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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14

Dielectric Barrier Discharge Plasma Actuator for Flow Control

This report is Part II of the final report of NASA Cooperative Agreement contract no. NNX07AC02A. It includes a Ph.D. dissertation. The period of performance was January 1, 2007 to December 31, 2010. Part I of the final report is the overview published as NASA/CR-2012- 217654. Asymmetric dielectric barrier discharge (DBD) plasma actuators driven by nanosecond pulses superimposed on dc bias voltage are studied experimentally. This produces non-self-sustained discharge: the plasma is generated by repetitive short pulses, and the pushing of the gas occurs primarily due to the bias voltage. The parameters of ionizing pulses and the driving bias voltage can be varied independently, which adds flexibility to control and optimization of the actuators performance. The approach consisted of three elements coupled together: the Schlieren technique, burst mode of plasma actuator operation, and 2-D numerical fluid modeling. During the experiments, it was found that DBD performance is severely limited by surface charge accumulation on the dielectric. Several ways to mitigate the surface charge were found: using a reversing DC bias potential, three-electrode configuration, slightly conductive dielectrics, and semi conductive coatings. Force balance measurements proved the effectiveness of the suggested configurations and advantages of the new voltage profile (pulses+bias) over the traditional sinusoidal one at relatively low voltages. In view of practical applications certain questions have been also addressed, such as electrodynamic effects which accompany scaling of the actuators to real size models, and environmental effects of ozone production by the plasma actuators.

Opaits, Dmitry, F.↗

Using neutrons and x rays to measure plasma conditions in a solid sphere of deuterated polyethylene compressed to densities of 35 g/cc at temperatures of 2 keV and pressures of 40 Gbar

This paper describes an experiment that shock compresses the center of a solid deuterated polyethylene sphere, CD 2 , to densities of 35 g/cc and temperatures of 2 keV with corresponding pressure of 40 Gbar. The design employs a strong spherically converging shock launched through a solid ball of material using a Hohlraum radiation drive. As the shock coalesces at the center it produces a hot spot that we characterize by measuring the x-ray self-emission and 2.45 MeV neutrons emitted. Two-dimensional images and time-resolved measurements of the x rays emitted determine the size and time duration of the hot spot, leading to an estimated 2k eV electron temperature. The neutron time of flight spectrometer measures an average ion temperature of 1.06 ± 0.15 keV and neutron yield of 7.0 (±0.5) × 10 9 DD neutrons. Our new distribution function tool enables us to create a forward model of the experimental data based on 1D radiation-hydrodynamic simulations, leading to a better understanding of the plasma conditions that produce the measured neutrons and x rays. Furthermore, our simulations indicate that the x rays are produced in a short-lived hot-dense core over tens of picoseconds, whereas the neutron emission continues for about 200 ps, as the hot core starts to expand, thereby leading to a lower mean temperature of the plasma during neutron production. This finding is in agreement with the experimental data, and we therefore conclude that the forward-modeling is a useful tool for inferring the conditions of the hot spot in a laser-driven implosion during burn.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Resolution of electron emission mechanisms in an argon arc with a hot tungsten cathode

The regenerative nature of the interaction between the electron emission processes at the cathode surface and the ion-, excited-atom-, and photon-production processes in the plasma was examined. Semiquantitative estimates of the thickness of the species production layer, the current partition, and the time constants were made. These results were used to interpret experimental measurements of the current decay of an argon arc at 46.7 kPa, 3.2-7.9 A, and 28-18 V, with a self-sustained hot tungsten cathode. After the discharge is suddenly connected to a voltage clamp, the disparity of decay rates for different emission processes permits the separation of thermionic emission from the faster-decaying components. The observed thermionic current constitutes about 30% of the total emission. The high nonthermionic portions of the current could not be explained in terms of the present understanding of the emission processes.

Chen, M. M.↗

DBD plasma-assisted ethanol steam reforming for green H 2 production: Process optimization through response surface methodology (RSM)

Herein this work investigates ethanol steam reforming (ESR) to produce hydrogen (H 2 ) in a dielectric barrier discharge (DBD) plasma reactor. A five-level, three-factor experiment design was performed using a response surface methodology (RSM) to evaluate the combined effects of the three process parameters, including discharge power, total flow rate, and ethanol-to-water (EtOH/H 2 O) molar ratio on the plasma-assisted ESR reaction. Quadratic regression models were employed in RSM to fit the experimental results and present the correlation between process parameters and targeted responses (EtOH conversion, H 2 yield, H 2 selectivity, and specific energy requirement (SER) for H 2 production). The results suggested that the EtOH/H 2 O molar ratio is considered to have the most significant effect on the EtOH conversion and H 2 , H 2 selectivity, while the total flow rate is the most significant parameter determining SER for H 2 production. Process optimization demonstrated the optimal process conditions, including a discharge power of 55.9 W, a total flow rate of 26.7 ml/min, and an EtOH/H 2 O molar ratio equal to 0.34. A validation test was performed and confirmed the feasibility of the optimization process.

08 HYDROGEN↗

Collaborative Research: Explosive reconnection in relativistic magnetically-dominated plasmas (Final Report)

Magnetic fields can be the dominant component of astrophysical plasmas, so that the magnetic energy density might exceed even the rest-mass energy density of matter. In this extreme (and largely unexplored) regime the magnetic field controls the overall plasma evolution, dissipation, and acceleration of non-thermal particles. This plasma regime, applicable to a variety of astrophysical sources - magnetars, pulsars and pulsar wind nebulae (PWNe), jets of Active Galactic Nuclei (AGNs) and Gamma-Ray Bursters (GRBs) - is dramatically different from laboratory plasmas, the magnetospheres of planets, and the interplanetary plasma. Relativistic astrophysical sources then provide an unique opportunity to study the fundamental plasma physics of magnetically-dominated plasmas; a novel and fast-evolving field of theoretical research which, by investigating energy conversion and particle energization processes in plasmas, is of vital importance to the Fusion Energy Sciences DoE program. Data coming from astrophysical high-energy missions, especially the Crab Nebula flares recently observed by the Fermi and AGILE satellites, suggest that the acceleration of non-thermal particles to the highest energies occurs in magnetic reconnection events - a major change of paradigm in high-energy astrophysics. Most importantly, observations demand that particle acceleration should proceed extremely fast (with accelerating electric field of the order of the magnetic field) and on macroscopic scales (much larger, e.g., than the microscopic plasma skin depth). We are conducting studies of the microphysics of magnetically-dominated plasmas focussing in particular on the highly dynamic regime of explosive reconnection and associated particle acceleration in relativistic plasmas. We are studying the stability and explosive plasma dynamics, particle acceleration and radiation production in a number of idealized plasma configurations that approximate relevant astrophysical sources (like the magnetic ABC structures and interacting flux tubes, as well as generalizations of analytical models of X-point collapse to relativistic plasmas). The well-studied case of the Crab Nebula is taken as a prototypical example for the application of the model. We are combining analytical studies of explosive magnetic dynamics and dissipation in relativistic plasmas with particle-in-cell (PIC) simulations and fluid simulations. The theoretical model, fluid and particle-in-cell simulations are cross-checked for agreement and convergence.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Direct nuclear-powered lasers

The development of direct nuclear pumped lasers is reviewed. Theoretical and experimental investigations of various methods of converting the energy of nuclear fission fragments to laser power are summarized. The development of direct nuclear pumped lasers was achieved. The basic processes involved in the production of a plasma by nuclear radiation were studied. Significant progress was accomplished in this area and a large amount of basic data on plasma formation and atomic and molecular processes leading to population inversions is available.

Jalufka, N. W.↗

Ion bombardment experiments suggesting an origin for organic particles in pre-cometary and cometary ices

During the Giotto and Vega encounters with Comet Halley both organic particles called CHON and energetic ions were detected. The acceleration of ions to hundreds of keV in the vicinity of the bow shock and near the nucleus may be a demonstration of a situation occurring in the early solar system (perhaps during the T Tauri stage) that led to the formation of organic particles only now released. Utilizing a Van de Graaff accelerator and a target chamber having cryogenic and mass spectrometer capabilities, frozen gases were bombarded at 10 K with 175 keV protons with the result that fluffy solid material remains after sublimation of the ice. Initial experiments were carried out with a gas mixture in parts of 170 carbon monoxide, 170 argon, 25 water, 20 nitrogen, and 15 methane formulated to reflect an interstellar composition in experiments involving the freezing out of the products of a plasma. The plasma experiments resulted in a varnish-like film residue that exhibited luminescence when excited with ultraviolet radiation, while the ion bombardment created particulate material that was not luminescent.

Wdowiak, Thomas J.↗

Physics of the central engine

Physical processes which may be important in the central engines of AGNs are discussed. Black hole accretion models have been elaborated during the past few years, and provide a plausible framework for jet and spectrum formation. However, the specific mechanisms responsible for producing the observed continuum radiation remain uncertain. Consideration is given to nonthermal models for the IR continuum, constraints on thermal plasma, and the production of relativistic electrons.

Begelman, Mitchell C.↗

Magnetic Flux Compression Reactor Concepts for Spacecraft Propulsion and Power (MSFC Center Director's Discretionary Fund; Project No. 99-24)

This technical publication (TP) examines performance and design issues associated with magnetic flux compression reactor concepts for nuclear/chemical pulse propulsion and power. Assuming that low-yield microfusion detonations or chemical detonations using high-energy density matter can eventually be realized in practice, various magnetic flux compression concepts are conceivable. In particular, reactors in which a magnetic field would be compressed between an expanding detonation-driven plasma cloud and a stationary structure formed from a high-temperature superconductor are envisioned. Primary interest is accomplishing two important functions: (1) Collimation and reflection of a hot diamagnetic plasma for direct thrust production, and (2) electric power generation for fusion standoff drivers and/or dense plasma formation. In this TP, performance potential is examined, major technical uncertainties related to this concept accessed, and a simple performance model for a radial-mode reactor developed. Flux trapping effectiveness is analyzed using a skin layer methodology, which accounts for magnetic diffusion losses into the plasma armature and the stationary stator. The results of laboratory-scale experiments on magnetic diffusion in bulk-processed type II superconductors are also presented.

Litchford, R. J.↗

Innovative techniques for the production of energetic radicals for lunar processing including cold plasma processing of local planetary ores

Hydrogen reduction of ilmenite has been studied by a number of investigators as a potential means for recovery of oxygen from lunar soil. Interest in this process has always rested with the simplicity of the flow diagram and the utilization of established technology. Effective utilization of hydrogen in the reduction process at temperatures of 1200 C and below has always been disappointing and, as such, has led other investigators to focus attention on other systems. Effective utilization of hydrogen in the reduction of ilmenite can be significantly enhanced in the presence of a non-equilibrium hydrogen plasma. Ilmenite at solid specimen temperatures of 600 C to 970 C were reacted in a hydrogen plasma. Those experiments revealed that hydrogen utilization can be significantly enhanced. At a specimen temperature of 850 C the fraction of H2 reacted was 24 percent compared to the 7 percent theoretical limit calculated with thermodynamic theory for the same temperature. An added advantage for a hydrogen plasma involves further reduction of TiO2. Reduction of the iron oxide in ilmenite yields TiO2 and metallic iron as by products. Titanium forms a number of oxides including TiO, Ti2O3, Ti3O5 and the Magneli oxides (Ti4O7 to Ti50O99). In conventional processing of ilmenite with hydrogen it is possible to reduce TiO2 to Ti7O13 within approximately an hour, but with poor utilization of hydrogen on the order of one mole of H2 per thousand. In the cold or non-equilibrium plasma TiO2 can be rapidly reduced to Ti2O3 with hydrogen utilization exceeding 10 percent. Based on design considerations of the plasma reactor greater utilization of the hydrogen in the reduction of TiO2 is possible.

Bullard, D.↗

Plasma-based global pathway analysis to understand the chemical kinetics of plasma-assisted combustion and fuel reforming

The Global Pathway Analysis (GPA) algorithm helps analyze the chemical kinetics of complex combustion systems by identifying important global reaction pathways connecting a source species to a sink species through various important intermediate species (i.e., hub species). Here, the present work aims to extend GPA algorithm to plasma-assisted combustion and fuel reforming systems to identify the dominant global pathways in such systems at various conditions. In addition, the present study extends the ability of GPA algorithm to identify reaction cycles involving the excitation of high-concentration species (e.g., O 2 , N 2 , and fuel) to their vibrational and electronic states and the subsequent de excitation to their ground state, based on their significance on the reactivity of plasma-assisted systems in terms of gas heating and radical production. Provisions are made in the GPA algorithm to evaluate the reactivity of identified re action pathways and cycles based on the element-flux transfer (i.e., dominance), heat release, and radical production rate. The newly developed Plasma-based Global Pathway Analysis (PGPA) algorithm is then used to analyze the plasma assisted combustion of ammonia and reforming of methane. The PGPA analyses elucidated the significance of vibrational-translational cycles on the reactivity of NH 3 /air mixtures. Further, analyses on the production of NO ascribed the early reforming of NH 3 to N 2 and H 2 in impeding the production of NO during plasma-assisted NH 3 ignition. Lastly, the enhanced reforming of CH 4 /N 2 mixtures using plasma has been attributed to electron impact dissociation of CH 4 when compared to thermal reforming. In contrast, conventional path-Flux analysis (PFA) was found to require significant manual effort and pre-analysis intuitions from expert knowledge, making it arduous to provide valuable in sights into plasma chemistry. The user-friendly and automated nature of PGPA thus provides a valuable tool for assessing the kinetics of plasma-assisted systems helpful in analyzing and, further, a foundation in reducing plasma-assisted chemistry, without the needs of expert knowledge.

33 ADVANCED PROPULSION SYSTEMS↗

Sequential Dosing Strategies for Controlling Selectivity and Plasma-Phase Contributions in Plasma Catalysis

Plasma-assisted catalysis has advanced in recent years, particularly for transforming stable reactants at atmospheric pressure and ambient temperature. However, achieving a deeper understanding of the many plasma and catalytic contributions remains a significant goal, as improving product yield and selectivity in plasma catalysis depends on proper catalyst selection, which is often challenging due to the complex interplay between plasma-phase and plasma-surface reactions. A sequential methodology has emerged as a means to decouple the catalyst activity from plasma-phase reactions. In this approach, nonthermal plasma is used in one step to activate and/or convert a gas phase or surface bound reactant, while in a second step, the catalyst directs product formation under steady-state or temperature-programmed conditions. This review examines studies using this technique for reactions involving N 2 , CO 2 , and SO 2 , offering insights into reaction mechanisms and catalyst behavior/selection for these transformations. These systematic studies provide a framework that can be applied to other plasma-assisted reactions. We also highlight remaining questions, propose directions for future studies, and discuss the potential of applying this methodology to other reaction systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Production and Persistence of Extreme Two-temperature Plasmas in Radiative Relativistic Turbulence

Turbulence is a predominant process for energizing electrons and ions in collisionless astrophysical plasmas, and thus is responsible for shaping their radiative signatures (luminosity, spectra, and variability). To better understand the kinetic properties of a collisionless radiative plasma subject to externally driven turbulence, we investigate particle-in-cell simulations of relativistic plasma turbulence with external inverse Compton cooling acting on the electrons. We find that ions continuously heat up while electrons gradually cool down (due to the net effect of radiation), and hence the ion-to-electron temperature ratio T i /T e grows in time. Furthermore, we show that Ti/Te is limited only by the size and duration of the simulations (reaching ${T}_{i}/{T}_{e}\sim {10}^{3}$), indicating that there are no efficient collisionless mechanisms of electron–ion thermal coupling. This result has implications for models of radiatively inefficient accretion flows, such as observed in the Galactic center and in M87, for which so-called two-temperature plasmas with ${T}_{i}/{T}_{e}\gg 1$ have been invoked to explain their low luminosity. Additionally, we find that electrons acquire a quasi-thermal distribution (dictated by the competition of turbulent particle energization and radiative cooling), while ions undergo efficient nonthermal acceleration (acquiring a harder distribution than in equivalent nonradiative simulations). There is a modest nonthermal population of high-energy electrons that are beamed intermittently in space, time, and direction; these beamed electrons may explain rapid flares in certain high-energy astrophysical systems (e.g., in the Galactic center). These numerical results demonstrate that extreme two-temperature plasmas can be produced and maintained by relativistic radiative turbulence.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

The polar ionosphere

Self-consistent concepts which in many cases demonstrate the required relationships between electric currents, conductivity and electric fields are emerging from International Magnetospheric Study period research on the polar ionosphere and its role in the coupling between the ionosphere and the magnetopause. Observed phenomena may now be explained in terms of realistic variations in the electric current, conductivity and electric field parameters, and the distribution and composition of plasma can be reconciled with large scale plasma motion and ion production regions. Gaps remain, however, in the current understanding of the polar ionosphere's electrodynamic and plasma properties.

Heelis, R. A.↗

Investigations of microwave plasmas - Applications in electrothermal thruster systems

Experimental studies which have been conducted to develop understanding of plasma processes used for spacecraft propulsion are reviewed. The techniques discussed are calorimetry and volume measurements using the TM 011 and TM 012 modes in the microwave cavity system. The use of plasmas in electrical propulsion and microwave induction is reviewed. Plasma containment, microwave power production, energy distribution, and the pressure and flow dependence of the energy distribution are addressed. The plasma dimensions and their dependence on pressure, flow, and power are considered.

Haraburda, Scott S.↗

Plasma-catalyst modeling for materials selection: challenges and opportunities in nitrogen oxidation

Reliable kinetic models are essential to rationalize observations and to guide the selection of appropriate plasma-catalyst combinations. Kinetic models coupling plasma- and heterogeneous-catalytic-chemistries, however, are primitive. Here, we combine reduced plasma chemistries and density functional theory parameterized surface reactions to model NO formation from N2 oxidation, an alternative nitrogen fixation process. We first show plasma excited species can enhance turnover frequencies of both Pt and Au. The enhancing potential is a function of plasma species and their densities. We then compare NO production between plasma/Pt and plasma/Au with an integral reactor model and explore the dependence of NO production as a function of plasma conditions, reactor configurations and chemical compositions. Plasma/Pt generates more NO than plasma/Au under most thermal and plasma parametric conditions. Plasma/Au outperforms plasma/Pt under high plasma excitations at low temperatures. Furthermore, these results highlight that selection of plasma-catalyst combinations should consider the properties of plasmas, materials and the coupling of the two.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗