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At least 253 records · Page 14

Water-Activated VOPO 4 for Magnesium Ion Batteries

Rechargeable Mg batteries, using high capacity and dendrite-free Mg metal anodes, are promising energy storage devices for large scale smart grid due to low cost and high safety. However, the performance of Mg batteries is still plagued by the slow reaction kinetics of their cathode materials. Recent discoveries demonstrate that water in cathode can significantly enhance the Mg-ion diffusion in cathode by an unknown mechanism. Here, we propose the water-activated layered-structure VOPO 4 as a novel cathode material and examine the impact of water in electrode or organic electrolyte on the thermodynamics and kinetics of Mg-ion intercalation/deintercalation in cathodes. Electrochemical measurements verify that water in both VOPO 4 lattice and organic electrolyte can largely activate VOPO 4 cathode. Thermodynamic analysis demonstrates that the water in the electrolyte will equilibrate with the structural water in VOPO 4 lattice, and the water activity in the electrolyte alerts the mechanism and kinetics for electrochemical Mg-ion intercalation in VOPO 4 . Theoretical calculations and experimental results demonstrate that water reduces both the solid-state diffusion barrier in the VOPO 4 electrode and the desolvation penalty at the interface. To achieve fast reaction kinetics, the water activity in the electrolyte should be larger than 10 –2 . The proposed activation mechanism provides guidance for screening and designing novel chemistry for high performance multivalent-ion batteries.

25 ENERGY STORAGE↗

In situ formed catalysts for active, durable, and thermally stable ammonia protonic ceramic fuel cells at 550 °C

Ammonia protonic ceramic fuel cells (NH 3 -PCFCs) are promising and attractive energy-conversion devices owing to their high energy density, zero-carbon emission, and safety. The development of NH 3 -PCFCs, however, depends largely on the insufficient activity and poor durability of typical Ni-based anodes for ammonia decomposition, especially at low temperatures such as 550 °C. Herein, we report a self-assembled heterostructured Ru 0.95 Cu 0.05 Ni x (RCN) catalyst obtained through an in situ reaction between the surface-decorated Ru 0.95 Cu 0.05 nanoparticles and the Ni grain in the anode under typical processing conditions. At 550 °C, Ni–BaZr 0.1 Ce 0.7 Y 0.1 Yb 0.1 O 3 anode-supported PCFCs with RCN catalysts exhibit a high peak power density of 0.732 W cm -2 and a significantly enhanced durability of 100 h in NH 3 . Moreover, the cells demonstrate improved thermal stability compared with the bare cell during a 31-cycle thermal cycling test in NH 3 between 550 and 700 °C. In conclusion, the enhanced performance is likely attributed to the synergistic effects of Ru and Cu in RCN for NH 3 decomposition, resulting in a more vital interaction of NH 3 than that of the bare anode surfaces, as confirmed by NH 3 thermal conversion, electrochemical performance, and theoretical simulations.

30 DIRECT ENERGY CONVERSION↗

Review—Polymer/Ceramic Interface Barriers: The Fundamental Challenge for Advancing Composite Solid Electrolytes for Li-Ion Batteries

Composite-solid electrolytes, in which ion-conducting polymers are combined with superionic ceramics, could revolutionize electrochemical-energy-storage devices enabling higher energy density, providing greater stability during operation and enhanced safety. However, the interfacial resistance between the ceramic and polymer phases strongly suppresses the ionic conductivity and presents the main obstacle to the use of these materials. Here, we emphasize the need for a distinct focus on reducing energy barriers to interfacial ion transport and improving the cation transference number. To achieve this goal, it is essential to develop a fundamental understanding of the parameters that influence the interfacial barriers to ion transport in composite electrolytes, and to understand the effect of the type of ceramic ("active" and "inert") and its content on ion-transport phenomena. We suggest that adapting the polymer chemistry, mainly directed on polymerized ionic liquids, (PolyILs), and combined with functionalization of the surface of ceramic nanoparticles is a promising route for overcoming the high-energy-barrier challenge. Owing to high content of ion-conducting ceramics and high t+ of PolyILs, the fractional contribution of the migrating cationic species to the total ionic conductivity of polymer-in-ceramic electrolytes via an interfacial percolation path, will be close to unity, thus eliminating complications that might arise from emerging concentration gradients during the operation of solid-state batteries.

25 ENERGY STORAGE↗

Federal Radiological Monitoring and Assessment Center Monitoring Manual Volume 1, Operations

The Monitoring division is primarily responsible for the coordination and direction of: Aerial measurements to delineate the footprint of radioactive contaminants that have been released into the environment. Monitoring of radiation levels in the environment; Sampling to determine the extent of contaminant deposition in soil, water, air and on vegetation; Preliminary field analyses to quantify soil concentrations or depositions; and Environmental and personal dosimetry for FRMAC field personnel, during a Consequence Management Response Team (CMRT) and Federal Radiological Monitoring and Assessment Center (FRMAC) response. Monitoring and sampling techniques used during CM/FRMAC operations are specifically selected for use during radiological emergencies where large numbers of measurements and samples must be acquired, analyzed, and interpreted in the shortest amount of time possible. In addition, techniques and procedures are flexible so that they can be used during a variety of different scenarios; e.g., accidents involving releases from nuclear reactors, contamination by nuclear waste, nuclear weapon accidents, space vehicle reentries, or contamination from a radiological dispersal device. The Monitoring division also provides technicians to support specific Health and Safety Division activities including: The operation of the Hotline; FRMAC facility surveys; Assistance with Health and Safety at Check Points; and Assistance at population assembly areas which require support from the FRMAC. This volume covers deployment activities, initial FRMAC activities, development and implementation of the monitoring and assessment plan, the briefing of field teams, and the transfer of FRMAC to the EPA.

61 RADIATION PROTECTION AND DOSIMETRY↗

CPAP Ventilators Needed for Rapid Response to COVID-19 by Modification of CPAP Equipment

Early on in the COVID-19 pandemic, potential ventilator shortages were a critical issue identified by national health care providers. Capacity modeling at the time suggested patient demand may exceed ventilator supply. Thus, the challenge became finding an urgent interim solution to meet health care needs. Our initial hypothesis was that CPAP technology could be modified to provide similar functionality to a ventilator, relieving demand and allowing physicians to decide which patients need high end machines, ultimately saving lives. In conjunction with medical experts and pulmonologists, we were able to identify three key thrusts associated with this research problem: (1) modification of CPAP technology to allow for 02 input that would be capable of providing ventilation; (2) development of an alarming function that would provide real-time audible alarms to alert medical personnel to critical conditions, which would be used inline with CPAP technology; and (3) a method of sterilizing expiratory air from such a system in order to protect medical personnel from biohazard, since CPAPs vent to the atmosphere. We were unable to realize results for thrust 1 (CPAP modification for 02); we identified potential safety issues associated with utilizing medical grade oxygen with a common CPAP device. In order to characterize and mitigate these issues, we would need to partner closely with a device manufacturer; such a partnership could not be achieved in the timeframe needed for this rapid response work. However, we determined that some medical grade BiPAP devices do not need this modification and that the significant progress on thrusts 2 and 3 would be sufficient to buy down risk of a massive ventilator shortage. Our team built a prototype alarm system that can be utilized with any assistive respiratory device to alert on all key conditions identified by medical personnel (high pressure, low pressure, apnea, loss of power, low battery). Finally, our team made significant progress in the rapid prototyping and demonstration of an inline UV air purifier device. The device is cost efficient and can be manufactured at scale with both commercially available and additively manufactured parts. Initial tests with SARS-CoV-2 analog bacteriophage MS2 show 99% efficacy at reducing bioburden. Following a successful demonstration of the prototype device with medical personnel, we were able to obtain follow-on (non-LDRD) funding to provide additional device characterization, validation, and production in order to respond to an immediate regional need.

42 ENGINEERING↗

APPLICATIONS OF CURRENT TECHNOLOGY FOR CONTINUOUS MONITORING OF SPENT FUEL

Advancements in technology have opened many opportunities to improve upon the current infrastructure surrounding the nuclear fuel cycle. Embedded devices, very small sensors, and wireless technology can be applied to Security, Safety, and Nonproliferation of Spent Nuclear Fuel. Security, separate of current video monitoring systems, can be improved by integrating current wireless technology with a variety of sensors including motion detection, altimeter, accelerometer, and a tagging system. By continually monitoring these sensors, thresholds can be set to sense deviations from nominal values. Then alarms or notifications can be activated as needed. Safety can be improved in several ways. First, human exposure to ionizing radiation can be reduced by using a wireless sensor package on each spent fuel cask to monitor radiation, temperature, humidity, etc. Since the sensor data is monitored remotely operator stay-time is decreased and distance from the spent fuel increased, so the overall radiation exposure is reduced as compared to visual inspections. The second improvement is the ability to monitor continuously rather than periodically. If changes occur to the material, alarm thresholds could be set and notifications made to provide advanced notice of negative data trends. These sensor packages could also record data to be used for scientific evaluation and studies to improve transportation and storage safety. Nonproliferation can be improved for spent fuel transportation and storage by designing an integrated tag that uses current infrastructure for reporting and in an event; tracking can be accomplished using the Iridium satellite system. This technology is similar to GPS but with higher signal strength and penetration power, but lower accuracy. A sensor package can integrate all or some of the above depending on the transportation and storage requirements and regulations. A sensor package can be developed using off the shelf technology and applying it to each specific need. There are products on the market for smart meters, industrial lighting control and home automation that can be applied to the Back End Fuel Cycle. With a little integration and innovation a cost effective solution is achievable.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Adaptive protection opportunities, gap assessments, and designs

This report provides a comprehensive overview of adaptive protection schemes in use by distribution systems for protection, switching and control on their systems. A significant focus is placed on how existing schemes can be impacted by increasing penetrations of DER as well as how these schemes can enable DER penetrations to increase. EPRI have conducted a survey of member utilities and performed a comprehensive literature review with the goal of baselining the research and identifying gaps with a focus on the issues that were encountered with adaptive protection on real systems. The five adaptive protection applications that are most prevalent on systems today are discussed in detail. These are weather-based fuse-saving, adaptive protection to reduce short-circuit current, adaptive protection for DER, adaptive protection for microgrids, and distribution automation. A broad overview of the technology is given for each scheme. Issues that have been encountered by utilities are highlighted and the safety and reliability impacts are also examined. As distribution systems, intelligent electronic devices, grid equipment and distribution management systems are rapidly evolving, adaptive protection techniques and technologies will become more widely adopted. This report proposes a framework for a conceptual automatic adaptive protection system. EPRI have ongoing research, development and demonstration projects in all of the constituent elements, however challenges remain to link the elements together in a secure and reliable way. EPRI will continue research into automated adaptive protection applications and challenges for the systems of today and future applications to assist system operators in managing the evolving system.

14 SOLAR ENERGY↗

Multi-Physics Investigation of a Natural Circulation Molten Salt Micro-Reactor that Utilizes an Experimental In-Pile Device to Improve Core Physics and System Thermal-Hydraulic Performance.

INL employee PhD Dissertation - The Molten Salt Reactor (MSR) concept is a rapidly evolving Generation IV design that has recently attracted favorable attention due to the potential for reducing waste generation, realizing passive safety features, and seizing on the opportunity for cost effective economics. This thesis investigates the performance benefit of a new device invented by the doctoral candidate. The device is referred to as a Wrapped Helix around an Inclined Plane or WHIP. The WHIP is protected under a provisional patent filed with the USA Patent Office on 28 September 2021 under application number 63/261,776, BEA docket number BA-1254. The WHIP device can be located in-core or near-core to promoted enhanced thermal-hydraulics and neutronics performance. While the WHIP can be employed in a variety of solid or liquid fuel designs, this thesis investigates the device’s benefit in the application of a natural-circulation, micro-molten salt nuclear battery concept (MsNB). This thesis will specifically investigate the temperature coefficient of the MsNB fuel (FLiNaK) using novel temperature sensitivity techniques unique to Serpent particle transport code, evaluate the WHIP’s thermal-hydraulic and neutronic performance effects using both established (STAR-CCM+) and novel (Python code developed to estimate the circulation effective delayed neutron fraction, ßef f ) analytical and numerical methods, evaluate the neutron noise behavior of the MsNB and how the WHIP may alter the character of the MsNB’s transfer function, and how the WHIP affects the autonomous, load-following performance under transient power conditions using Python code developed by the candidate. The sum body of this work, in part, has been published in three journal articles as the timing of the provisional patent process has allowed. Results show that creative utilization of WHIP engineering design and function reduces reactor system volume, fuel loading, control/stability in the buoyant regime

buoyant flow↗

MEXIICO: a new equipment to study the pressure impact on the irradiated fuel behavior

The new MEXIICO experimental loop has recently been started in the LECA-STAR hot-cell facility of the CEA Cadarache. It is dedicated to the understanding of the basic mechanisms occurring in nuclear fuels during nuclear reactor power transients and accidental situations. Under such conditions the nuclear fuels are submitted to thermo-mechanical stresses. These stresses play a major role on fission product release and fuel fragmentation. Evaluating such fuel behavior represents a key issue for reactor safety analyses. In the first part of the paper, we describe the complete MEXIICO device, which main component is a hot isostatic press allowing to perform analytical experiments in the [20 -1600 C. degrees / 10 MPa - 160 MPa] region. As shown by simulations (ALCYONE fuel performance code), the upper value of the pressure (160 MPa) is consistent with the one experienced by fuels under nuclear power transients. We also present the experimental loop starting from the argon pressurized feed-line, the furnace and its associated instrumentation and the exhaust line equipped with specific valves and flowmeters controlling the pressure and flowrate. We then focus on the gamma spectrometry measurement which allows recording the fission gas release kinetics. In the second part of the paper, we detail the capability of the MEXIICO device to provide new experimental data regarding the influence of pressure on the fission gas release and fuel fragmentation, and to determine a pressure threshold above which fission gas release and fuel fragmentation may be inhibited. This device also allows investigating the impact of pressure on the microstructure evolution, coupling it with post-test microanalysis examinations: this procedure will allow characterizing the effect of temperature and pressure on the bubble evolution and interconnection. Evolutions of the fuel modeling, needed to simulate correctly these new experimental data, will be also presented. In the last section of the paper, we present the commissioning tests of the MEXIICO device showing the good reproducibility of the tests performed first in conventional laboratory and then in hot-cell laboratory. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

JHR Project: a future Material Testing Reactor working as an International user Facility: The key-role of instrumentation in support to the development of modern experimental capacity

Research and development on fuel and material behaviour under irradiation is a key issue for sustainable nuclear energy in order to meet specific needs by keeping the best level of safety. These needs mainly deal with a constant improvement of performances and safety in order to optimize the fuel cycle and hence to reach nuclear energy sustainable objectives. A sustainable nuclear energy requires a high level of performances in order to meet specific needs such as: - Pursuing improvement of the performances and safety of present and coming water cooled reactor technologies. This will require a continuous R and D support following a long-term trend driven by the plant life management, safety demonstration, flexibility and economics improvement. Experimental irradiations of structure materials are necessary to anticipate these material behaviours and will contribute to their optimisation. - Upgrading continuously nuclear fuel technology in present and future nuclear power plants to achieve better performances and to optimise the fuel cycle keeping the best level of safety. Fuel evolution for generation II, III and III+ is a key stake requiring developments, qualification tests and safety experiments to ensure the competitiveness and safety: experimental tests exploring the full range of fuel behaviour determine fuel stability limits and safety margins, as a major input for the fuel reliability analysis. To perform such accurate and innovative progress and developments, specific and ad hoc instrumentation, irradiation devices, measurement methods are necessary to be set up inside or beside the material testing reactor (MTR) core. These experiments require beforehand in situ and on line sophisticated measurements to accurately determine different key parameters such as thermal and fast neutron fluxes and nuclear heating in order to precisely monitor and control the conducted assays. The new Material Testing Reactor JHR (Jules Horowitz Reactor) currently under construction at CEA Cadarache research centre in the south of France will represent a major Research Infrastructure for scientific studies regarding material and fuel behavior under irradiation. It will also be devoted to medical isotopes production. Hence JHR will offer a real opportunity to perform R and D programs regarding needs above and hence will crucially contribute to the selection, optimization and qualification of these innovative materials and fuels. The JHR reactor objectives, principles and main characteristics associated to specific experimental devices associated to measurement techniques and methodology, their performances, their limitations and field of applications will be presented and discussed. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Leak Detection and H2 Sensor Development for Hydrogen Applications

The objectives of this report are: (1) Develop a low cost, low power, durable, and reliable hydrogen safety sensor for a wide range of vehicle and infrastructure applications; (2) Continually advance test prototypes guided by materials selection, sensor design, electrochemical R&D investigation, fabrication, and rigorous life testing; (3) Disseminate packaged sensor prototypes and control systems to DOE Laboratories and commercial parties interested in testing and fielding advanced prototypes for cross-validation; (4) Evaluate manufacturing approaches for commercialization; and (5) Engage an industrial partner and execute technology transfer. Recent developments in the search for sustainable and renewable energy coupled with the advancements in fuel cell powered vehicles (FCVs) have augmented the demand for hydrogen safety sensors. There are several sensor technologies that have been developed to detect hydrogen, including deployed systems to detect leaks in manned space systems and hydrogen safety sensors for laboratory and industrial usage. Among the several sensing methods electrochemical devices that utilize high temperature-based ceramic electrolytes are largely unaffected by changes in humidity and are more resilient to electrode or electrolyte poisoning. The desired sensing technique should meet a detection threshold of 1% (10,000 ppm) H 2 and response time of {approx_equal}1 min, which is a target for infrastructure and vehicular uses. Further, a review of electrochemical hydrogen sensors by Korotcenkov et.al and the report by Glass et.al suggest the need for inexpensive, low power, and compact sensors with long-term stability, minimal cross-sensitivity, and fast response. This view has been largely validated and supported by the fuel cell and hydrogen infrastructure industries by the NREL/DOE Hydrogen Sensor Workshop held on June 8, 2011. Many of the issues preventing widespread adoption of best-available hydrogen sensing technologies available today outside of cost, derive from excessive false positives and false negatives arising from signal drift and unstable sensor baseline; both of these problems necessitate the need for unacceptable frequent calibration.

08 HYDROGEN↗

Reconstruction of tokamak plasma safety factor profile using deep learning

Abstract The motional Stark effect (MSE) diagnostic has been a standard measurement for the magnetic field line pitch angle in tokamaks that are equipped with neutral beams. However, the MSE data are not always available due to experimental constraints, especially in future devices without neutral beams. Here we develop a deep-learning based model (SGTC-QR) that can reconstruct the safety factor profile without the MSE diagnostic to mimic the traditional equilibrium reconstruction with the MSE constraint. The model demonstrates promising performance, and the sub-millisecond inference time is compatible with the real-time plasma control system.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Testing Instrument Extremes in the TREAT Facility

TREAT is a transient power-shaping reactor whose primary mission is to enhance safety performance by testing nuclear fuels and materials under thermodynamic and neutronic conditions ranging from off-normal to extreme. Transient testing of nuclear fuels is analogous to car crash testing, in that the dramatic changes commonly seen when comparing the test specimens' initial and final state points necessitate in-situ measuring in order to interpret and understand the evolution of the experiment. TREAT’s experiment design strategy utilizes a highly reconfigurable and accessible reactor core that affords flexibility when installing experiment devices, thanks to the lack of a primary coolant boundary and the inclusion of multiple access points in the reactor bioshield. Within the experiment devices, the test specimens (which are integrated with their test environments), desired instrumentation diagnostics, and safety considerations are all contained in a single engineered package. The experiments encompass various types of environments (e.g., water, sodium, and gas at temperature and pressure), as well as a range of control options (e.g., static or flowing coolants). The experimental conditions are uniquely representative of advanced reactors, providing challenges to sensor performance but also affording a unique opportunity for development and qualification of sensors suited to these environments.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Monitoring critical facilities by using advanced RF devices

The ability to monitor critical environment parameters of nuclear plants at all times, particularly during and after a disruptive accident, is vital for the safety of plant personnel, rescue and recovery crews, and the surrounding communities. Conventional hard-wired assets that depend on supplied power may be decimated as a result of such events, as witnessed in the Japanese Fukushima nuclear power plant in March 2011. Self-powered monitoring devices operating on a wireless platform, on the other hand, may survive such calamity and remain functional. The devices would be pre-positioned at strategic locations, particularly where the dangerous build-up of contamination and radiation may preclude subsequent manned entrance and surveillance. Equipped with sensors for β-γ radiation, neutrons, hydrogen gas, temperature, humidity, pressure, and water level, as well as with criticality alarms and imaging equipment for heat, video, and other capabilities, these devices can provide vital surveillance information for assessing the extent of plant damage, mandating responses (e.g., evacuation before impending hydrogen explosion), and enabling overall safe and efficient recovery in a disaster. A radio frequency identification (RFID)-based system - called ARG-US - may be modified and adapted for this task. Developed by Argonne for DOE, ARG-US (meaning 'watchful guardian') has been used successfully to monitor and track sensitive nuclear materials packages at DOE sites. It utilizes sensors in the tags to continuously monitor the state of health of the packaging and promptly disseminates alarms to authorized users when any of the preset sensor thresholds is violated. By adding plant-specific monitoring sensors to the already strong sensor suite and adopting modular hardware, firmware, and software subsystems that are tailored for specific subsystems of a plant, a Remote Area Modular Monitoring (RAMM) system, built on a wireless sensor network (WSN) platform, is being developed by Argonne National Laboratory. ARG-US RAMM, powered by on-board battery, can sustain extended autonomous surveillance operation during and following an incident. The benefits could be invaluable to such critical facilities as nuclear power plants, research and test reactors, fuel cycle manufacturing centers, spent-fuel dry-cask storage facilities, and other nuclear installations. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Comparative Assessment of Experimental Testing of Instrument with an Embedded Digital Device Using Model-Based and Conventional Methods

The use of digital equipment has not been widespread in U.S. nuclear facilities. A major contributing factor to this situation arises from regulatory concerns about common cause failures (CCFs) stemming from the use of identical software in redundant systems, questions as to how to quantify the reliability of software-based products, validity of tools that are used for software verification and validation (V&V), and the effectiveness of software QA procedures. Compounding the concerns are sporadic incidents of digital equipment malfunctions in nuclear power plants, including lockups resulting from software memory leaks, feedwater control malfunctions due to excessive traffic on Ethernet networks, software logic errors, and other problems leading to plant trips. Additionally, the limited amount of demonstrated research and a lack of industry consensus on quantitative software reliability methodologies has hindered the widespread adoption of digital I&C in the nuclear industry. In a recent Regulatory Issue Summary (RIS), the U.S. Nuclear Regulatory Commission (NRC) identified concerns about the impact of greater use of instrumentation and control (I&C) equipment with an embedded digital device (EDD) [1]. Specifically, the NRC staff states that increased use of such devices “may increase a facility’s vulnerability to a CCF” (i.e., common-cause failure). The prevailing NRC guidance regarding software CCF (SCCF) identifies two design attributes that are acceptable for eliminating CCF concerns: (1) diversity or (2) testability (specifically, 100% testability). Either solution can result in high costs and remaining licensing uncertainty (i.e., how much diversity is enough? how to ensure test coverage of every possible sequence of device states?). Consequently, many utilities and reactor designers have limited or avoided more extensive use of digital technology to minimize licensing, scheduling, and financial risk. Without development of cost effective qualification methods to satisfy regulatory requirements and address the potential for CCF vulnerability associated with EDDs, the nuclear power industry may not be able to realize the benefits of digital technology achieved by other industries. In order to address these challenges, the U.S. Department of Energy (DOE) is sponsoring this research to assess the prospect of CCF in digital I&C equipment. The purpose of the current research is to develop an effective approach employing science-based methods to resolve concerns about CCF vulnerability that serve to inhibit deployment of advanced instrumentation (e.g., sensors, actuators, microcontrollers) with EDDs in nuclear power applications. The research objectives address the challenge of establishing high levels of safety and reliability assurance needed for the qualification of EDDs (e.g., microprocessors, programmable logic devices) that are subject to software design faults, complex failure modes, and CCF vulnerability. Specific objectives are: (1) assess the regulatory context for treatment of CCF vulnerability a graded approach to their qualification, (3) develop and extend model-based testing methods to enable effective demonstration of whether devices are subject to CCF, which may arise from vulnerabilities introduced at any stage of the design lifecycle, (4) establish a cost-effective testing framework that incorporates automation and test scenario prioritization, and (5) demonstrate the qualification approach through selection and testing of candidate digital device(s). This report documents an assessment of the results from experimental testing of a representative instrument with an embedded digital device. The experiment serves as a proof-of-concept demonstration of a model-based testing (MBT) framework. The objective of MBT is to ensure that an EDD undergoes suitably comprehensive testing to establish that it is not subject to SCCF. The approach by which MBT accomplishes this objective is through development and application of an effective test suite that provides the appropriate coverage to detect the full range of postulated faults that may arise at the requirements, design, and code (implementation) level of the EDD software. The findings of the experiment involve the application of the MBT framework by Ohio State University (OSU) through testing of the selected demonstration instrument (i.e., the prototype smart pressure sensor developed by Virginia Commonwealth University, VCU). In addition, the experiment findings also involve application of a more conventional black-box testing approach that serves as a baseline against which the MBT methodology can be compared. The primary outcome documented in this report is the comparative analysis of the capabilities demonstrated for each method. The results of the analysis demonstrate clear benefits that arise from the MBT methodology. The comparison indicates greater effectiveness from the more comprehensive evidence available through MBT and enhanced efficiency achieved through automation within the MBT framework. The structure of the report addresses the approach and application of each test method as well as the comparative analysis of the experimental results. Chapter 2 gives a summary overview of the demonstration approach. Chapter 3 covers the baseline testing and Chapter 4 documents the model-based testing. Chapter 5 describes the findings of the comparative analysis and presents the conclusions that can be drawn about the effectiveness and efficiency of the MBT methodology.

47 OTHER INSTRUMENTATION↗

Recent Developments and Trends in Redox Flow Batteries

Stationary energy storage systems are needed to facilitate the widespread integration of intermittent renewable electricity generators, such as solar photovoltaic and wind turbines, and to improve the energy efficiency of the electrical grid. While no single technology can meet all needs, redox flow batteries (RFBs) have shown a favorable balance of cost, safety, and performance for many high-value applications. RFBs are rechargeable electrochemical devices that utilize the reversible redox reactions of two soluble electroactive species for energy storage. A compelling feature of the RFB configuration is the independent scaling of power and energy which enables cost-effective implementation of electrochemical couples with low energy density. Aqueous RFBs have been the subject of the vast majority of research efforts to date, which have yielded industry-level demonstrations. By comparison, non-aqueous RFBs are still in their infancy but have the potential for high energy density due to the extended stability window of non-aqueous electrolytes and the enriched selection of redox materials due to the broad variety of organic solvents. This chapter aims to introduce emerging, potentially transformative, strategies for enhancing RFB technologies through molecular design, electrolyte development, and cell-level engineering. Detailed discussions focus on recent developments in redox active materials (inorganic – aqueous, organic – aqueous, inorganic – non-aqueous, and organic – non-aqueous) and in system design (interdigitated flow fields, semi-solid flow cells, and hybrid flow cells). Future research directions and key challenges for RFB technologies are also highlighted.

Su, Liang↗

Energy and Power Evolution Over the Lifetime of a Battery

Li-ion batteries currently are dominant energy storage devices for electric vehicles. Rechargeable batteries with lower cost, longer lifetime, and higher safety are desired in support of building of a green grid infrastructure. The continued investment in new battery materials, novel battery structures, advanced manufacturing processes, and accelerated testing/validation of battery performance has led to significant progress in battery development and deployment. Battery safety/reliability, which is essential to the success of a battery technology in the real world, naturally becomes the next big topic in battery research. Recently, the increasing interest in long-duration storage, fast charging, battery secondary use, and material recycling to build a circular industry and sustainable material supply chain has compelled further attention to understand the energy/power evolution and safety over the lifetime of a battery. Here, in this short Viewpoint, we discuss some high-level analyses on the energy/power evolution of rechargeable batteries over their life cycles aiming to inspire more discussion on the safety and sustainability of some representative and emerging battery technologies.

25 ENERGY STORAGE↗