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At least 253 records · Page 14

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NASA NTRSDate not supplied

Influence of evaporation rate and chamber pressure on the FUV reflectance and physical characteristics of aluminum films

Space telescopes for studying astrophysical phenomena from the far ultraviolet (FUV) to the near infrared (NIR) require durable mirror coatings with high and uniform reflectance over a very broad spectral region. While coatings for the optical and NIR region are well developed with proven performance, the FUV band presents significant challenges, particularly below 115 nm. Recent developments in physical vapor deposition (PVD) coating processes of aluminum mirrors that are protected with a metal-fluoride overcoat to prevent oxidation (such as LiF, MgF2, or AlF3) have improved reflectance in the FUV. While the emphasis in these studies has been placed on improving the deposition conditions of the metal-fluoride overcoats, less attention has been devoted to how deposition parameters (such as vacuum conditions or deposition rates) may affect the quality of the aluminum mirrors. This paper presents characterization of Al+MgF2 coupons made by flash evaporation of aluminum followed by resistive evaporation of MgF2. Samples were manufactured under a variety of processing conditions and the relationship between processing variables and mirror FUV reflectivity is analyzed. Performance characterization was based on the measured near-normal reflectance in the FUV (90-180 nm), and normal-incidence transmittance in the visible was done to analyze the possible presence of pinholes in the mirror. We demonstrated pinhole-free Al/MgF2 mirrors deposited at room temperature with a reflectivity of 0.91 at 122 nm wavelength. This reflectivity enhancement was achieved solely through parameter optimization.

Manuel A. Quijada↗

NASA NTRSDate not supplied

Development of the GeoNEX Level 2G Products: Exploiting the Diurnal Variability of TOA Reflectance in Atmospheric Correction

This study develops a new atmospheric correction algorithm to generate the Level 2G products, in particular the gap-filled Surface Reflectance at 10-minute time steps, for the Geostationary-NASA Earth Exchange (GeoNEX) project. The algorithm is based on the MODIS MAIAC (Multi-Angle Implementation of Atmospheric Correction) framework but with significant modifications to exploit angular/temporal information from the diurnal variability of the GeoNEX L1G TOA (Top-of-Atmosphere) reflectance. The algorithm starts by evaluating the roughness/smoothness of the diurnal time series of the TOA reflectance. Because rapid changes in TOA reflectance are generally caused by passing clouds or shadows, rough segments of the time series are automatically filtered out while the smooth segments are further tested for brightness and temperature to identify clear-sky and snow-free observations. Next the algorithm runs the MAIAC RTM (Radiative Transfer Model) to retrieve the Ross-Thick-Li-Sparse (RTLS) BRDF model parameters and the daily-mean atmospheric optical depth (AOD) that allow the RTM to optimally simulate the observed diurnal variability of clear-sky TOA reflectance. Once the initial RTLS parameters are retrieved after the algorithm’s burn-in period, they are used as the prior information to predict the AOD level for the next days, while the subsequent clear-sky observations are used to make necessary adjustments to the RTLS parameters in an continuous fashion. This “prediction-analysis” cycle is then iterated to process the full time series of the L1G data, skipping only total-cloudy days or when surface snow is detected. We tested the algorithm over a list of selected AERONET sites. The retrieved results (the daily mean AOD and the RTLS parameters) reasonably agree with the ground-based measurements. Importantly, the results indicate that the diurnal cycles of surface reflectance are continuous functions of the illumination-view geometry. Thus we can use the retrieved RTLS model to accurately fill in data gaps on partial cloudy days. Also, our algorithm is totally independent from the traditional approaches based on the use of spectral band ratios between the shortwave infrared (e.g., 2.2µm) and the visible (e.g., 0.47µm and 0.64µm) bands. Our results thus demonstrate that the high-frequent diurnal geostationary observations contain unique information that helps us improve atmospheric correction of remote sensing data.

GeoNEX↗

NASA NTRSDate not supplied

Development of a Global Reference Surface Reflectance and BRDF Datasets from Geostationary Satellite Observations and AERONET Measurements

Surface reflectances and their dependency on illumination-view geometries (i.e., BRDF) are the foundation of many high-level satellite products for land and water monitoring. Yet it is difficult to evaluate the quality of satellite-based surface reflectances with ground-based measurements due to the spatial scale differences. In order to fill the gap, here we develop a reference dataset of surface reflectance and BRDF at the global AERONET sites with data streams from operational geostationary sensors including Himawari 8/9 AHI, GK-2A AMI, and GOES 16/17 ABI. Taking the top-of-atmosphere (TOA) reflectance and the site measured atmospheric aerosol optical depth (AOD) as the main inputs, we apply the GeoNEX-AC algorithm to performance accurate atmospheric correction and derive 10-minute surface reflectance and daily Ross-Thick-Li-Sparse (RTLS) BRDF parameters at AERONET sites where coincident AOD measurements and TOA observations are available from 2016 (for Himawari) or 2018 (for GOES) onwards. The algorithm ensures that the retrieved surface BRDF parameters, along with the site-measured AOD, allow the atmospheric radiative transfer model, SHARM, accurately simulate the observed TOA reflectance at diurnal and longer time scales. They are our best estimates of the surface optical properties and thus can serve as the “reference” to evaluate the performance of operational atmospheric correction algorithms (where AOD is assumed unknown and needs to be retrieved). The reference BRDF also allow us to evaluate the spectral band ratios between the SWIR (e.g., 2200 nm) and the visible (e.g., 650 nm) regions, which are commonly used in operational atmospheric correction algorithms. Finally, we demonstrate that the reference dataset can be used to develop potential data synergies between different GEO satellites as well as GEO-LEO sensors.

Weile Wang↗

DOE OSTI2019

Optical fiber connector ferrule assembly having dual reflective surfaces for beam expansion and expanded beam connector incorporating same

An expanded beam ferrule includes a first ferrule halve having first reflective surfaces and a second ferrule halve having second reflective surfaces, which together retain optical fibers. The pair of reflective surfaces output collimated light parallel to the mid-plane of the ferrule. An external sleeve aligns the external surface of two similar ferrules, with corresponding second reflective surfaces of the ferrules facing each other. Output light from an optical fiber held in one ferrule is bent twice by the pair of reflective surfaces, with beam divergence after the first bent, and collimation after the second bent. The collimated light is transmitted to the facing second reflective surface in a facing second ferrule aligned by the sleeve, which is subject to optical reshaping in reverse to that undertaken in the first ferrule, so as to converge and focus light to input to the optical fiber held in the other ferrule.

Li, Shuhe↗

DOE OSTI2020

Optical fiber connector ferrule assembly having dual reflective surfaces for beam expansion and expanded beam connector incorporating same

42 ENGINEERING↗

DOE OSTI2020

Reflectance of Silicon Photomultipliers at Vacuum Ultraviolet Wavelengths

Characterization of the vacuum ultraviolet (VUV) reflectance of silicon photomultipliers (SiPMs) is important for large-scale SiPM-based photodetector systems. In this work, we report the angular dependence of the specular reflectance in vacuum of SiPMs manufactured by Fondazionc Bruno Kessler (FBK) and Hamamatsu Photonics K.K. (HPK) over wavelengths ranging from 120 to 280 nm. Refractive index and extinction coefficient of the thin silicon-dioxide film deposited on the surface of the FBK SiPMs are derived from reflectance data of an FBK silicon wafer with the same deposited oxide film as SiPMs. The diffuse reflectance of SiPMs is also measured at 193 nm. We use the VUV spectral dependence of the optical constants to predict the reflectance of the FBK silicon wafer and FBK SiPMs in liquid xenon.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

DOE OSTI2020

An Unmanned Aerial System (UAS) for concurrent measurements of solar-induced chlorophyll fluorescence and hyperspectral reflectance toward improving crop monitoring

Unmanned aerial system (UAS)-based remote sensing can provide high spatial- and temporal-resolution crop monitoring for precision management. Existing crop monitoring UAS primarily use conventional techniques such as multi-spectral broadband vegetation indices (VIs) to track canopy structure/biomass. Recently developed lightweight hyperspectral sensors can track crop physiology and performance via complementary signals such as solar-induced chlorophyll fluorescence (SIF) and photochemical reflectance index (PRI) that can be derived from hyperspectral reflectance. However, few existing UAS can acquire high-quality SIF and hyperspectral reflectance. Here, we designed a novel UAS that simultaneously captures far-red SIF and hyperspectral reflectance, using a single bifurcated fiber and motorized arm to measure downwelling and upwelling irradiance. The UAS was tested over (1) a heterogeneous corn field with spatially varying crop yield potential and (2) a set of soybean and corn plots under differing nutrient treatments. Our UAS can maintain stability under low-to-moderate winds (2–3 m/s) with <0.4 m geolocation accuracy, <0.1 m altitude drift, and <1.5° error of the fiber optic from nadir position during scanning. Weekly seasonal campaigns reveal that SIF outperforms conventional VIs such as the normalized difference vegetation index (NDVI) for distinguishing plots with different crop yield potential, especially after canopy closure when NDVI tends to saturate. The UAS can capture the diurnal dynamics of SIF and PRI for both corn and soybean. At the seasonal scale, SIF acquired from the UAS correlates well with that from a fixed SIF tower system ( R 2 = 0.81), which measured the same target albeit with different footprints, demonstrating the capability of UAS in characterizing the seasonal progression of crop activity. In conclusion, our newly developed UAS provides high-quality SIF and hyperspectral reflectance, facilitating mechanistic understanding of the physiological control on photosynthesis dynamics. Our findings also imply that this UAS could enable extension of fixed tower-based systems to monitor multiple targets from diurnal to seasonal scales and improve monitoring of heterogeneous fields.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2022

Fluorescence strobo-stereoscopy for specular reflection-suppressed full field of view imaging

This report introduces fluorescence strobo-stereoscopy (FSS) to suppress strong specular reflection and enable the full field of view (FFOV) 3D surface imaging while the part is rotating. Specular reflection off the target surface significantly degrades the image quality and becomes critical for highly reflective surface measurements. In FSS, the fluorescent dye-doped fluid applied on the machined surface is excited upon incident ultra-violet light and becomes a new light source by Stokes' Law. Thus, specular reflection off of smooth surface can be suppressed by separating the fluorescent light from the excitation light. The developed FSS comprises a pair of imaging cameras, spatial filters, and an excitation light source. As a result, FSS effectively rejected the specular reflection and improved the FFOV 3D surface image quality of the machined part by enhancing contrast in the rotating target surface. Such enhancements in 3D imaging allowed to identify manufacturing tolerance of the part and to detect the surface features. The axial and lateral accuracy errors of FSS were 2.3% and 1.4% with the target size of 4.07 mm and 0.215 mm, respectively. A whole view reconstruction of the cylindrical target sample was performed, and the corresponding cylindricity and diameter deviation were assessed. The fluid media effect and the target surface quality effect were discussed.

3D surface imaging↗

DOE OSTI2023

Stationary Bragg reflection of laser light in inhomogeneous absorbing plasmas inside inertial confinement fusion Hohlraums

Laser-produced plasma in inertial confinement fusion (ICF) Hohlraums are marked with density non-uniformity whose length scale can go down to micrometers. This scale is of the order of the laser wavelength. The WKB approximation, which is classically used in radiation-hydrodynamic codes to compute the laser trajectory, cannot correctly take into account such small-scale inhomogeneity of the plasma. Going beyond this approximation, we predict a novel mechanism for the laser reflection. Here we show that an electromagnetic plane wave with wave number k resonates with the k B =2 k Fourier component of a multimode perturbation of the background density and generates a reflected wave. It is the first time that this reflection is considered for stationary inhomogeneous ICF plasmas, and the energy absorption is taken into account. This mechanism, which is a form of Bragg reflection, can occur away from the critical surface and generate a drift of the location of the laser absorption. Furthermore, this absorption will be periodically modulated with a k B wave number. The stationary Bragg reflection can explain ongoing discrepancies between experimental and numerical data about laser trajectory and absorption in ICF Hohlraums.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

NASA NTRS2011

Daytime Water Detection Based on Sky Reflections

A water body s surface can be modeled as a horizontal mirror. Water detection based on sky reflections and color variation are complementary. A reflection coefficient model suggests sky reflections dominate the color of water at ranges > 12 meters. Water detection based on sky reflections: (1) geometrically locates the pixel in the sky that is reflecting on a candidate water pixel on the ground (2) predicts if the ground pixel is water based on color similarity and local terrain features. Water detection has been integrated on XUVs.

water detections↗

NASA NTRS2018

A Cloud Algorithm Based on the O2-O2 477 nm Absorption Band Featuring an Advanced Spectral Fitting Method and the Use of Surface Geometry-Dependent Lambertian-Equivalent Reflectivity

We discuss a new cloud algorithm that retrieves an effective cloud pressure, also known as cloud optical centroid pressure (OCP), from oxygen dimer (O2-O2) absorption at 477nm after determining an effective cloud fraction (ECF) at 466nm, a wavelength not significantly affected by trace-gas absorption and rotational Raman scattering. The retrieved cloud products are intended for use as inputs to the operational nitrogen dioxide (NO2) retrieval algorithm for the Ozone Monitoring Instrument (OMI) flying on the Aura satellite. The cloud algorithm uses temperature-dependent O2-O2 cross sections and incorporates flexible spectral fitting techniques that account for specifics of the surface reflectivity. The fitting procedure derives O2-O2 slant column densities (SCDs) from radiances after O3, NO2, and H2O absorption features have been removed based on estimates of the amounts of these species from independent OMI algorithms. The cloud algorithm is based on the frequently used mixed Lambertian-equivalent reflectivity (MLER) concept. A geometry-dependent Lambertian-equivalent reflectivity (GLER), which is a proxy of surface bidirectional reflectance, is used for the ground reflectivity in our implementation of the MLER approach. The OCP is derived from a match of the measured O2-O2 SCD to that calculated with the MLER method. Temperature profiles needed for computation of vertical column densities are taken from the Global Modeling Initiative (GMI) model. We investigate the effect of using GLER instead of climatological LER on the retrieved ECF and OCP. For evaluation purposes, the retrieved ECFs and OCPs are compared with those from the operational OMI cloud product, which is also based on the same O2-O2 absorption band. Impacts of the application of the newly developed cloud algorithm to the OMI NO2 retrieval are discussed.

cloud fraction and pressure↗

NASA NTRS2020

REFLECTANCE PRI DOES NOT EQUAL TRANSMITTANCE PRI

Starting from leaf reflectance and transmittance measurements, we calculated two substantially different values of the Photochemical Reflectance Index (PRI) for each of 22 corn leaves having leaf chlorophyll concentrations ranging from high to low. Leaf reflectance and transmittance were measured simultaneously, precluding changes in leaf light use efficiency (LEU) between measurements. We propose the proportion of leaves reflecting v. transmitting direct beam sunlight toward a canopy reflectance sensor is a potential source of variability in estimates of canopy bidirectional PRI.

Reflectance↗

NASA NTRS2020

Neural Network Reflectance Prediction Model for Both Open Ocean and Coastal Waters

Remote sensing of global ocean color is a valuable tool for understanding the ecology and biogeochemistry of the worlds oceans, and provides critical input to our knowledge of the global carbon cycle and the impacts of climate change. Ocean polarized reflectance contains information about the constituents of the upper ocean euphotic zone, such as colored dissolved organic matter (CDOM), sediments, phytoplankton, and pollutants. In order to retrieve the information on these constituents, remote sensing algorithms typically rely on radiative transfer models to interpret water color or remote-sensing reflectance; however, this can be resource-prohibitive for operational use due to the extensive CPU time involved in radiative transfer solutions. In this work, we report a fast model based on machine learning techniques, called Neural Network Reflectance Prediction Model (NNRPM), which can be used to predict ocean bidirectional polarized reflectance given inherent optical properties of ocean waters. This supervised model is trained using a large volume of data derived from radiative transfer simulations for coupled atmosphere and ocean systems using the successive order of scattering technique (SOS-CAOS). The performance of the model is validated against another large independent test dataset generated from SOS-CAOS. The model is able to predict both polarized and unpolarized reflectances with an absolute error (AE) less than 0.004 for 99% of test cases. We have also shown that the degree of linear polarization (DoLP) for unpolarized incident light can be predicted with an AE less than 0.002 for 99% of test cases. In general, the simulation time of SOS-CAOS depends on optical depth, and required accuracy. When comparing the average speeds of the NNRPM against the SOS-CAOS model for the same parameters, we see that the NNRPM is able to predict the Ocean BRDF 6000 times faster than SOS-CAOS. Both ultraviolet and visible wavelengths are included in the model to help differentiate between dissolved organic material and chlorophyll in the study of the open ocean and the coastal zone. The incorporation of this model into the retrieval algorithm will make the retrieval process more efficient, and thus applicable for operational use with global satellite observations.

radiative transfer↗

NASA NTRS2012

Assessment of a Bidirectional Reflectance Distribution Correction of Above-Water and Satellite Water-Leaving Radiance in Coastal Waters

Water-leaving radiances, retrieved from in situ or satellite measurements, need to be corrected for the bidirectional properties of the measured light in order to standardize the data and make them comparable with each other. The current operational algorithm for the correction of bidirectional effects from the satellite ocean color data is optimized for typical oceanic waters. However, versions of bidirectional reflectance correction algorithms specifically tuned for typical coastal waters and other case 2 conditions are particularly needed to improve the overall quality of those data. In order to analyze the bidirectional reflectance distribution function (BRDF) of case 2 waters, a dataset of typical remote sensing reflectances was generated through radiative transfer simulations for a large range of viewing and illumination geometries. Based on this simulated dataset, a case 2 water focused remote sensing reflectance model is proposed to correct above-water and satellite water-leaving radiance data for bidirectional effects. The proposed model is first validated with a one year time series of in situ above-water measurements acquired by collocated multispectral and hyperspectral radiometers, which have different viewing geometries installed at the Long Island Sound Coastal Observatory (LISCO). Match-ups and intercomparisons performed on these concurrent measurements show that the proposed algorithm outperforms the algorithm currently in use at all wavelengths, with average improvement of 2.4% over the spectral range. LISCO's time series data have also been used to evaluate improvements in match-up comparisons of Moderate Resolution Imaging Spectroradiometer satellite data when the proposed BRDF correction is used in lieu of the current algorithm. It is shown that the discrepancies between coincident in-situ sea-based and satellite data decreased by 3.15% with the use of the proposed algorithm.

LISCO(LONG ISLAND SOUND COASTAL OBSERVATORY)↗

DOE OSTI2021

Structure of Molten Alkali Chlorides at Charged Interfaces and the Prediction and Interpretation of Their X-ray Reflectivity

The fundamental properties of molten salts have been the subject of research that spans a century. Yet, in the past few years, there has been an unprecedented surge in interest for these systems in the bulk and under confinement by walls and interfaces including under applied potentials. This is driven by the prospect of exciting and very practical energy technologies, including those in the solar and nuclear fields. This article sets to answer two simple but fundamental questions. How does the liquid structure of alkali chlorides change at a real interface when it is charged? Also, how would such changes on the liquid side of the interface be detected in X-ray reflectivity experiments? We use an interface mimicking conductive diamond, which because of its lattice spacing, is an excellent choice for reflectivity experiments. The reason for our interest in X-ray reflectivity is that, as opposed to electrochemical measurements alone, this is likely the only technique in which atomic level information at the liquid side of the interface can be gained under the extreme temperature environments of molten salts. As it will become apparent, the interpretation of reflectivity results in terms of atomic positions is complex when multiple species with different X-ray contrasts on the liquid side are considered. A theoretical scheme termed “the peaks and antipeaks analysis of reflectivity” originally introduced in our prior work (J. Phys. Chem. C2019, 123 (8), 4914–4925) is expanded to interpret the structural changes at the interface as a function of applied electrical bias.

36 MATERIALS SCIENCE↗

DOE OSTI2026

Interference-Limited Absorption in Dense Molecular Nanolayers Near Reflecting Surfaces

We investigate linear resonant absorption by a dense ensemble of molecules confined to a sub-wavelength layer in two geometries: (i) a free-standing film in a homogeneous space and (ii) the same film placed at a controlled distance from a reflecting surface. In both cases, increasing the effective light–matter coupling (via molecular density/oscillator strength) produces a nonmonotonic response: absorption rises to an optimum and then decreases as the film becomes increasingly radiatively bright and reflective. Finite-difference time-domain simulations and analytical transfer-matrix calculations agree quantitatively and yield compact ridge conditions for the optimum. We interpret the trends using a scattering/port picture: the isolated film is a symmetric two-port system (reflection and transmission), which bounds single-sided resonant absorption to ≤50% in the ultrathin limit (reflecting transition saturation), whereas adding a mirror suppresses transmission and converts the structure into an effectively one-port absorber. In the mirror-backed geometry, interference can cancel reflection, and unity absorption is obtained at critical coupling, when radiative leakage is balanced by intrinsic molecular loss. These results clarify fundamental limits and design rules for collective absorption in dense molecular layers near dielectric or metallic boundaries.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2020

Stochastic Inversion of Gaussian Random Media Using Transverse Coherence Functions for Reflected Waves: Theory and Method

The transverse coherence functions (TCFs) of phase and amplitude fluctuations of a seismic wave are powerful to estimate the spatial distribution, length scales, and strength of random heterogeneities. However, TCFs have been formulated for transmitted waves only, not for reflected waves. In this paper, we derive reflection TCFs for Gaussian random media. Furthermore, we propose to invert for Gaussian random media using the reflection TCFs based on the grid search. We validate the new reflection TCF formulas using 2D finite-difference numerical experiments. The numerical example also illustrates the feasibility and efficiency of the inversion. The stochastic inversion using reflected waves can be used in both exploration and global seismology.

58 GEOSCIENCES↗

DOE OSTI2019

Effect of reflections on 2D tomographic reconstructions of filtered cameras and on interpreting spectroscopic measurements in the JET ITER-like wall divertor

Considering reflections from metallic wall surfaces in generation of tomographic reconstructions of the tangentially viewing, visible-range spectroscopic divertor cameras in JET has been observed to yield enhanced spatial accuracy and significant reduction of emission artifacts in experimentally resolved 2D line emission distributions. Neglection of reflections in the tomography process was found to lead to overestimation of the emission near the wall surfaces by up to a factor of 4, as well as to formation of bright emission artifacts between the main emission regions and the wall surfaces, comprising locally up to 50% of the emission. Mimicking divertor spectroscopy measurements by integrating the tomographic reconstructions along vertical lines-of-sight implies that reflections comprise 15%–25% of the observed line-integrated emission peaks. Additionally, the spatial differences in the reflection contribution between the different lines-of-sight are less pronounced than in the 2D reconstructions due to the dominance of the brightest emission regions through which the spectroscopic lines-of-sight pass. However, postprocessing EDGE2D-EIRENE simulations using the CHERAB code and synthetic spectroscopy suggests a decrease of the spectroscopically inferred divertor electron temperature by up to 75%, when redistribution of the observed light due to reflections is considered.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗