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NASA NTRS1999

The Mars 2001 Athena Precursor Experiment (APEX)

The Athena Precursor Experiment (APEX) is a suite of scientific instruments for the Mars Surveyor Program 2001 (MSP'01) lander. The major elements of the APEX pay load are: (1) Pancam/Mini-TES, a combined stereo color imager and mid-infrared point spectrometer. (2) An Alpha-Proton-X-Ray Spectrometer (APXS) for in-situ elemental analysis. (3) A Mossbauer Spectrometer for in-situ determination of the mineralogy of Fe-bearing rocks and soils. (4) A Magnet Array that can separate magnetic soil particles from non-magnetic ones.

Squyres, S. W.↗

NASA NTRS2018

Breakthrough Propulsion Study: Assessing Interstellar Flight Challenges and Prospects

Progress toward developing an evaluation process for interstellar propulsion and power options is described. The goal is to contrast the challenges, mission choices, and emerging prospects for propulsion and power, to identify which prospects might be more advantageous and under what circumstances, and to identify which technology details might have greater impacts. Unlike prior studies, the infrastructure expenses and prospects for breakthrough advances are included. This first year's focus is on determining the key questions to enable the analysis. Accordingly, a work breakdown structure to organize the information and associated list of variables is offered. A flow diagram of the basic analysis is presented, as well as more detailed methods to convert the performance measures of disparate propulsion methods into common measures of energy, mass, time, and power. Other methods for equitable comparisons include evaluating the prospects under the same assumptions of payload, mission trajectory, and available energy. Missions are divided into three eras of readiness (precursors, era of infrastructure, and era of breakthroughs) as a first step before proceeding to include comparisons of technology advancement rates. Final evaluation "figures of merit" are offered. Preliminary lists of mission architectures and propulsion prospects are provided.

Marc G. Millis↗

NASA NTRS2019

Analyses of Aliphatic Aldehydes and Ketones in Carbonaceous Chondrites

Aliphatic aldehydes and ketones are essential building blocks for the synthesis of more complex organic compounds. Despite their potentially key role as precursors of astrobiologically important molecules, such as amino acids and carboxylic acids, this family of compounds has scarcely been evaluated in carbonaceous chondrites. The paucity of such analyses likely derives from the low concentration of aldehydes and ketones in the meteorites and from the currently used chromatographic methodologies that have not been optimized for meteorite analysis. In this work, we report the development of a novel analytical method to quantify the molecular distribution and compound-specific isotopic analysis of 29 aliphatic aldehydes and ketones. Using this method, we have investigated the molecular distribution and C-13-isotopic composition of aldehydes and ketones in 10 carbonaceous chondrites from the CI, CM, CR, and CV groups. The total concentration of carbonyl compounds ranged from 130 to 1000 nmol g(exp -1) of meteorite with formaldehyde, acetaldehyde, and acetone being the most abundant species in all investigated samples. The C-13-isotopic values ranged from -67 to +64‰ and we did not observe clear relationships between C-13-content and molecular weight. Accurately measuring the relative abundances, determining the molecular distribution and isotopic composition of chondritic organic compounds is central in assessing both their formation chemistry and synthetic relationships.

Organic carbon↗

NASA NTRS2019

Organometallic Compounds as Carriers of Extraterrestrial Cyanide in Primitive Meteorites

Extraterrestrial delivery of cyanide may have been crucial for the origin of life on Earth since cyanide is involved in the abiotic synthesis of numerous organic compounds found in extant life; however, little is known about the abundance and species of cyanide present in meteorites. Here, we report cyanide abundance in a set of CM chondrites ranging from 50 ± 1 to 2472 ± 38 nmol·g1, which relates to the degree of aqueous alteration of the meteorite and indicates that parent body processing inuenced cyanide abundance. Analysis of the Lewis Cliff 85311 meteorite shows that its releasable cyanide is primarily in the form of [FeII (CN)5(CO)]3 and [FeII(CN)4(CO)2]2-. Meteoritic delivery of iron cyanocarbonyl complexes to early Earth likely provided an important point source of free cyanide. Iron cyanocarbonyl complexes may have served as precursors to the unusual FeII(CN)(CO) moieties that form the catalytic centers of hydrogenases, which are thought to be among the earliest enzymes.

cyanide↗

NASA NTRS1985

Strat-trop exchange

Exchange between the stratosphere and troposphere is important to the chemical composition of both regions. The export of ozone from the stratosphere provides the troposphere with a means of initiating photochemistry. The precursor molecules originating from the planetary surface provide the stratosphere with its chemical feedstock from which the ozone-controlling HO(x), NO(x), and Cl(x) photochemistries are driven. The tropopause is defined both statistically and in a local, synoptic sense by the value P(sub theta) = .000016 K sq m/kg/s, taken from an objective analysis of 8 years of zonal, temporal mean cross sections of potential temperature, wind and potential vorticity.

Tuck, A. F.↗

NASA NTRS2012

First Detection of Krypton and Xenon in a White Dwarf

We report on the first detection of the noble gases krypton (Z = 36) and xenon (54) in a white dwarf. About 20 KrVI-VII and Xe VI-VII lines were discovered in the ultraviolet spectrum of the hot DO-type white dwarf RE 0503-289. The observations, performed with the Far Ultraviolet Spectroscopic Explorer, also reveal highly ionized photospheric lines from other trans-iron group elements, namely Ga (31), Ge (32), As (33), Se (34), Mo (42), Sn (50), Te (52), and I (53), from which gallium and molybdenum are new discoveries in white dwarfs, too. For Kr and Xe, we performed an NLTE analysis and derived mass fractions of log Kr = -4.3 plus or minus 0.5 and log Xe = -4.2 plus or minus 0.6, corresponding to an enrichment by factors of 450 and 3800, respectively, relative to the Sun. The origin of the large overabundances is unclear. We discuss the roles of neutron-capture nucleosynthesis in the-precursor star and radiation-driven diffusion. It is possible that diffusion is insignificant and thaI the observed metal abundances constrain the evolutionary history of the star. Its hydrogen deficiency may be the consequence of a late helium-shell nash or a binary white dwarf merger.

Werner, Klaus↗

NASA NTRS2020

First Detections of Dichlorobenzene Isomers and Trichloromethylpropane from Organic Matter Indigenous to Mars Mudstone in Gale Crater, Mars: Results from the Sample Analysis at Mars Instrument Onboard the Curiosity Rover

Chromatographic analysis of the Cumberland mudstone in Gale crater by the Sample Analysis at Mars (SAM) instrument revealed the detection of two to three isomers of dichlorobenzene. Their individual concentrations were estimated to be in the 0.5–17 ppbw range relative to the sample mass. We also report the first detection of trichloromethylpropane and the confirmation of the detection of chlorobenzene previously reported. Supporting laboratory experiments excluded the SAM internal background as the source of those compounds, thus confirming the organic carbon and chlorine of the newly detected chlorohydrocarbons are indigenous to the mudstone sample. Laboratory experiments also demonstrated that the chlorohydrocarbons were mainly produced from chemical reactions occurring in the SAM ovens between organic molecules and oxychlorines contained in the sample. The results we obtained show that meteoritic organics and tested chemical species (a polycyclic aromatic hydrocarbon, an amino acid, and a carboxylic acid) were plausible organic precursors of the chlorinated aromatic molecules detected with SAM, thus suggesting that they could be among the organic molecules present in the mudstone. Results from this study coupled with previously reported detections of chlorinated aromatics (<300 ppbw) indigenous to the same mudstone highlight that organics can be preserved from the harsh surface conditions even at shallow depth. The detection of new chlorohydrocarbons with SAM confirms that organic molecules should have been available in an environment favorable to life forms, strengthening the habitability aspect of Gale crater. Key Words: Mars—Chlorinated organic molecules—In situ measurements—Sample Analysis at Mars— Mudstone—Gale crater. Astrobiology 20, 292–306.

Szopa, Cyril↗

NASA NTRS1986

Analysis of rainfall over northern Peru during El Nino: A PCDS application

In an examination of GOES satellite data during the 1982 through 1983 El Nino period, the appearance of lee wave cloud patterns was revealed. A correlation was hypothesized relating an anomalous easterly flow across the Andes with the appearance of these wave patterns and with the subsequent onset of intense rainfall. The cloud patterns are belived to be associated with the El Nino period and could be viewed as precursors to significant changes in weather patterns. The ultimate goal of the researchers will be the ability to predict occurrences of rainstorms associated with the appearance of lee waves and related cloud patterns as harbingers of destruction caused by flooding, huaycos, and other catastrophic consequences of heavy and abnormal rainfall. Rainfall data from about 70 stations in northern Peru from 1980 through 1984 were formatted to be utilized within the Pilot Climate Data System (PCDS). This time period includes the 1982 through 1983 El Nino period. As an example of the approach, a well-pronounced lee wave pattern was shown from a GOES satellite image of April 4, 1983. The ground truth data were then displayed via the PCDS to graphically demonstrate the increase in intensity and areal distribution of rainfall in the northern Peruvian area in the next 4 to 5 days.

Goldberg, R.↗

NASA NTRSDate not supplied

First Optical Constants from 0.4 to 1.6 µm of Titan Aerosol Analogs Produced in the NASA Ames COSmIC Facility and Their Use in a New Analysis of Cassini VIMS Observations

We have determined the real and imaginary refractive indices (n and k, respectively), from the visible to the near infrared (0.4 to 1.6 μm), of five laboratory-generated organic refractory materials produced from gas-phase chemistry with the NASA Ames COSmIC facility. The solid samples were produced using a plasma discharge in the stream of a 200-K supersonic jet-cooled expansion of different gas mixtures to study the impact of the molecular precursors on the solid sample optical properties. Three samples were produced from N2:CH4 (95:5) gas mixtures using three different high voltages (700V, 800V and 1000V) to vary the energy in the plasma discharge. One sample was produced from a N2:CH4:C2H2 (94:5:5:0.5) gas mixture, with a high voltage of 1000 V. The fifth sample was produced in an Ar:CH4 (95:5) gas mixture with a high voltage of 1000 V to produce a nitrogen-free hydrocarbon sample. The optical constants, n and k, of these five samples were determined using spectral reflectance measurements. They appear to be positively correlated with the nitrogen content in the solid sample, i.e., a sample with larger nitrogen content exhibits higher n and k values. We have used these refractive indices as input parameters in a radiative transfer model to analyze Cassini Visible Infrared Mapping Spectrometer (VIMS) observations of Titan’s atmosphere. The results show that using the tholin samples with higher n and k values (higher nitrogen content) provides a better fit to the observational data than using the samples with lower n and k values (lower nitrogen content). The Titan tholins with higher nitrogen content therefore appear to be more representative of the Titan aerosols observed by VIMS.

Titan Aerosol Analogs↗

NASA NTRS2001

Modeling of Multi-Tube Pulse Detonation Engine Operation

The present paper explores some preliminary issues concerning the operational characteristics of multiple-tube pulsed detonation engines (PDEs). The study is based on a two-dimensional analysis of the first-pulse operation of two detonation tubes exhausting through a common nozzle. Computations are first performed to assess isolated tube behavior followed by results for multi-tube flow phenomena. The computations are based on an eight-species, finite-rate transient flow-field model. The results serve as an important precursor to understanding appropriate propellant fill procedures and shock wave propagation in multi-tube, multi-dimensional simulations. Differences in behavior between single and multi-tube PDE models are discussed, The influence of multi-tube geometry and the preferred times for injecting the fresh propellant mixture during multi-tube PDE operation are studied.

Ebrahimi, Houshang B.↗

NASA NTRS2009

NASA Manned Launch Vehicle Lightning Protection Development

Historically, the National Aeronautics and Space Administration (NASA) relied heavily on lightning avoidance to protect launch vehicles and crew from lightning effects. As NASA transitions from the Space Shuttle to the new Constellation family of launch vehicles and spacecraft, NASA engineers are imposing design and construction standards on the spacecraft and launch vehicles to withstand both the direct and indirect effects of lightning. A review of current Space Shuttle lightning constraints and protection methodology will be presented, as well as a historical review of Space Shuttle lightning requirements and design. The Space Shuttle lightning requirements document, NSTS 07636, Lightning Protection, Test and Analysis Requirements, (originally published as document number JSC 07636, Lightning Protection Criteria Document) was developed in response to the Apollo 12 lightning event and other experiences with NASA and the Department of Defense launch vehicles. This document defined the lightning environment, vehicle protection requirements, and design guidelines for meeting the requirements. The criteria developed in JSC 07636 were a precursor to the Society of Automotive Engineers (SAE) lightning standards. These SAE standards, along with Radio Technical Commission for Aeronautics (RTCA) DO-160, Environmental Conditions and Test Procedures for Airborne Equipment, are the basis for the current Constellation lightning design requirements. The development and derivation of these requirements will be presented. As budget and schedule constraints hampered lightning protection design and verification efforts, the Space Shuttle elements waived the design requirements and relied on lightning avoidance in the form of launch commit criteria (LCC) constraints and a catenary wire system for lightning protection at the launch pads. A better understanding of the lightning environment has highlighted the vulnerability of the protection schemes and associated risk to the vehicle, which has resulted in lost launch opportunities and increased expenditures in manpower to assess Space Shuttle vehicle health and safety after lightning events at the launch pad. Because of high-percentage launch availability and long-term on-pad requirements, LCC constraints are no longer considered feasible. The Constellation vehicles must be designed to withstand direct and indirect effects of lightning. A review of the vehicle design and potential concerns will be presented as well as the new catenary lightning protection system for the launch pad. This system is required to protect the Constellation vehicles during launch processing when vehicle lightning effects protection might be compromised by such items as umbilical connections and open access hatches.

McCollum, Matthew B.↗

NASA NTRS2024

Electrostatic Waves and Electron Holes in Simulations of Low-Mach Quasi-Perpendicular Shocks

Collisionless low Mach number shocks are abundant in astrophysical and space plasma environments, exhibiting complex wave activity and wave-particle interactions. In this paper, we present 2D Particle in-Cell (PIC) simulations of quasi-perpendicular nonrelativistic (vsh ≈ (5500−22000) km/s) low Mach number shocks, with a specific focus on studying electrostatic waves in the shock ramp and the precursor regions. In these shocks, an ion-scale oblique whistler wave creates a configuration with two hot counter streaming electron beams, which drive unstable electron acoustic waves (EAWs) that can turn into electrostatic solitary waves (ESWs) at the late stage of their evolution. By conducting simulations with periodic boundaries, we show that EAW properties agree with linear dispersion analysis. The characteristics of ESWs in shock simulations, including their wavelength and amplitude, depend on the shock velocity. When extrapolated to shocks with realistic velocities (vsh ≈ 300 km/s), the ESW wavelength is reduced to one tenth of the electron skin depth and the ESW amplitude is anticipated to surpass that of the quasi-static electric field by more than a factor of 100. These theoretical predictions may explain a discrepancy, between PIC and satellite measurements, in the relative amplitude of high and low-frequency electric field fluctuations.

Plasma astrophysics↗

NASA NTRS1978

The 1977 surface ozone study of eastern Virginia

Data were collected by primarily twelve ground stations positioned throughout the eastern shore - tidewater area of Virginia and North Carolina. From an analysis of the ozone and wind data, certain trends were found such as the existence of a bias in ozone concentrations between stations and a linear correlation between average ozone concentration and latitude. In addition, higher ozone levels were found with surface winds from certain preferred directions at the various sites. The results, however, do not substantiate ozone or ozone precursor transport.

Williams, M. E.↗

NASA NTRS2020

Ozone Production in the Soberanes Smoke Haze: Implications for Air Quality in the San Joaquin Valley During the California Baseline Ozone Transport Study

The Soberanes Fire burned 132,127 acres along the central California coast between July 22 and October 12, 2016, generating dense smoke and a variety of gaseous compounds that drifted eastward into the San Joaquin Valley Air Basin (SJVAB), an ‘extreme’ non‐attainment area for ozone (O3). These gases included nitrogen oxides (NOx) and volatile organic compounds (VOC), the photochemical precursors of O3. The fire started during the California Baseline Ozone Transport Study (CABOTS), a field campaign that brought aircraft, surface, and remote sensing measurements of O3 and related species to central California. In this paper, we use the CABOTS measurements to assess the impact of the Soberanes Fire on ozone and particulate air quality in the SJVAB. We focus our analysis on July 27 ‐ August 2 when the smoke haze was heaviest and the highest O3 concentrations in the SJVAB during 2016 were recorded. Our analyses suggest that while 40 to 60 ppbv of fire‐generated O3 was transported to the eastern SJVAB in the 1‐3 km altitude range, relatively little smoke or fire‐generated O3 reached the surface in the Visalia area.

Andrew O. Langford↗

NASA NTRSDate not supplied

Hot Structure Concepts and Materials for Space Exploration Project

Hot structures are multifunctional material systems that integrate the functions of thermal protection systems (TPS) and primary structure to increase mass efficiency in aerospace vehicles. The goal of this project was to improve our capabilities for developing lightweight, reusable, and reliable hot structures concepts to enable advanced space exploration missions. Specifically, current hot structure carbon/carbon (C/C) composite material systems have low interlaminar strength, which can lead to material failures at low load levels, and large material property variability in as-fabricated parts. Two parallel paths were followed to address these shortcomings. First, analysis models were developed to identify the conditions under which excessive interlaminar stresses occur and to evaluate the potential of stitching the C/C laminae to improve the interlaminar thermal-structural response. This effort included the development of high-fidelity, fracture-based thermal-structural finite element analysis models to evaluate critical features needed to produce efficient hot structure concepts. The second path focused on developing atomistic and mesoscale simulation tools to model the fabrication process in an effort to reduce the time and cost of production while improving the quality of the resulting parts. Aspects of the process currently being investigated include the infusion of the matrix precursor into the fiber preform, the cure of the precursor molecules into their polymeric form, and the carbonization and graphitization of the polymer to form the carbon matrix material. Results of the 6-month study are presented herein.

thermal↗

NASA NTRS1996

Interaction of Light and Ethylene on Stem Gravitropism

The major objective of this study was to evaluate light-regulated ethylene production during gravitropic bending in etiolated pea stems. Previous investigations indicated that ethylene production increases after gravistimulation and is associated with the later (counter-reactive) phase of bending. Additionally, changes in the counter-reaction and locus of curvature during gravitropism are greatly influenced by red light and ethylene production. Ethylene production may be regulated by the levels of available precursor (1-aminocyclopropane-l-carboxylic acid, ACC) via its synthesis, conjugation to malonyl-ACC or glutamyl-ACC, or oxidation to ethylene. The regulation of ethylene production by quantifying ACC and conjugated ACC levels in gravistimulated pea stemswas examined. Also measured was the changes in protein and enzyme activity associated with gravitropic curvature by electrophoretic and spectrophotometric techniques. An image analysis system was used to visualize and quantify enzymatic activity and transcriptional products in gravistimulated and red-light treated etiolated pea stem tissues.

Harrison, Marcia A.↗

NASA NTRS1972

Review of methods used in lunar organic analysis - Extraction and hydrolysis techniques.

Extraction, hydrolysis, and crushing procedures have been useful in discovering some of the carbon compounds in lunar samples from the Apollo 11 and 12 missions. The nonaqueous solvent system used mostly in lunar sample work has been benzene:methanol. Two methods of extraction have been sonication and Soxhlet extraction, sonication appearing to be the preferred method. Extraction of lunar samples with water and acid hydrolysis of the water extract has proved to be the best method in the search for amino acids or their precursors. Direct acid hydrolysis of lunar samples provided evidence for the presence of carbides or carbide-like materials in lunar surface samples. Hydrolysis of lunar samples with DF, DC1, and NaOD has shown that methane and ethane are indigenous to the moon.

Kvenvolden, K. A.↗

NASA NTRS2007

Saharan Air and Atlantic Tropical Cyclone Suppression From a Global Modeling Perspective

During summer 2006, the NASA African Monsoon Multidisciplinary Analysis (NAMMA) organized a field campaign in Africa called Special Observation Period (SOP-3), in which scientists in the field were involved in a number of surface network and aircraft measurements. One of the scientific goals of the campaign was to understand the nature and causes for tropical cyclogenesis originating out of African Easterly Waves (AEWs, westward propagating atmospheric disturbances sometimes associated with precursors of hurricanes), and the role that the Saharan Air Layer (SAL, a hot and dry air layer advecting large amounts of dust) can play in the formation or suppression of tropical cyclones. During the NAMMA campaign a high-resolution global model, the NASA GEOS-5, was operationally run by the NASA Global Modeling and Assimilation Office (GMAO) in support to the mission. The daily GEOS-5 forecasts were found to be very useful by decision-making scientists in the field as an aid to discriminate between developing and non-developing AEWs and plan the flight tracks. In the post-event analyses which were performed mostly by the Goddard Laboratory for Atmospheres, two events were highlighted: a non-developing AEW which appeared to have been suppressed by Saharan air, compared to a developing AEW which was the precursor of hurricane Helene. Both events were successfully predicted by the GEOS-5 during the real-time forecasts provided in support to the mission. In this work it is found that very steep moisture gradients and a strong thermal dipole, with relatively warm air in the mid-troposphere and cool air below, are associated with SAL in both the GEOS-5 forecasts and the NCEP analyses, even at -great distance- from the Sahara. The presence of these unusual thermodynamic features over the Atlantic Ocean, at several thousands of kilometers from the African coastline, is suggestive that SAL mixing is very minimal and that the model's capability of retaining the different properties of air masses during transport are important to represent effectively the role of dry air intrusions in the tropical circulation.

Reale, O.↗