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At least 253 records · Page 14

Percolative Sulfide Core Formation in Oxidized Meteorite Parent Bodies

Most models of planetary differentiation involve the formation of metallic cores during or after extensive silicate melting, but some volatile-rich reservoirs in the protoplanetary disk did not accrete substantial amounts of Fe,Ni-metal. Instead, their potential core-forming assemblages were dominated by Fe,Ni-sulfides and oxides due to high ƒ O 2 and ƒ S 2 . Derivative melts from these assemblages may have been capable of percolative migration leading to core formation prior to silicate melting. However, no direct evidence for this process has been reported in meteoritic literature. Similarly, while many iron meteorites are thought to represent cores of their respective parent bodies, no direct evidence for Fe,Ni-sulfide/oxide cores have been reported to-date. The most promising potential for such evidence may be found in the anomalous noble metal trace element proportions of restitic oxidized primitive achondrites (i.e., brachinites, log ƒ O 2 ~IW-1), which are similar to those found in sulfides of Rumuruti-type chondrites (RCs) that contain only trace amounts of Fe,Ni-metal at log ƒ O 2 ≥ IW-1. This work addresses the following outstanding questions: (1) Are molten sulfides in oxidized meteorite assemblages capable of percolative melt migration? (2) How is this process recorded in the noble metal (i.e., siderophile/chalcophile) trace element geochemistry of relevant meteorites? (3) Did O,S-rich meteorite parent bodies form sulfide cores?

S. D. Crossley↗

Relationship of peroxyacetyl nitrate to active and total odd nitrogen at northern high latitudes: influence of reservoir species on NOx and O3

Measurements of peroxyacetyl nitrate (PAN), NO, NO2, HNO3, NOy (total odd nitrogen), and O3 were made in the high-latitude troposphere over North America and Greenland (35 degrees to 82 degrees N) during the Arctic Boundary Layer Expedition (ABLE 3A) (July-August 1988) throughout 0-to 6-km altitudes. These data are analyzed to quantitatively describe the relationships between various odd nitrogen species and assess their significance to global tropospheric chemistry. In the free troposphere, PAN was as much as 25 times more abundant than NOx. PAN to NOx ratio increased with increasing altitude and latitude. PAN was found to be the single most abundant reactive nitrogen species in the free troposphere and constituted a major fraction of NOy, PAN to NOy ratios were about 0.1 in the boundary layer and increased to 0.4 in the free troposphere. A 2-D global photochemical model with C1-C3 hydrocarbon chemistry is used to compare model predictions with measured results. A sizable portion (approximately 50%) of the gaseous reactive nitrogen budget is unaccounted for, and unknown organic nitrates and pernitrates are expected to be present. Model calculations (August 1, 70 degrees N) show that a major fraction of the observed NOx (50 to 70% of median) may find its source in the available PAN reservoir. PAN and the unknown reservoir species may have the potential to control virtually the entire NOx availability of the high latitude troposphere. It is predicted that the summer NOx and O3 mixing ratios in the Arctic/sub-Arctic troposphere would be considerably lower in the absence of the ubiquitous PAN reservoir. Conversely, this PAN reservoir may be responsible for the observed temporal increase in tropospheric O3 at high latitudes.

NASA Center ARC↗

Investigating the Sensitivity of Surface-Level Nitrate Seasonality in Antarctica to Primary Sources Using a Global Model

Determining the sources of total nitrate (TNIT NO-3 + HNO3) reaching Antarctica is a long-standing challenge. Here we analyze the monthly sensitivity of surface-level TNIT in Antarctica to primary sources using a global 3-D chemical transport model, GEOS-Chem, and its adjoint. Modeled seasonal variation of TNIT concentrations shows good agreement with several measurement studies, given that the lack of post-depositional processing in the model leads to an expected underestimate of maximum values in November through January. Remote NOx sources have the greatest impact May-July, during when the model background concentrations are sensitive to NOx emissions from fossil fuel combustion, soil, and lightning originating from 25S to 65S. In this season, NOx is transported to Antarctica as TNIT, which is formed above continental source regions at an altitude of 5-11 km. In other seasons, more NOx is transported as a reservoir species (e.g., peroxyacetyl nitrate, PAN) through the free troposphere, transforming into TNIT within a cone of influence that extends to 35S and above 4 km altitude. Photolysis of PAN over Antarctica is the main driver of modeled NOx seasonality. Stratospheric production and loss of tracers are relatively unimportant in monthly sensitivities in GEOS-Chem, driving only a few percent of surface level variability of TNIT. A small peak concentration in August is captured by the model, although some measured values in August fall outside the range of simulated concentrations. Modifications to the model to represent sedimentation of polar stratospheric clouds (PSCs) lead to increased surface level August TNIT concentrations. However, this simple representation does not explicitly account for PSC particle deposition or disappearance of the tropopause in the middle of winter, and thus the influence of stratospheric nitrate sources estimated in this study is likely a lower bound.

stratosphere↗

Modeling Orifice Pulse Tube Coolers

We have developed a calculational model that treats all the components of an orifice pulse tube cooler. We base our analysis on 1-dimensional thermodynamic equations for the regenerator and we assume that all mass flows, pressure oscillations and temperature oscillations are small and sinusoidal. Non-linear pressure drop effects are included in the regenerator to account for finite pressure amplitude effects. The resulting mass flows and pressures are matched at the boundaries with the other components of the cooler: compressor, aftercooler, cold heat exchanger, pulse tube, hot heat exchanger, orifice and reservoir. The results of the calculation are oscillating pressures, mass flows and enthalpy flows in the main components of the cooler. By comparing with the calculations of other available models, we show that our model is very similar to REGEN 3 from NIST and DeltaE from Los Alamos National Lab. Our model is much easier to use than other available models because of its simple graphical interface and the fact that no guesses are required for the operating pressures or mass flows. In addition, the model only requires a few minutes of running time allowing many parameters to be optimized in a reasonable time. A version of the model is available for use over the World Wide Web at http://irtek.arc.nasa.gov. Future enhancements include adding a bypass orifice and including second order terms in steady mass streaming and steady heat transfer. A two-dimensional anelastic approximation of the fluid equations will be used as the basis for the latter analysis. Preliminary results are given in dimensionless numbers appropriate for oscillating compressible flows. The model shows how transverse heat transfer reduces enthalpy flow, particularly for small pulse tubes. The model also clearly shows mass recirculation in the open tube on the order of the tube length. They result from the higher order Reynolds stresses. An interesting result of the linearized approach is that the steady mass streaming does not affect the enthalpy flow at second order. The major effect of recirculating mass streaming is to increase transverse temperature gradients, which leads to higher entropy production and reduced efficiency.

Roach, Kittel P.↗

The Connection between Model Performance on the CCMVal Transport Diagnostics and Simulated Sensitivity of Ozone to Chlorine Change

The chemistry climate models that contributed simulations for past and future ozone evolution to the 2010 Scientific Assessment of Ozone Depletion were subject to extensive evaluation by the SPARC (Stratospheric Processes and their Role in Climate) CCMVal (Chemistry-Climate Model Validation) activity. The sensitivity of ozone to changes in composition and climate varies among the models, but the relationship between these variations and the model evaluations of CCMVal is not obvious. We have learned that the transport evaluation can be used to interpret the comparisons between observed and simulated columns of chlorine reservoirs, hydrochloric acid (HCl) and chlorine nitrate (ClONO2); these comparisons were part of the CCMVal evaluation of chemistry. The simulations with best performance on the transport diagnostics most faithfully reproduce the evolution and seasonal variation of the chlorine reservoirs as observed at NDACC (Network for Detection of Atmospheric Composition Change) stations (NyAlesund 78.9N, Kiruna 67.8N, Harestua 60.2N, Jungfraujoch 46.6N, Toronto 43.6N, Kitt Peak 31.9N, Izana 28.3N, Mauna Loa 19.5N, Lauder 45S and Arrival Heights 77.8S). In the simulations, the HCl in the lower stratosphere depends on total inorganic chlorine (Cly) and partitioning between HCl and ClON02. Total inorganic chlorine depends on the fractional release of chlorine from source gases, and ratio of ClON02 to HCl is inversely dependent on methane and varies quadratically with ozone. Simulated HCl from various models may agree with observations even though Cly is in error, partitioning is in error, or both. Simulated ozone sensitivity to chlorine is shown to be greater for models that produce larger values of chlorine nitrate for background chlorine levels, and vice versa. Comparisons with the NDACC data show why the models with 'best' transport have similar sensitivity to chlorine change. The realistic evolution of the simulated HCl and ClONO2 columns suggests realistic levels of Cly in the lower atmosphere. In addition, the wide range values for the sensitivity of ozone to chlorine obtained from the CCMVal simulations is explained by the wide range in lower atmospheric columns of ClONO2 and the concomitant wide range of levels for chlorine monoxide.

Douglass, Anne↗

Spatially Refined Satellite Gravimetry Captures Human Signatures in Global Terrestrial Water Storage Trends

Human activities have directly altered the water cycle through water management, aquifer pumping, agricultural irrigation, and land use change. Although satellite gravimetry has transformed global hydrological research, its coarse resolution limits attribution of freshwater change to human activities at many management-relevant scales. Here we assessed global terrestrial water storage (TWS) trends from April 2002 to November 2025 using “stacked” regression of Level-1B intersatellite ranging data, which leverages temporal information and variability to dramatically improve effective spatial resolution relative to standard approaches. We combined this refined product with rigorous uncertainty analysis, autocorrelation-robust geostatistical methods, and literature assessment to evaluate TWS trend associations with land and water use, climate variability, and glacial mass loss. We identified TWS trend hotspots exhibiting significant spatial associations with anthropogenic 40 drivers, including groundwater and surface-water irrigation, rainfed agriculture, deforestation, and reservoir impoundment. Across these regions, cumulative TWS losses (3,122 Gt) substantially exceeded gains (2,432 Gt). Compared with traditional regression of monthly mascons, our approach yielded regional trend magnitudes that are on average 33% larger, revealing that global freshwater depletion, particularly from groundwater pumping, is considerably more acute than previously estimated. Multivariate regression models show that humans account for a significant share of the spatial variability in TWS trends on every non-polar continent except Australia. We detected localized TWS gains linked to rainfed agriculture, surface water irrigation, and reservoir filling that were unresolved in earlier gravimetric studies. The methodology provides a foundation for future gravity missions to independently track decadal freshwater change with unprecedented spatial fidelity.

groundwater↗

Analysis of Salinity Intrusion in the San Francisco Bay-Delta using a GA- Optimized Neural Net, and Application of the Model to Prediction in the Elkhorn Slough Habitat

The San Francisco Bay Delta is a large hydrodynamic complex that incorporates the Sacramento and San Joaquin Estuaries, the Burman Marsh, and the San Francisco Bay proper. Competition exists for the use of this extensive water system both from the fisheries industry, the agricultural industry, and from the marine and estuarine animal species within the Delta. As tidal fluctuations occur, more saline water pushes upstream allowing fish to migrate beyond the Burman Marsh for breeding and habitat occupation. However, the agriculture industry does not want extensive salinity intrusion to impact water quality for human and plant consumption. The balance is regulated by pumping stations located alone the estuaries and reservoirs whereby flushing of fresh water keeps the saline intrusion at bay. The pumping schedule is driven by data collected at various locations within the Bay Delta and by numerical models that predict the salinity intrusion as part of a larger model of the system. The Interagency Ecological Program (IEP) for the San Francisco Bay/Sacramento-San Joaquin Estuary collects, monitors, and archives the data, and the Department of Water Resources provides a numerical model simulation (DSM2) from which predictions are made that drive the pumping schedule. A problem with this procedure is that the numerical simulation takes roughly 16 hours to complete a C:~ prediction. We have created a neural net, optimized with a genetic algorithm, that takes as input the archived data from multiple stations and predicts stage, salinity, and flow at the Carquinez Straits (at the downstream end of the Burman Marsh). This model seems to be robust in its predictions and operates much faster than the current numerical DSM2 model. Because the system is strongly tidal driven, we used both Principal Component Analysis and Fast Fourier Transforms to discover dominant features within the IEP data. We then filtered out the dominant tidal forcing to discover non-primary tidal effects, and used this to enhance the neural network by mapping input-output relationships in a more efficient manner. Furthermore, the neural network implicitly incorporates both the hydrodynamic and water quality models into a single predictive system. Although our model has not yet been enhanced to demonstrate improve pumping schedules, it has the possibility to support better decision-making procedures that may then be implemented by State agencies if desired. Our intention is now to use this model in the smaller Elkhorn Slough complex near Monterey Bay where no such hydrodynamic model currently exists. At the Elkhorn Slough, we are fusing the neural net model of tidally-driven flow with in situ flow data and airborne and satellite remote sensation data. These further constrain the behavior of the model in predicting the longer-term health and future of this vital estuary.

Thompson, David E.↗

Observations of denitrification and dehydration in the winter polar stratospheres

It is argued that denitrification of the Arctic stratosphere can be explained by the selective growth and sedimentation of aerosol particles rich in nitric acid. Because reactive nitrogen species moderate the destruction of ozone by chlorine-catalyzed reactions by sequestering chlorine in reservoir species such as ClONO2, the possibility of the removal of reactive nitrogen without dehydration should be allowed for in attempts to model ozone depletion in the Arctic. Indeed, denitrification along with elevated concentrations of reactive chlorine observed in 1989 indicate that the Arctic was chemically primed for ozone destruction without an extended period of temperatures below the frost point, as is characteristic of the Antarctic.

Fahey, D. W.↗

Fundamentals of chemistry modeling applicable to a vectorized particle simulation

This paper describes the fundamentals of extending the vectorized particle simulation method derived by Baganoff and McDonald (1990), McDonald and Baganoff (1988), and McDonald (1989) for modeling chemically reacting flows. Details of reaction mechanics per reaction are presented, with particular attention given to the quantum nature of the vibrational mode. The models of reactive flows developed here were verified through a simulation of a superheated diatomic gas relaxing thermochemically to equilibrium in a reservoir.

Haas, Brian L.↗

A New Paradigm for Gamma Ray Bursts: Long Term Accretion Rate Modulation by an External Accretion Disk

We present a new way of looking at the very long term evolution of GRBs in which the disk of material surrounding the putative black hole powering the GRB jet modulates the mass flow, and hence the efficacy of the process that extracts rotational energy from the black hole and inner accretion disk. The pre-Swift paradigm of achromatic, shallow-to-steep "breaks" in the long term GRB light curves has not been borne out by detailed Swift data amassed in the past several years. We argue that, given the initial existence of a fall-back disk near the progenitor, an unavoidable consequence will be the formation of an "external disk" whose outer edge continually moves to larger radii due to angular momentum transport and lack of a confining torque. The mass reservoir at large radii moves outward with time and gives a natural power law decay to the GRB light curves. In this model, the different canonical power law decay segments in the GRB identified by Zhang et al. and Nousek et al. represent different physical states of the accretion disk. We identify a physical disk state with each power law segment.

Cannizzo, John↗

NASA’s MODIS/VIIRS Global Water Reservoir Product Suite from Moderate Resolution Remote Sensing Data

Global reservoir information can not only benefit local water management but can also improve our understanding of the hydrological cycle. This information includes water area, elevation, and storage; evaporation rate and volume values; and other characteristics. However, operational wall-to-wall reservoir storage and evaporation monitoring information is lacking on a global scale. Here we introduce NASA’s new MODIS/VIIRS Global Water Reservoir product suite based on moderate resolution remote sensing data—the Moderate Resolution Imaging Spectroradiometer (MODIS), and the Visible Infrared Imaging Radiometer Suite (VIIRS). This product consists of 8-day (MxD28C2 and VNP28C2) and monthly (MxD28C3 and VNP28C3) measurements for 164 large reservoirs (MxD stands for the product from both Terra (MOD) or Aqua (MYD) satellites). The 8-day product provides area, elevation, and storage values, which were generated by first extracting water areas from surface reflectance data and then applying the area estimations to the pre-established Area–Elevation (A–E) relationships. These values were then further aggregated to monthly, with the evaporation rate and volume information added. The evaporation rate and volume values were calculated after the Lake Temperature and Evaporation Model (LTEM) using MODIS/VIIRS land surface temperature product and meteorological data from the Global Land Data Assimilation System (GLDAS). Validation results show that the 250 m area classifications from MODIS agree well with the high-resolution classifications from Landsat (R^(2) = 0.99). Validation of elevation and storage products for twelve Indian reservoirs show good agreement in terms of R^(2) values (0.71–0.96 for elevation, and 0.79–0.96 for storage) and normalized root-mean-square error (NRMSE) values (5.08–19.34% for elevation, and 6.39–18.77% for storage). The evaporation rate results for two reservoirs (Lake Nasser and Lake Mead) agree well with in situ measurements (R^(2) values of 0.61 and 0.66, and NRMSE values of 16.25% and 21.76%). Furthermore, preliminary results from the VIIRS reservoir product have shown good consistency with the MODIS based product, confirming the continuity of this 20-year product suite. This new global water reservoir product suite can provide valuable information with regard to water-sources-related studies, applications, management, and hydrological modeling and change analysis such as drought monitoring.

Yao Li↗

The Critical Role of the Routing Scheme in Simulating Peak River Discharge in Global Hydrological Models

Global hydrological models (GHMs) have been applied to assess global flood hazards, but their capacity to capture the timing and amplitude of peak river discharge which is crucial in flood simulations has traditionally not been the focus of examination. Here we evaluate to what degree the choice of river routing scheme affects simulations of peak discharge and may help to provide better agreement with observations. To this end we use runoff and discharge simulations of nine GHMs forced by observational climate data (1971-2010) within the ISIMIP2a (Inter-Sectoral Impact Model Intercomparison Project phase 2a) project. The runoff simulations were used as input for the global river routing model CaMa-Flood (Catchment-based Macro-scale Floodplain). The simulated daily discharge was compared to the discharge generated by each GHM using its native river routing scheme. For each GHM both versions of simulated discharge were compared to monthly and daily discharge observations from 1701 GRDC (Global Runoff Data Centre) stations as a benchmark. CaMa-Flood routing shows a general reduction of peak river discharge and a delay of about two to three weeks in its occurrence, likely induced by the buffering capacity of floodplain reservoirs. For a majority of river basins, discharge produced by CaMa-Flood resulted in a better agreement with observations. In particular, maximum daily discharge was adjusted, with a multi-model averaged reduction in bias over about two-thirds of the analysed basin area. The increase in agreement was obtained in both managed and near-natural basins. Overall, this study demonstrates the importance of routing scheme choice in peak discharge simulation, where CaMa-Flood routing accounts for floodplain storage and backwater effects that are not represented in most GHMs. Our study provides important hints that an explicit parameterisation of these processes may be essential in future impact studies.

peak river discharge↗

The reaction Cl + H2CO yields HCl + HCO: Decreased sensitivity of stratospheric ozone to chlorine perturbations

The absolute rate constant for the reaction Cl + H2CO yields HCl + HCO has been determined by the flash-photolysis-resonance fluorescence method to be + or - 0.9 (2 sigma) x 10 to the -11th power cu cm/molecule per sec at 298 K and to have a negligible temperature dependence. This rate, which at stratospheric temperatures is more than 2000 times faster than the rate of Cl + CH4 and more than a factor of 2 faster than Cl + HO2, indicates that formaldehyde (H2CO) will compete significantly with methane (CH4) and HO2 for the conversion of active chlorine in the stratosphere to the inactive reservoir HCl. Chlorine will thus be a less efficient destroyer of stratospheric ozone than previously believed. One-dimensional eddy-diffusion photochemical model calculations indicate that the eventual ozone depletion for a steady-state chlorfluoromethane release at 1975 rates (750,000 tons/year) will be lowered from 20% to 18.5% by the inclusion of this reaction.

Stief, L. J.↗

FIB-NanoSIMS-TEM Coordinated Study of a Wark-Lovering Rim in a Vigarano Type A CAI

Wark-Lovering (WL) rims are thin multi layered mineral sequences that surround most Ca, Al-rich inclusions (CAIs). Unaltered WL rims are composed of the same primary high temperature minerals as CAIs, such as melilite, spinel, pyroxene, hibonite, perovskite, anorthite and olivine. It is still unclear whether the rim minerals represent a different generation formed by a separate event from their associated CAIs or are a byproduct of CAI formation. Several models have been proposed for the origins of WL rims including condensation, flashheating, reaction of a CAI with a Mg-Si-rich reservoir (nebular gas or solid); on the basis of mineralogy, abundances of trace elements, O and Mg isotopic studies. Detailed mineralogical characterizations of WL rims at micrometer to nanometer scales have been obtained by TEM observations, but so far no coordinated isotopic - mineralogical studies have been performed. Thus, we have applied an O isotopic imaging technique by NanoSIMS 50L to investigate heterogeneous distributions of O isotopic ratios in minerals within a cross section of a WL rim prepared using a focused ion beam (FIB) instrument. After the isotopic measurements, we determine the detailed mineralogy and microstructure of the same WL FIB section to gain insight into its petrogenesis. Here we present preliminary results from O isotopic and elemental maps by NanoSIMS and mineralogical analysis by FE-SEM of a FIB section of a WL rim in the Vigarano reduced CV3 chondrite.

Cai, A.↗

Vapor flow into a capillary propellant-acquisition device

An analytical model is described that specifies the conditions needed to cause a flow of vapor through the screens of a start basket. The analytical model is composed of several original submodels that interrelate the evaporation of the liquid in the basket, the bubble-point change of a screen in the presence of wicking, the drying out of a screen through a combination of evaporation and pressure difference, the vapor flow rate across a wet screen as a function of pressure difference, and the effect on wicking of a difference between the static pressure of the liquid reservoir and the vapor surrounding the screen. Most of the interrelations were demonstrated by a series of separate-effects tests, which were also used to determine certain empirical constants. The equations of the model were solved numerically for typical start basket designs. A simplified start basket was constructed and tested to verify these predictions, using both volatile and non-volatile liquids. The test results verified the trends predicted by the model.

Dodge, F. T.↗

Pluto's Global Surface Composition Through Pixel-by-Pixel Hapke Modeling of New Horizons Ralph LEISA Data

On July 14th 2015, NASA's New Horizons mission gave us an unprecedented detailed view of the Pluto system. The complex compositional diversity of Pluto's encounter hemisphere was revealed by the Ralph/LEISA infrared spectrometer on board of New Horizons. We present compositional maps of Pluto defining the spatial distribution of the abundance and textural properties of the volatiles methane and nitrogen ices and non-volatiles water ice and tholin. These results are obtained by applying a pixel-by-pixel Hapke radiative transfer model to the LEISA scans. Our analysis focuses mainly on the large scale latitudinal variations of methane and nitrogen ices and aims at setting observational constraints to volatile transport models. Specifically, we find three latitudinal bands: the first, enriched in methane, extends from the pole to 55degN, the second dominated by nitrogen, continues south to 35 degN, and the third, com- posed again mainly of methane, reaches 20 degN. We demonstrate that the distribution of volatiles across these surface units can be explained by differences in insolation over the past few decades. The latitudinal pattern is broken by Sputnik Planitia, a large reservoir of volatiles, with nitrogen playing the most important role. The physical properties of methane and nitrogen in this region are suggestive of the presence of a cold trap or possible volatile stratification. Furthermore our modeling results point to a possible sublimation transport of nitrogen from the northwest edge of Sputnik Planitia toward the south.

Protopapa, S.↗

Global exchange of water vapor on Mars

Observations of the global distribution and seasonal variation of the Martian atmospheric water vapor have been made from the Viking orbiters for a continuous period covering more than half of a Martian year. The seasonal dependence of the latitude distribution of the column abundance of vapor is consistent with a model in which the vapor is in equilibrium with the regolith at polar and middle latitudes. The results indicate the existence of a permanent reservoir of water ice buried at a depth of 10 cm to 1 meter at all latitudes poleward of 40 deg. The behavior of the vapor in the summer hemisphere suggests an annual net transport of the vapor phase from the southern to the northern hemisphere, with deposition of ice of thickness on the order of a few milligrams per sq cm at northern polar latitudes. The hemispheric asymmetry is the result of the propagation of global dust storms originating in the south.

Farmer, C. B.↗

A basic code for the prediction of transient three-dimensional turbulent flowfields

A primitive pressure-velocity finite difference code has been developed to predict transient three-dimensional turbulent flow. The code is a simplified yet effective prediction procedure for use by persons with little experience in computational fluid dynamics, and into which user-oriented complexities can easily be added. The method is based on the transient two-dimensional Los Alamos SOLA prediction technique for laminar flows. Turbulence is simulated by means of a two-equation turbulence model; species diffusion and buoyancy are also included. Two applications of the code are presented to local destratification near the release structure of a reservoir and to the deflection of a jet entering normally into a uniform cross-flow. Predicted results exhibit good agreement with experimental data, showing that a useful characterization of fully three-dimensional flows is now available.

Busnaina, A. A.↗