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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
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NASA NTRS1972

Infrared spectroscopy experiment on the Mariner 9 mission - Preliminary results.

The Mariner 9 IR spectroscopy experiment has provided good-quality spectra of many areas of Mars, predominantly in the southern hemisphere. Large portions of the thermal emission spectra are significantly affected by dust with a silicon oxide content approximately corresponding to that of an intermediate igneous rock, thus implying that Mars has undergone substantial geochemical differentiation. Derived temperature profiles indicate a warm daytime upper atmosphere with a strong warming over the south polar cap. Atmospheric water vapor is clearly observed over the south polar area and less strongly over other regions.

Hanel, R. A.↗
NASA NTRS1993

Evaluation of infrared emission spectroscopy for mapping the Moon's surface composition from lunar orbit

Infrared thermal emission spectroscopy is evaluated for its possible application to compositional mapping of the Moon's surface from lunar orbit. Principles of the mid-IR (approximately 4-25 microns) technique, previous lunar ground-based observations, and laboratory studies of Moon samples are reviewed and summarized. A lunar thermal emission spectrometer experiment is described, patterned after a similar instrument on the Mars Observer spacecraft. Thermal emission spectrometry from a polar-orbiting lunar spacecraft could provide a valuable mapping tool to aid in exploration for lunar resources and help provide understanding of the origin of the Moon and history of lunar surface processes.

Nash, Douglas B.↗
NASA NTRS2005

XMM-Newton Observations of Four Millisecond Pulsars

I present an analysis of the XMM-Newton observations of four millisecond pulsars, J0437-4715, J2124-3358, J1024-0719, and J0034-0534. The new data provide strong evidence of thermal emission in the X-ray flux detected from the first three objects. This thermal component is best interpreted as radiation from pulsar polar caps covered with a nonmagnetic hydrogen atmosphere. A nonthermal power-law component, dominating at energies E greater than or equal to 3 keV, can also be present in the detected X-ray emission. For PSR J0437-4715, the timing analysis reveals that the shape and pulsed fraction of the pulsar light curves are energy dependent. This, together with the results obtained from the phase-resolved spectroscopy, supports the two-component (thermal plus nonthermal) interpretation of the pulsar's X-ray radiation. Highly significant pulsations have been found in the X-ray flux of PSRs 52124-3358 and 51024-0719. For PSR 50034-0534, a possible X-ray counterpart of the radio pulsar has been suggested. The inferred properties of the detected thermal emission are compared with predictions of radio pulsar models.

Zavlin, Vyacheslav E.↗
NASA NTRS2014

Sedimentary Mounds on Mars: Tracing Present-day Formation Processes into the Past

High resolution photography and spectroscopy of the martian surface (MOC, HiRISE) from orbit has revolutionized our view of Mars with one and revealed spectacular views of finely layered sedimentary materials throughout the globe [1]. Some of these sedimentary deposits are 'mound' shaped and lie inside of craters (Fig 1). Crater mound deposits are found throughout the equatorial region, as well as ice-rich deposits found in craters in the north and south polar region [2-4]. Despite their wide geographical extent and varying volatile content, the 'mound' deposits have a large number of geomorphic and structural similarities that suggest they formed via equivalent processes. Thus, modern depositional processes of ice and dust can serve as an invaluable analog for interpreting the genesis of ancient sedimentary mound deposits.

Niles, P. B.↗
NASA NTRS1972

Investigation of the Martian environment by infrared spectroscopy on Mariner 9.

Preliminary analysis of Mariner 9 IR spectroscopic data through May 1972 shows spectral features due to carbon dioxide, water vapor, and silicate dust suspended in the atmosphere. Measurements obtained during and after the planet-wide dust storm indicate that large diurnal variations in atmospheric temperature existed up to at least 30 km. Analysis of spectral features due to the atmospheric dust provides a SiO2 content of 60 (plus or minus 10)%, implying substantial geochemical differentiation. Water vapor estimates yield abundances of 10 to 20 precipitable microns, and no water vapor was detected over the north polar region.

Hanel, R.↗
NASA NTRS1992

Thermal oxidation of single-crystal silicon carbide - Kinetic, electrical, and chemical studies

This paper presents kinetic data from oxidation studies of the polar faces for 3C and 6H SiC in wet and dry oxidizing ambients. Values for the linear and parabolic rate constants were obtained, as well as preliminary results for the activation energies of the rate constants. Examples are presented describing how thermal oxidation can be used to map polytypes and characterize defects in epitaxial layers grown on low tilt angle 6H SiC substrates. Interface widths were measured using Auger electron spectroscopy (AES) with Ar ion beam depth profiling and variable angle spectroscopic ellipsometry (VASE) with effective medium approximation (EMA) models. Preliminary electrical measurements of MOS capacitors are also presented.

Petit, J. B.↗
NASA NTRS2012

Portable Remote Imaging Spectrometer (PRISM): Laboratory and Field Calibration

We report the characteristics of the Portable Remote Imaging Spectrometer, an airborne sensor specifically designed for the challenges of coastal ocean research. PRISM has high signal to noise ratio and uniformity, as well as low polarization sensitivity. Acquisition of high quality data has been demonstrated with the first engineering flight.

imaging spectrometer↗
NASA NTRS2019

Evidence for Dry Carbonatite Metasomatism in the Oceanic Lithosphere from Peridotite Xenoliths of Samoa and Lanzarote

Water in Earth’s mantle affects processes like magmatism and plate tectonics. Experiments show that CO2-rich fluids lower the water solubility in olivine, implying that CO2-rich melts/fluids may dehydrate the lithosphere during metasomatism. To test this hypothesis, we report water concentrations (by polarized FTIR) of olivines, orthopyroxenes (OPX) and clinopyroxenes (CPX) from Savai’i (Samoa) and Lanzarote (Canary Islands) peridotite xenoliths with evidence of carbonatite metasomatism. Savai’i peridotites are highly depleted harzburgites and dunites with spinel Cr# (Cr/(Cr+Al)) ranging from 0.4 to 0.76 (estimated degree of melting: 191.5%). Strong Light Rare Earth Element (LREE) enrichments with Ti and Zr depletions in OPX and CO2-rich fluid inclusions (via Raman spectroscopy) are consistent with carbonatite metasomatism. Olivine, OPX and reconstructed bulk rock water concentrations (0.67-3.8, 17-89 and 4-26 ppm H2O, respectively) are low and show no apparent relationship with extent of carbonatite metasomatism. Calculated water concentrations of melts in equilibrium with Savai’i OPX (OPX/melt partitioning of water 0.0063 to 0.011) are, on average (0.540.32 wt% H2O), lower than host Samoan lavas (0.63 to 1.5 wt% H2O), despite the LREE enrichments in OPX. Lanzarote peridotites are also highly depleted (degree of melting from spinel Cr#: 171.8%).Water concentrations are low in olivines (1.7-5.3 ppm H2O) and variable in pyroxenes (OPX: 42-103 ppm H2O; CPX: 105-301 ppm H2O), and show no apparent correlation with indicators of carbonatite metasomatism. Both Savai’i and Lanzarote peridotites show negative correlations between water and degree of melting (i.e. Mg/(Mg+Fe), Cr#), suggesting melt depletion rather than metasomatism may have influenced their water concentrations. Calculated water concentrations of melts in equilibrium with Lanzarote CPX (average 1.90.75 wt% H2O; CPX/melt partitioning of water 0.011 to 0.012) are similar to those for Western Canaries lavas (average 1.80.31 wt%; CPX/melt partitioning of water 0.016 to 0.021) inferred from their CPX phenocrysts. However, calculated Ce concentrations in such melts (352 to 378 ppm; CPX/melt partitioning of Ce 0.07) are an order of magnitude greater than the lavas, and similar to carbonatites. This leads to H2O/Ce to be an order of magnitude lower in the inferred melts (26 to 57) than estimates for Western Canary lavas (280150). These low H2O/Ce ratios may suggest H2O loss from CPX during ascent, but the lack of strong water diffusion gradients in Lanzarote minerals does not support this. Instead we hypothesize that carbonatite metasomatism resulted in greater enrichment of Ce over H2O. Assuming carbonatite magmas are water rich, this implies a lower partitioning of water between minerals and melts during metasomatism, as suggested by experiments. Our data suggests carbonatite metasomatism does not result in significant re-hydration of the lithosphere, in contrast to silicate metasomatism as previously observed in Hawaiian peridotites.

Ashley, Aaron↗
NASA NTRS1985

IUE spectroscopy, visible-band photometry, and polarimetry of HD 47732 (V641 Monocerotis)

Several high- and low-dispersion IUE spectra are described for the hot, massive close binary HD 47732. The stellar silicon lines do not show theoretically expected strength, the weakness being attributed to incipicent emission. A weak stellar wind is measurable with an expansion velocity of about 500 km/s. There is difficulty in fitting a model atmosphere to all of the IUE continuum and visible band and IR measures. These difficulties are resolved by appealing to a 22,500 K model atmosphere and a distinctive interstellar extinction law. Numerous V band measures show the polarization to be variable, but not strongly in a phased-locked way. This suggests sporadic outbursts of gas feeding the shell. Several seasonal V band light curves are discussed, and the seasonal variations among them are attributed to variable developments of a systemic shell which scatters the photospheric light and dilutes to a variable degree the light variation due to ellipticity of figure of the component stars.

Koch, R. H.↗
NASA NTRS1991

FOS spectroscopy of resolved structure in the nucleus of NGC 1068

The results of FOS spectroscopy of the continuum peak of NGC 1068 in the wavelength range 2200-7000 A are reported. Detailed analysis reveals the emission lines to be complex in shape and to consist of a number of different velocity components. Both the Balmer lines and the strong forbidden lines have a contribution from a component with full width at half-maximum on the order of 2200 km/s. However, the broad H-beta emission observed in polarized light is not detected. This implies that the continuum peak is not the mirror which reflects light from the hidden Seyfert I nucleus. It could possibly contribute some of the reflected light, but the equivalent width of the H-beta BLR line, if present at all, is much weaker than expected from the ground-based nuclear polarized-flux spectrum.

Caganoff, S.↗
NASA NTRS1988

Ozone on Mars - The effects of clouds and airborne dust

Photochemistry in the winter polar atmosphere of Mars is examined for several latitudes, cloud types, and dust abundances. Variations in cloud opacities and cloud types change O3 abundances by only a few percent. However, typical dust abundances induce 10-50 percent increases in O3 abundances, primarily because photodissociation rates are drastically reduced by dust absorption. Furthermore, annual, latitudinal, and seasonal cycles in dust opacity cause variations of 50 percent or greater in the corresponding cycles in O3 abundances. The reflectance spectroscopy technique that has been used to measure the O3 abundance may have difficulty detecting these variations.

Lindner, Bernhard Lee↗
NASA NTRS1989

SONGS - A high resolution imaging gamma-ray spectrometer for the Space Station

The overall design and the instrumental features of the Space-Station Observer for Nuclear Gamma-ray Spectroscopy (SONGS) instrument are described. SONGS comprises an array of 19 two-segment n-type Ge detectors, which have the capability of determining the interaction site in either the upper or the lower segment or in both segments. The detectors provide high energy resolution of 1 keV at 100 keV and of 2 keV at 1 MeV. The close-packed Ge sensor array provides a natural sensitivity for the measurement of gamma ray polarization in the 100 keV to 1 MeV energy range, making it possible to obtain information on the structure of the magnetosphere of neutron stars and of the accretion disk of black holes.

Nakano, G. H.↗
NASA NTRS1985

Consequences of hot gas in the broad line region of active galactic nuclei

Models for hot gas in the broad line region of active galactic nuclei are discussed. The results of the two phase equilibrium models for confinement of broad line clouds by Compton heated gas are used to show that high luminosity quasars are expected to show Fe XXVI L alpha line absorption which will be observed with spectrometers such as those planned for the future X-ray spectroscopy experiments. Two phase equilibrium models also predict that the gas in the broad line clouds and the confining medium may be Compton thick. It is shown that the combined effects of Comptonization and photoabsorption can suppress both the broad emission lines and X-rays in the Einstein and HEAO-1 energy bands. The observed properties of such Compton thick active galaxies are expected to be similar to those of Seyfert 2 nuclei. The implications for polarization and variability are also discussed.

Kallman, T.↗
NASA NTRS1985

Consequences of hot gas in the broad-line region of active galactic nuclei

Models for hot gas in the broad line region of active galactic nuclei are discussed. The results of the two phase equilibrium models for confinement of broad line clouds by Compton heated gas are used to show that high luminosity quasars are expected to show Fe XXVI L alpha line absorption which will be observed with spectrometers such as those planned for the future X-ray spectroscopy experiments. Two phase equilibrium models also predict that the gas in the broad line clouds and the confining medium may be Compton thick. It is shown that the combined effects of Comptonization and photoabsorption can suppress both the broad emission lines and X-rays in the Einstein and HEAO-1 energy bands. The observed properties of such Compton thick active galaxies are expected to be similar to those of Seyfert 2 nuclei. The implications for polarization and variability are also discussed.

Kallman, T.↗
NASA NTRS1993

Spots on RS CVn from spectroscopy and photometry

We have used contemporaneous spectra and V light curves to form spot models for RS CVn in 1991 and 1992. More than two spots are needed to fit all the properties of the observations. In fact, moderately small spots (22 x 28 deg in latitude and longitude) having only a slight effect on the rotational light curve were eclipsed in both years, and we find that a collection of 6-8 such moderate spots is required to fit the line profiles in each year. These groups of spots also account naturally for a difference in level of light between the two years. There is no evidence for polar spots larger than 18 degrees in radius. We have also derived new orbits from radial velocities of the stars, which give the mass ratio Mc/Mh = 1.04 +/-0.02.

Eaton, Joel A.↗
NASA NTRS2004

Probing a GRB Progenitor at a Redshift of z=2: A Comprehensive Observing Campaign of the Afterglow of GRB 030226l

We report results from a comprehensive optical/near-infrared follow-up observing campaign of the afterglow of GRB 030226, including VLT spectroscopy and polarimetry, supplemented by Chandra X-ray and BOOTES-1 rapid response observations. First observations at ESO started 0.2 days after the burst when the afterglow was at a magnitude of R approx. 19. The multi-color light curve of the afterglow, with a break around 1 day after the burst, is achromatic within the observational uncertainties even during episodes of short-term fluctuations. Close to the break time the degree of linear polarization of the afterglow light was less than 1.1%, consistent with low intrinsic polarization observed in other afterglows. VLT spectra show a foreground absorber of Mg II at a redshift z=1.042 and two absorption line systems at redshifts z=1.962+/-0.001 and at z=1.986+/-0.001, placing the lower limit for the redshift of the GRB close to 2. The kinematics and the composition of the absorbing clouds is very similar to those observed in the afterglow of GRB 021004, supporting the view that at least some GRBs are physically related to the explosion of a Wolf-Rayet star.

Klose, S.↗
NASA NTRS1999

Chemical Sensors Based on IR Spectroscopy and Surface-Modified Waveguides

Sol-gel processing techniques have been used to apply thin porous films to the surfaces of planar infrared (IR) waveguides to produce widely useful chemical sensors. The thin- film coating serves to diminish the concentration of water and increase the concentration of the analyte in the region probed by the evanescent IR wave. These porous films are composed of silica, and therefore, conventional silica surface modification techniques can be used to give the surface a specific functional character. The sol-gel film was surface-modified to make the film highly hydrophobic. These sensors were shown to be capable of detecting non-polar organic analytes, such as benzonitrile, in aqueous solution with detection limits in the ppb range. Further, these porous sol-gel structures allow the analytes to diffuse into and out of the films rapidly, thus reaching equilibrium in less than ten seconds. These sensors are unique because of the fact that their operation is based on the measurement of an IR absorption spectrum. Thus, these sensors are able to identify the analytes as well as measure concentration with high sensitivity. These developments have been documented in previous reports and publications. Recently, we have also targeted detection of the polar organic molecules acetone and isopropanol in aqueous solution. Polar organics are widely used in industrial and chemical processes, hence it is of interest to monitor their presence in effluents or decontamination process flows. Although large improvements in detection limits were expected with non-polar organic molecules in aqueous solutions using very hydrophobic porous sol-gel films on silicon attenuated total reflectance (Si ATR) waveguides, it was not as clear what the detection enhancements might be for polar organic molecules. This report describes the use of modified sol-gel-coated Si ATR sensors for trace detection and quantitation of small polar organic molecules in aqueous solutions. The detection of both acetone and isopropanol molecules in aqueous solution has been previously reported for chalcogenide fiber optic sensors. The sol-gel film was produced using a mixture of ethyltriethoxysilane and tetraethoxysilane and the surface modification was carried out using trimethylchlorosilane. We have demonstrated that this film concentrates the target polar analytes from aqueous solution in the region probed by the evanescent wave to improve detection limits by as much as a factor of 450.

Lopez, Gabriel P.↗