, mounting configuration, etc. Objective 4: Enable continued high system performance in modern PV systems, as turnover and advances in technology bring new suppliers and high-efficiency modules into the market.

14 SOLAR ENERGY↗