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At least 253 records · Page 14

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DOE OSTI2026

Impact of solvent forces and broken symmetry on the assembly of designed proteins at a liquid-solid interface

The era of protein design has enabled the creation of hybrid protein-inorganic interfaces, leading to both surface-directed self-assembly of de novo protein architectures and protein-directed formation of inorganic materials. However, the resulting patterns of protein assembly are often unexpected, implying that essential interactions are not accounted for in current design platforms. Here, we use high-speed atomic force microscopy (AFM) analyzed through machine learning to follow the assembly of protein nanorods in aqueous electrolytes on two types of mica exhibiting disparate symmetry elements, which are imprinted on the overlying hydration structure. Using Monte Carlo simulations, we reproduce the observed phases and show that an observed smectic phase, previously thought to be unstable for non-interacting rods in two dimensions, emerges when crystal symmetry introduces a directional bias. The findings demonstrate the importance of incorporating solvent forces as modulated by the hydration structure inherent to interfacial systems when designing protein assemblies at liquid-crystal interfaces. Coupling physics-based simulations that can account for these factors to de novo protein design algorithms can lead to improved design platforms for bio-inspired, hybrid materials.

bioinspired materials↗

NASA NTRS1972

A translator and simulator for the Burroughs D machine

The D Machine is described as a small user microprogrammable computer designed to be a versatile building block for such diverse functions as: disk file controllers, I/O controllers, and emulators. TRANSLANG is an ALGOL-like language, which allows D Machine users to write microprograms in an English-like format as opposed to creating binary bit pattern maps. The TRANSLANG translator parses TRANSLANG programs into D Machine microinstruction bit patterns which can be executed on the D Machine simulator. In addition to simulation and translation, the two programs also offer several debugging tools, such as: a full set of diagnostic error messages, register dumps, simulated memory dumps, traces on instructions and groups of instructions, and breakpoints.

Roberts, J.↗

NASA NTRS1973

Influence of various surface pretreatments on adherence of sputtered molybdenum disulfide to silver, gold, copper, and bronze

Solid film lubricants of radio frequency sputtered molybdenum disulfide (MoS2) were applied to silver, gold, copper, and bronze surfaces that had various pretreatments (mechanical polishing, sputter etching, oxidation, and sulfurization). Optical and electron transmission micrographs and electron diffraction patterns were used to interpret the film formation characteristics and to evaluate the sputtering conditions in regard to the film and substrate compatibility. Sputtered MoS2 films flaked and peeled on silver, copper, and bronze surfaces except when the surfaces had been specially oxidized. The flaking and peeling was a result of sulfide compound formation and the corresponding grain growth of the sulfide film. Sputtered MoS2 films showed no peeling and flaking on gold surfaces regardless of surface pretreatment.

Spalvins, T.↗

NASA NTRS1973

Evaluate the application of ERTS-A data for detecting and mapping sea ice

The author has identified the following significant results. The results of the analysis of data collected during the spring and summer demonstrate that ERTS-1 imagery has a high potential for monitoring arctic sea ice conditions during the time for maximum ice extent through ice-breakup season. In the eastern Beaufort Sea area, the combination of ERTS-1 orbital overlap and a high incidence of cloud-free conditions during the spring assures a high frequency of repetitive satellite coverage. In the mid-Beaufort Sea, numerous fractures and leads can be identified, even in the early spring data. Ice features that can be identified include: development of fractures leading to the formation of distinct ice floes; growth and deterioration of leads; evidence of shearing movements of ice masses; formation of new grey ice within leads; distinction between grey, grey-white, and older forms of ice; and the deterioration of the ice surface evidenced by the formation of puddles, thaw holes, and drainage patterns. Ice conditions in the Bering Sea near St. Lawrence Island reported by aircraft observers participating in the Bering Sea Expedition are in close agreement with the ice conditions mapped from the corresponding ERTS-1 imagery. Ice features identified were: boundaries between grey ice and first year ice, shear leads, and occurrence of open water.

Barnes, J. C.↗

NASA NTRS1976

Chemical fractionations in meteorites. IX - C3 chondrites

Radiochemical neutron activation is applied to the analysis of four C3V chondrites and three C3O chondrites for 17 trace elements (U, Re, Ir, Ni, Au, Sb, Ge, Ag, Rb, Cs, Bi, Tl, Br, Se, Te, In, and Cd). It is shown that both classes exhibit a typical chondritic step pattern, reflecting loss of volatiles during chondrule formation. It appears that the H2S/H2 ratio is the key variable to account for the condensation of chalcophile elements as a function of H2S. C3O's seem to have condensed in a region where enough metallic Fe was present to buffer the H2S pressure, whereas C3V's condensed in a more oxidized region where H2S was in excess. Accretion temperatures for both subclasses is determined. Sb and Au show variable depletion, presumably reflecting variable loss during chondrule formation.

Anders, E.↗

NASA NTRS1979

Vortex pattern development on the upper surface of a swept wing at high angle of attack

An experimental study, based on a swept wing, was undertaken in the water tunnel and the wind tunnel at low speeds, with a view to improving the understanding of the intervening phenomena and to make easier their modelling. The vortex flow effects on the wing are first illustrated from global effort measurements and static pressure distributions. The domain of existence of this type of flow is deduced as a function of both sweep angle and angle of attack. By a phenomenological study in the water tunnel, an attempt is made to describe the physical pattern of the vortex flow, from its formation near the apex to its breakdown at the trailing edge. Lastly, by means of a clinometric probe, the flow field over the wing is determined.

Mirande, J.↗

NASA NTRS1982

Three-dimensional flows about simple components at angle of attack

The structures of three dimensional separated flow about some chosen aerodynamic components at angle of attack are synthesized, holding strictly to the notion that streamlines in the external flow (viscous plus inviscid) and skin friction lines on the body surface may be considered as trajectories having properties consistent with those of continuous vector fields. Singular points in the fields are of limited number and are classified as simple nodes and saddles. Analogous flow structures at high angles of attack about blunt and pointed bodies, straight and swept wings, etc., are discussed, highlighting the formation of spiral nodes (foci) in the pattern of the skin friction lines. How local and global three dimensional separation lines originate and form is addressed, and the characteristics of both symmetric and asymmetric leeward wakes are described.

Peake, D. J.↗

NASA NTRS1982

Three-dimensional flows about simple components at angle of attack

Peake, D. J.↗

NASA NTRS1985

Bone and muscle atrophy with suspension of the rat

In order to identify a suitable model for the study of muscle atrophy due to suspension in space, a modified version of the Morey tail suspension model was used to measure the atrophic responses of rat bone and muscle to 14-30 days of unloading of the hindlimbs. The progress of atrophy was measured by increases in methylene diphosphonate (MDP) uptake. It is found that bone uptake of methylene diphosphonate followed a phasic pattern similar to changes in the bone formation rate of immobilized dogs and cats. Increased MDP uptake after a period of 60 days indicated an accelerated bone metabolism. Maximum muscle atrophy in the suspended rats was distinctly different from immobilization atrophy. On the basis of the experimental results, it is concluded that the tail suspension model is an adequate simulation of bone atrophy due to suspension.

Leblanc, A.↗

NASA NTRS1992

Effect of impact angle on central-peak/peak-ring formation and crater collapse on Venus

Although asymmetry in ejecta patterns and craters shape-in-plan are commonly cited as diagnostic features of impact angle, the early-time transfer of energy from impactor to target also creates distinctive asymmetries in crater profile with the greatest depth uprange. In order to simulate gravity-controlled crater-growth, laboratory experiments use loose particulate targets as analogs for low-strength material properties following passage of the shock. As a result, impact crater diameter D in laboratory experiments generally is many times greater than the impactor diameter 2r (factor of 40), and early-time asymmetries in energy transfer from oblique impacts are consumed by subsequent symmetrical crater growth, except at the lowest angles (less than 25 deg). Such asymmetry is evident for oblique (less than 60 deg from horizontal) impacts into aluminum where D/2r is only 2 to 4. Because cratering efficiency decreases with increasing crater size and decreasing impact angle, large scale planetary craters (4080 km) should have transient excavation diameters only 6-10 times larger than the impactor. At basin scales, D/2r is predicted to be only 3-5, i.e., approaching values for impacts into aluminum in laboratory experiments. As a result, evidence for early-time asymmetry in impactor energy transfer should become evident on planetary surfaces, yet craters generally retain a circular outline for all but the lowest impact angles.

Schultz, Peter H.↗

NASA NTRS1993

Tectonics of Neyterkob corona on Venus

Neyterkob double corona (50 deg N 202 deg) presents an area of corona-related interfering tectonic patterns which are formed in different phases of evolution of the corona and modified by regional stresses. Analyzing the patterns can reveal something about the coronal formation. Tectonic features form distinct units on topographic depressions, slopes, and volcanic flows extending over one radius of the corona. A remarkable amount of compressional features were found near the rim and related to interaction between adjacent coronae. Radial extension was mainly observed on a peculiar NE-SW trending high crossing the corona. Concentric fractures were found to the east partly connected to the lithospheric flexure. Tectonic features indicate movements of volcanic activity and modification of the area by more regional stresses.

Kauhanen, K.↗

NASA NTRS2005

Influence of Silicate Melt Composition on Metal/Silicate Partitioning of W, Ge, Ga and Ni

The depletion of the siderophile elements in the Earth's upper mantle relative to the chondritic meteorites is a geochemical imprint of core segregation. Therefore, metal/silicate partition coefficients (Dm/s) for siderophile elements are essential to investigations of core formation when used in conjunction with the pattern of elemental abundances in the Earth's mantle. The partitioning of siderophile elements is controlled by temperature, pressure, oxygen fugacity, and by the compositions of the metal and silicate phases. Several recent studies have shown the importance of silicate melt composition on the partitioning of siderophile elements between silicate and metallic liquids. It has been demonstrated that many elements display increased solubility in less polymerized (mafic) melts. However, the importance of silicate melt composition was believed to be minor compared to the influence of oxygen fugacity until studies showed that melt composition is an important factor at high pressures and temperatures. It was found that melt composition is also important for partitioning of high valency siderophile elements. Atmospheric experiments were conducted, varying only silicate melt composition, to assess the importance of silicate melt composition for the partitioning of W, Co and Ga and found that the valence of the dissolving species plays an important role in determining the effect of composition on solubility. In this study, we extend the data set to higher pressures and investigate the role of silicate melt composition on the partitioning of the siderophile elements W, Ge, Ga and Ni between metallic and silicate liquid.

Singletary, S. J.↗

NASA NTRS1988

Electron Diffraction Evidence for the Ordering of Excess Nickel Atoms by Relation to Stoichiometry in Nickel-Rich Beta'-Nial Formation of a Nickel-Aluminum (Ni2al) Superlattices

In electron diffraction patterns of nickel-rich beta-NiAl alloys, many anomalies are observed. One of these is the appearance of diffuse intensity maxima between the reflexions of the B2 structure. This is explained by the short-range ordering of the excess nickel atoms on the simple cubic sublattice occupied only by aluminum atoms in the stoichiometric, perfectly ordered NiAl alloy. After annealing Ni 37.5 atomic percent Al and Ni 37.75 atomic percent Al for 1 week at 300 and 400 C, the diffuse intensity maxima transformed into sharp superstructure reflexions. These reflexions are explained by the formation of the four possible variants of an ordered hexagonal superstructure corresponding to the Ni2Al composition. This structure is closely related to the Ni2Al3 structure (same space group) formed by the ordering of vacancies on the nickel sublattice in aluminum-rich beta-NiAl alloys.

Reynaud, F.↗

NASA NTRS1992

Effects of equatorially trapped ions on refilling of the plasmasphere

The kinetic aspects of shock formation in response to the equatorial heating of ions are reported by means of small-scale kinetic simulations of countersteaming plasma flows along a spatially varying magnetic field having the features of the dipolar magnetic field lines. Attention is given to the trapping of the field-aligned flowing ions in response to the simulated equatorial heating of ions and the associated self-consistent structures in the electric potentials and the f-plasma flow pattern. Trapping is found to lead to the formation of electrostatic shocks, which propagate away from the 'equator' as seen in the hydrodynamic model of Singh and Torr (1990). The shocks form near the mirror points of the 'equatorially' heated ions. The second stage of the refilling with equatorially trapped ions is reported. A variety of structures in density and temperature distributions as the refilling proceeds slowly is found.

Singh, Nagendra↗

NASA NTRS2012

Tiled WMS/KML Server V2

This software is a higher-performance implementation of tiled WMS, with integral support for KML and time-varying data. This software is compliant with the Open Geospatial WMS standard, and supports KML natively as a WMS return type, including support for the time attribute. Regionated KML wrappers are generated that match the existing tiled WMS dataset. Ping and JPG formats are supported, and the software is implemented as an Apache 2.0 module that supports a threading execution model that is capable of supporting very high request rates. The module intercepts and responds to WMS requests that match certain patterns and returns the existing tiles. If a KML format that matches an existing pyramid and tile dataset is requested, regionated KML is generated and returned to the requesting application. In addition, KML requests that do not match the existing tile datasets generate a KML response that includes the corresponding JPG WMS request, effectively adding KML support to a backing WMS server.

Plesea, Lucian↗

NASA NTRS2012

CometQuest: A Rosetta Adventure

Leon, Nancy J.↗

NASA NTRSDate not supplied

Mapping Organic-Mineral Associations in Jezero crater

The search for potential signs of life on Mars, a primary aim of the Mars 2020 mission, is greatly informed by the detection of organic matter1. The presence of organic matter also provides key information about the habitability and biological potential of the planet throughout its history. The Perseverance rover was designed for in situ science with the ability to collect a suite of promising samples for eventual return to Earth. One of its instruments, Scanning Habitable Environments with Raman and Luminescence for Organics and Chemicals (SHERLOC), is a deep ultraviolet (DUV) Raman and fluorescence spectrometer designed to map the distribution of organic molecules and minerals on rock surfaces at a resolution of 100 μm2. With its unique spectral mapping capabilities, SHERLOC enables a novel understanding of organic-mineral relationships on Mars to better determine their formation, deposition, and preservation mechanisms. The rover’s landing site within Jezero crater combines a high potential for past habitability as the site of an ancient lake basin with a diverse set of minerals, including carbonates and clays, that may preserve organic materials and potential biosignatures. The Jezero crater floor includes three formations (fm); two of these, Máaz and Séítah, were explored as part of the mission’s first campaign. Here, we report the detection of multiple species of aromatic organic molecules using Raman and fluorescence spectroscopy across ten targets in the two formations. This is the first evidence of organic molecules in Martian materials obtained using Raman spectroscopy, and among the first using fluorescence spectroscopy, beyond Earth3. We report specific spatial patterns and classes of organic molecules in these compositionally distinct formations, potentially indicating different fates of carbon in these environments. Our findings indicate that there is a diversity of aromatic molecules prevalent on the Martian surface and these materials persist despite exposure to surface conditions. These organic molecules are largely found within minerals linked to aqueous processes, suggesting that these processes may have had a key role in organic synthesis, transport from their point of origin, or preservation.

Sunanda Sharma↗

NASA NTRS1996

Muscle organizers in Drosophila: the role of persistent larval fibers in adult flight muscle development

In many organisms muscle formation depends on specialized cells that prefigure the pattern of the musculature and serve as templates for myoblast organization and fusion. These include muscle pioneers in insects and muscle organizing cells in leech. In Drosophila, muscle founder cells have been proposed to play a similar role in organizing larval muscle development during embryogenesis. During metamorphosis in Drosophila, following histolysis of most of the larval musculature, there is a second round of myogenesis that gives rise to the adult muscles. It is not known whether muscle founder cells organize the development of these muscles. However, in the thorax specific larval muscle fibers do not histolyze at the onset of metamorphosis, but instead serve as templates for the formation of a subset of adult muscles, the dorsal longitudinal flight muscles (DLMs). Because these persistent larval muscle fibers appear to be functioning in many respects like muscle founder cells, we investigated whether they were necessary for DLM development by using a microbeam laser to ablate them singly and in combination. We found that, in the absence of the larval muscle fibers, DLMs nonetheless develop. Our results show that the persistent larval muscle fibers are not required to initiate myoblast fusion, to determine DLM identity, to locate the DLMs in the thorax, or to specify the total DLM fiber volume. However, they are required to regulate the number of DLM fibers generated. Thus, while the persistent larval muscle fibers are not obligatory for DLM fiber formation and differentiation, they are necessary to ensure the development of the correct number of fibers.

Non-NASA Center↗