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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 253 records · Page 14
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NASA NTRS1988

Photochemical modeling of the Antarctic stratosphere: Observational constraints from the airborne Antarctic ozone experiment and implications for ozone behavior

The rapid decrease in O3 column densities observed during Antarctic spring has been attributed to several chemical mechanisms involving nitrogen, bromine, or chlorine species, to dynamical mechanisms, or to a combination of the above. Chlorine-related theories, in particular, predict greatly elevated concentrations of ClO and OClO and suppressed abundances of NO2 below 22 km. The heterogeneous reactions and phase transitions proposed by these theories could also impact the concentrations of HCl, ClNO3 and HNO3 in this region. Observations of the above species have been carried out from the ground by the National Ozone Expedition (NOZE-I, 1986, and NOZE-II, 1987), and from aircrafts by the Airborne Antarctic Ozone Experiment (AAOE) during the austral spring of 1987. Observations of aerosol concentrations, size distribution and backscattering ratio from AAOE, and of aerosol extinction coefficients from the SAM-II satellite can also be used to deduce the altitude and temporal behavior of surfaces which catalyze heterogeneous mechanisms. All these observations provide important constraints on the photochemical processes suggested for the spring Antarctic stratosphere. Results are presented for the concentrations and time development of key trace gases in the Antarctic stratosphere, utilizing the AER photochemical model. This model includes complete gas-phase photochemistry, as well as heterogeneous reactions. Heterogeneous chemistry is parameterized in terms of surface concentrations of aerosols, collision frequencies between gas molecules and aerosol surfaces, concentrations of HCl/H2O in the frozen particles, and probability of reaction per collision (gamma). Values of gamma are taken from the latest laboratory measurements. The heterogeneous chemistry and phase transitions are assumed to occur between 12 and 22 km. The behavior of trace species at higher altitudes is calculated by the AER 2-D model without heterogeneous chemistry. Calculations are performed for solar illumination conditions typical of 60, 70, and 80 S, from July 15 to October 31.

Rodriguez, Jose M.↗
NASA NTRS1959

A Numerical Method for Obtaining Monoenergetic Neutron Flux Distributions and Transmissions in Multiple-Region Slabs

This method is investigated for semi-infinite multiple-slab configurations of arbitrary width, composition, and source distribution. Isotropic scattering in the laboratory system is assumed. Isotropic scattering implies that the fraction of neutrons scattered in the i(sup th) volume element or subregion that will make their next collision in the j(sup th) volume element or subregion is the same for all collisions. These so-called "transfer probabilities" between subregions are calculated and used to obtain successive-collision densities from which the flux and transmission probabilities directly follow. For a thick slab with little or no absorption, a successive-collisions technique proves impractical because an unreasonably large number of collisions must be followed in order to obtain the flux. Here the appropriate integral equation is converted into a set of linear simultaneous algebraic equations that are solved for the average total flux in each subregion. When ordinary diffusion theory applies with satisfactory precision in a portion of the multiple-slab configuration, the problem is solved by ordinary diffusion theory, but the flux is plotted only in the region of validity. The angular distribution of neutrons entering the remaining portion is determined from the known diffusion flux and the remaining region is solved by higher order theory. Several procedures for applying the numerical method are presented and discussed. To illustrate the calculational procedure, a symmetrical slab ia vacuum is worked by the numerical, Monte Carlo, and P(sub 3) spherical harmonics methods. In addition, an unsymmetrical double-slab problem is solved by the numerical and Monte Carlo methods. The numerical approach proved faster and more accurate in these examples. Adaptation of the method to anisotropic scattering in slabs is indicated, although no example is included in this paper.

Schneider, Harold↗
NASA NTRS1980

Semiclassical study of the quenching of excited-state fluorine atom by hydrogen molecule - Comparison between reactive and nonreactive processes

Semiclassical calculations are carried out for the quenching of excited-state fluorine atom by collinear collisions with hydrogen molecule. The overall quenching probability is the sum of two contributions: the reactive quenching probability associated with the formation of hydrogen fluoride and the nonreactive quenching probability leading to ground-state fluorine atom and hydrogen molecule. The reactive probability is greater in the threshold region of the collision energy, whereas the nonreactive probability dominates for energies above the threshold region.

Yuan, J.-M.↗
NASA NTRS1980

Spectroscopy and atomic physics of highly ionized Cr, Fe, and Ni for tokamak plasmas

The paper considers the spectroscopy and atomic physics for some highly ionized Cr, Fe, and Ni ions produced in tokamak plasmas. Forbidden and intersystem wavelengths for Cr and Ni ions are extrapolated and interpolated using the known wavelengths for Fe lines identified in solar-flare plasmas. Tables of transition probabilities for the B I, C I, N I, O I, and F I isoelectronic sequences are presented, and collision strengths and transition probabilities for Cr, Fe, and Ni ions of the Be I sequence are given. Similarities of tokamak and solar spectra are discussed, and it is shown how the atomic data presented may be used to determine ion abundances and electron densities in low-density plasmas.

Feldman, U.↗
NASA NTRS1993

Collisions of small Spacewatch asteroids with the Earth

The discovery, with the Spacewatch Telescope, of 8 Earth-approaching objects smaller than 100 m in diameter has been reported. I have calculated the probability and velocity of collision with Earth for each of these objects. Using a code we have successfully employed to model the Tunguska and Revelstoke atmospheric explosions, I have simulated the entry of these objects into Earth's atmosphere, assuming iron, stony, carbonaceous, and cometary compositions. The smallest of these objects, with tens to hundreds of kilotons of kinetic energy, pose a substantial threat at the surface only if they are iron objects. An object is taken to 'pose a substantial threat' if it either craters the ground, or explodes in the atmosphere with sufficient energy at low enough altitude to create an overpressure at the surface capable of felling trees or destroying buildings. Larger objects, with energies greater than about a megaton, devastate the surface regardless of whether they are of iron, stony, or carbonaceous composition. Iron objects crater the ground, whereas stony and carbonaceous objects explode in the atmosphere low enough to fell trees and damage buildings over thousands of square kilometers. Spacewatch objects, if presumed to be of carbonaceous composition, are as dangerous as their stony counterparts, as the former objects' lower yield strengths (and hence, higher explosion altitudes) are roughly compensated by their larger masses (as derived from their lower albedos for a given observed magnitude). Although comets are intrinsically less dangerous than asteroids, the 90 m diameter Spacewatch objects would devastate hundreds of square kilometers at the surface, even if cometary.

Chyba, C. F.↗
NASA NTRS1974

Orientational invariance of the rotational transition probability in the sudden approximation

Semiclassical collisions of an atom with a rigid-rotor molecule are examined in the sudden approximation. The rotational transition probability is shown to be invariant with respect to the choice of orientation for the molecular coordinate system; this fact contradicts recently reported results of a computer analysis. The present analysis may lead to an improved interpretation of recent molecular beam measurements.

Stallcop, J. R.↗
NASA NTRS1993

Models for direct Monte Carlo simulation of coupled vibration-dissociation

A new model for reactive collisions is developed within the framework of a particle method, which simulates coupled vibration-dissociation (CVD) behavior in high-temperature gases. The fundamental principles of particle simulation methods are introduced with particular attention given to the probability functions employed to select thermal and reactive collisions. Reaction probability functions are derived which favor vibrationally excited molecules as reaction candidates. The new models derived here are used to simulate CVD behavior during thermochemical relaxation of constant-volume O2 reservoirs, as well as the dissociation incubation behavior of postshock N2 flows for comparisons with previous models and experimental data.

Haas, Brian L.↗
NASA NTRS1978

On the possibility of negative activation energies in bimolecular reactions

The temperature dependence of the rate constants for model reacting systems was studied to understand some recent experimental measurements which imply the existence of negative activation energies. A collision theory model and classical trajectory calculations are used to demonstrate that the reaction probability can vary inversely with collision energy for bimolecular reactions occurring on attractive potential energy surfaces. However, this is not a sufficient condition to ensure that the rate constant has a negative temperature dependence. On the basis of these calculations, it seems unlikely that a true bimolecular reaction between neutral molecules will have a negative activation energy.

Jaffe, R. L.↗
NASA NTRS1983

Cometary impacts with the sun - Physical and dynamical considerations

Michels et al. (1982) observed the apparent impacting of the sun by a comet, and Sekanina (1982) showed that the comet, 1979XI, was probably a member of the Kreutz group of sun-grazing comets, although its perihelion of 0.35 solar radii was much smaller than the 1.2-1.9 solar radii common for this comet class. The perihelion change cannot be explained by planetary, stellar, or nongravitational perturbations. The most plausible explanation is collision with another body, probably a comet, at large heliocentric distance. The probability of such an event is, however, extremely small. The sublimation of the comet's nucleus before impact is discussed, and it is suggested that its ultimate destruction probably resulted from the shock of entry into the denser regions of the solar atmosphere, just above the photosphere.

Weissman, P. R.↗
NASA NTRS1984

Meteoroid capture into earth orbit by atmospheric drag

A probabilistic analysis, based on orbital mechanics, is performed to evaluate the chances of meteoroids entering into earth orbit and the potential population of such objects. The problem is addressed in terms of meteoroids on earth collision courses, slowed by atmosphere entry/exit, entering elliptical orbits with apogees above the atmosphere. The overall capture probability is derived by integrating the capture fraction dependence on velocity and size over the probability frequency distribution of the collision courses. Account is taken of eventual orbit decay, lunar infall and ejection after encounters with the moon. The results indicate that the probability that a natural 10-100 m diam object has achieved earth orbit is negligibly small.

Friedlander, A. L.↗
NASA NTRS1993

Excitation rate coefficients and line ratios for the optical and ultraviolet transitions in S II

New calculations are reported for electron excitation collision strengths, rate coefficients, transition probabilities, and line ratios for the astrophysically important optical and UV lines in S II. The collision strengths are calculated in the close coupling approximation using the R-matrix method. The present calculations are more extensive than previous ones, including all transitions among the 12 lowest LS terms and the corresponding 28 fine-structure levels in the collisional-radiative model for S II. While the present rate coefficients for electron impact excitation are within 10-30 percent of the previous values for the low-lying optical transitions employed as density diagnostics of H II regions and nebulae, the excitation rates for the UV transitions 4S super 0 sub 3/2 - 4Psub 1/2,3/2,5/2 differ significantly from earlier calculations, by up to factor of 2. We describe temperature and density sensitive flux ratios for a number of UV lines. The present UV results are likely to be of interest in a more accurate interpretation of S II emission from the Io plasma torus in the magnetosphere of Jupiter, as well as other UV sources observed from the IUE, ASTRO 1, and the HST.

Cai, Wei↗
NASA NTRS1979

Collisional evolution of asteroids - Populations, rotations, and velocities

The collisional evolution of various initial populations of asteroids is simulated numerically and compared with the present asteroid size-frequency distribution to find those populations which collisionally relax to the present belt. Both orbital and size distributions are treated, as well as the simultaneous evolution of two collisionally interacting populations with different physical properties. If the initial belt distribution was a power law, the initial belt population at the time when the present high-collision speed was established was probably only modestly larger than the present population. However, other distributions allow a more massive early belt. The rotational evolution due to collisions of asteroids with power-law distributions is also examined and compared with observations, leading to conclusions generally in agreement with those of size evolution. The high-collision speed in the present belt is likely due to Jupiter. Gravitational stirring by massive Jupiter-scattered planetesimals or secular resonances sweeping through the belt are the most probable mechanisms.

Davis, D. R.↗
NASA NTRS1972

Variance reduction in Monte Carlo analysis of rarefied gas diffusion

The present analysis uses the Monte Carlo method to solve the problem of rarefied diffusion between parallel walls. The diffusing molecules are evaporated or emitted from one of two parallel walls and diffused through another molecular species. The analysis treats the diffusing molecule as undergoing a Markov random walk and the local macroscopic properties are found as the expected value of the random variable, the random walk payoff. By biasing the transition probabilities and changing the collision payoffs the expected Markov walk payoff is retained but its variance is reduced so that the M. C. result has a much smaller error.

Perlmutter, M.↗
NASA NTRS1972

Variance reduction in Monte Carlo analysis of rarefied gas diffusion.

The problem of rarefied diffusion between parallel walls is solved using the Monte Carlo method. The diffusing molecules are evaporated or emitted from one of the two parallel walls and diffuse through another molecular species. The Monte Carlo analysis treats the diffusing molecule as undergoing a Markov random walk, and the local macroscopic properties are found as the expected value of the random variable, the random walk payoff. By biasing the transition probabilities and changing the collision payoffs, the expected Markov walk payoff is retained but its variance is reduced so that the Monte Carlo result has a much smaller error.

Perlmutter, M.↗
NASA NTRS1993

X-ray variability in V444 Cygni-Evidence for colliding winds

Phase-resolved ROSAT observations of the soft X-ray flux from V444 Cygni confirm the orbital dependence of the flux suggested by analysis of imaging proportional counter (IPC) observations. The X-ray behavior suggests that a region of X-ray emitting gas exists between the 2 stars, probably produced by a collision between the WR and O star winds.

Corcoran, M. F.↗
NASA NTRS2005

Experimental and analytical investigation of a modified ring cusp NSTAR engine

A series of experimental measurements on a modified laboratory NSTAR engine were used to validate a zero dimensional analytical discharge performance model of a ring cusp ion thruster. The model predicts the discharge performance of a ring cusp NSTAR thruster as a function the magnetic field configuration, thruster geometry, and throttle level. Analytical formalisms for electron and ion confinement are used to predict the ionization efficiency for a given thruster design. Explicit determination of discharge loss and volume averaged plasma parameters are also obtained. The model was used to predict the performance of the nominal and modified three and four ring cusp 30-cm ion thruster configurations operating at the full power (2.3 kW) NSTAR throttle level. Experimental measurements of the modified engine configuration discharge loss compare well with the predicted value for propellant utilizations from 80 to 95%. The theory, as validated by experiment, indicates that increasing the magnetic strength of the minimum closed reduces maxwellian electron diffusion and electrostatically confines the ion population and subsequent loss to the anode wall. The theory also indicates that increasing the cusp strength and minimizing the cusp area improves primary electron confinement increasing the probability of an ionization collision prior to loss at the cusp.

cathodes↗